[HN Gopher] A 3K-year-old copper smelting site could be key to u...
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       A 3K-year-old copper smelting site could be key to understanding
       origins of iron
        
       Author : pseudolus
       Score  : 112 points
       Date   : 2025-09-28 17:21 UTC (4 days ago)
        
 (HTM) web link (phys.org)
 (TXT) w3m dump (phys.org)
        
       | Terr_ wrote:
       | > Sparkly hematite mineral was used as a flux by copper smelters.
       | Its distinctive appearance may have helped to attract attention
       | from ancient miners and prospectors.
       | 
       | Every once in a while I pull up some Wikipedia article with idle
       | curiosity of "If I were transported back in time, could I
       | usefully help this get invented?"
       | 
       | One result of this is a helpless appreciation for how complicated
       | it can be to even _identify_ what kind of substance is present
       | without a staggeringly complex dependency-tree of identifying
       | other chemicals, assaying tests, and the economic surplus to use
       | reagents for analysis.
       | 
       | Things could have been very different if iron ore was hard to
       | distinguish.
        
         | jandrewrogers wrote:
         | Absolutely. As luck would have it, many epithermal mineral
         | deposits have both sparkly hematite _and_ copper ore in the
         | same structure. This is a well-known motif in mineral
         | exploration. They show up in the same geography but are
         | separated into different layers. You can find many papers on
         | the structure of these ore bodies. These are known as supergene
         | deposits[0].
         | 
         | The most important features of these deposits is that they act
         | like distillation columns for metals. Due to weathering and
         | associated sulfuric acid, different metals separate out at
         | different layers of the geology. This creates valuable
         | concentrations for mining purposes.
         | 
         | In modern mining, we kind of ignore these structures for iron
         | mining purposes even though they are frequently > 50% iron by
         | mass. If you find such a thing, you are more interested in the
         | gold, silver, copper potential that is capped by an iron-rich
         | gossan mineral. Iron is a cost sensitive commodity, you need to
         | be able to mine it at very high concentrations and scales to be
         | profitable. If that mineral has a pile of gold, silver, etc
         | distilled underneath it, you'll be more interested in that.
         | 
         | Not all copper comes from these mineral formations but a lot
         | is. Often, the hematite is mixed in with the copper mineral. I
         | have a mineral exploration prospect right now which is
         | essentially this. Amazing hematite crystals mixed with copper
         | with strong assay signs of gold underneath. It is a predictable
         | motif in mineral exploration.
         | 
         | [0] https://en.wikipedia.org/wiki/Supergene_(geology)
        
           | throwup238 wrote:
           | _> Amazing hematite crystals mixed with copper with strong
           | assay signs of gold underneath._
           | 
           | Any chance we HN rockhounds could get some specimens? 8-)
        
           | pjc50 wrote:
           | This is similar to the "rare earth tailings" phenomenon,
           | isn't it. A mine is built to extract one metal, the most
           | profitable at that time, and everything else unextracted ends
           | up in mine tailings or refinery slag. But, in addition to
           | truly worthless silicates, that "waste" includes a bunch of
           | other metals at low purity which may eventually be economic
           | to extract.
        
             | IAmBroom wrote:
             | Leadville Colorado was the site of a very minor gold rush,
             | that mostly produced large piles of lead tailings.
             | 
             | Until someone noticed the lead tailings were not lead, but
             | oxidized silver.
        
           | lightedman wrote:
           | "Amazing hematite crystals mixed with copper with strong
           | assay signs of gold underneath."
           | 
           | Did you actually assay out anomalous gold concentrations or
           | are you seeing the sulfides and oxides that are associated
           | with gold? If the former, what sort of concentration are you
           | getting?
        
