[HN Gopher] Reinventing circuit breakers with supercritical CO2
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       Reinventing circuit breakers with supercritical CO2
        
       Author : rbanffy
       Score  : 95 points
       Date   : 2025-06-15 23:01 UTC (1 days ago)
        
 (HTM) web link (spectrum.ieee.org)
 (TXT) w3m dump (spectrum.ieee.org)
        
       | gnabgib wrote:
       | The article's title doesn't seem to be accurate.
       | 
       | - It doesn't exist (there is mention of a prototype - but that's
       | not really a debut, all the images in the article are generic).
       | 
       | - The $3.9M funding ended May 18th
       | https://arpa-e.energy.gov/programs-and-initiatives/search-al...
       | and there doesn't seem to be a related paper yet (other than this
       | IEEE "maybe" from April)
       | 
       | - The project is (unfortunately) called _TESLA: Tough and
       | Ecological Supercritical Line Breaker for AC_ 2022:
       | https://www.sf6andalternativescoalition.org/wp-content/uploa...
        
         | tomhow wrote:
         | OK, we retitled it to a more modest subtitle from the article.
        
       | idiotsecant wrote:
       | At first I thought that would be wildly impractical but CO2 goes
       | supercritical at just shy of 90degF and a little over 1kpsi.
       | Those kinds of pressures are pretty well unknown in a substation,
       | but occur all the time in refineries and the like. It's basically
       | just a pressure vessel with a relatively mild heater requirement.
       | Eminently doable. I think we will probably see these deployed in
       | the next few decades. SF6 is an amazing material but really,
       | really horrible as a greenhouse gas.
        
         | PaulHoule wrote:
         | For years they had an SF6 tank in my building because somebody
         | had a wind tunnel (the first photo)
         | 
         | https://batl.mae.cornell.edu/facilities/
         | 
         | the machine is still there but they took out the SF6 tank.
        
         | sokka_h2otribe wrote:
         | Super critical c02 is a regular extraction process method for
         | certain molecules! You can find it in a number of laboratory
         | applications. Anyway, yes, doable - essentially for the reasons
         | you mention. But also literally done at the moment, for the
         | general extraction process capabilities of supercrit CO2
        
         | angus-g wrote:
         | Here's a guy playing with a supercritical CO2 pressure vessel
         | on a table (seems a little brave to be shaking something at
         | such high pressures!)
         | https://www.youtube.com/watch?v=2d7RGQMCX24
        
       | Full_Clark wrote:
       | > The work may be niche, but the impact could be high. About 1
       | percent of SF6 leaks from electrical equipment. In 2018, that
       | translated to 8,200 tonnes of SF6 emitted globally, accounting
       | for about 1 percent of the global-warming value that year.
       | 
       | This figure is for the electricity sector only, not overall
       | global emissions. Still, considering the sheer volume of CO2
       | puffing up from power stations, it's impressive that the normal
       | operation of SF6 breakers accounts for an integer percentage of
       | their GHG impact.
       | 
       | ----
       | 
       | Global emissions were 53 Gt CO2 equivalent in 2023 [0]. 38% of
       | CO2 emissions are attributed to the electricity sector in 2023.
       | [1] This figure seems to be strictly CO2, not including other
       | GHG, and I can't quickly find a sector-by-sector breakdown for
       | that year. Per IPCC reports in 2022, electricity production and
       | heating accounted for 34% of global GHG in 2019 [2], so for back-
       | of-the-envelope math, it's reasonable.
       | 
       | Per the article, the GHG impact of SF6 is 25k CO2, so 8.2k tons
       | SF6 emitted annually is 205 million tons CO2e. This is 0.39% of
       | 53 Gt CO2e (the global value), or nearly exactly 1% of the
       | electricity sector's 38% share.
       | 
       | [0] https://www.statista.com/statistics/1285502/annual-global-
       | gr... [1] https://www.statista.com/statistics/1129656/global-
       | share-of-... [2] https://www.epa.gov/ghgemissions/global-
       | greenhouse-gas-overv...
       | 
       | edit: replaced typos of C02 with correct CO2
        
         | kragen wrote:
         | Thank you for doing these calculations! 0.39% of anthropogenic
         | global warming is surprisingly large, but it doesn't sound like
         | a big impact to me. I mean, it sounds like about the same
         | greenhouse effect impact as the San Bernardino metropolitan
         | area (5 million people) or the Chongqing metropolitan area (12
         | million people).
         | 
         | Retric: I regret not having responded in time to your comments,
         | which I agree with.
        
