[HN Gopher] Exotic new superconductors delight and confound
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       Exotic new superconductors delight and confound
        
       Author : ernesto95
       Score  : 216 points
       Date   : 2024-12-09 15:47 UTC (5 days ago)
        
 (HTM) web link (www.quantamagazine.org)
 (TXT) w3m dump (www.quantamagazine.org)
        
       | jmward01 wrote:
       | The great thing about watching advances in superconductors is
       | that any day we could discover the first true practical room temp
       | superconductor and that one day changes the world immensely. I
       | personally think we are likely to find one in the next 5-10
       | years, but that estimate is based on nothing but hope and
       | optimism on my part.
        
         | NullHypothesist wrote:
         | Better scientific understanding of the underlying process (as
         | highlighted by this article), better pattern detection (AI),
         | and better simulation capabilities (quantum computing) all
         | point to accelerating progress on this front.
         | 
         | What makes me particularly optimistic is the wide range of
         | scenarios in which superconductivity is observed (also
         | highlighted in the article); different mechanisms leading to a
         | similar result suggests much better opportunity for the
         | existence of a room-temp SC than if it were a highly similar
         | pattern.
         | 
         | Certainly such a discovery has some serendipity and luck baked
         | in, but given these advances across the board, 5-10 years seems
         | like a reasonable bet (then another decade or two to widespread
         | adoption). Let's hope we don't blow everything up before then.
        
           | fuzzfactor wrote:
           | From the final paragraph:
           | 
           | _experimentalists are still the ones leading the way.
           | "Everyone's rushing as fast as they can," Yankowitz said._
           | 
           | In my experience, the final line is what contributes to my
           | optimism most:
           | 
           | _"I can't believe that we're six years in and you can't take
           | a break."_
        
         | dtquad wrote:
         | For the most valuable applications it is also "good enough" to
         | find a superconductor that can be cooled with cheap liquid
         | nitrogen and retain the magnetic field tolerance, current-
         | carrying capacity, and thermal stability of a superconductor
         | cooled with expensive liquid helium.
         | 
         | Some so-called "high temperature" superconductors begin
         | superconducting at liquid-nitrogen temperature or higher.
         | However in real life applications like MRI and particle
         | accelerators it turned out that they still need to be cooled
         | with much colder liquid helium to get the desired magnetic
         | field tolerance, current-carrying capacity etc. Finding a high-
         | quality liquid-nitrogen-grade superconductor with these desired
         | properties would be a revolution in itself.
        
           | BariumBlue wrote:
           | I know we've got cuprates, superconductors formed with copper
           | oxide, useful up to 133Kelvin, higher than Nitrogen cooling's
           | capability of 77K.
           | 
           | I've read of them being used in wind turbines and particle
           | accelerators, as well as concepts for fusion reactors.
           | 
           | Your comment makes it sound like they have insufficient field
           | tolerance / current characteristics though. I don't think
           | I've heard about Cuprates at all recently.
        
             | throwup238 wrote:
             | Cuprates are also brittle ceramics so they're difficult to
             | shape and larger pieces and assemblies tend to run into
             | issues with grain boundaries that interfere with
             | superconductivity, so there's a lot of practical issues.
             | The classic superconductors are very low temperature but
             | are much easier to cast.
        
               | FredFS456 wrote:
               | There's a few fusion startup companies using
               | superconducting ReBCO tape to make their magnets. From
               | the results that they're getting, I think we've largely
               | cracked the engineering problems of making "wire" from
               | ReBCO and it's largely just a scaling game now. I do want
               | to point out that they're still cooling with liquid
               | hydrogen at ~20K for high current capacity though.
        
               | cyberax wrote:
               | I invested in a couple of fusion startups (because why
               | the hell not?), and the word on the street is that
               | flexible tapes/wires are still not a solved question.
               | Nobody can make them with consistent quality in large
               | enough batches.
        
           | NL807 wrote:
           | >and retain the magnetic field tolerance, current-carrying
           | capacity
           | 
           | Even if it doesn't meet those requirements, room temperature
           | superconductors will have immense value in low-power
           | applications, micro electronics, sensing, etc.
        
           | dtgriscom wrote:
           | Data point: liquid nitrogen is cheaper than milk.
        