             | jandrewrogers wrote:
             | I have only assayed samples from the iron cap. You would
             | not expect to find much in that part of the formation but
             | it still came in at 1-2g/ton. There is a large area of
             | visually striking bornite[0] that I have not yet been able
             | to properly sample which is roughly the area you would
             | expect the gold to concentrate. It is in the walls of a
             | narrow, deep canyon at high elevation. The region was mined
             | for gold/copper a century ago, so the existence is not
             | surprising.
             | 
             | The location makes access extremely challenging. It
             | requires 3 hours of hiking, assuming you are fit, and
             | borderline technical mountaineering once you get close to
             | the site. The lower parts of the canyon are also under tens
             | of meters of ice most of the year, which creates a separate
             | set of safety issues. When these mountains were prospected
             | in the 1920s, it would have been underneath a deep
             | permanent snow field. I've visited some of the old gold
             | mines in the area for calibration and this deposit appears
             | substantially larger than those.
             | 
             | The discovery was accidental. I was looking for a waterfall
             | I had seen on satellite imagery in the backcountry and came
             | across an enormous chunk of molybdenite[1] while climbing
             | across granite scree. I made several trips to find the
             | source of the molybdenite higher up the mountains, which I
             | never did, but while searching for that I localized a bunch
             | of other beautiful sulfide/oxide mineral specimens to the
             | above canyon. It gives me a great excuse to explore parts
             | of the mountains no one has been into before.
             | 
             | [0] https://en.wikipedia.org/wiki/Bornite
             | 
             | [1] https://en.wikipedia.org/wiki/Molybdenite
        
         | scoopr wrote:
         | > Every once in a while I pull up some Wikipedia article with
         | idle curiosity of "If I were transported back in time, could I
         | usefully help this get invented?"
         | 
         | This reminds me of the book "How to invent everything" by Ryan
         | North, to kind of see the fast-path for many inventions :)
        
         | GreenWatermelon wrote:
         | One of the axioms I go by is that people were never stupid. Our
         | ancestors 5000 and 10000 years ago were just as smart ,
         | intelligent and curios as we are today.
         | 
         | With regards to metals, I have no doubt someone, be it a kid
         | apprentice or a master smelter, experimented with melting
         | different rocks to see what comes out. After all, if you
         | already know that different rocks spew out different metals
         | (copper, tin, etc..) it logically follows that there may be
         | more.
         | 
         | And then someone, be it the same person or a different person
         | entirely, would've surely conducted experiments. After all, you
         | already have Tin, Copper, and Bronze which combines both of
         | them; all with different properties. Of course someone will
         | want to know how this new shiny metal the smelter spewed out
         | fares compared with other existing ones.
         | 
         | Then some smith will want to try making something with that
         | metal, new things are exciting. Many people here are familiar
         | with the desire to try out a new Programming language or
         | framework just for the sake of it, and a Bronze age smith is no
         | different. Then someone will give that mee Iron sword/knife/axe
         | a try , duel a friend, ruin their bronze weapon, and said
         | friend will be like "holy shit I want an iron sword too it's
         | way too good" and bam you got a meme.
        
           | bombcar wrote:
           | "That old Copper++ is worthless, you need to try this _Rust_
           | "
        
           | card_zero wrote:
           | Ideas improve over time. So people in the past have worse
           | ideas. This might include fear of change, and some
           | mythological notion of an eternal golden way of life, which
           | you must dutifully maintain by spending a thousand years not
           | inventing pottery, and if anybody dares to try it, beating
           | them up.
        
             | pixl97 wrote:
             | The improvement of ideas over time is a rather complex
             | process.
             | 
             | It's multiple things working together. Typically you have
             | to have an excess of calories which leads to free time in
             | at least part of the population. While the 'fear of change'
             | as gods fault is more of a post ad hoc rationalization of
             | the horizon problem. That is any change in behaviors in the
             | good times could lead to death in the hard times. Moving
             | away from what works has risks.
        
           | Sharlin wrote:
           | > Then someone will give that mee Iron sword/knife/axe a try
           | , duel a friend, ruin their bronze weapon, and said friend
           | will be like "holy shit I want an iron sword too it's way too
           | good" and bam you got a meme.
           | 
           | Iron is not a superior material to bronze, if anything it's
           | inferior. Iron's either soft or brittle, depending on carbon
           | content, neither of them awesome qualities in a tool or a
           | weapon. Also, iron's considerably more difficult to smelt,
           | and fully melting iron was not possible at the temperatures
           | achievable with Bronze Age technology. Even after you learned
           | that you need to use charcoal and very high temperatures to
           | reduce iron ore, what you got was a spongy mass of very
           | impure iron at the bottom of your furnace that you then had
           | to refine further.
           | 
           | The biggest thing that iron had going for it was _logistics_.
           | Where there was copper, there was no tin, and vice versa.
           | Sourcing tin required trade routes thousands of kilometers
           | long - no doubt the demand for tin was a large boon to long-
           | distance trade across Europe and Asia, but it made bronze an
           | expensive commodity.
           | 
           | It required new furnace technologies and a millennium worth
           | of experimentation to perfect the art of controlling the
           | carbon content (and what we now know is the crystal
           | structure) of iron-carbon alloys precisely enough to make
           | _steel_ , and in particular steel blades that combine a hard
           | (martensitic) edge and a flexible (austenitic) spine.
           | 
           | (For the record, Dwarf Fortress (unsurprisingly) is one of
           | the few games that get this mostly right.)
        
