[HN Gopher] Producing fuels from 1,500 degrees of solar heat
       ___________________________________________________________________
        
       Producing fuels from 1,500 degrees of solar heat
        
       Author : doener
       Score  : 117 points
       Date   : 2024-06-25 10:43 UTC (4 days ago)
        
 (HTM) web link (www.thechemicalengineer.com)
 (TXT) w3m dump (www.thechemicalengineer.com)
        
       | ttt333 wrote:
       | I have no idea if technology like this will prove to be scalable,
       | economically competitive, or even practical... but it does seem
       | pretty dang cool as a concept
        
         | jfengel wrote:
         | It's a great way to say "Absolutely no more fossil fuels. For
         | things that need hydrocarbons we'll make them. They cost more
         | but it's better than cooking the planet."
         | 
         | With a side bonus of not sending money to oil rich theocracies
         | like Saudi Arabia and Texas.
        
           | mgerdts wrote:
           | With methane as an input, I worry that this will be hard to
           | scale up to the point of no more fossil fuels. Can we get
           | that much methane from biomass?
        
             | jaggederest wrote:
             | Considering agriculture and forestry combined produce about
             | 5 billion tons of methane emissions a year, I don't think
             | there's a shortage of availability.
             | 
             | It'll be a lot more work to capture and direct all that,
             | but the biosphere spins off plenty of decomposition
             | byproducts.
        
               | defrost wrote:
               | Is it more or less energy dense than oil?
               | The consumption of oil has steadily increased over the
               | last three decades, totaling 4.53 billion metric tons in
               | 2023,
               | 
               | That's oil shipped and used, not methane drifting free
               | from biowaste across the plant.
               | 
               | How much can we _actually_ capture, how much energy is
               | that, and how great is the conversion challenge to shift
               | most cars to methane, etc?
               | 
               | It appears a little larger than a handwave problem IRL.
        
             | waldothedog wrote:
             | > Can we get that much methane from biomass?
             | 
             | I know that food waste generates a heck of a lot of methane
             | in landfills, but I'd love if someone could add some rough
             | napkin math on this!
        
               | pfdietz wrote:
               | Biomass availability in the US:
               | 
               | https://www.energy.gov/eere/bioenergy/2023-billion-ton-
               | repor...
               | 
               | One would like to focus on existing streams before having
               | to increase area used to grow biomass.
        
             | tejtm wrote:
             | be afraid.
             | 
             | methane hydrates;
             | 
             | strip mining ocean floors could keep fossil fuel
             | consumption going at current rates for millennia.
             | 
             | but before that we could get we stuff in the permafrost
             | 
             | all terrible ideas ... so probable.
             | 
             | https://duckduckgo.com/?q=methane+hydrates&t=lm&ia=web
        
           | osigurdson wrote:
           | Texas?
        
             | wussboy wrote:
             | Yup
        
             | jfengel wrote:
             | At the moment, Oklahoma next door is even more prominent:
             | they just mandated teaching the bible in public schools.
             | But it's much the same.
        
               | selimthegrim wrote:
               | Were you thinking of Louisiana?
        
           | tomcam wrote:
           | How is Texas a theocracy?
        
       | pfdietz wrote:
       | This is just using solar heat to reform methane from biogas. I
       | was hoping it would be using solar heat for production of the
       | reduced chemicals from water or CO2. This latter problem is much
       | harder, but there have been proposals, for example using heat to
       | reduce transition metal oxides with evolution of oxygen, then
       | reacting the oxides with steam to make hydrogen.
       | 
       | M2O3 --> 2 MO + 1/2 O2
       | 
       | 2 MO + H2O --> M2O3 + H2
        
         | jillesvangurp wrote:
         | The main issue with CO2 is that the concentrations in air are
         | pretty low. A couple of hundreds of parts per million. So, most
         | synthetic fuel generation is bottle necked on getting enough
         | CO2.
         | 
         | If you are processing a kg of air, you'd be getting only a
         | fraction of a gram of CO2. So if you want to produce say a ton
         | of fuel, you are looking at processing many millions of tons of
         | air.
         | 
         | That's why a lot of synthetic fuel generation is often paired
         | with carbon capture schemes or bio mass (like this one). But of
         | course a lot of those carbon sources aren't actually that
         | clean. Biomass sounds nice until you realize that farming is a
         | big emitter of CO2. And generating fuel from carbon capture of
         | course defeats the purpose. You capture it at great cost and
         | then you create a fuel. Which you then burn and dump in the
         | atmosphere.
         | 
         | This particular scheme in Germany exists because of the
         | influence of car manufacturers there. Companies like BMW are
         | dragging their heels getting rid of their ICE car manufacturing
         | operations and pretending that there are unicorn solutions like
         | hydrogen, synthetic fuels, etc. are great excuses to keep their
         | factories going for a few years longer. Of course EVs are
         | eating their lunch at this point and they are now actually
         | producing lots of those as well.
        
           | chii wrote:
           | > You capture it at great cost and then you create a fuel.
           | Which you then burn and dump in the atmosphere.
           | 
           | But if the need for carbon based fuels is not able to be
           | eliminated, this is the next best thing. It is better than
           | digging more of it out of the ground, and then burn and dump
           | it into the air!
        