           | Full_Clark wrote:
           | In terms of impact, it doesn't sound major, I agree. But it's
           | still work that will need to be done. As industry and
           | transport become more electrified, and electric generation
           | gets decarbonized, impacts like high-multiple GHG gases will
           | become a bigger and bigger share of CO2e still happening.
           | 
           | Atmospheric CO2 is already too high to avert terrible long-
           | term impacts of global climate change. Unless we manage to
           | make massive cost reductions for atmospheric CO2
           | sequestration, weaning entirely off of fossil fuels will not
           | be sufficient to avoid climate change impacts if we still add
           | long-lived GHG molecules to the atmosphere. (SF6 has an
           | atmospheric lifetime on the order of 1000s of years.)
           | 
           | Think of it like the tide going out in a rocky bay. As the
           | water level recedes, rock pillars that used to be too deep
           | underwater to worry about now are close enough to the surface
           | to cause you trouble. On the other side of the same coin,
           | putting in the work to clear them helps give you as big a
           | space to operate in as you had before.
        
             | kragen wrote:
             | > _Unless we manage to make massive cost reductions for
             | atmospheric CO2 sequestration,_
             | 
             | We will. The main reason atmospheric carbon capture is
             | expensive is that it requires a lot of energy, and the cost
             | of energy is falling through the floor because of cheap
             | renewables. Expensive high-efficiency chemistries for
             | carbon capture will cede to simpler, energy-hungrier
             | chemistries, the ultimate reductio ad absurdum being
             | something like soda lime. Soon enough synfuel from
             | atmospheric carbon capture will be an attractive
             | alternative to fossil fuels for transport (within 15
             | years), and then it's just a question of capturing the
             | combustion products from the fuel. We may need to start
             | adding high-multiple GHGs to the atmosphere to compensate
             | for carbon dioxide we remove to make plastic. Hopefully
             | shorter-half-life GHGs than sulfur hexafluoride, though.
             | 
             | The US has taken a very aggressive policy stance against
             | renewables and in favor of fossil fuels, but ultimately it
             | can't prevent the inevitable. If it continues to punish the
             | importation of renewable energy equipment, US subjects will
             | import cheap synfuel, or, failing that, they'll import
             | electrolytic iron, zinc, or magnesium to use as fuel, from
             | countries like Chile, China, and Dubai.
        
               | toomuchtodo wrote:
               | I am bullish on the rapid global uptake of low carbon
               | electrical generation (global solar PV deployment alone
               | is almost at 1 TW/year), but bearish on carbon
               | sequestration being viable unless sucking the CO2 out of
               | the ocean (due to energy required via atmospheric
               | capture). It's not just energy required, but how much
               | carrier (whether that's air or water) you need to process
               | per unit of CO2 removed.
               | 
               |  _Stanford Study: Renewable Energy Beats Carbon Capture
               | on Cost and Climate Impact_ -
               | https://carbonherald.com/stanford-study-renewable-energy-
               | bea... - June 11th, 2025
               | 
               |  _Energy, Health, and Climate Costs of Carbon-Capture and
               | Direct-Air-Capture versus 100%-Wind-Water-Solar Climate
               | Policies in 149 Countries_ -
               | https://pubs.acs.org/doi/10.1021/acs.est.4c10686 |
               | https://doi.org/10.1021/acs.est.4c10686
               | 
               |  _Climeworks' capture fails to cover its own emissions_ -
               | https://heimildin.is/grein/24581/ - May 15th, 2025
        
               | kragen wrote:
               | I'm skeptical of the Heimildin article, because it
               | contains obvious factual errors:
               | 
               | > _equivalent to almost four times Iceland 's electricity
               | production, which is about 20 terawatts per year._
               | 
               | You can't measure electricity production in terawatts per
               | year; you can measure things like solar panel deployment
               | speed in those units, as you correctly did. This makes me
               | wonder how many other factual errors I failed to spot in
               | the article.
               | 
               | But, yes, we should not expect atmospheric carbon capture
               | to be economically feasible yet, and when it is, we
               | should expect most companies that attempt it to fail,
               | just as most solar panel companies have failed. But
               | remember that solar energy is free when the sun is up;
               | there's no economic benefit to curtailing your electric
               | production because your batteries are full. So we should
               | expect vastly more energy-intensive approaches than
               | Climeworks' to be viable.
               | 
               | Atmospheric carbon capture isn't an alternative to
               | renewable energy. It's what you do in response to the
               | much lower energy costs resulting from renewable energy,
               | and to reverse the damage already done.
        
               | Full_Clark wrote:
               | > Expensive high-efficiency chemistries for carbon
               | capture will cede to simpler, energy-hungrier
               | chemistries, the ultimate reductio ad absurdum being
               | something like soda lime
               | 
               | I haven't looked into the topic much at all but that does
               | resonate. It reminds of the way solar farms are becoming
               | less fine-tuned (e.g., no sun-tracking tilt motors
               | anymore) as panel costs drops through the floor.
        
           | burnished wrote:
           | But large enough that if you did similar 100 times you'd
           | almost halve it!
        
         | gsf_emergency wrote:
         | Not just academic: Hitachi have already _deployed_ a different
         | gas (mix) last month
         | 
         | https://www.hitachienergy.com/news-and-events/press-releases...
        
       | Mengkudulangsat wrote:
       | Isn't SF6 very dense?
       | 
       | Why would its greenhouse warming potential matter if it's never
       | going high up into the atmosphere in the first place?
        