             | jmward01 wrote:
             | How interesting..... Of course liquid nitrogen + milk (with
             | one or two other things) is worth more than the sum of its
             | parts.
        
               | nharada wrote:
               | Yeah, haven't you seen how much they charge for Dippin
               | Dots??
        
             | saagarjha wrote:
             | I mean it's literally selling air :P
        
             | nick3443 wrote:
             | How can we take advantage of this to reduce my grocery
             | bill? :)
        
           | nine_k wrote:
           | Mechanical properties are very important, too. Able to bend,
           | able to be cut, able to withstand mild shocks and vibration
           | without fracturing. Something you can make actual _wires_
           | from, at least at some stage. This, superconducting at liquid
           | nitrogen temperature, would produce a revolution.
           | Transmission lines alone would be huge.
        
             | anyfoo wrote:
             | > Transmission lines alone would be huge.
             | 
             | Or small! :D
        
               | nine_k wrote:
               | But either way freezin' cool!
        
             | popol12 wrote:
             | How would we cool transmission lines to liquid nitrogen
             | temperature?
        
               | yencabulator wrote:
               | https://www.youtube.com/watch?v=3gFUwGedayw
        
             | jmyeet wrote:
             | > Transmission lines alone would be huge.
             | 
             | Transmission lines are a great example of competing
             | demands. Copper is a better conductor so why do we use
             | aluminium? Because of weight. And weight is a huge factor
             | in supporting large cables over long distances.
             | 
             | Metals are also ductile, which is important for a cable to
             | hang in gravity under its own weight, be moved by the wind
             | and so on. Assumedly exotic crystals wouldn't have this
             | property. Even if they could, what would the weight be?
             | Would the cross-section need to be much larger? Particular
             | to this family of superconductors, tungsten isn't exactly
             | the easiest thing to do deal with, particularly on a
             | massive scale.
             | 
             | There's an interesting Reddit thread about this topic [1].
             | One issue it raises is we'd need to essentiaally rebuild
             | our entire infrastructure and transformers are a big part
             | of that.
             | 
             | Personally, I think energy is going to get an awful lot
             | more _local_. Solar is our future (IMHO). The ability to
             | store excess power generated during the day and then use it
             | when it 's dark or cloudy will obviate the need to
             | expensive long-line transmission infrasturcture from
             | distant power plants.
             | 
             | Lastly, the GP is correct: liquid nitrogen is _incredibly
             | cheap_. It 's basically the cost of drinking water. Getting
             | something we could use at liquid nitrogen cooling
             | temperatures would be incredibly impactful.
             | 
             | [1]: https://www.reddit.com/r/AskPhysics/comments/12etlkr/w
             | ouldnt...
        
               | nick3443 wrote:
               | Cheaper batteries meeting the storage requirements for
               | renewables would be a game changer!
        
               | BurningFrog wrote:
               | Maybe superconducting transmission lines need to be
               | underground
        
           | kulahan wrote:
           | >to get the desired magnetic field tolerance
           | 
           | Interesting, then, that the article actually mentions a
           | superconductor that got _stronger_ in the presence of a
           | magnet! Wild things we 're learning here!
        
           | Panzer04 wrote:
           | For the most valuable applications, sure - but a lot of the
           | biggest historical advances came not from the first
           | application of that new tech, but from that new tech becoming
           | cheap and ubiquitous.
           | 
           | Maybe (cheap) room-temp superconductors won't actually be
           | that interesting (maybe it just increases energy transmission
           | efficiency 5-10%), but perhaps it's availability catalises a
           | whole range of new applications that were never considered
           | before.
        
             | raelming wrote:
             | If room temperature superconductors existed that were
             | practical for transmission scale wires, it would be
             | possible to make a global superconducting electrical grid.
             | The middle East could fill their desert with solar panels
             | and export that electricity to Europe. The sunny side of
             | the planet could export solar power to the nighttime side
             | of the planet. You could make electrical motors out of it a
             | fraction of the size of current motors, like 1000 of
             | horsepower out of a soda can, which would revolutionize the
             | design of pretty much everything in the world with moving
             | parts. Mechanical transmissions would go the way of the
             | vacuum tube. Any vehicle or ship that's not completely
             | electrified would be hybrid electric at least. You could
             | also miniaturize transformers which has a lot more
             | implications for making everything that uses a lot of power
             | to be much more powerful and cheaper.
        