             | mrob wrote:
             | One big advantage of iron is that you can forge it. Bronze
             | has to be cast or cold worked (with annealing steps as
             | necessary). You can't forge weld bronze either, so you need
             | to braze/solder parts together. A skilled blacksmith can
             | forge things from iron quickly and with little waste. It's
             | especially important for things like nails and arrowheads
             | that are needed in mass quantities.
        
               | Sharlin wrote:
               | Good point!
        
             | themotherhucker wrote:
             | Very minor semantic nitpick as a metallurgist, martensitic
             | and austenitic are not terms that distinguish the ductility
             | of the metal, they are ways the atoms organize into crystal
             | structures (which do have an effect on hardness/ductility).
             | 
             | Austenite is one of the high temperature crystal structures
             | of iron, and is not usually seen at room temperature except
             | in certain non-heat-treatable stainless steels, and in
             | highly alloyed steels some small amounts of retained
             | austenite remains that doesn't get the chance to transform
             | due to low cooling rates and suppressed M_f temperatures.
             | Martensite forms by rapidly cooling austenite without
             | giving the atoms the ability to re-organize into their
             | preferred structure (ferrite, pearlite, or cementite
             | depending on the carbon concentration). This transformation
             | actually changes the size of the crystal matrix, which
             | locks in a ton of internal stress as atoms want to move
             | around but can't. All of this internal stress must then be
             | overcome by an external stress to move the atoms around,
             | resulting in a much harder material.
             | 
             | Martensite requires extremely fast cooling rates (on the
             | order of 100s of degrees/second), which is why most carbon
             | steels are quenched to harden them. These cooling rates are
             | only able to be achieved a little ways into the bulk of the
             | material, so you usually end up with a hardened case made
             | of martensite, and a softer more ductile core that is
             | usually pearlite (layers of ferrite [pure iron] and
             | cementite [iron carbide]) that form due to the slower
             | cooling in the core. This is usually actually more
             | desirable than an entirely through hardened piece, as the
             | hard surface can resist wear and indentation, while the
             | soft core increases the ductility and toughness which
             | reduces the risk of fracture.
        
               | Sharlin wrote:
               | Thanks, I was a bit confused by the different allotropes.
               | Interesting that the martensite transform naturally only
               | happens on the surface (which as you say is actually
               | desirable) due to the rapid cooling it requires, I didn't
               | know that. But of course it makes sense that quenching
               | doesn't instantly cool the bulk of the workpiece.
        
             | peterfirefly wrote:
             | > Where there was copper, there was no tin, and vice versa.
             | 
             | There were some exceptions on the British Isles. Even some
             | mines that had both.
        
           | peterfirefly wrote:
           | > Our ancestors 5000 and 10000 years ago were just as smart ,
           | intelligent and curios as we are today.
           | 
           | That sounds nice but axiomatic egalitarianism might, just
           | might, not be empirically true.
           | 
           | We know that there are vast differences in all modern uniform
           | populations we have tested -- intelligence is normally
           | distributed and the differences between the tails are huge.
           | 
           | We also know that different populations have different
           | distributions -- slightly different standard deviations,
           | sometimes vastly different means.
           | 
           | Why wouldn't that also have been true at the dawn of history
           | and in pre-history?
           | 
           | Since we do now know many alleles that influence intelligence
           | and we roughly know their effect sizes (very small for almost
           | all of them) and since we can actually sequence really old
           | DNA in some cases, we can actually come up with reasonable
           | guesses for how intelligent people were thousands of years
           | ago.
           | 
           | And what do you know? They _do_ differ. Or at least, their
           | allele frequencies do for those alleles that we are pretty
           | sure have an influence on intelligence. Some of them really
           | do seem to have been pretty dim. Others not so dim.
           | 
           | PS: It's difficult to make an iron sword/knife/axe that is
           | better than a bronze one.
        
