[HN Gopher] Linear, symmetric, self-selecting 14-bit molecular m...
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       Linear, symmetric, self-selecting 14-bit molecular memristors
       (2023)
        
       Author : weirdcat
       Score  : 91 points
       Date   : 2024-09-12 08:07 UTC (14 hours ago)
        
 (HTM) web link (www.researchgate.net)
 (TXT) w3m dump (www.researchgate.net)
        
       | myrmidon wrote:
       | Takes me back... There was significant hype around those things
       | when they first managed to build them at scale (~15 years ago),
       | because they were promising for low power, high density
       | persistent storage and are also academically interesting: The
       | "concept" of memristors was explored over 50 years ago (they are
       | passive components that couple electrical charge and magnetical
       | flux, just like a resistor does with current/voltage, a capacitor
       | with voltage/charge or an inductivity with current/flux).
       | 
       | But I think the main problem was that they never managed to scale
       | up the clock speeds sufficiently, even though structure size (=>
       | density) was already highly promising from the start.
       | 
       | Maybe in a slightly different history with some discoveries in
       | different orders these could have replaced flash memory in SSDs
       | completely.
       | 
       | But that whole episode thought me that betting on early
       | technology is _hard_ , and always a risky business, because no
       | matter how promising an approach looks, if it turns out that you
       | can not find the necessary improvements in only a single
       | dimension, then the whole thing is kinda doomed and will probably
       | never be competitive (=> a highly relevant insight especially
       | when speculating about things like novel battery chemistries or
       | the like).
        
         | floating-io wrote:
         | I remember that too; I was very, very interested, but it never
         | materialized. Very disappointing.
         | 
         | That said, I think this is something a bit different, or at
         | least a different application. If my translation of the summary
         | is correct (I'm not very fluent in sciencese), it's basically
         | using them as some kind of matrix multiplier rather than
         | memory. Whether they're making use of power-off data retention
         | at all was unclear to me, but then I just skimmed it.
         | 
         | Interesting, but I was really hoping for fast, persistent
         | memory to appear.
        
         | DrBazza wrote:
         | Is that actually the case? Or have memristors just proven to be
         | a 'boring' technology that's just quietly replaced other bits
         | and pieces that we don't hear about? A bit like graphene was
         | supposed to be this wonder material, and now it's found in the
         | soles of trail and hiking boots.
        
           | myrmidon wrote:
           | > Or have memristors just proven to be a 'boring' technology
           | that's just quietly replaced other bits and pieces that we
           | don't hear about?
           | 
           | As far as I know, they have no application apart from
           | academic toy/reseearch subject right now. And you have to
           | consider that there are a lot of niches for storage
           | technology that they _could_ have taken over (because there
           | is a lot of tradeoffs to make, e.g. latency, bandwidth,
           | persistence, density, power consumption).
           | 
           | We might be just a few breakthoughs from those things
           | replacing flash memory in SSDs, or revolutionizing neural-
           | network accelerator hardware, but I am quite skeptical for
           | now.
           | 
           | Note: I still believe that this (and other stuff i'm
           | skeptical about) is SUPER worthwhile to research and always a
           | huge uphill battle, simply because we have invested hundreds
           | of billions of dollars into improvements of CMOS technology
           | and processes, and collected over half a century of
           | experience with it...
           | 
           | But new tech is to me kinda like a startup-- not every
           | technology is the future, just like not every startup is a
           | unicorn. Investing is still the right move, but you have to
           | be realistic about expectations (which modern media is
           | absolutely not)
        
             | chc4 wrote:
             | I'm under the impression Intel's 3D XPoint/Optane memory
             | was based off the same process used for memristors.
        
               | HarHarVeryFunny wrote:
               | Yes, but they were never able to get the performance to
               | the point where it could be used as regular memory as
               | opposed to storage (SSD).
        
               | mapt wrote:
               | IIRC, performance was fantastic, but they were never
               | able/willing to match the data density and data cost
               | improvements in stacked-NAND flash, and without forcing
               | themselves into the market at competitive rates, nobody
               | wanted to write applications or design hardware suited to
               | their unique strengths as low-latency caches.
               | 
               | There is still, to this day, a numerical niche for these
               | drives, which is being served imperfectly by either
               | normal TLC drives of very large size, SLC cache drives,
               | or DRAM expansion cards connecting to the CPU through a
               | PCIE bus. Just not at the prices they wanted to charge.
        
