[HN Gopher] Nxylon: New super-black material made from wood
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       Nxylon: New super-black material made from wood
        
       Author : throwaway2562
       Score  : 160 points
       Date   : 2024-08-03 16:06 UTC (4 days ago)
        
 (HTM) web link (news.ubc.ca)
 (TXT) w3m dump (news.ubc.ca)
        
       | oniony wrote:
       | This, different article, https://www.earth.com/news/new-super-
       | black-wonder-wood-calle..., suggests the process is high-energy
       | plasma affecting the cut ends of the basswood fibres.
        
         | bradrn wrote:
         | That article has a paper link:
         | https://doi.org/10.1002/adsu.202400184
        
       | hoseja wrote:
       | How does it compare to the other super-black materials, the
       | Vantablacks and the like?
        
         | HPsquared wrote:
         | Probably less carcinogenic.
        
           | Cthulhu_ wrote:
           | I dunno, it looks like they're creating carbon
           | nanostructures; while wood carbon / soot seems fairly benign,
           | I still wouldn't want to breathe it.
        
             | cenamus wrote:
             | And tar/pitch is definitely carcinogenic
        
           | tetris11 wrote:
           | that's what a lot people with wood burners _used_ to say...
        
             | throwanem wrote:
             | Yeah, but everybody chain-smoked from age 3 in those days,
             | so it's not easy to tell.
        
         | Cthulhu_ wrote:
         | Here [0] is the paper in question, it has a chart that shows
         | the reflection rate of this one at around 0.3 - 2%; the paper
         | itself has the following quote for the competitors:
         | 
         | > Far lower reflectance values have been achieved with
         | materials containing aligned carbon nanotubes (CNT), for
         | example a low-density CNT array (0.045%),[11] the coating
         | Vantablack (0.035%)[7] and a CNT-metal foil (0.005%).[12] The
         | current holder of the "record" for a low reflectivity material
         | (<0.0002%) is an ion-track micro-textured polymer with anti-
         | backscatter matrix.[13]
         | 
         | So they're arguing that it's on-par with Vantablack but not the
         | newer materials.
         | 
         | [0] https://onlinelibrary.wiley.com/doi/10.1002/adsu.202400184
        
           | shibbidybop wrote:
           | From your numbers Vantablack is 0.035%, whereas the new
           | process bottoms out at 0.3%. So they're within 10x of
           | Vantablack, but not on the same level.
        
         | Alifatisk wrote:
         | If my understanding is correct, Nxylon is lighter than
         | Vantablack (in terms of weight) but reflects slightly more
         | light. This means that it is less effective than Vantablack at
         | absorbing light.
        
       | dbacar wrote:
       | "The researchers have developed prototype watches and jewelry"
       | What kind of a research team is this, fashion? :)
        
         | tetris11 wrote:
         | Also, the black parts there really didn't look that dark.
        
           | swiftcoder wrote:
           | They are also all watch designs that I get served instagram
           | ads for, coincidentally
        
             | nvalis wrote:
             | I recognized the right watch immediately to be this one
             | [0]. But i guess they just replaced parts of the watchfaces
             | with their material?
             | 
             | [0]: https://www.holzwerk-uhren.de/en/products/holzwerk-
             | eifel
        
           | MisterBastahrd wrote:
           | Those watches have crystals on them.
        
       | kingkongjaffa wrote:
       | What's the chemistry at play here to achieve this?
       | 
       | Does it burn "lighter" compounds away to leave dark ones behind?
       | Does it cause a reaction to turn lighter compounds darker? I
       | couldn't see details of the mechanism. Which is important since
       | presumably some mechanisms would give a hint that the process can
       | be tried on other materials or types of wood.
       | 
       | The article mentions it works on other types of wood but doesn't
       | explain why, or if it works on all woods.
        
         | cenamus wrote:
         | Well they say it doesn't rely on pigments, so I'm inclined to
         | think it uses some sort of nano-structures, like "improved"
         | vantablack. Like a forest where light goes in, but just get's
         | scattered long before it can make its way back out. Ben did a
         | really nice video about that homemade stuff, including (of
         | course) some electron microscope images.
         | 
         | https://www.youtube.com/watch?v=Xr1AiExSAnU
        
           | flir wrote:
           | Maybe the cut cell acts like a hemispherical shell coated in
           | carbon. Light enters, bounces around inside a couple of
           | times, gets absorbed?
        
         | neom wrote:
         | Two things are at play, the lignin (light absorbing) is
         | emphasized and the cellulose is burnt away (light reflecting),
         | and it seems this combined pretty unique lattice system (they
         | use a similar synthetic system when producing regular
         | ultrablack paint but the natural one appears to be more
         | complex) create the blackness.
        
         | HPsquared wrote:
         | It's probably a combination of the surface being black in
         | colour (charcoal), plus a surface texture that absorbs light.
         | 
         | It brings to mind the way feathers and insects often have
         | brightly-coloured parts that aren't due to pigment but rather
         | the microstructure preferentially absorbing/reflecting specific
         | wavelengths, giving a colour.
         | 
         | https://en.wikipedia.org/wiki/Structural_coloration
         | 
         | Similarly, I wouldn't be surprised if the microstructure is
         | tuned to work best (lowest reflectance) in the visible light
         | range.
         | 
         | EDIT: limited wavelength range also applies to other "super-
         | black" materials
         | https://en.wikipedia.org/wiki/Super_black#Technology
        
         | Scaevolus wrote:
         | Check the paper, especially figure 5:
         | https://doi.org/10.1002/adsu.202400184
         | 
         | Burning the end-grain wood makes a particularly complex porous
         | structure that minimizes the chance of reflected light escaping
         | ("velvety").
        