           | Terr_ wrote:
           | > One of the axioms I go by is that people were never stupid.
           | 
           | Or in some cases, "poor, not stupid" [0], where even geniuses
           | had no power or resources to pursue great innovations
           | compared to the immediate priority of Not Starving.
           | 
           | [0] https://acoup.blog/2020/07/24/collections-bread-how-did-
           | they...
        
         | cultofmetatron wrote:
         | pretty much why gold was probably the earliest worked metals.
         | easy to identify, can be cold worked in a lot of cases. doesn't
         | corrode.
        
       | akssri wrote:
       | Note: there have been actual Iron-working sites discovered in
       | India that are older than this, dated to 1600 BC [0]. A lot of
       | this has been ignored (just like the Painted-Grey ware continuity
       | from IVC), partly I imagine, because it calls into question a lot
       | of the racial non-sense that passes for "Indology".
       | 
       | [0]https://www.jstage.jst.go.jp/article/isijinternational/54/5/..
       | .
       | 
       | [1]https://www.lkouniv.ac.in/site/writereaddata/siteContent/202..
       | .
       | 
       | Edit: Apparently Tamil Nadu state in South India has claimed to
       | have found a site from 3500 BC (not yet peer-reviewed AFAICT),
       | 
       | https://www.bbc.com/news/articles/c62e36jm4jro
        
         | contrarian1234 wrote:
         | nowhere in the article do they claim its the oldest iron...
         | 
         | they just had a theory that copper processing lead to
         | discoveries in iron processing.
         | 
         | the evidence they found seems to support that.
         | 
         | theyre not claiming this particular site is where the iron age
         | started. and it has nothing to do with what some people in
         | india did. Maybe they too discovered iron processing through a
         | similar process. and i dont understand what racial things your
         | bringing up..
        
           | akssri wrote:
           | This discovery is only of interest because the Iron-Age, as
           | per standard-theory, started around 1200 BC. in the
           | Caucuses/Anatolia or the near-East - which fits with another
           | theory which claims that this allowed the "Aryans" to invade
           | India with their technological superiority around this same
           | time and replace the (dark-skinned) natives genetically.
           | 
           | (Note: the above is obviously a caricature, but current
           | versions of theory don't change the structure, only the
           | emphasis on "race").
           | 
           | No one would care about a copper-smelt site from 500 BC.; nor
           | would they care about this one if the Indian archaeological
           | claims were accepted (but that one also destroys centuries of
           | Western history-making about India, and all the social-
           | theories that depend on it).
           | 
           | This is all a digression from the main claims, so I'd prefer
           | that people don't pull on this thread. For more information
           | on how 'race' was ingested into Indology, I'd refer the
           | interested reader to the excellent book by Adluri/Bagchi [0].
           | 
           | [0] https://academic.oup.com/ahr/article-
           | abstract/120/3/1132/197...
        
             | card_zero wrote:
             | > This is all a digression from the main claims, so I'd
             | prefer that people don't pull on this thread
             | 
             | You want to say your piece and get no back-chat?
             | 
             | Romans started to hit people with iron swords at a certain
             | date, influencing the history of Europe substantially, so
             | the origin of _that_ iron age is interesting. Elsewhere, a
             | copper smelting site of 500 BC would be interesting:
             | consider the Moche, in Peru, who independently had a sort
             | of bronze age around that time while Europe was into iron.
             | (I don 't think they did anything much with their bronze
             | because they were too preoccupied with body fluids and
             | erotic pottery.)
        
               | WhereIsTheTruth wrote:
               | Ancient Egypt began to use iron objects centuries before
               | most of Europe, the metal was still rare and prized
               | 
               | Tutankhamun's dagger, for example, was crafted from iron
               | and was probably a diplomatic gift from Mitanni (modern
               | day Syria/Turkey)
               | 
               | Way before your Roman Empire
        
               | card_zero wrote:
               | Extremely rare meteoric iron, yes. So, not a historically
               | significant iron age. Neat and all, but not a big
               | cultural upheaval, making one dagger.
        
               | fennecfoxy wrote:
               | >Way before your Roman Empire
               | 
               | Lmao the one-sided cucumber measuring going on in this
               | whole comment chain.
               | 
               | Like one whole side is interested in talking about the
               | origins of certain _types_ of metalworking and the other
               | is more interested in chest-beating about the
               | technicalities of who did it first.
        
