[HN Gopher] NASA: Mystery of Life's Handedness Deepens
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       NASA: Mystery of Life's Handedness Deepens
        
       Author : bookofjoe
       Score  : 50 points
       Date   : 2024-11-22 14:35 UTC (2 days ago)
        
 (HTM) web link (www.nasa.gov)
 (TXT) w3m dump (www.nasa.gov)
        
       | robthebrew wrote:
       | https://www.nature.com/articles/s41377-020-00367-8
        
         | __MatrixMan__ wrote:
         | That's a relevant paper, but this is the one which "deepened"
         | the mystery: https://www.nature.com/articles/s41467-024-52362-x
         | 
         | It asserts:
         | 
         | > L-proteins need not emerge from a D-RNA World
         | 
         | So if more than one amino acid chirality could have emerged,
         | why did we get the one we got and not several?
         | 
         | From the paper in the parent comment:
         | 
         | > Achiral linearly polarized light interacts with chiral
         | objects and their enantiomers differently. An interesting
         | example is a light-driven motor. Linearly polarized light can
         | rotate a gammadion-shaped gold structure embedded in a silica
         | block as a motor.
         | 
         | Imagine you were using some kind of optical tweezers to
         | manipulate chiral molecules. I wonder if there's a reason that
         | such a device would work better if you had a sample which had
         | the same chirality. Suppose so...
         | 
         | If one of your samples made its way to Earth and replicated...
         | Well that would be a reason for earth proteins to be biased in
         | one direction, despite the laws of physics not prescribing such
         | a bias.
        
           | madaxe_again wrote:
           | https://en.m.wikipedia.org/wiki/Optical_tweezers
           | 
           | I suppose there's no reason you couldn't use circularly
           | polarised light to achieve the effect you're talking about.
        
       | throwawaymaths wrote:
       | What is the mystery? Perhaps one handedness was just first by
       | chance and won because it self replicated the other handedness
       | away by consuming it as food.
        
         | griffzhowl wrote:
         | Well, that's the question isn't it? Is it just a frozen
         | accident, or is there some nonarbitrary reason for the left-
         | handed molecules to be favoured?
        
           | madaxe_again wrote:
           | Perhaps aliens eat right handed life, but left handed life is
           | poison to them.
           | 
           | Seriously. It would be a pretty good selector, and said
           | "alien" need be no more than a snippet of RNA - and it would
           | be entirely gone from earth now, eliminated by us sinister
           | life forms.
           | 
           | The only evidence would be the ubiquitous absence of
           | R-entantiomers in life.
           | 
           | I think I might be lifting from Asimov - _The Left Hand of
           | the Electron_.
        
       | andrewflnr wrote:
       | While all right-handed amino acids would presumably be fine, do
       | we have any idea whether mixed chirality would work? I suspect
       | no, since they presumably have different folding behavior but
       | might be tricky to distinguish chemically during the protein
       | synthesis process, making e.g. different codons for left and
       | right-handed amino acids infeasible to implement. I'd love to
       | hear from a biologist whether any of that is correct.
        
         | fredgrott wrote:
         | fun fact some left handed amino acids are poisonous to most
         | mammals
        
         | gilleain wrote:
         | So a couple of things i remember from back in the old
         | structural bioinformatics days...
         | 
         | Firstly, there are naturally occurring mixed-chirality
         | (alternating) peptides. They are usually circular iirc.
         | 
         | Secondly, no you can't really have larger proteins with both
         | left and right (ignoring glycine). They would not fold into
         | nice helix/sheet strucures and likely just be random coil.
         | 
         | For cells to have mixed populations of all-L and all-R proteins
         | would mean doubling up all the machinery for creating them.
         | 
         | One theory that I thought was reasonable for why there's a
         | monochiral world is that once the arbitrary choice is made (L
         | or R) then that gets 'locked in' by all the machinery around
         | that choice. As in, L 'won'.
        
