[HN Gopher] Scientists discover oldest poison, on 60k-year-old a...
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       Scientists discover oldest poison, on 60k-year-old arrows
        
       https://archive.ph/qGfbk
        
       Author : noleary
       Score  : 77 points
       Date   : 2026-01-08 23:24 UTC (23 hours ago)
        
 (HTM) web link (www.nytimes.com)
 (TXT) w3m dump (www.nytimes.com)
        
       | gilleain wrote:
       | The poisions?
       | 
       | Buphanidrine :
       | https://pubchem.ncbi.nlm.nih.gov/compound/Buphanidrine
       | 
       | and
       | 
       | Epibuphanisine
       | https://pubchem.ncbi.nlm.nih.gov/substance/349793761
       | 
       | which are nearly identical compounds (it seems) except for one
       | having an additional -OMe (Methylether) group. Looks like they
       | are https://en.wikipedia.org/wiki/Crinine (s)
       | 
       | From the https://en.wikipedia.org/wiki/Boophone_disticha plant.
        
         | CGMthrowaway wrote:
         | > having an effect akin to that of scopolamine
         | 
         | The motion sickness patch? Gives "just shoot me" a new meaning
         | in 6,000 BC
        
           | ChrisMarshallNY wrote:
           | _> 6,000 BC_
           | 
           | 58,000 BC
        
       | adolph wrote:
       | For context, this is towards the end of prehistoric human time
       | period Middle Paleolithic [0] and in the middle of geological
       | time period Late Pleistocene [1].
       | 
       | 0. https://en.wikipedia.org/wiki/Middle_Paleolithic
       | 
       | 1. https://en.wikipedia.org/wiki/Late_Pleistocene
        
       | WillAdams wrote:
       | How was it determined that these are arrowheads, as opposed to
       | atlatl darts?
       | 
       | The oldest known/discovered/documented bows only go back to
       | ~7,000 BC (Holmegaard bows from Northern Europe).
        
         | chrneu wrote:
         | Can't directly answer your questions, but generally each
         | region/time period has their own style of arrowheads, so my
         | assumption here would be that this region tends to create
         | arrowheads in this style. The paper mentions this is a pretty
         | old site/artifacts, so I'd wager they found other "arrowheads".
         | 
         | Arrowhead might also be being used generically here to mean
         | sharpened stone tip on a projectile or thrown weapon.
         | 
         | I'm no expert in this area, but it may just be that we aren't
         | sure if these are arrowheads or just sharpened stones that were
         | put on something. Someone correct me if I'm being ignorant. The
         | article really makes it seem like a lot is unknown here, since
         | we're dealing with 60,000 years.
        
           | Twiin wrote:
           | There are a number of ways they're able to tell the
           | difference between arrowheads and sharpened stones put on a
           | stick, including high-resolution CT to look at the stress
           | microcracks of the arrowhead. Bow-fired arrows and thrown
           | spearheads have different launch stress profiles as well as
           | impact profiles. There are a lot of overlapping types of
           | analysis that happen to establish what technology did or did
           | not exist in a given area at a given time.
        
       | icyfox wrote:
       | At the risk of being overly pedantic, topologists would typically
       | classify this as venom.
       | 
       | Venom is inert if digested; it's only a problem if it gets in
       | your blood stream. So arrows that were laced with venom and
       | thereby contaminated meat were actually perfectly safe to eat.
       | 
       | Poison is different. If ingested, inhaled, or absorbed it will
       | kill you.
        
         | VanshPatel99 wrote:
         | TIL. I always thought that "If it bite you -> you die = venom"
         | and "If you eat, bite, touch -> you die = poison". But your
         | differentiation makes more sense
        
         | hyrix wrote:
         | These chemicals are derived from plants where even pedants
         | would classify them as poisons.
         | 
         | The genus name Boophone is from the Greek bous = ox, and
         | phontes= killer of, a clear warning that eating the plant can
         | be fatal to livestock.
        
           | icyfox wrote:
           | Fair point about the source, but the classification usually
           | follows the mode of delivery, not the organism of origin.
           | 
           | Many plant-derived compounds function as venoms once
           | deliberately introduced into the bloodstream (arrow coatings,
           | darts, etc.), even if they're also toxic when ingested.
           | Curare is the one example here: plant-based, lethal in blood,
           | but largely harmless if eaten.
           | 
           | So while Boophone is absolutely a poison in the ecological
           | sense, using it on arrows still fits the venom/toxin
           | distinction better than a purely ingested poison. Otherwise
           | how would people hunt with this if they would get sick the
           | second they ate the meat?
        
       | ojo-rojo wrote:
       | It's humbling to think about all the things people have gone
       | through over the past couple hundred thousand years. Somewhere
       | around 117 billion humans have ever lived...? It makes it seem
       | kind of small when we think only 50 or 100 years out when
       | thinking of what the future would be.
        
       | shevy-java wrote:
       | Man has a rather unkind history.
       | 
       | The even worse thing is that in 2026 this hasn't quite improved
       | significantly. What is the main poison used today? I guess that
       | may depend on the definition, probably particles being taken in
       | by the lung in general. But specific poison it may be antifreeze?
       | Or perhaps that is just more famous. Food poisoning probably is
       | among the highest, but it would not be deliberate usually, so it
       | should be counted in another category.
        
         | jayzalowitz wrote:
         | the main poison used today is dopamine.
        
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       (page generated 2026-01-09 23:00 UTC)