               | noduerme wrote:
               | Just out of curiosity, what was their deal with their
               | precious bodily fluids? Some Dr Strangelove type
               | paranoia? Or just a usual Friday at a swingers club?
        
               | card_zero wrote:
               | It was all about the irrigation, apparently. It's vital
               | to keep life-giving fluids in your irrigation canal, and
               | by extension also in your body, otherwise you're a loser.
               | Something along those lines.
        
           | lukan wrote:
           | "they just had a theory that copper processing lead to
           | discoveries in iron processing."
           | 
           | Is there any theory how it could have been any different?
           | 
           | It sounds obvious, that advances in metal working comes from
           | those working with metals and not from carpet makers.
        
             | card_zero wrote:
             | They found ancient inhabitants of Georgia using iron ore as
             | flux for copper smelting, so it's a theory of _how_ they
             | went from one to the other. It 's not terribly exciting but
             | it beats "they tried smelting rocks at random to see if
             | anything good would happen".
        
               | GreenWatermelon wrote:
               | Smelting random rocks (with fairly distinct appearances)
               | sounds like a very logical thing to do. I would say it's
               | a natural human impulse to experiment with random stuff
               | and see what happens, that's curiosity.
               | 
               | What sound highly improbable is someone having access to
               | this obviously different ore (used as a flux) but never
               | thinking of smelting it.
        
             | contrarian1234 wrote:
             | i have zero background in this topic.. but if i were to
             | guess there are >100x more ceramic kilns than there are
             | bronze smelters
             | 
             | if some people chucked random ores into ceramic kilns,
             | maybe one would get out some iron slag and then iterate
             | from there
             | 
             | theres a great blog series about making iron.
             | 
             | https://acoup.blog/2020/09/18/collections-iron-how-did-
             | they-...
             | 
             | its easy on paper, but when you get into the details its
             | actually tricky
        
               | dboreham wrote:
               | Having been a kid living in a place that had open fires
               | burning (new houses were under construction and the
               | builders often made fires to get rid of scrap materials),
               | I can say that the desire in the primitive mind to throw
               | random things into a roaring fire to see what happens, is
               | strong.
        
       | teleforce wrote:
       | Fun fact, in the Quran prophet David (Dawwud) was granted a
       | miracle that he can shape and mould iron easily, perhaps for
       | building weaponary and armor.
       | 
       | Another fun fact, there's a surah or chapter name iron (Al-
       | Hadiid) in the Quran [2].
       | 
       | [1] Quran 34:10:
       | 
       | https://quran.com/saba/10
       | 
       | Indeed, We granted David a (great) privilege from Us,
       | (commanding:) "O mountains! Echo his hymns! And the birds as
       | well." We made iron mouldable for him.
       | 
       | [2] Surah Al-Hadiid (Quran 57):
       | 
       | https://quran.com/al-hadid
        
         | rajamaka wrote:
         | Not sure I see the relevance
        
           | peterfirefly wrote:
           | "We waz smiths", I think.
        
       | jmpeax wrote:
       | The tech tree of future games will have us smelt copper to unlock
       | iron.
        
         | bheadmaster wrote:
         | RuneScape has it right the first time.
        
         | atwrk wrote:
         | Already implemented in the Civilization series since the very
         | first one, "Sid Meier's Civilization" from 1991 :)
        
       | _joel wrote:
       | Watched a good video on "The Old Copper Culture", apparently they
       | were using and working copper 9000 years ago, due to massive
       | natural deposits of pure copper, something I never knew.
       | (interesting geological reasons too) - worth a watch
       | https://www.youtube.com/watch?v=lf7cKSFCeag
        
       | INTPenis wrote:
       | It's kinda romantic to think that innovation in those days likely
       | came from the industrial sites. Maybe it was perfected later by
       | an aristocrat, but it was more likely to be discovered by the
       | ones who had ready access to smelters and were already using them
       | all day every day.
        
         | XorNot wrote:
         | Also the economic situation it implies: industrial sites with
         | specialists who were heavily engaged in one type of industry,
         | such that they had the chance to notice and develop these sorts
         | of innovations and discoveries.
        
           | noduerme wrote:
           | Go into any restaurant kitchen. You can see in realtime how -
           | half by pure superstition - humans can adopt totally
           | unexplained, unscientific, but highly refined procedures and
           | ingredients that enhance some particular effect in the thing
           | they're working on. It just takes an archaeologist to find
           | the science behind the cooking.
        
