[HN Gopher] Potential ozone depletion from satellite demise duri...
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       Potential ozone depletion from satellite demise during atmospheric
       reentry
        
       Author : nobody9999
       Score  : 135 points
       Date   : 2024-06-13 10:06 UTC (12 hours ago)
        
 (HTM) web link (agupubs.onlinelibrary.wiley.com)
 (TXT) w3m dump (agupubs.onlinelibrary.wiley.com)
        
       | isodev wrote:
       | Very interesting study. I guess putting things in orbit is
       | absolutely going to cost us but I hope we will have this under
       | control before it gets out of hand.
       | 
       | Unfortunately, just like green house gases, it requires the very
       | people who benefit from ignoring these kind of problems to pay
       | attention and well...
        
         | DennisP wrote:
         | One of the main reasons we have governments is to solve those
         | sorts of problems. That's how the ozone problem was
         | successfully addressed before.
        
           | hi-v-rocknroll wrote:
           | The Montreal protocol worked because it was focused on a
           | limit set of changes. Something similar could also work again
           | if metal satellites and uncontrolled hypersonic reentry
           | spaceship metal parts were outlawed as well.
           | 
           | Unfortunately, the lack of a gradual set of limited changes
           | is why the same process cannot be replicated for climate
           | change remediation. Countries are trying to tackle the entire
           | problem as an "impossible" monolith rather than breaking it
           | up into separate industry and lifestyle practices to address
           | incrementally.
        
           | renhanxue wrote:
           | The Montreal Protocol was nothing short of miraculous. It was
           | the first international treaty to be ratified by all 198
           | members of the UN (including the Holy See), and it's been
           | called "perhaps the single most successful international
           | agreement to date" by former UN Secretary General Kofi Annan.
           | It's one of history's greatest achievements of environmental
           | policy and international cooperation.
           | 
           | The impact of CFC's on the ozone layer was first proposed in
           | a scientific paper in 1973; the authors testified before the
           | US House of Representatives in 1974 and significant funding
           | was provided to study the problem. The Montreal Protocol was
           | then signed in 1987 despite industry protests that the
           | research was uncertain and there was no crisis that demanded
           | urgent action. This was only 14 years (!) after the effect
           | was first hypothesized. The discoverers of the effect won the
           | Nobel Prize for chemistry in 1995.
           | 
           | I don't expect to see anything even remotely as successful as
           | the Montreal Protocol in my lifetime.
        
       | boxed wrote:
       | I would have liked an estimate of the natural sources to compare.
        
         | martinclayton wrote:
         | It's in section 3.3.
         | 
         | - Natural Al estimated at 141.1 metric tons / year not varying.
         | 
         | - Human-made: 2016: 5.36 tons, 2022: 41.7 tons, "future" could
         | be 912 tons, i.e. more than 6x natural.
         | 
         | I think the last figure is based on many planned large
         | satellite constellations being deployed.
        
       | golol wrote:
       | If aluminum is the issue, could steel and plastics be a solution?
       | Especially with Starship coming online, weight should be less of
       | an issue.
        
         | justin66 wrote:
         | Anything's possible but the mass of the satellite won't cease
         | to be something they need to optimize, even with a heavier
         | booster. Those little satellites use thrusters themselves when
         | they're in orbit.
        
           | ginko wrote:
           | There's also magnesium alloys, but if MgO is any better in
           | the stratosphere is anyone's guess
        
             | dylan604 wrote:
             | There's a lot of really smart people that understand
             | chemistry at a much better level than the typical reader on
             | an internet forum. Do we really need to "guess"? Seems like
             | we could study this to actually determine what would happen
             | with controlled experiments. One might go so far as to call
             | that the scientific method.
        
               | s1artibartfast wrote:
               | Nope, it is unknowable because ginko doesnt know /s
        
           | kortilla wrote:
           | The thrusters are to offset atmospheric drag, which
           | accumulates with surface area, not mass.
        
             | justin66 wrote:
             | Weird half-true comment. Imaging satellites change their
             | orbits, satellites operating in constellations station-
             | keep, etc.
        
             | roywiggins wrote:
             | More mass still means you get less velocity out of your
             | fuel, even if the drag stays constant.
        
               | ordu wrote:
               | But you also lose less velocity with the same drag.
        