         | AlexErrant wrote:
         | I'm not a believer in that timeline. There's a large distance
         | between superconductivity in the lab and commercial application
         | (since you specified "changes the world immensely").
         | 
         | E.g. MRIs still use NiTi (critical temperature of ~10 kelvins),
         | discovered in 1962, for a number of reasons (this is in spite
         | of MgB2 having a critical T of ~39k, ReBCO with a critical T of
         | ~90k, and BSCCO with a critical T of ~108k):
         | 
         | > In this paper, we analyze conductor requirements for
         | commercial MRI magnets beyond traditional NbTi conductors,
         | while avoiding links to a particular magnet configuration or
         | design decisions. Potential conductor candidates include MgB2,
         | ReBCO and BSCCO options. The analysis shows that no MRI-ready
         | non-NbTi conductor is commercially available at the moment. For
         | some conductors, MRI specifications will be difficult to
         | achieve in principle. For others, cost is a key barrier. In
         | some cases, the prospects for developing an MRI-ready conductor
         | are more favorable, but significant developments are still
         | needed. The key needs include the development of... [omitted]
         | 
         | https://pmc.ncbi.nlm.nih.gov/articles/PMC5472374/
         | 
         | Unfortunately, it probably won't be as simple as "step 1
         | discover material, step 2 manufacture, step 3 profit".
        
           | jeffparsons wrote:
           | One exciting thing that could still happen in the shorter
           | term (if/when a promising novel "high temperature
           | superconductor" is confirmed) is an explosion of investment
           | into research in the area. So even if it takes decades for
           | Material X to end up in MRI machines, there would still be a
           | steady stream of juicy progress to read about while we wait!
        
           | FredFS456 wrote:
           | There's some fusion startups successfully making >10T magnets
           | using ReBCO tape now, so hopefully things will scale up/cost
           | down enough to be used in MRIs.
        
         | IAmNotACellist wrote:
         | Too soon. I still tear up over LK-99
        
         | tedsanders wrote:
         | I'd bet that the first room temperature superconductor does not
         | "change the world immensely."
         | 
         | Resistive losses are just one of very many attributes of a
         | conductor. Others important attributes include:
         | 
         | - current capacity (will you need humongously thick wires to
         | match charge carried by aluminum or copper?)
         | 
         | - ductility (can it be formed into wires cheaply?)
         | 
         | - cost (does CapEx outweigh electricity savings? is it
         | expensive enough that people will cut and steal it?)
         | 
         | - weight (can it hang from power poles? can it be transported
         | on the backs of trucks?)
         | 
         | - temperature sensitivity (does it crack at low temperature?
         | melt at high temperature? change electrical properties
         | depending on the weather? stop conducting on hot days?)
         | 
         | - chemical stability (will it oxidize over a 50-year
         | lifecycle?)
         | 
         | - toxicity (will kids be poisoned if they touch it / eat it?)
         | 
         | - machinability (can it be formed into tiny wires? can it be
         | patterned onto chips?)
         | 
         | - electromigration resistance (will the material break down
         | over time from carrying charge?)
         | 
         | - tensile strength (can it be hung from power poles at their
         | current spacing? would we need to rip out all power poles
         | across the planet? would we need more expensive underground
         | lines?)
         | 
         | - abundance in the Earth's crust (will the price skyrocket if
         | we suddenly need to produce an annual megaton to replace the
         | world's powerlines?)
         | 
         | - geographic concentration (are the primary deposits
         | concentrated in a single country, introducing potential supply
         | chain and geosecurity risks?)
         | 
         | - etc.
         | 
         | It's very likely that the first material which does better on
         | resistivity is going to do worse on these other dimensions.
         | Resistivity is rarely the number one criterion in selecting
         | conductors, from power lines to computer chips.
         | 
         | One of the reason incumbent technologies are difficult to
         | replace is that they win on criteria that are less salient to
         | potential innovators. Aluminum is a common metal for power
         | lines not because it has the lowest resistivity, but because
         | it's by far the best we've got when evaluating this whole
         | portfolio of needs.
        