       | OJFord wrote:
       | Can anyone recommend a book (I'm imagining sort of 'coffee table'
       | style picture book, but not necessarily) on technological
       | advancements through human history, ideally roughly
       | chronologically but more organised around what needed to happen
       | before the next was possible?
        
         | arethuza wrote:
         | Well, there is "The Book - The Ultimate Guide to Rebuilding
         | Civilization" - I don't have a copy but it certainly looks
         | interesting:
         | 
         | https://howtorebuildcivilization.com/en-gb
        
         | massenpunkt wrote:
         | I started reading Josephine Quinn's book "How the world made
         | the west" and I can recommend it. It goes quite into detail and
         | is not of the sort "coffee-table"-style picture book. It
         | explains the origins of technologies, trade between groups and
         | challenges the common view how civilizations evolved.
        
           | fennecfoxy wrote:
           | Based on the title it sounds like the intentions of the
           | author were more politically motivated than anything else.
        
             | peterfirefly wrote:
             | Based on reading the Guardian review (that predictably
             | praises it and seems to be written by someone who doesn't
             | know much history) and a much better review on a website
             | run, weirdly enough, by Christians (written by someone who
             | does know history), I would agree.
             | 
             | The first half of the quality review praises the good parts
             | of the book, the second half is where the meat is.
             | 
             | It is probably a useful book if you don't know much about
             | the classical world but it doesn't seem like one should
             | take one's politics from it.
             | 
             | Quality review:
             | 
             | https://www.thegospelcoalition.org/reviews/how-world-made-
             | we...
             | 
             | Low quality review:
             | 
             | https://www.theguardian.com/books/2024/feb/28/how-the-
             | world-...
        
             | kristianp wrote:
             | The author is a professor of ancient history at Oxford
             | University. What makes you think it is political? A book
             | can specialise in Western history without having a hidden
             | agenda.
        
         | frostburg wrote:
         | A history of technology, edited by Singer, several volumes and
         | many authors. It's old historiographically (from the Fifties)
         | but very detailed and comprehensive; I have a recent Italian
         | paperback edition but you should be able to find it in English
         | easily enough. Lots of fascinating details.
         | 
         | I'll see if I can come up with something with more up to date
         | scholarship / better pictures (the work above is effectively
         | but simply illustrated).
        
         | WillAdams wrote:
         | A broad overview, and kid-friendly, there is:
         | https://www.goodreads.com/book/show/6314442-robert-crowther-...
         | which is just what it says on the cover --- a tour through a
         | house showing when things were invented.
         | 
         | A lot more focused there is:
         | https://goodreads.com/book/show/35068671-the-perfectionists
         | (but it's a rather dry text and quite periodic and focused on
         | specific technologies)
         | 
         | Perhaps:
         | 
         | https://www.goodreads.com/book/show/48815394-1-000-invention...
         | 
         | There's a site which has come up here a couple of times along
         | these lines which I'm not finding, but Britannica has:
         | 
         | https://www.britannica.com/story/history-of-technology-timel...
        
         | whycome wrote:
         | James Burke should write the book to accompany his
         | "Connections" tv show.
        
           | dredmorbius wrote:
           | He did:
           | 
           | <https://openlibrary.org/search?isbn=9780333248270>
        
         | dredmorbius wrote:
         | James Burke's _Connections_ (companion to his 1978 television
         | series of the same name) does this in fair part, though it
         | tracks a number of distinct (and somewhat idiosyncratic) paths
         | through time.
         | 
         | <https://openlibrary.org/search?isbn=9780333248270>
         | 
         | There's Joseph Needham's _Science and Civilisation in China_
         | though that 's not exactly a coffee-table book. It's staggering
         | in its own way, however:
         | 
         | <https://en.wikipedia.org/wiki/Science_and_Civilisation_in_Ch..
         | .>
        
       | metalman wrote:
       | poor speculation
       | 
       | there are multiple plausible pathways for the dicovery of iron
       | and other metals, the most prominent bieng through the extreamly
       | ancient discovery of porcelain, and baked pottery indipendently
       | at numerous sites world wide, and there are many types of
       | ores(rocks,dirt) and fluxes, such as sand,or salt...the list is
       | impossibly long. It is always good to keep in mind that basic
       | technological developments predate our species,the key technology
       | is of course, fire. I have been instructed in various methods of
       | exploiting the properties of fire and natural materials to achive
       | a wide range results including smelting ore to getting durable
       | finnishes and experimentation in the hardening of copper. Many
       | people are out there right now,working with found materials and
       | producing metals and other peoducts in startlingly large
       | quantities useing purely ancient manual methods. Current state of
       | the art metalurgical operations are optimised in ways that go way
       | beyond anything imaginable to the casual observer and exploit
       | exotic phenomina that is counterintuitive and invisible to the
       | naked eye.
        