               | HarHarVeryFunny wrote:
               | But wasn't the potentially transformative market intended
               | to be "persistent DRAM" for instant-on devices removing
               | the distinction between memory and storage, requiring
               | DRAM-like speed rather than NAND-like speed ?
               | 
               | I recall their early R/W speed performance projections
               | being far faster than what they ever achieved with Optane
               | drives.
        
               | wtallis wrote:
               | The products that used a PCIe X4 interface with a block
               | storage protocol layered on top were never intended to
               | deliver the best performance the memory was capable of.
        
               | HarHarVeryFunny wrote:
               | Sure, but Intel never got to the point of packaging it as
               | memory (DIMMs) since the performance wasn't there.
        
               | wtallis wrote:
               | Yes, they did ship the DIMMs: https://www.intel.com/conte
               | nt/www/us/en/products/docs/memory...
        
               | HarHarVeryFunny wrote:
               | Interesting - I wasn't aware, but even avoiding the PCI
               | bus the performance must have been lacking as that link
               | talks of "memory tiering". I guess this was "mid tier"
               | somewhere between SSD and DRAM, which is a bit of a no-
               | mans land especially in terms of conventional systems
               | architecture ... really just a fast type of storage, or
               | storage cache (a bit like a hybrid SSD-HDD drive).
        
               | mapt wrote:
               | This was always a strange point of contention - Intel
               | denied using memristors. I assume there were some sort of
               | patent or trademark issues.
               | 
               | WP:
               | 
               | "Development of 3D XPoint began around 2012.[8] Intel and
               | Micron had developed other non-volatile phase-change
               | memory (PCM) technologies previously;[note 1] Mark Durcan
               | of Micron said 3D XPoint architecture differs from
               | previous offerings of PCM, and uses chalcogenide
               | materials for both selector and storage parts of the
               | memory cell that are faster and more stable than
               | traditional PCM materials like GST.[10] But today, it is
               | thought of as a subset of ReRAM.[11] According to patents
               | a variety of materials can be used as the chalcogenide
               | material.[12][13][14]
               | 
               | 3D XPoint has been stated to use electrical resistance
               | and to be bit addressable.[15] Similarities to the
               | resistive random-access memory under development by
               | Crossbar Inc. have been noted, but 3D XPoint uses
               | different storage physics.[8] Specifically, transistors
               | are replaced by threshold switches as selectors in the
               | memory cells.[16] 3D XPoint developers indicate that it
               | is based on changes in resistance of the bulk
               | material.[2] Intel CEO Brian Krzanich responded to
               | ongoing questions on the XPoint material that the
               | switching was based on "bulk material properties".[3]
               | Intel has stated that 3D XPoint does not use a phase-
               | change or memristor technology,[17] although this is
               | disputed by independent reviewers.[18]
               | 
               | According to reverse engineering firm TechInsights, 3D
               | XPoint uses germanium-antimony-tellurium (GST) with low
               | silicon content as the data storage material which is
               | accessed by ovonic threshold switches (OTSes)[19][20]
               | made of ternary phased selenium-germanium-silicon with
               | arsenic doping.[21][22]"
        
           | hwillis wrote:
           | > graphene was supposed to be this wonder material, and now
           | it's found in the soles of trail and hiking boots.
           | 
           | I mean, that's not because graphene has become a routine part
           | of our material repertoire. It has no reason to be in those
           | things, does nothing, and is just marketing fuel. We may put
           | "graphene" in things, but we are not much closer to using its
           | interesting properties.
        
             | marcosdumay wrote:
             | Right now, graphene is an amazing component of filters and
             | composite materials. But only of the very expensive kinds
             | of those.
             | 
             | We don't put it on a lot of things. It's expensive as hell.
        
         | ants_everywhere wrote:
         | > if it turns out that you can not find the necessary
         | improvements in only a single dimension, then the whole thing
         | is kinda doomed and will probably never be competitive
         | 
         | I don't know, we've been working on digital computers since at
         | least the late 1800s. Sometimes technology just takes a while.
         | 
         | That does make it hard to gamble on it if the time horizon is
         | longer than you need to make a profit.
         | 
         | But I don't think we should convince ourselves that a
         | technology that takes longer than 15 years to become profitable
         | is doomed. If we thought like that we'd still be subsistence
         | hunter gatherers.
        