         | Metacelsus wrote:
         | It will mix throughout the troposphere like any other gas.
        
         | pfdietz wrote:
         | Gases in the atmosphere separate by molecular weight only at
         | very high altitude, above the "homopause". This is from 80 to
         | 120 km. Below that altitude, turbulence remixes gases faster
         | than they can separate.
        
       | robocat wrote:
       | SF6 is a significant greenhouse gas but what is troubling is that
       | "SF6 is a very stable compound in the atmosphere, with an average
       | residence time of about 3,200 years".
       | 
       | From
       | https://www.energynetworks.org/assets/images/Resource%20libr... :
       | It is estimated that SF6 currently contributes about 0.2% of the
       | global warming potential of the annual greenhouse gas emissions
       | in the UK.            SF6 in electrical equipment is contained
       | and not intentionally released during operation. Recycling of SF6
       | from electric power equipment, using commercial gas reclaimers,
       | is becoming common practice [in the UK].
       | 
       | SF6 huff and talk is fun though:
       | https://youtu.be/d-XbjFn3aqE?t=29s
       | 
       | > About 1 percent of SF6 leaks from electrical equipment. In
       | 2018, that translated to 8,200 tonnes of SF6 emitted globally,
       | accounting for about 1 percent of the global-warming value that
       | year.
       | 
       | There's something wrong with that figure. Global production was
       | about 7500 tons in 1995, and countries have been trying to use
       | less since then. 50% of production used in OEM equipment and 31%
       | by Electric Utilities (maybe recharging breakers after
       | inspections?). See:
       | https://www.epa.gov/sites/default/files/2016-02/documents/co...
        
       | tigerlily wrote:
       | Hey CO2 is still greenhouse. I guess not while it's contained and
       | in its supercritical state, but if it's released to atmosphere
       | then gas it will be.
       | 
       | Excited for the guys at Chalfont to test this out eventually,
       | another fun chance to see if something goes boom :)
        
         | Aurornis wrote:
         | > Hey CO2 is still greenhouse
         | 
         | SF6 has 25,000 times the 100-year global warming potential as
         | CO2.
         | 
         | You'd have to accidentally vent thousands of these breakers to
         | equal the same global warming potential as one SF6 breaker
         | 
         | When it comes to topics like this, reducing it to a binary is-
         | or-isn't greenhouse gas is the wrong way to look at it.
        
           | colechristensen wrote:
           | These breakers are carbon neutral because the CO2 comes
           | either straight from the atmosphere or is harvested from
           | sources that would otherwise be vented to the atmosphere.
        
           | tigerlily wrote:
           | I was responding to the badly editorialised title which read
           | "without greehouse gases". I think I am on pretty solid
           | ground here, the title misled.
           | 
           | Now the title reads "Reinventing". Is this a pejorative?
           | Engineers make firsts too. TFA's title works just fine.
        
         | excalibur wrote:
         | This. I don't doubt that the new design is a vast emissions
         | improvement. But the title clearly says without greenhouse gas,
         | and CO2 is the poster child for greenhouse gases.
        
           | tigerlily wrote:
           | The thing that baffles me is folk in this community so
           | willingly put their critical thinking skills to one side to
           | downvote your post.
        
       | numpad0 wrote:
       | SF6? The DRIE etchant gas?
        
         | b3orn wrote:
         | Yes, but for DRIE you need plasma so you ionise it.
        
         | pfdietz wrote:
         | Another fluorinated greenhouse gas used in etching is nitrogen
         | trifluoride. It's second only to SF6 in its GWP.
        
       | buildsjets wrote:
       | I'm certain that I have seen CF3I (trifluoroiodomethane) used or
       | proposed to be used as an arc quenching agent in HV breakers. It
       | also may soon be replacing Halon (CF3Br, bromotrifluoromethane)
       | for aircraft fire extinguishing.
        
       | mikewarot wrote:
       | Interesting but just not practical, especially when there is a
       | well proven system in use.
       | 
       | I get that we don't want SF6 released unnecessarily, but grid
       | components need to be reliable, and a breaker that could turn
       | into bomb if it loses temperature control seems loke a very bad
       | idea.
       | 
       | PS: I had a small amount of SF6 injected into my eyeball a few
       | years ago, and it helped save my sight.
        
       | hoseja wrote:
       | Is there a word for this? Subpar lead-free solders and
       | piezoelectrics, subpar coolants etc. Greenshittification?
        
         | morsch wrote:
         | Engineering involves trade-offs. It's easier when you don't
         | consider all of them. But it's poor workmanship.
        
       | wkat4242 wrote:
       | One of the drawbacks of SF6 is said to be the protective
       | clothing. But it sounds like CO2 at almost-liquid pressures will
       | be even more dangerous to an unprotected human.
       | 
       | Though I looked it up and the pressure isn't as high as I thought
       | at around 72 bar. Still enough to make weak parts explode though.
       | 
       | In other words, I don't think this will be the end of protective
       | gear.
        
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