       | cpursley wrote:
       | This is an interesting book on the general area:
       | 
       | https://www.goodreads.com/book/show/1831667.The_Horse_the_Wh...
        
       | ReptileMan wrote:
       | Can anyone explain iron - unless it is steel (which was not a
       | common knowledge trough history) it is worse than bronze in every
       | aspect. So what lead to the iron age?
        
         | noduerme wrote:
         | Anemia? Also, the earth made way more sense when it was flat.
        
         | chrisco255 wrote:
         | Tin was hard to come by in those days and necessary for bronze.
         | Late bronze age led to civilizational collapse and trade
         | networks that distributed tin broke down. Iron was more
         | abundant and could be more useful by itself than copper alone.
         | May have been used for farm implements at first.
        
           | arnsholt wrote:
           | To expand on "tin was hard to come by", I believe two major
           | sources of tin have been identified for bronze used in the
           | Fertile Crescent: one in Cornwall, and one in Afghanistan.
           | They had to travel _really far_ abroad to make this stuff.
        
         | bluGill wrote:
         | The early processes for smelting iron resulted in a little
         | steel which would be easy to collect and save for one big work.
         | Over thousands of years you learn more and more of how to
         | 'encourage this'
        
         | aidenn0 wrote:
         | 1. Once you know how to make a hot enough furnace, iron is
         | cheaper to make than bronze. Instead of finding copper and tin
         | ore separately, you just need red rocks and a whole lot of
         | trees. Quantity can trump quality.
         | 
         | 2. There was steel in use already prior to 1000BC. High Carbon
         | steel was being produced in both Europe and Asia by 400 BC.
         | When people say "the iron age" it includes the usage of steel
         | (which is mostly iron).
        
           | tstrimple wrote:
           | And there are drastically more red rocks than green ones
           | available. Iron makes up something like 5% of the earth's
           | crust. Copper is around 0.006%. On parts of the earth you
           | could just pick up chunks of iron from bogs. It was literally
           | just lying around.
        
         | peterfirefly wrote:
         | Transportation costs used to be huge.
        
       | vanderZwan wrote:
       | > _These discoveries give weight to a long-discussed theory that
       | iron was invented by copper smelters._
       | 
       | Not to be flippant but who else could reasonably be expected to
       | have invented it? Or is the implication that there were
       | metalworkers at the time who weren't also copper smelters?
        
         | jonathaneunice wrote:
         | Right?
         | 
         | "Early metallurgists found to have been experimenting with the
         | properties of metals and ores, laying the foundation for future
         | advances that would prove economically and technologically
         | important" is not the biggest possible reveal.
        
           | vanderZwan wrote:
           | To be clear, I'm not dismissing the research, which seems to
           | be more about _how_ they discovered it. I can understand if
           | that was /is an open question, and these possible answers are
           | pretty interesting. I was just wondering if there were
           | competing theories here with reasons to doubt one is more
           | likely than the other.
        
             | hluska wrote:
             | Many years ago, my roommate was working on his PhD in
             | geology while my history obsession was in full bloom and we
             | talked about this a little. He made some interesting points
             | about iron versus copper supply and how its relative
             | abundance meant that some cultures would have had access to
             | iron long before access to copper.
             | 
             | The transition to iron was very slow and some places kept
             | using bronze for centuries. There's also no single point
             | (known) for where the Iron Age started. In Nigeria, for
             | example, it seems most likely that Nok people worked with
             | iron first and had no significant Copper or Bronze Age.
             | 
             | I think that the closest answer is that we don't know for
             | sure, but evidence seems to show that the path to iron
             | followed different paths in different parts of the world.
             | In some cases, the copper industry would have been heavily
             | involved. In other places, an iron industry seemed to take
             | shape before a copper industry, so the developments would
             | have been independent.
        
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