           | DennisP wrote:
           | Since Starship itself is made of steel, it seems possible
           | that the satellites could be as well.
           | 
           | Assuming it's overall heavier, you have to carry more fuel,
           | and then the rocket equation kicks in and you have to carry
           | more fuel than that. That's all extra weight that makes your
           | launch more expensive. But if your cost to launch is $30/lb
           | instead of $1200/lb, you've got the budget for it.
        
             | dr_orpheus wrote:
             | But it's not just the cost of the launch, its also going to
             | be the cost of the satellite itself.
             | 
             | More mass means you need larger reaction wheels (or CMGs)
             | to control the attitude of the spacecraft, larger reaction
             | wheels means you need more power to control those reaction
             | wheels, more power means you need more solar
             | arrays/batteries, more solar arrays means more mass and
             | moment of inertia...which means you need larger reaction
             | wheels and on and on and on.
             | 
             | Often people talk about the "tyranny of the rocket
             | equation" but many other things on a satellite are the
             | "tyranny of other non-linear systems"
             | 
             | You can end up seeing that in companies like K2 Space.
             | Their goal is to take advantage of cheaper launch costs
             | with large, cheap satellites. But if you read in the
             | article [0] they had to do things like develop new reaction
             | wheels in house because "there was not a suitable supply
             | chain for spacecraft bus like Mega Class". Starting from
             | scratch on mechanisms like that for space is not super
             | cheap.
             | 
             | https://spacenews.com/k2-space-plans-first-launch-as-
             | company...
        
         | HPsquared wrote:
         | Or visiting satellites to be deorbited and encapsulating them
         | inside a re-entry vehicle with refractory tiles.
        
       | adrian_b wrote:
       | The Japanese have already been concerned by this problem for a
       | few years.
       | 
       | Their solution has been to develop satellites made mostly of
       | wood, which will burn completely upon reentry.
       | 
       | The first such wooden satellite is planned to be launched in
       | September. It is intended mainly for collecting data about the
       | behavior of wood in the outer space, e.g. on wood expansion,
       | contraction and degradation, along with internal temperature and
       | electronic equipment performance.
       | 
       | An alternative to wood would be the use of synthetic polymers,
       | but those are typically more sensitive to radiation, so more
       | research would be needed for finding a suitable plastic and
       | appropriate additives to decrease the radiation sensitivity.
       | 
       | Wood or plastic would not be suitable for ships hosting humans,
       | because they are not hermetic, but they may be an acceptable
       | choice for satellites with a short lifetime and with much more
       | relaxed constraints for the composition and pressure of the
       | internal atmosphere (which may not be needed at all, e.g. when
       | the internally produced heat reaches the external radiant cooling
       | surfaces through solid paths or through pipes with circulant
       | liquid).
        
         | elil17 wrote:
         | That would be so awesome! Reminds me of the sci-fi book
         | "Children of Time"
        
           | RALaBarge wrote:
           | From the science we do on spider silk, who knows...we could
           | one day see a Spider(Portiid)-derived hull cladding to fit
           | around the lumber!
        
           | will1am wrote:
           | Yeah, the book has thought-provoking take on evolution
        
         | IshKebab wrote:
         | What about something like carbon fibre?
        
           | dr_orpheus wrote:
           | It is used quite a bit in the space industry already. But it
           | is more expensive so it is usually confined to applications
           | where you really need the weight savings, or you need
           | something with a more controlled coefficient of thermal
           | expansion. Thermal expansion of carbon fiber is small so you
           | get less mismatch when you use it with things like optics or
           | as part of solar panels.
           | 
           | And a common place you find carbon fiber in the space
           | industry is actually carbon fiber skinned aluminum honeycomb
           | panels. Very light and very stiff.
           | 
           | https://www.rockwestcomposites.com/shop/plates-panels-
           | angles...
        
         | mafuku wrote:
         | So the Hearthians' timber ships made sense after all
        
         | genpfault wrote:
         | > Their solution has been to develop satellites made mostly of
         | wood, which will burn completely upon reentry.
         | 
         | "When finishing the surface of your wooden satellite you must,
         | of course, use an orbital sander."[1]
         | 
         | [1]: https://www.metafilter.com/203958/Yes-they-wood-build-a-
         | sate...
        
           | hunter2_ wrote:
           | Could just send it into the astral plane.
        
           | wil421 wrote:
           | Just don't use a random orbital sander or you may lose your
           | satellite.
        