             | jillesvangurp wrote:
             | Mainly jet fuel. Cars and trucks will do just fine on
             | batteries.
             | 
             | The point with carbon capture is that the captured carbon
             | still comes from fossil fuels. You burn it, you capture it,
             | make fuel, and then you burn it again. So, it's slightly
             | less worse than burning it only once but 100% of it still
             | ends up in the atmosphere.
             | 
             | Synthetic fuels made with biomass are more sustainable but
             | only if the biomass is produced sustainably. Which it often
             | isn't. Dumping a lot of CO2 in the air to produce corn and
             | then turn it into ethanol would be the classic example here
             | of something a lot of countries do at scale that isn't
             | really all that green.
        
               | usrusr wrote:
               | > The point with carbon capture is that the captured
               | carbon still comes from fossil fuels
               | 
               | That's not a property of carbon capture, it's a property
               | of the fuel coming in on the other side of the
               | (stationary) process. We certainly won't be seeing carbon
               | capture of jet fuel any time soon, so the fuel preceeding
               | the capture will definitely not be the one produced.
               | Think waste incineration, think bioplastics (don't waste
               | that precious energy on some pointless biodegradation!),
               | think single use paper, think moving the part of the
               | natural carbon cycle that happens in bushfires and the
               | like into a controlled environment.
        
               | jillesvangurp wrote:
               | Actually jet fuel is already being synthesized from a mix
               | of biomass and captured carbon.
               | 
               | A lot of the carbon capture schemes propose capturing
               | carbon from coal plants or similar sources where massive
               | amounts of fossil fuels are being burned.
               | 
               | But you are right that there are clean sources as well.
               | But mostly with carbon capture, the source is fossil
               | fuel.
        
               | usrusr wrote:
               | Fossil burning plants that capture carbon do it for the
               | greenwashing, not because there might be some use for the
               | concentrated CO2. Renewable burning plants have little
               | incentive to greenwash. Renewable burning does exist, and
               | I suppose that group is much bigger than the tiny subset
               | of fossil burning plants that actually do capture. If we
               | include waste incineration plants in the renewable group
               | (the true multifuel specialists) then the conclusion is
               | that capacity is already abundant, and some of those
               | might actually be considering capture (but their
               | greenwashing pressure isn't remotely as big as in e.g.
               | the coal business, where the greenwashing is nothing less
               | than an existential last ditch hail mary attempt)
        
               | pfdietz wrote:
               | It turns out one place in the US where CO2 capture is
               | actually already being done on a large scale is in
               | bioenergy. As I understand it, 25% of the CO2 produced by
               | ethanol production in the US is captured. I think it's
               | mostly being used for enhanced oil production, but it
               | _is_ being used.
        
           | usrusr wrote:
           | That's why for every very high value use case (see chii
           | sibling post) you keep some low value use cases running that
           | don't really require high energy concentration fuel. Burn
           | shrubs, waste (e.g. bioplastics), whatever for heat and
           | stationary power and capture that CO2. Low concentration
           | fuels are well available in renewable form and will be
           | forever. Bottleneck solved, at least as long as you don't
           | imagine you could keep up fossil age consumption rates with
           | synthfuels (you can't). Leave those many millions of tons of
           | air to processes we already run on them anyways.
           | 
           | You are right (also with that last paragraph), direct air
           | capture is usually a scam. I might be willing to grant a weak
           | exception to projects that put serial self-containedness
           | front and center, e.g. terraform industries (not to be
           | confused with terraform labs...) would certainly be
           | overwhelmed if they tried to tailor a capturing biomass plant
           | to the local situation with each installation. But even they
           | should better spell out in their advertising "optional, could
           | be substituted with:" for the DAC.
        
           | generic92034 wrote:
           | > Of course EVs are eating their lunch at this point and they
           | are now actually producing lots of those as well.
           | 
           | Are actual EV sales numbers reflecting this, in Germany?
        
             | swiftcoder wrote:
             | Despite their loud complaints about electric cars, yes. EVs
             | sales are rising rapidly, and account for >30% of new car
             | sales in the past year (and that's not counting PHEVs)
        
               | generic92034 wrote:
               | In the past year EV sales went very well, agreed. But
               | recently I am seeing articles like this one:
               | 
               | https://www.tagesschau.de/wirtschaft/unternehmen/vw-
               | elektros...
               | 
               | A sharp decline in EV sales for Volkswagen, so they are
               | asking for subsidies.
        
             | pfdietz wrote:
             | Battery prices are falling very quickly this year, so EV
             | sales globally are set to explode.
        
               | generic92034 wrote:
               | That might be the case, but currently EV prices are
               | generally still significantly higher than ICE car prices
               | of the same class, hitting a slow economy in some EU
               | countries. Maybe Chinese EV can fill that gap.
        