           | myrmidon wrote:
           | Absolutely! For the record: I don't think that memristors
           | _are_ doomed to be useless-- we 'll have to find out.
           | 
           | My point is just that even with research-tech that sounds
           | absolutely _amazing_ (low power, persistent, high density)
           | you just need to fail on a single dimension for it to
           | basically become irrelevant.
           | 
           | This is also why its so easy for media to overhype research
           | results, which (predictably) results in continuous
           | disappointments and loss of trust (of the public) in science
           | reporting and/or even science in general...
        
           | nine_k wrote:
           | Regarding technology taking time: look at LEDs.
           | 
           | - The effect first discovered: 1907.
           | 
           | - First prototype device built: 1927.
           | 
           | - First commercially viable parts shipping: early 1960s.
           | 
           | - Ubiquitous and cheap as an indicator device: 1980s.
           | 
           | - Highly efficient, used for lighting: 2010s.
           | 
           | The principle never changed along the way. The specific
           | materials changed quite a bit.
        
         | marcosdumay wrote:
         | They never promised high-density. Semiconductor memristors were
         | always fated at staying at a much lower density than the same
         | amount of capacitive memory. And that's before you get into the
         | manufacturing issues and the problem that it loses "data" when
         | read.
         | 
         | Those things where hyped out of nowhere, with lots of blatant
         | lies making into the popular discourse (like that high-density
         | prediction). I don't even know why, because nobody was making
         | any serious bet on them. They are a very interesting design,
         | that may still get some real-world usage (the manufacturing
         | problems are a showstopper right now), but won't ever compete
         | with flash.
        
         | mikewarot wrote:
         | I think that Memristors are perfect for use as configuration
         | RAM for FPGAs and FPGA-like things. Something that you want to
         | be able to update, but not frequently, and read all the time.
         | 
         | Of course, then the question becomes one of refreshing their
         | state, like DRAM.
        
       | baq wrote:
       | > 460x less energy than digital computers
       | 
       | The brain is running on 20W of power and it has the best LLM, the
       | best robotics control unit, very good sensor integration and all
       | the other exciting stuff which we* want** AIs to have. I'd rather
       | have that than nuclear powerplants feeding data centers.
       | 
       | * overreaching a bit
       | 
       | ** also not really true for everyone
        
         | go_elmo wrote:
         | Nit: we take 20w of chemical energy not electrical one like
         | computers, way worse efficiency compared to solar panels Id say
        
           | im3w1l wrote:
           | Our current society converts chemical energy to electrical,
           | not the other way round. So its the electrical energy user
           | that needs a lossy conversion step.
        
             | tlb wrote:
             | Fossil fuel plants are chemical -> heat -> mechanical ->
             | electrical. The heat -> mechanical step is the inefficient
             | one, sadly limited to ~40% efficiency even with very fancy
             | machinery. Most other conversions can be above 90%
             | efficient.
        
               | pfdietz wrote:
               | The efficiency of gas-fired combined cycle power plants
               | can exceed 60% (lower heating value). And their capex is
               | just over $1/W. Combustion turbines are amazing.
               | 
               | With a SOFC topping cycle they might approach 70-80%
               | efficiency. SOFC with just a combustion turbine (no steam
               | bottoming) could exceed 60%. Granted, SOFCs are direct
               | chemical->electrical conversion, but their waste heat is
               | very usefully hot.
               | 
               | I don't think it's entirely a coincidence that nuclear
               | power plants in the US stopped being built about the same
               | time combustion turbines (by themselves, without the
               | steam bottoming cycle) reached efficiency parity with
               | high temperature steam turbines.
               | 
               | (SOFC = solid oxide fuel cell, which operate around 1000
               | C.)
               | 
               | ("Lower heating value" is based on energy that could be
               | obtained burning natural gas to CO2 and water vapor. An
               | additional 10% could be obtained by condensing the water
               | vapor to liquid, this is "higher heating value".)
        