         | observationist wrote:
         | Nanocrystalline cellulose (NCC) could be a great constituent
         | component of a composite material. Not only would it burn, but
         | anything that doesn't burn and makes it to the surface is
         | biodegradable; there's lots of stuff that eats cellulose. NCC
         | can be formed into highly strong and rigid structural pieces,
         | or combined with carbon fiber, fiberglass, hemp, or other
         | fibers to create ultra strong and durable composite material.
         | high mechanical strength, with a tensile modulus of
         | approximately 150 GPa and a modulus of elasticity ranging from
         | 18 to 50 GPa. CNCs also exhibit excellent thermal stability,
         | undergoing gradual thermal transitions and decomposition
         | between 150 degC and 600 degC
        
         | tivert wrote:
         | > Their solution has been to develop satellites made mostly of
         | wood, which will burn completely upon reentry.
         | 
         | I like how the Google image search for "japan wooden satellite"
         | (https://www.google.com/search?q=japan+wooden+satellite&udm=2)
         | is gummed up with garbage AI generated images of satellites
         | with wooden solar panels. This wooden Borg cube with off-kilter
         | panels is my favorite:
         | https://indianspacetechnology.com/wooden-satellite-
         | lignosat-.... This one is also great:
         | https://www.universetoday.com/161473/building-a-satellite-
         | ou.... I guess the satellite went back in time to the
         | Cretaceous period, where North America had an inland sea?
         | 
         | The future is looking bright, guys!
        
           | quasse wrote:
           | Kagi returns basically the same result set including the AI
           | generated slop, which is disappointing.
        
             | tivert wrote:
             | I'm not sure how they could do any better. AI is enabling
             | the degradation of the public web, and that's what they
             | search.
             | 
             | Pretty soon the web's going to be one big Mikkelsen Twins
             | ebook.
        
               | lstamour wrote:
               | Well, here's an actual photo they could have used: https:
               | //www.japantimes.co.jp/news/2024/05/29/japan/science-h...
               | 
               | And here is an earlier rendering from 2021: https://www.j
               | apantimes.co.jp/news/2021/12/31/national/japan-...
               | 
               | And it only took a simple Google search to find, from a
               | reputable news source.
        
           | shadowgovt wrote:
           | Without AI you'd still be looking at dozens of artists'
           | mockups of wooden satellites because they have to put
           | _something_ at the top of the blog post or news article to
           | catch viewer attention.
        
         | will1am wrote:
         | But sill wood usage does have an impact on the environment too
        
           | blackguardx wrote:
           | So does corn. In fact much of the wood used in construction
           | in the US is grown like corn in a cornfield.
        
           | whatevaa wrote:
           | Everything you do does. Question is how much.
        
           | s1artibartfast wrote:
           | I assume you mean the high atmospheric particulate. It would
           | be interesting to see how this compares
        
         | pdabbadabba wrote:
         | It's an interesting effort, but the supposed issue addressed in
         | the paper is not that aluminum does not fully burn up during
         | reentry. It generally does, just like wood. It's that, when it
         | does so, it releases alumina.
         | 
         | Maybe this is better because the vaporized wood would. not
         | release any alumina. But you'd then have to look at the impact
         | of _wood 's_ combustion products when introduced directly to
         | the upper atmosphere. I'm not sure anyone has seriously studied
         | that question.
        
       | jl6 wrote:
       | I couldn't see a quantitative estimate of how much ozone would be
       | depleted in a typical year as a result of the extra catalyst
       | being present. If it's only ~hundreds of tons, that seems both
       | immaterial (there are about 3 billion tons of ozone in the
       | atmosphere currently) and potentially easy to replace (fly up
       | there and dump some fresh ozone).
        
         | gmm1990 wrote:
         | I think it says its a catalyst, for some chlorine reaction. So
         | its not out of the question 300 tons (per year) could effect
         | ozone concentrations.
        
           | marcosdumay wrote:
           | There's absolutely no estimation of the impact. Your 300 tons
           | of activated chlorine per year idea is as baseless as the
           | GP's 300 tons of ozone, but the GP is aware that his number
           | is a complete invention.
           | 
           | Any exercise in making numbers out of nothing is completely
           | useless.
           | 
           | (Besides, is chlorine activation really a bottleneck in ozone
           | depletion? AFAIK it gets activated by UV light quite
           | quickly.)
        
             | gmm1990 wrote:
             | GP never implied the amount of ozone just the amount of
             | aluminum oxide. All I know is catalysts can speed up
             | reactions by orders of magnitude. CFCs actually created a
             | hole in the ozone layer so its not like human activities
             | haven't accidentally created problems before. Probably
             | something that at least needs to be ruled out.
        