           | pfdietz wrote:
           | The proposal described was using methane from biogas. But the
           | microbial decomposition of carbohydrates that creates biogas
           | also creates CO2, in equal molar quantity:
           | 
           | (CH2O)2 --> CH4 + CO2
           | 
           | So, if you want to get as much fuel as you can out of the
           | carbon in biomass, you want to use extra hydrogen (and in
           | this case, it would mean they wouldn't have to separate out
           | the methane in the biogas; just add hydrogen and reform the
           | whole mixture). That extra CO2 is available without the need
           | for expensive direct air capture: the plants already captured
           | it. You could even directly hydrogenate biomass (or, perhaps,
           | molecules derived from aggressive depolymerization of
           | biomass) instead of going through biogas. This is Virent's
           | approach. It avoids the need to break all the C-C bonds
           | before recreating them in the synfuel.
           | 
           | There have been efforts to use solar energy to directly
           | gasify biomass. A company called Sundrop, out of Colorado,
           | was trying to commercialize this 15 years ago. But then
           | fracking dropped the price of natural gas and it all
           | collapsed; the remnants of the company were bought by
           | Chesapeake Energy (a natural gas producer) not long after.
        
       | bradfitz wrote:
       | > It uses an AI-based method involving drones to calibrate the
       | mirrors 200 times faster compared to traditional techniques using
       | cameras, Synhelion says. Precision is key to ensure the mirrors
       | track the sun and efficiently reflect its light into a solar
       | receiver at the top of a 20 m tall tower.
       | 
       | Naively I would assume we know where the sun is and how to
       | calculate the angles. What are drones and AI doing?
        
         | ulfw wrote:
         | Creating investor hype. What else?
        
         | XorNot wrote:
         | Calibrating out mechanical backlash and mis-alignment in the
         | mountings I assume.
        
           | usrusr wrote:
           | As in fly a scanning pattern around the focus point and look
           | for mirrors that blind the drone instead of frying the tower.
           | 
           | Should be crazy efficient compared to the terrible
           | alternative which would require something like deliberately
           | de-focusing all other mirrors only to be able to verify that
           | the mirror under test actually does project the sun where
           | expected.
           | 
           | Tempted to keep my initial upvote on the "investor hype"
           | sibling, out of spite for all projects that do, but the
           | ability to check arbitrary points in the nonilluminated
           | volume for accidental illumination must really make do much
           | of a difference I can't. Thanks for pointing me in the right
           | direction!
        
             | fl7305 wrote:
             | > fly a scanning pattern around the focus point and look
             | for mirrors that blind the drone instead of frying the
             | tower.
             | 
             | Or just put up a big black board with reference points on
             | it, and point a camera at that?
        
               | usrusr wrote:
               | So then you have a live image of a big black board?
               | 
               | The beauty of the misalignment patrol drone is that it
               | does not leave you guessing wich one exactly of your
               | large number of inexpensive mirrors is out of line. The
               | culprit clearly lights up in the video feed.
        
               | fl7305 wrote:
               | You normally keep all mirrors pointed at the real target.
               | Then take one at a time and point it at the black board
               | off to the side.
               | 
               | You can then use the camera image of the position of the
               | sun spot on the black board to figure out your new
               | calibration settings for this particular mirror.
        
               | usrusr wrote:
               | Ah, separate target for testing assumptions in isolation.
        
         | ekianjo wrote:
         | AI can be just a linear regression these days
        
         | fl7305 wrote:
         | > Naively I would assume we know where the sun is and how to
         | calculate the angles. What are drones and AI doing?
         | 
         | Yes, you know exactly where the sun is in a global coordinate
         | system.
         | 
         | The problem is that your mirrors are not fixed in that global
         | coordinate system.
         | 
         | You need to continuously re-calibrate the local coordinate
         | system of the mirrors against the global system.
        
           | sgc wrote:
           | That is a simple math + sensor problem, not an AI and drone
           | problem.
           | 
           | https://www.topconpositioning.com/us/en/solutions/technology.
           | ..
        
             | vlovich123 wrote:
             | I think it's more that it's been shown that a motor at each
             | panel is more expensive than manually rotatable mirrors
             | that are maintained by a smaller set of mirrors. For
             | example, there was a startup a few years back that had
             | robots on a rail system go to each panel and adjust it.
             | 
             | The reason should be obvious in that the motors are higher
             | maintenance systems so you don't want to scale with the
             | size of your plant. I imagine drones are being used for a
             | similar purpose: the drones further reduce how many
             | adjusters you need vs rails and the AI is so that the
             | drones can actually adjust the panels.
        
               | fl7305 wrote:
               | For concentrated solar polar, you need almost constant
               | movement of the mirrors to keep tracking the sun well
               | enough.
               | 
               | So you need independent azimuth+elevation for each
               | mirror.
        
               | vlovich123 wrote:
               | https://www.technologyreview.com/2012/09/04/184005/a-robo
               | t-t...
               | 
               | There's always a performance/cost target you're trying to
               | hit. Sometimes it's not about performance at all costs
               | and it's ok to sacrifice some optimality to get a much
               | cheaper solution.
               | 
               | So while the mirrors are independently adjusted, the
               | there's a single motor robot on a rail that comes by and
               | custom adjusts each mirror instead of having the mirrors
               | self adjust locally at all times.
        
               | remipch wrote:
               | Interesting, do you have any links about this startup ?
               | 
               | You say it's more expensive, do you have a rough estimate
               | of the cost of such a panel (with or without motors) ?
               | 
               | I'm asking because I'm currently working on a small scale
               | automated solar concentrator and I haven't managed to get
               | an idea of how much such a panel costs.
               | 
               | I have only found some sun trackers for photovoltaic
               | panels but they have different angular accuracy
               | requirements than CSP.
        