           | SequoiaHope wrote:
           | Well lots of these limit the applications but something could
           | have these limitations and still be a commercial success in
           | some valuable niche fields.
        
           | skeaker wrote:
           | I think even if it's only usable in niche scenarios it would
           | still be a commercial success. Superconductors are useful
           | even when they're hard to use, as seen with existing cold
           | temperature superconductors which a room temperature one
           | could certainly replace and become a commercial success in
           | doing so. With that said, you're likely correct that the
           | first attempt won't catch on for mass adoption.
        
             | zardo wrote:
             | > as seen with existing cold temperature superconductors
             | which a room temperature one could certainly replace and
             | become a commercial success in doing so.
             | 
             | High temperature superconductors are only seeing commercial
             | use in the last few years (after their discovery in the
             | 80s) due to issues like poor ductility.
        
           | ethbr1 wrote:
           | Electromagnets.
        
         | EasyMark wrote:
         | Why is room temperature important, what if "the world's first
         | superconductor at 0C" was the headline?
        
           | jmward01 wrote:
           | I agree, 'room temp' isn't exactly precise. Even if it could
           | work at 'room temp' if it didn't work just above that it
           | would be too finicky for a lot of applications. Somewhere
           | around there is likely the 'magic' point for a huge number of
           | applications that will change the world. The perfect would
           | be, of course, one with a very broad range of environments it
           | could perform in. I think we are on track to figure out how
           | to make something truly sci-fi in its properties: Strong,
           | wide range of temp/conditions, flexible, etc etc. Once we get
           | the theory perfect I bet the world will really open up.
        
           | scheme271 wrote:
           | I don't think room temperature is important per se. Rather
           | it's shorthand for a superconductor that functions without
           | special cooling. Even if the temperature range is somewhat
           | limited, it's still possible to be pretty useful (e.g. deep
           | ocean temps are fairly cold and stable so a superconducting
           | cable to power repeaters on fiber optic cables might be
           | useful).
        
         | tizzy wrote:
         | Is their existence just speculation or is there mathematical /
         | empirical observations that suggest they exist we just don't
         | know about them? Is it guaranteed, or highly likely, that one
         | exists we just haven't found it?
        
         | Ygg2 wrote:
         | I don't think we'll really see a superconductor that ticks all
         | the boxes.
         | 
         | Reality is too noisy for such effects to take hold. If there
         | was I think evolution would have already used it by now.
        
           | philipkglass wrote:
           | Do you mean biological evolution? There are a vast number of
           | useful materials that terrestrial organisms cannot evolve
           | because they're incompatible with the chemical/physical
           | conditions inside living things. Organisms never evolved the
           | use of aluminum structures, for example, even though aluminum
           | has many useful properties and is more terrestrially abundant
           | than carbon.
        
         | t0lo wrote:
         | I don't think we need more change right now. We're struggling
         | to make a healthy society with meaning with the leaps in
         | technology of the past 15 years in ML and computing and
         | manufacturing power/ actual power
        
       | kurthr wrote:
       | One thing that goes unmentioned about room temperature
       | superconductors is that they store energy as well. U =
       | (B2/(2u0))V. 2u0 is about 2.5E-6N/A2
       | 
       | So a 1m3 7T magnetic field would be about 20MJ or 7KWh. That
       | doesn't sound like much, but collapse times could be microsec to
       | generate GW of EM.
        
         | xbar wrote:
         | This is a useful fact to have handy.
        
         | justlikereddit wrote:
         | Commercial MRI quenching doesn't result in explosions and
         | there's 7T research MRIs so I assume the issue with how to
         | bleed off energy is solved in a safe enough manner already
        
         | gaze wrote:
         | These novel new superconductors are generally considered to be
         | "bad superconductors." They have really low critical fields.
        