       | barrenko wrote:
       | Hopefully the writers of Parks & Recreation will be aware of this
       | research when writing the second reunion show.
       | 
       | https://youtu.be/pTme7k5sV-o?si=sbAYH5FAg4n4G4LS
        
         | parpfish wrote:
         | How much more black could it be? None. None more black.
        
       | Hnrobert42 wrote:
       | The ceiling and wall tiles mentioned at the very end of the
       | article sound really cool.
        
         | pmcarlton wrote:
         | A room where all the walls, floor, and ceiling are made of this
         | would be pretty disorienting, wouldn't it? Even with a light
         | source that let you see all the people in the room, wouldn't it
         | just look like you're all in a pocket dimension?
        
       | digging wrote:
       | > Most surprisingly, Nxylon remains black even when coated with
       | an alloy, such as the gold coating applied to the wood to make it
       | electrically conductive enough to be viewed and studied using an
       | electron microscope. This is because Nxylon's structure
       | inherently prevents light from escaping rather than depending on
       | black pigments.
       | 
       | I don't follow this at all. If it's coated with an alloy, Nxylon
       | isn't on the surface of the object anymore, the alloy is. So the
       | alloy should be reflecting light. What am I missing?
        
         | vczf wrote:
         | A layer of very thin gold can be transparent.
        
           | digging wrote:
           | I see, thanks for filling that in.
        
             | wlesieutre wrote:
             | Famously seen on the Apollo space suit sun visors. Their
             | gold layer is thick enough to look gold, but thin enough
             | that you can see through it:
             | 
             | http://heroicrelics.org/apollo-wwwttm/apollo-
             | suit-a7l-leva-v...
             | 
             | http://heroicrelics.org/apollo-wwwttm/apollo-
             | suit-a7l-leva-v...
        
               | ComputerGuru wrote:
               | You can see through it at least in part because of the
               | tint/opacity effect, where there is more light on the
               | outside than the inside. It's why you can't see through
               | it the other way around (it's reflective, you don't see
               | the astronauts' eyes).
               | 
               | That would imply the result of overlaying Nxylon with
               | this would be gold-colored, not ultra-black..
        
         | loaph wrote:
         | I interpreted this along the lines of it not being a pigment,
         | rather it's black because something about it's physical
         | structure at a small scale causes light to not reflect back.
         | Adding a thin coating of gold would not necessarily change that
         | structure so it would continue not reflecting light.
         | 
         | ^ pure conjecture
        
           | pb060 wrote:
           | I believe it's something called "structural absorption",
           | similar to what happens on birds of paradise feathers [1]
           | 
           | [1] https://www.nature.com/articles/s41467-017-02088-w
        
           | digging wrote:
           | > Adding a thin coating of gold would not necessarily change
           | that structure
           | 
           | My confusion is that I would normally expect a layer of gold
           | not to permit any light to pass through. The underlying
           | structure wouldn't be receiving any light, so there would be
           | no photons to trap. Apparently a layer of gold can be applied
           | thinly enough to transmit appreciable light, though.
        
           | xelamonster wrote:
           | This part of the article confused me, because what does a
           | black pigment do if not "inherently prevent light from
           | escaping"? That's kind of just the definition of absorb.
        
       | peter_d_sherman wrote:
       | https://www.youtube.com/watch?v=pAgnJDJN4VA
        
       | ted_dunning wrote:
       | Sounds like a great way to build black body emission sources.
       | 
       | Just panel the interior of a box with this stuff and put a hole
       | in one wall.
       | 
       | It does depend on the spectral properties a lot. Figure 3 in
       | https://onlinelibrary.wiley.com/doi/10.1002/adsu.202400184 seems
       | to indicate that the behavior in the very near infrared will be
       | pretty good. It stands to reason that this behavior could be
       | optimized by process improvements.
        
       | ComputerGuru wrote:
       | > Nxylon (niks-uh-lon), after Nyx
       | 
       | It seems the most straightforward spelling (and easier to
       | pronounce by looking at it if you are taking any kind of cues
       | from the rest of loan words in the language) would have been
       | Nyxlon.
        
         | YeGoblynQueenne wrote:
         | I read it as "N-xylon", where "xulon" is wood in Greek.
        
       | groby_b wrote:
       | Looking at the watch photographies, how is this "super-black"?
        
       | fernly wrote:
       | A pity they hadn't read Gene Wolf's _Book of the New Sun_ in
       | which the main character wears robes of "the hue fuligin, which
       | is darker than black, admirably erases all folds, bunchings and
       | gatherings so far as the eye is concerned, showing only a
       | featureless dark."[1] From the Latin for soot.[0]
       | 
       | [0] https://www.merriam-webster.com/dictionary/fuliginous
       | 
       | [1] http://www.technovelgy.com/ct/content.asp?Bnum=1495
        
       | ljsprague wrote:
       | Does it rub off?
        
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