               | vlovich123 wrote:
               | Not the startup I was thinking of as I can't find links
               | for it but same concept:
               | 
               | https://www.technologyreview.com/2012/09/04/184005/a-robo
               | t-t...
        
         | overcast wrote:
         | Wasting investor money and using a disproportionate amount of
         | the worlds energy to build chat bots.
        
       | soist wrote:
       | There used to be a company that tried to do this to directly
       | generate electricity: eSolar (https://www.cbsnews.com/news/an-
       | interview-with-esolars-bill-...)
        
         | hn_throwaway_99 wrote:
         | There are lots of companies that used heliostats to generate
         | electricity, but that's not really a problem anymore. My
         | understanding is that:
         | 
         | 1. Photovoltaic panels absolutely cratered in price, so they
         | are, generally, much more economical.
         | 
         | 2. Not mentioned in TFA but these things have environmental
         | concerns because they are basically bird killing machines. Any
         | bird unfortunate enough to fly through the concentrated "death
         | rays" is instantly fried to a crisp. So these things need
         | solutions like drones to keep birds away.
         | 
         | Generating gas from solar is an attractive option because it's
         | then basically just another form of storage. But it would be
         | great if we could generate gas from solar to power existing gas
         | power plants. The primary problem is that the efficiency of
         | generating gas from (solar-powered) electricity is quite low.
        
       | theamk wrote:
       | This sounds very cool, but "annually producing several thousand
       | litres of fuel"?
       | 
       | An average US car consumes ~1800 litres/year... So this 600 kW
       | solar facility is just enough for one or two cars?
       | 
       | A random search shows you need ~2kW worth of solar to charge your
       | electric car daily, so this technology needs to improve a lot to
       | be competitive with batteries. Hopefully they figure it out
       | before they build the full-size plant.
        
       | Animats wrote:
       | > _" annually producing several thousand litres of fuel."_
       | 
       | That's maybe 10 liters a day. Seems low for the size of the
       | installation. A liter of gasoline is about 10KWh. So if this
       | thing gets 5 hours a day of full sunlight, it's putting out 2KW.
       | That's like 5 standard solar panels.
       | 
       | Either I'm calculating this wrong or this is insanely
       | inefficient.
        
         | wolfi1 wrote:
         | it is insanely inefficient. whereelse I read you need 3 liters
         | of gasoline to produce 1 liter of synfuel
        
         | ChuckMcM wrote:
         | What is your measure of efficiency? I ask because the cost of
         | sunlight is nominally zero so 10kWh/$0 is a really big number
         | :-).
         | 
         | Note that the article said that as a thermal plant it operates
         | 24/7 by storing heat in a high thermal mass fluid. Another shot
         | at this is Terraform Industries
         | (https://terraformindustries.com/) which is doing something
         | similar with direct PV -> Fuel (rather than using CSP)
         | 
         | The "magic bean", the "trick", the "secret sauce" here is that
         | there are huge swathes of land that are currently both high
         | sunlight receivers and not used (can't farm them, no one wants
         | to live there, think deserts) That could be used to crank out
         | liquid fuel that has no issue being losslessly transported over
         | long distances and for applications that are unlikely to run on
         | batteries any time soon. Making fuel for those by taking CO2
         | out of the atmosphere is a double win.
        
           | roenxi wrote:
           | The plant is physically quite large; the sunlight might be
           | free but capital and deprecation will influence that ratio.
           | 
           | Although if they can do this economically then good. I have a
           | soft-spot for any solar farm that can be made to look a bit
           | like a flower.
        
           | chii wrote:
           | > sunlight is nominally zero
           | 
           | the investment into the panels is not free though. But i do
           | agree - converting electricity into fuels is great, but only
           | if said electricity does not have another use and would've
           | been wasted otherwise.
        
             | h0l0cube wrote:
             | The capex in something, the opex is neglible, but the
             | opportunity cost doesn't make sense until energy prices go
             | very low or negative is some permanent fashion, or both
             | fuel costs are very high and the switching to alternatives
             | costs too much, or is even infeasible (e.g., air and space
             | transport, shipping, steel production). A premium might
             | make sense for specialist operators who want 'carbon
             | neutral fuel', and have customers willing to pay for it.
        
               | jfengel wrote:
               | A fossil fuel tax would capture the externality that's
               | currently not accounted for, and shift the viability of a
               | project like this.
               | 
               | All that's needed is the desire to avert much larger
               | costs in the future. Or in other words, an absolute
               | impossibility.
        
           | herewulf wrote:
           | > Making fuel for those by taking CO2 out of the atmosphere
           | is a double win.
           | 
           | It's just a single win because the CO2 is going right back
           | into the atmosphere as the fuel is used (carbon neutral, not
           | carbon negative). Still, a win is better than the loss that
           | extracted fuels amount to.
        
             | zemvpferreira wrote:
             | I agree but you could still argue that any economic
             | incentive to develop better carbon capture is another win.
             | If captured fuel gets lots of use, maybe it will become
             | cheap enough to manufacture that we will do so purely for
             | environmental reasons.
        
             | beojan wrote:
             | You don't have to use all the fuel produced.
             | 
             | Presumably some could be used to make plastics and
             | everything else we make from oil. You could also bury some.
        