       | Animats wrote:
       | Wow. Go over to [1] and read the papers. This is good stuff. When
       | someone finds new physics, interesting things result.
       | 
       | Tungsten disulfide/boron nitride superconductors? That's a new
       | direction.
       | 
       | This article describes a new research result as a new research
       | result, not as "trillion dollar industry by 2027". That helps
       | credibility.
       | 
       | [1] https://physics.mit.edu/faculty/long-ju/
        
         | simpaticoder wrote:
         | _> This article describes a new research result as a new
         | research result, not as "trillion dollar industry by 2027"._
         | 
         | I don't like that language either, but it may be wise to
         | understand that different audiences are reading this, and it
         | may be effective for the author to reach the others in this
         | way. And besides, in general it's easier for a rationalist to
         | ignore such language than it is for an industrialist to add it.
        
           | exmadscientist wrote:
           | Bollocks. "Hype language" has a very strong correlation with
           | people who don't know what they're talking about. (Probably
           | because most people who use it do not, in fact, know what
           | they're talking about, even if some might.) So other experts
           | in the field _will_ look down on you if you speak like a
           | British university press release.
        
             | simpaticoder wrote:
             | I agree with you. I just think it is wasted effort to
             | complain about the quality of press releases. I am
             | consigned to their poor quality, and my solution is to read
             | primary sources.
        
         | nomel wrote:
         | As someone who knows nothing about this, how is something like
         | "Tungsten disulfide/boron nitride" selected? Is it based on
         | some models? Or, is it more of a random walk?
        
           | mensetmanusman wrote:
           | They are choosing from a subset of materials that can form
           | stable 2D crystals in order to test effects of relative twist
           | angles on their energy bands.
        
             | halflife wrote:
             | Are 2d crystals the depth of 1 molecule?
        
               | mensetmanusman wrote:
               | One layer of somewhat coplanar atoms.
        
           | gaze wrote:
           | They're two materials that 2D materials people commonly
           | stock. BN is thought to be a pretty innocuous insulator.
           | Might as well be the lettuce of the sandwich. However, it's
           | now showing that it has effects on the nearby layers, so
           | people are playing with it in heterobilayer devices.
           | 
           | A large part of the field of 2D materials is just trying
           | stuff.
        
         | m463 wrote:
         | otoh, "a graphene device produced a mythical form of
         | superconductivity"
         | 
         | :)
        
       | metalman wrote:
       | room temperature superconductors are inevitable, all matter is
       | conductive and photo active in some way or another,and conduction
       | is one of the non optional components of reality, so the number
       | of possible compounds that might superconduct is huge and now
       | that there apear to be multiple mechanisms that superconduction
       | can function from, means that the search will begin in earnist
       | its a multi trillion dollar app
        
         | zardo wrote:
         | Is a 400C superconductor also inevitable?
        
           | bawolff wrote:
           | Given enough pressure it already exists!
        
         | EasyMark wrote:
         | Why is it inevitable? Is there some physics principle that
         | proves they should exist even they're beyond current scientific
         | knowledge?
        
       | steveoscaro wrote:
       | Question - is this a field ripe for breakthroughs using advancing
       | AI capabilities? Or not likely because LLMs haven't ingested much
       | data that could help reason in this field (or whatever reason)?
        
       | MrLeap wrote:
       | Could this "reality search" stuff be parallelized?
       | 
       | Could reaction permutation and property testing occur in a more
       | automated fashion than is currently?
        
       | spullara wrote:
       | I wish all the smart physicists were working on this instead of
       | string theory.
        
         | poincaredisk wrote:
         | Why not both? We need people working on moonshots in hope of a
         | breakthrough that will leap us forward. Even if, in case of
         | string theory, we probably both agree that the chance is slim
         | at this point (but I'm not a physicist, so nobody asked my
         | opinion and nobody should listen to it).
        
       | BoneZone wrote:
       | I worked in Cory Deans lab when he did a brief professorship at
       | City College. He is the most sharply intelligent person I have
       | ever worked with, a savage experimentalist always devising new
       | ways to experiment in nanofabrication and his theoretical
       | curiosity is boundless. Additionally, he's a really nice Canadian
       | when he goes to the pub!
       | 
       | If you ever wonder why these products using graphene aren't
       | commercially viable, it is insanely difficult to work with and
       | prepare. Imagine trying to make a sandwich that's 5x5 microns in
       | area and about 2-3nm thick. Graphene is essentially atomic tissue
       | paper subject to all sorts of contamination and small scale
       | effects.
        
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