           | raverbashing wrote:
           | That's why the most efficient use of Superman would be to
           | turn a giant crank generating energy
        
             | pfdietz wrote:
             | https://www.smbc-comics.com/index.php?db=comics&id=2305
        
           | hwillis wrote:
           | Actually, no! Producing ATP is ~30% efficient, which is much
           | better than premium consumer solar panels. And while that
           | heat is technically waste, even if it was more efficient we
           | would still generate heat other ways just to keep warm.
           | 
           | What's even more shocking is that conversion of food to
           | energy period is ~90% efficient, which is _crazy_ to me. The
           | fact that you can _burn_ food and measure the energy given
           | off, and that 's _very close_ to how much energy you get from
           | eating it- that 's insane.
           | 
           | The efficiency of the human body is all over the place.
           | Muscles are only ~30% efficient, and the rest is waste
           | heat... but humans walk using orders of magnitude less power
           | than any walking robot. As far as I know we have never made a
           | powered walking machine that is 10% as efficient as a person.
           | The only way we can beat it is with a carefully balanced,
           | specially-lubricated pair of legs that is leaned downhill on
           | a treadmill and powered by gravity.
        
             | fragmede wrote:
             | I'd wait until walking robots are commonplace before
             | discounting our ability to make an efficient one. I don't
             | think I've seen one in person yet.
        
               | hwillis wrote:
               | I wouldn't. We have been trying[1]; humans are genuinely
               | shocking in this way. Mechanical systems should have _so
               | many_ advantages over humans; springs are 10x better than
               | tendons, motors are 3x better than muscles. It 's
               | possible humans evolved walking as a _predatory tactic_.
               | Even if we develop a super-efficient walking robot,
               | humans are efficient at _several_ speeds, and keep that
               | efficiency while varying their stride and foot placement,
               | _and_ with one of the largest most complex brains of any
               | animal. And the ratio of leg /torso length is pretty
               | variable among humans! Not to mention the flexible spine
               | and swinging hips _should_ be a huge energy sap, but they
               | just kind of... aren 't.
               | 
               | Beating human locomotion in the general case is pretty
               | far off. It's a combination of body plan, extreme
               | optimization of joints and energy storage, and _really_
               | good algorithms.
               | 
               | One killer feature of the human body is synovial fluid.
               | It's very thin, non-newtonian, self-replenishing and
               | contained in particularly low-friction bearing surfaces.
               | It's certainly better than 99.9% of mechanical joints,
               | because these surfaces filter, heal and re-lubricate
               | themselves. Mechanical joints have sticky grease so they
               | stay lubricated without maintenance, and work in the
               | presence of water and grit. It's doubtful that any joint
               | that doesn't heal itself can compete, long-term.
               | 
               | [1]: https://spectrum.ieee.org/durus-sri-ultra-efficient-
               | humanoid...
        
               | fragmede wrote:
               | A very select group has tried for not very long, but I
               | think the most gains in efficiency are going to come from
               | giving bipedal robots rollerblades.
        
               | hwillis wrote:
               | Absolutely correct, evolution will never ever beat a 10
               | cent ABEC-7 bearing. Skateboards really changed
               | manufacturing by making a specific size of wildly precise
               | bearing incredibly cheap. One day a robot will be able to
               | step directly onto ice skates, but meanwhile I'm looking
               | forward to the blooper reel because it's gonna be funny
               | as hell
        
               | marcosdumay wrote:
               | As long as they have decent brakes... Because stairs and
               | obstacles exist, and getting over them beats overall
               | efficiency almost every time.
        
             | Workaccount2 wrote:
             | To be fair, our food to energy conversion is so efficient
             | because the foods we eat are already in a very energy ready
             | state. Our bodies don't bother with stuff that is harder to
             | convert.
        
               | hwillis wrote:
               | true, but recycling proteins is also pretty amazing.
               | These are the most complex machines we know of, elegant
               | atomic factories that do the seemingly impossible... and
               | you dip them in acid and then you can pop them apart like
               | a string of beads, to be reassembled into a totally new
               | molecular miracle.
        
         | Aardwolf wrote:
         | > and it has the best LLM
         | 
         | It takes many years to train it though
        
           | moffkalast wrote:
           | And it's EoL after about 40 years too.
        