             | Scaevolus wrote:
             | Carbon-neutral combustion is a win over carbon-positive
             | combustion of extracted coal/oil/gas.
        
           | hnaccount_rng wrote:
           | It's not entirely clear, that we can use e.g. deserts "for
           | free". Changing the albedo of significant amounts of surface
           | can have far reaching consequences. And unlike already
           | populated areas (were this already happened), we don't really
           | know what will happen there (probably until we try)
        
             | spookie wrote:
             | This is a good point. Urban areas are responsible in part
             | for "global warming", just by their albedo. [1]
             | 
             | [1] https://doi.org/10.1038/s41467-022-31558-z
        
               | jfengel wrote:
               | "In part" means 0.00107degC over the next century. That's
               | less than a thousandth of the overall rise. So it's
               | really not the top priority. Even assuming this
               | technology increases it by a factor of 10 it's a massive
               | net gain to displace fossil fuels.
        
           | dmurray wrote:
           | This is a cool project, but it's fair to say that 10 litres
           | of petrol a day isn't sufficient scale to be described as
           | "THE WORLD'S first industrial plant using solar heat to make
           | fuels". It's a research prototype.
        
           | conradev wrote:
           | My measure of efficiency would at least incorporate capex
           | 
           | It takes a non-zero amount of energy to build all of that
           | energy-capturing equipment - question is, how much?
        
             | ChuckMcM wrote:
             | Sure, if you're doing a TCO analysis you figure out a
             | deprecation schedule for your physical plant and your OpEx
             | for the day to day operations. Of course the CapEx for
             | "one" versus the CapEx per instance for "one thousand" will
             | be quite different. Also how much site prep is needed, how
             | much can be built offsite in a factory setting Etc. So a
             | full economic analysis would incorporate all of that. Then
             | price that against the price of fuel with the carbon and
             | environmental externalities priced in, sure. That would
             | give you a solid set of reasoning to say whether these
             | systems are worse, similar to, or better than existing
             | systems.
             | 
             | If you _wait_ for all of that to be in place (versus
             | risking capital today that might have been used for other
             | things) then you risk dying from those aforementioned
             | externalities of  'business as usual' (aka the do nothing
             | hypothesis).
             | 
             | John was, in my reading, defining "efficiency" to be
             | turning the solar power available as electricity in the
             | surface area of the plant into liquid fuel. And my response
             | to that is always that the solar energy was going to hit
             | that patch of ground anyway, and if you don't have the
             | infrastructure to move it to where it is needed "right now"
             | or store it, then its wasted. California is, today, having
             | days where Solar and/or Wind generation is discarded
             | because there are no customers demanding it. At some point
             | (hopefully soon) we'll get better at dealing with this
             | situation, and converting that "extra" power into syngas is
             | a good use for it.
        
         | almostnormal wrote:
         | > That's maybe 10 liters a day. Seems low for the size of the
         | installation. A liter of gasoline is about 10KWh. So if this
         | thing gets 5 hours a day of full sunlight, it's putting out
         | 2KW. That's like 5 standard solar panels.
         | 
         | > Either I'm calculating this wrong or this is insanely
         | inefficient.
         | 
         | With your numbers: 10 l/day * 10 kWh/l / 5 h/day = 20 kW
        
           | Animats wrote:
           | Right. That's better. But there's more mirror area there than
           | even 50 standard solar panels.
        
         | herewulf wrote:
         | It's a pilot plant. Its purpose is to develop, test, and
         | demonstrate the technology. If successful then they can follow
         | through with plans to build bigger plants that run at full
         | capacity. They won't get the funding for the latter step
         | without the former step first.
        
         | swiftcoder wrote:
         | It's a small-scale prototype of a much larger plant:
         | 
         | > Synhelion already has plans to build a much larger plant in
         | Spain in 2025 that will ramp production up to around 1,000 t/y.
         | And beyond that, its ambition is to be manufacturing 1m t/y
         | within a decade
        
       | nashashmi wrote:
       | They should come up with a way to turn leaves into oil. Send it
       | down fractured wells and pump it out 10 years later.
        
       | peter_d_sherman wrote:
       | Related:
       | 
       | Fischer-Tropsch process
       | 
       | https://en.wikipedia.org/wiki/Fischer%E2%80%93Tropsch_proces...
        