       | westurner wrote:
       | From "Amplification of electromagnetic fields by a rotating body"
       | https://news.ycombinator.com/item?id=41873531 :
       | 
       | > _ScholarlyArticle: "Amplification of electromagnetic fields by
       | a rotating body" (2024)
       | https://www.nature.com/articles/s41467-024-49689-w _
       | 
       | >> _Could this be used as an engine of some kind?_
       | 
       | > _What about helical polarization?_
       | 
       | If there is locomotion due to a dynamic between handed molecules
       | and, say, helically polarized fields; is such handedness a
       | survival selector for life in deep space?
       | 
       | Are chiral molecules more likely to land on earth?
       | 
       | > _" Chiral Colloidal Molecules And Observation of The Propeller
       | Effect" https://pmc.ncbi.nlm.nih.gov/articles/PMC3856768/_
       | 
       | > _Sugar molecules are asymmetrical / handed, per 3blue1brown and
       | Steve Mould. /?
       | https://www.google.com/search?q=Sugar+molecules+are+asymmetr..._
       | _https://www.google.com/search?q=Sugar+molecules+are+asymmetr..._
       | 
       | > _Is there a way to get to get the molecular propeller effect
       | and thereby molecular locomotion, with molecules that contain
       | sugar and a rotating field or a rotating molecule within a
       | field?_
        
         | westurner wrote:
         | Though, a new and plausible terrestrial origin of life
         | hypothesis:
         | 
         | Methane + Gamma radiation => Guanine && Earth thunderstorms =>
         | Gamma Radiation
         | https://news.ycombinator.com/item?id=42131762#42157208 :
         | 
         | > _A terrestrial life origin hypothesis: gamma radiation
         | mutated methane (CH4) into Glycine (the G in ACGT) and then DNA
         | and RNA._
        
       | nativeit wrote:
       | > "We are analyzing OSIRIS-REx samples for the chirality
       | (handedness) of individual amino acids, and in the future,
       | samples from Mars will also be tested in laboratories for
       | evidence of life including ribozymes and proteins," said Dworkin.
       | 
       | I clicked the hyperlink for OSIRIS-REx samples, and it didn't
       | contain any information about what kinds of materials were found,
       | but this statement suggests amino acids were collected from
       | OSIRIS-REx--did I miss this news? Were there proteins found on an
       | asteroid?
        
         | nativeit wrote:
         | Indeed I did miss that, what an incredible find, I can't
         | believe this never broke through into my routine news feeds!
         | 
         | https://www.hou.usra.edu/meetings/lpsc2024/pdf/1219.pdf
        
           | jebarker wrote:
           | How suggestive is this of life elsewhere in the universe?
        
       | jcims wrote:
       | Only tangentially related, but because they are so amazing here
       | are a few videos that illustrate the process of transcription
       | (creating mRNA from DNA) and translation (creating a protein from
       | mRNA).
       | 
       | https://www.youtube.com/watch?v=SMtWvDbfHLo
       | 
       | https://www.youtube.com/watch?v=TfYf_rPWUdY
       | 
       | The common complaint with these videos is that everything is more
       | complex. One thing that isn't evident is that these specific
       | videos (built mostly by Drew Barry) actually model a lot of other
       | molecules to create a more realistic physical environment with
       | brownian motion and whatnot. Then the irrelevant molecules are
       | simply made transparent in the rendering.
       | 
       | Obviously it's still much much more complex (eg the constant
       | stream of ATP used to drive many of these operations is not
       | illustrated).
       | 
       | There are these and many more great illustrations/explanations at
       | WEHImovies on youtube
       | 
       | https://www.youtube.com/@WEHImovies
        
       | Mistletoe wrote:
       | https://www.smithsonianmag.com/space/must-all-molecules-life...
       | 
       | More explanation here.
       | 
       | >Oftentimes both the left- and right-handed versions of, for
       | example, an amino acid, were found in equal amounts--exactly what
       | might be expected. But in many cases, one or more organic
       | molecule was found with an excess of one hand, sometimes a very
       | large excess. In each of those cases, and in every meteorite
       | studied so far by other researchers in the field, the molecule in
       | excess was the left-handed amino acid that is found exclusively
       | in life on Earth.
        
         | polishdude20 wrote:
         | Could these asteroids be from when the moon was created?
        
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