               | oasisbob wrote:
               | Correct. That's the same way I read that comment.
               | 
               | More fundamentally, chemical catalysts by definition are
               | not consumed by the reactions they catalyze.
               | 
               | Think: a cheese grater. It doesn't react with the cheese,
               | so a few ounces of grater could make hundreds of pounds
               | of grilled cheese.
               | 
               | A hypothetical 300 tons of catalyst is not limited
               | stoichiometrically to how much substrate it would affect.
        
         | ldoughty wrote:
         | If starlink thinks it may have 40,000 satellites at full
         | capacity[1] .. and we expect at least 1 if not 2 competitors..
         | 
         | With a 5-year lifespan for an LEO sat, that's potentially
         | 120,000 deorbits every 5 years...
         | 
         | That will add up quickly... I don't know the science of
         | aluminum oxide increase to ozone depletion.. but this can
         | certainly warrants more research and consideration
         | 
         | 1: https://starwalk.space/en/news/spacex-starlink-satellites-
         | ni...
        
           | aftbit wrote:
           | https://www.antipope.org/charlie/blog-static/2024/05/on-
           | mist...
        
           | AtlasBarfed wrote:
           | Can't they spray some ozone as they deorbit?
        
             | s1artibartfast wrote:
             | No, but I imagine they could include some other solid mass
             | that has a counter effect.
        
           | mathsmath wrote:
           | The satellites are typically much smaller than historic
           | satellites. I think ~50-60 are launched in a fairing that
           | would house 1 or two older-style satellite.
           | 
           | Does the mass make a difference?
        
             | kemotep wrote:
             | All of those starlinks are designed to burn up though. And
             | there will be many thousands more of them then there ever
             | was of those older larger satellites.
        
           | happyopossum wrote:
           | Why would the number of satellites be pertinent here? It's a
           | mass problem, and starlink satellites are tiny compared to
           | most of the satellites that are up there.
        
             | whoknowsidont wrote:
             | Many little number make big number. Mhmmm.
        
           | s1artibartfast wrote:
           | Im guessing it would make sense to release more pro ozone
           | catalyst. It may even be an option to release more it from
           | the ground, as an inverse to CFCs.
           | 
           | NOx is also has a global cooling effect, taking the edge off
           | climate change.
           | 
           | NOx and VOCs from power plants and diesel vehicles produce
           | ozone.
        
         | BurningFrog wrote:
         | Catalysts don't get consumed by the reactions they facilitate,
         | so the weight of the catalyst compared to the ozone doesn't say
         | much about the effect.
         | 
         | For example, consider that a car exhaust catalyst contains ~5
         | grams of platinum, and AFAIK, that doesn't really "wear out".
        
       | pwndByDeath wrote:
       | I'm no chemist but I noticed this other researcher wanted to dump
       | literal tons of another oxide into the atmosphere to counteract
       | global warming.
       | 
       | https://iopscience.iop.org/article/10.1088/1748-9326/aae98d/...
        
         | elil17 wrote:
         | An oxide is just a molecule with one oxygen atom and one other
         | element. Different oxides would have different effects on
         | atmospheric chemistry.
        
           | astrodust wrote:
           | "Nitrous oxide best oxide." -- Dominic Toretto
        
         | dmbche wrote:
         | See "Snowpiercer"
        
         | selimthegrim wrote:
         | see https://news.ycombinator.com/item?id=37344251
        
         | datameta wrote:
         | To geoengineer or not to geoengineer, that is the question. Can
         | we build models that six nines assure us of a small stable
         | improvement that stays near linear behavior, or asymptotic
         | better yet?
        
       | londons_explore wrote:
       | One option is to make the satellite survive re-entry rather than
       | burn up. Then just re-enter over a desert like australia or the
       | sahara so you can go find and collect the junk.
       | 
       | Single-use heat shields for smallish things like satellites are
       | quite easy I believe, although fold-out items like solar panels
       | would need to be designed to fold-in again.
        
       | ferfumarma wrote:
       | Please fine the companies who did this. This is a global problem
       | that affects everyone, but especially those of us in Australia.
        
         | pdabbadabba wrote:
         | Just so you know, the comment immediately below yours proposes
         | a solution where satellites are designed not to burn up at all
         | and are aimed at Australia during reentry.
         | 
         | > One option is to make the satellite survive re-entry rather
         | than burn up. Then just re-enter over a desert like australia
         | or the sahara so you can go find and collect the junk.
         | 
         | So be careful what you wish for!
        