       | carbonguy wrote:
       | This concept is not _quite_ smoke and mirrors, since there 's
       | nothing wrong with the science, but this article definitely reads
       | more like a breathless press release than something truly ground-
       | breaking. More notes below:
       | 
       | > Synhelion was founded in 2016 as a spin-off from ETH Zurich,
       | sparked by what the company founders describe as a crazy idea
       | they had: what if they could reverse combustion and turn carbon
       | dioxide and water back into fuel?
       | 
       | This is not a "crazy idea", but rather a straightforward
       | description of the chemistry involved. We call one implementation
       | of this process "photosynthesis", but there are others.
       | 
       | > The technology they've developed relies on four key components.
       | Mirrors - known as heliostats - that track the sun to focus its
       | energy on to a solar receiver. This in turn produces very high
       | process heat at temperatures exceeding 1,500degC. This heat
       | powers a thermochemical reactor that turns CO2, water and methane
       | into syngas, which can be processed via Fischer-Tropsch into
       | fuels.
       | 
       | Again, this is well-understood industrial process chemistry -
       | absolutely a good thing, in my opinion, but not new and sexy by
       | any stretch.
       | 
       | > And finally, a thermal store to release energy when the sun
       | goes down to allow the solar-powered facility to operate around
       | the clock.
       | 
       | This actually IS new and interesting in this application (or at
       | least, it is to me) - a shame that this isn't fleshed out more in
       | the article. I tried to see if there was more about this aspect
       | of their process on the Synhelion website, but their pages were
       | loading slowly and I lost patience. Sorry, team.
       | 
       | > The company says the design of its ultra-thin hexagonal mirrors
       | are key to achieving such high process heats.
       | 
       | Any physicists out there who have a speculation about why the
       | thinness of the mirrors makes a difference here? My understanding
       | is that the maximum temperature that mirrors can get you is
       | limited by the surface temperature of the sun, rather than the
       | mirrors themselves, but I'm certainly no expert on this point.
       | 
       | > It uses an AI-based method involving drones to calibrate the
       | mirrors 200 times faster compared to traditional techniques using
       | cameras, Synhelion says. Precision is key to ensure the mirrors
       | track the sun and efficiently reflect its light into a solar
       | receiver at the top of a 20 m tall tower.
       | 
       | This bit smells like trying to shoehorn in an application of "AI"
       | where it's not really needed - what's the actual improvement
       | using "drones and AI" over just pre-calculating a tracking curve
       | based on latitude + time of day/year? Or just putting down twice
       | as many mirrors and not bothering to make them track?
       | 
       | > "... The inauguration of DAWN marks the beginning of the era of
       | solar fuels - a turning point for sustainable transportation. Our
       | founding dream of producing renewable fuels from solar energy is
       | becoming a reality."
       | 
       | This is hyperbole, as eg. Prometheus was doing this two years
       | ago. Additionally, Synhelion will be hamstrung on growth as long
       | as they depend on biomass methane as a feedstock, but they can
       | solve that by buying methane from Terraform :)
        
         | leetnewb wrote:
         | Couple of points, but not a physicist or scientist.
         | 
         | 1. I believe most existing concentrating solar plants operate
         | below 1,000C. 1,500C might be well understood in producing
         | syngas using other energy sources, but operating a CSP at that
         | temperature is not. To the extent that a company is bringing a
         | CSP plant to market with 1000+ temperature operation, that is
         | novel.
         | 
         | 2. Heliostat design seems like a core focus of improving CSP
         | performance. A lot of research direction is on lowering the
         | cost and complexity of deploying and maintaining the mirrors.
         | See: https://www.nrel.gov/csp/solar-fields.html and
         | https://www.energy.gov/eere/solar/heliocon
        
           | fl7305 wrote:
           | 1,500 C sounds like it's way past what any normal metals can
           | handle?
           | 
           | But in this case, maybe it is enough to have just a small
           | part of the central reaction vessel handle 1,500 C? Maybe
           | using ceramics?
           | 
           | Or can you 3D print an Inconel chamber with builtin cooling
           | channels that makes it possible for the Inconel surface to
           | handle the incoming heat?
        
             | leetnewb wrote:
             | I think you nailed it on the ceramics. Pretty sure they are
             | looking at falling ceramic particles in the tower to
             | capture and transfer the concentrating solar.
        
             | pfdietz wrote:
             | Silicon carbide would work up to 1800 C. Various refractory
             | oxide ceramics could also work.
             | 
             | This whole approach needs direct sunlight, so it's not
             | great for a place, like Europe, where it's often cloudy. It
             | would be better for deserts, like in Chile, Namibia, or
             | maybe the Arabian Peninsula.
        
               | fl7305 wrote:
               | It's not great for a production site. But for engineering
               | tests, you can do a lot of stuff with no sun, and the
               | occasional clear skies are used for sun testing.
        
         | fl7305 wrote:
         | >> And finally, a thermal store to release energy when the sun
         | goes down to allow the solar-powered facility to operate around
         | the clock.
         | 
         | > This actually IS new and interesting in this application
         | 
         | Yes, it's a nice thing to have. But it is a major research and
         | engineering project just in itself. It is by no means a solved
         | problem where you can buy a working solution from someone.
         | 
         | > This bit smells like trying to shoehorn in an application of
         | "AI" where it's not really needed - what's the actual
         | improvement using "drones and AI" over just pre-calculating a
         | tracking curve based on latitude + time of day/year? Or just
         | putting down twice as many mirrors and not bothering to make
         | them track?
         | 
         | Open loop (just pre-calculate) is pretty inaccurate in a system
         | like this. Especially over time as the mirror positioning
         | degrades with accumulating inaccuracies.
         | 
         | So there might be a business case for their AI drone
         | calibration system. But just that part in itself is also a
         | major undertaking that requires a significant investmet over a
         | long time to make it a production system.
         | 
         | "Just add more mirrors" sounds like a better business
         | proposition, coupled with a much simpler autocalibration.
         | Perhaps an off-center bullseye target where each mirror
         | periodically aims itself, and a central vision system figures
         | out the azimuth/elevation offsets?
         | 
         | > This is hyperbole
         | 
         | I agree in that I'd be very surprised if they ever get to the
         | point of mass production.
         | 
         | But I agree with the point that generating synthetic fuels from
         | the sun in a 100% renewable way would be very significant.
         | 
         | Sure, in 30-50 years electrical transportation might meet 99%
         | of our needs. But we're not there yet.
        