           | bawana wrote:
           | Not really. Consider private equity's solution to our doctor
           | shortage. Import foreign trained physicians without requiring
           | additional training. Give them access to an electronic
           | medical record eith AI. Teach them how to click a mouse so
           | they can copy/paste notes.Use digital real time translation
           | to allow anyone to talk to anyone. Have them 'treat' 100
           | patients a day. Pay them next to nothing. When some patient
           | suffers, allow the legal system to crucify the imported
           | 'doctor'. Deport that one and get the next one.
           | 
           | Now you know why you always see new doctors
        
             | ben_w wrote:
             | Yes really, human doctors start a medical degree at what,
             | 17 or 18? Then it's a 4-6 year medical school followed by
             | 3-7 years residency depending on your country and education
             | system.
             | 
             | (This is also why LLMs passing medical exams, though
             | impressive, has not rendered the profession obsolete: LLMs
             | are book smart, but don't have the implicit knowledge that
             | we humans only gain from practical experience).
        
         | p3opl3 wrote:
         | Should we just not grow robots organically then? We have the
         | DNA structure.. why not..
        
       | trextrex wrote:
       | The original pre-print is available at:
       | https://www.researchsquare.com/article/rs-3647379/v1
       | 
       | which is probably a less spammy source than the ResearchGate
       | link.
        
         | dbcooper wrote:
         | What's wrong with Research Gate?
        
           | trextrex wrote:
           | What value does it provide over linking to the original
           | source?
           | 
           | Any website that constantly asks me to login is spammy in by
           | book. It's a for profit website that adds little value other
           | than duplicating information from primary sources and
           | occasionally mangling pdfs with redundant information to
           | advertise themselves.
        
             | SideQuark wrote:
             | They also provide a central place to search things, with a
             | richer interface than Google scholar, and have centralized
             | a significant amount of good sources.
             | 
             | There's a reason millions of researchers have joined. That
             | you don't find value or know what they provide is no reason
             | others should not learn the value they add.
        
               | p1esk wrote:
               | They also show ads:
               | https://www.researchgate.net/marketing-solutions
               | 
               | As a researcher I don't see any value there. I'll stick
               | with Arxiv, thanks.
        
               | SideQuark wrote:
               | That's fine. You also miss all papers not on arxiv. You
               | miss published versions of even the papers on Arxiv
               | (which are often improved versions), and you miss any
               | benefit peer review has on those papers.
               | 
               | I use arxiv nearly every day, and also a few places that
               | get things not on arxiv because the majority of papers
               | are simply not there. Arxiv is paid for by universities
               | paying subscriptions, locked in for five years at a time.
               | It's also funded by Simons Foundation (which may not pay
               | forever) and Cornell and many individual donors.
               | Affiliate groups like professional societies and govts
               | pay huge sums to keep it running. Many companies pay 10's
               | of thousands annually to be members.
               | 
               | Piggybacking on their money while taking affront at a
               | bigger, more comprehensive service, because they dare
               | post an ad, seems somewhat short sighted, but to each his
               | own.
               | 
               | ResearchGate is the largest academic social network, so
               | many use it for that reason. Here's an (2014) Nature
               | article on researcher usage of various sites that may
               | surprise you https://www.nature.com/news/online-
               | collaboration-scientists-...
               | 
               | Since a significant number of job postings for
               | researchers as well and communication and networking
               | opportunities are widely used on Research Gate, none of
               | which is present on Arxiv, you are simply missing likely
               | useful contacts and tools for your career. And I write
               | this as a researcher for several decades, long before any
               | of these were live.
               | 
               | As I said, enough people find value at research gate that
               | millions do pay.
        
         | tetris11 wrote:
         | I'm surprised they chose Researchgate to publish their pre-
         | print, instead of Arxiv
        
       | artemonster wrote:
       | Just a bit of context: MRAM exists as an IP for long time, but
       | their promise to execute code directly from it didnt really pan
       | out because of speed. So it competes against flash to store the
       | code that is booted into SRAM and it loses there too because of
       | mostly larger area
        
         | cubefox wrote:
         | I think memristors are technically more closely related to
         | ReRAM (RRAM) than to MRAM. Though ReRAM so far also just
         | unsuccessfully competes against NAND flash.
        
           | artemonster wrote:
           | Oh, yes, a typo. I meant RRAM
        
       | sroussey wrote:
       | This was later published in Nature:
       | 
       | https://www.nature.com/articles/s41586-024-07902-2
        
       | aappleby wrote:
       | This seems waaaaay too good to be true. What am I missing?
        
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