       | vixen99 wrote:
       | > What if they could reverse combustion and turn carbon dioxide
       | and water back into fuel?
       | 
       | Humbling thought that the green weed outside your window is doing
       | exactly that - plus, depending on the species, tens of thousands
       | of variations on a carbon theme.
        
       | phantom_wizard wrote:
       | Seems like cool concept, basically it's just solar furnace with
       | extra steps - to me it is a bit nonsense that it is placed in
       | Germany because there are far better locations on a globe like
       | Chile with 10 times more solar energy per m2.
       | 
       | I am glad, however, that the idea of solar furnace is still being
       | explored. Yesterday I was wondering if such installation could be
       | put on a large ship vessel which would solve problem of year
       | season. Also with our knowledge about tornado formations the ship
       | could be put in places with max solar input.
        
       | habibur wrote:
       | Reading the article I get a feeling that it's more like proof of
       | concept, than a economically feasible project, as there's no
       | mention of costs.
        
       | fl7305 wrote:
       | In my view, it sounds like they're trying to tackle way too much
       | at the same time.
       | 
       | Just the core system that converts input chemicals and heat to a
       | fuel is a major undertaking. Focus on that.
       | 
       | Adding their own mirror system might be doable, but only if they
       | use a well known and simple solution.
       | 
       | Trying to add an "AI drone mirror autocalibration" is a major
       | undertaking, enough to keep a medium sized company busy for a
       | number of years.
       | 
       | Likewise with the "solar energy storage system". Just run when
       | the sun is shining, and produce as much fuel you can from that.
       | 
       | If you have more incoming power from the sun than what you can
       | produce fuel from, concentrate on solving that instead. Or just
       | build something that is economical even if the mirror system is
       | way oversized in order to always keep the fuel conversion busy.
        
       | omneity wrote:
       | At this feeble level of efficiency we're probably better off
       | using the energy to split water into hydrogen or producing
       | ammonia.
       | 
       | It's a trade-off ultimately, either we get to use currently
       | deployed ICE systems and feed them with this solar fuel, or
       | deploy new engines to leverage hydrogen or ammonia based
       | vehicles.
       | 
       | Most probably better to bet on electricity storage tech catching
       | up and just switch everything to full electric.
        
         | jfengel wrote:
         | There are some things that will be tricky to convert, notably
         | airplanes. And it would be convenient to have synthetic gas for
         | driving peaker plants on the occasions where they're needed.
         | 
         | But yeah, ground transport needs to be electrified yesterday,
         | and the grid upgraded to support it. That can be done
         | incrementally, using existing technology.
        
           | omneity wrote:
           | In this case isn't biogas a much better option efficiency-
           | wise?
        
             | cduzz wrote:
             | I think all of these approaches are not "or" but are
             | instead "and" ...
             | 
             | We need both PV solar and "let's get some heat" solar; we
             | need LiFePO4 and nmc batteries; we probably even need to
             | keep fossil fuels and biodiesel and other biogas.
             | 
             | Every little incremental bit helps... It's a race between
             | turning into venus and turning into mad max's thunderdome.
        
               | mdale wrote:
               | I like how mad Max thunderdome is a given at this point
               | and the env work is just to prevent Venus #2
        
               | gwright wrote:
               | > the env work is just to prevent Venus #2
               | 
               | There is no science-based predictions that climate change
               | as we understand it today, will lead to Venus #2. That
               | idea is just fodder for climate hysteria and sci-fi
               | fantasy films.
        
               | gwright wrote:
               | > It's a race between turning into venus and turning into
               | mad max's thunderdome.
               | 
               | It is hard to tell how serious you are in that comment,
               | but just in case, worrying about runaway greenhouse gas
               | effect turning Earth into another Venus is climate
               | hysteria.
               | 
               | Poorly thought out energy policies due to climate
               | hysteria have a good chance at creating considerable
               | political unrest though (not sure about "thunderdome"
               | level of unrest).
               | 
               | Turns out when you restrict access to energy (e.g., by
               | increasing its cost), people get upset.
        
         | narrator wrote:
         | Ammonia will likely not be used for cars and only be used for
         | large industrial applications where there aren't any good
         | alternatives like container ships because it's so toxic. For
         | the same reason we don't have a make semiconductors at home
         | with hydrogen fluoride kit, we won't have ammonia fuel in
         | consumer oriented applications.
        
       | alchemist1e9 wrote:
       | Many years ago I remember seeing this same focused sunlight
       | design being used to generate electricity directly from the heat.
        
       | narrator wrote:
       | "This heat powers a thermochemical reactor that turns CO2, water
       | and methane into syngas"
       | 
       | The methane has to come from biomass, so this isn't quite closing
       | the loop here on a full solar only process. Pure CO2 and water to
       | synfuels is still wildly energy inefficient.
        
         | adolph wrote:
         | When you say inefficient, do you mean that the process results
         | in more entropy than work-producing fuel than another method of
         | recomposing molecules into methane, such as biological
         | processes?
        
           | narrator wrote:
           | If the Hysatas electrolyzer[1] is for real and scales up,
           | making hydrogen is going to get way more efficient. They can
           | make then make synfuels out of hydrogen for about a 40% loss.
           | Eventually, they could put these electrolyzers at major
           | airports and refuel hydrogen planes without having to move
           | the hydrogen much. That's the big weakness of hydrogen is
           | that it can't be moved around easily in pipelines. It can be
           | stored in underground caverns under low pressure for cheap
           | though.
           | 
           | [1]https://hysata.com/news/hysatas-electrolyser-breaks-
           | efficien...
        
             | adolph wrote:
             | Ok, I see two semi-related assertions now:
             | 
             | >>> Pure CO2 and water to synfuels is still wildly energy
             | inefficient.
             | 
             | > If the Hysatas electrolyzer is for real and scales up,
             | making hydrogen is going to get way more efficient.
             | 
             | From the article, Synhelion has a thermal reactor now:
             | solar radiation directed by heliostats into a thermal
             | reactor that feeds a Fischer-Tropsch process. It seems
             | difficult to establish relative efficiency of the whole to
             | the Hysatas electrolyzer which is one component of a larger
             | chain to capture and transmit energy to perform work.
             | 
             | If I were to assume a similar story for Hysatas where
             | photovoltaics feed electricity to electrolyze water and a
             | whole new infrastructure for fuel is stood up: What measure
             | would measure and demonstrate the relative efficiency
             | between the two processes?
        
               | narrator wrote:
               | The finding the biomass to make the methane from is the
               | non-scalable, energy intensive part. You have to collect
               | the biomass, load it on to a truck, ship it around on a
               | truck, and then unload it and dispose of it after it's
               | depleted.
               | 
               | If you only need air, electricity and water to make the
               | synthetic fuel, that's going to be scalable to a
               | civilizational level scale.
        
       | szundi wrote:
       | I'm looking forward to times when this silly technology kills all
       | plants because no CO2 remained in the air but people need fuel
        
       | LMSolar wrote:
       | Several comments... Disclaimer, I work in this space.
       | 
       | a) Surprised that on HN no one has commented on the similarities
       | with Heliogen: https://www.heliogen.com/ This US-based company
       | backed by Bill Gates and Bill Gross similarly focuses on high-
       | temperature heliostat applications, e.g. green hydrogen and
       | concrete etc. They even have similar hexagonal-mirror heliostats.
       | b) Why these CSP startups so often focus on moon-shot 'super
       | hard' applications like the above baffles me. There are LOTS of
       | great applications for lower temperature solar thermal systems -
       | which are much easier to build and operate. Our plastic-molding
       | systems are just one example: http://lm.solar c) It's a little
       | odd to be doing CSP in Germany - Heliostats need collimated light
       | (non-diffuse light, e.g. light that casts a shadow) and Germany
       | has pretty low DNI compared to, say, Morocco. I know the article
       | says they plan to deploy commercially to Spain, but even a test
       | system would be super hard to operate with frequent haze, high
       | cloud layers, etc. To be clear, not saying PV-solar is
       | impractical in Germany - PV can harvest diffuse light just fine.
       | 
       | Funny that the photo of the solar tower / target in the article
       | shows an overcast sky! Global Solar Atlas gives annual average
       | DNI of @ 1000 kWh/M2/year at Julich, which is way low.
       | https://globalsolaratlas.info/detail?c=50.922093,6.361102,11...
       | 
       | I wish them luck, but there are likely more practical, impactful
       | uses for CSP.
       | 
       | PS Re the 'sunlight is free' comments... yes but if your process
       | is very inefficient and/or requires a huge heliostat array then
       | CapEx goes way up (which has to be financed = cost) and then you
       | get into needing automated cleaning robots to keep your array
       | working well (see Ivanpah -
       | https://en.wikipedia.org/wiki/Ivanpah_Solar_Power_Facility ),
       | etc.
       | 
       | The cascading effects of moon-shot application => huge CSP system
       | => problems (high CapEx, huge physical sites, permitting
       | problems, need for automated cleaning etc) are exactly why we're
       | working on industrial uses for SMALL heliostat arrays. And why
       | grid-scale CSP (electric generation) systems generally get
       | trounced by PV+battery systems.
        
       | generuso wrote:
       | If they get some traction, it might be interesting. It reminded
       | me of another project which I have almost forgotten about.
       | 
       | David Doty is a respected name in a narrow circle of nuclear
       | magnetic resonance scientists for the hardware that his company
       | builds [1]. At some point about a quarter century ago, he became
       | obsessed with what he saw as an impending energy crisis, and
       | started to look precisely into the technical nuances and
       | economics of Fischer-Tropsch process. It seemed like a potential
       | solution to turn excess of renewable energy into an energy-dense
       | liquid fuel, which could then be distributed using the already
       | existing infrastructure.
       | 
       | Doty was always exceptionally meticulous in anything he did, and
       | so he went with a fine comb to find and eliminate inefficiencies
       | in the fuel synthesis process, wherever it was physically
       | possible. He funded a small team working on this, and they came
       | up with some improvements [2] which they have patented, presented
       | at conferences, etc. But despite all this work the economics of
       | the process was still not favorable.
       | 
       | [1] https://dotynmr.com/ [2] http://www.dotyenergy.com/
        
       ___________________________________________________________________
       (page generated 2024-06-29 23:01 UTC)