           | idiotsecant wrote:
           | Parent post: won't someone please think of Australia!!!!
           | 
           | Global military industrial complex: Now that you mention
           | it...
        
       | Culonavirus wrote:
       | Manufactured outrage.
        
         | hi-v-rocknroll wrote:
         | Maybe or maybe not. I want to know what "significant" means in
         | terms of stratosphere effects in DU/km^2 per kg of aluminum
         | oxide.
        
       | ck2 wrote:
       | Privatize the profit (and government helps pay for development)
       | then socialize the cleanup costs.
       | 
       | Why doesn't every messy industry like this have to pre-pay
       | massive insurance fees ahead of time for known and unknown
       | damages?
       | 
       | Note X isn't the only one with thousands of satellites, there are
       | several startups that are launching their own thousands. Soon
       | we'll have debris and burnup of dozens a day, that will add up.
        
         | mathsmath wrote:
         | It's kind of like the industrial revolution. I don't think
         | anyone knows what will happen (it's the classic human behavior
         | of kicking the problem down the road), but the collective human
         | mind has decided we want global connectivity now that it's
         | cheap.
         | 
         | I can't see the cat going back into the bag (or reengineered)
         | unless there have been proven negative results like the ozone
         | hole directly linked to CFCs.
        
       | selimthegrim wrote:
       | Other work on this from January but focusing on temperature in
       | stratosphere: https://arc.aiaa.org/doi/abs/10.2514/6.2024-2169
        
       | sandworm101 wrote:
       | How about just not letting them burn up? Give the core an organic
       | heatshield (wood?) and let it crash into the ocean. Even
       | thousands of them each year would be nothing compared to the
       | amount of waste regularly dumped into the oceans, an acceptable
       | compromise over ozone depletion.
        
         | BurningFrog wrote:
         | If thousands of intact satellites crash to Earth yearly, they
         | will hit and kill people, even just over the oceans.
         | 
         | People will also be upset about the environmental damage, real
         | or imagined.
        
           | sandworm101 wrote:
           | Thousands of small rocks fall from space every year, have
           | done so for a very long time. Human deaths are almost unheard
           | of.
        
             | mathsmath wrote:
             | Not only this, but they fall in a randomly-distributed
             | fashion. Most satellites are still under control and
             | steered to a predetermined area for reentry over the South
             | Pacific.
        
               | dr_orpheus wrote:
               | > Most satellites are still under control and steered to
               | a predetermined area for reentry over the South Pacific.
               | 
               | This is not true, most satellites do not perform
               | controlled re-entry. In order to perform controlled re-
               | entry, you need to have enough thrust to perform the
               | final de-orbit maneuver in a short amount of time before
               | you get so low that you start to lose attitude control of
               | the spacecraft and wouldn't be able to guarantee you are
               | firing your thrusters in the correct direction. To do
               | this in a short amount of time means you need a high
               | thrust system, in other words a chemical propulsion
               | system and not electric propulsion.
               | 
               | All of the Starlink satellites use electric propulsion to
               | do their de-orbit so they are performing uncontrolled re-
               | entry. NASA's Orbital Debris Mitigation Standard
               | Practices (ODMSP) say that you can perform uncontrolled
               | re-entry if the probably of casualties on the ground is
               | less than 1 in 10,000. There are NASA analysis tools that
               | are used to do that assessment of what kind of debris
               | would survive re-entry. This is likely getting updated in
               | the near future to be more conservative though as there
               | was recently a piece of an old ISS battery they thought
               | would burn up hit someone's house in Florida:
               | 
               | https://spacenews.com/uncontrolled-reentry-of-space-
               | debris-p...
        
               | mathsmath wrote:
               | I had to check, but you're not wrong - only 47% of total
               | are controlled re-entries. (https://en.wikipedia.org/wiki
               | /Spacecraft_cemetery#cite_note-...)
               | 
               | I thought I recently read about a law requiring a de-
               | orbit plan for anything launched. I would assume if most
               | of the mass doesn't burn up (Starlinks mostly burn up),
               | it would require them to hit the South Pacific patch or
               | similar.
        
       | will1am wrote:
       | I think as we continue to expand our use of space, it is crucial
       | to consider the environmental impacts!
        
       | LeifCarrotson wrote:
       | > _We find that the population of reentering satellites in 2022
       | caused a 29.5% increase of aluminum in the atmosphere above the
       | natural level, resulting in around 17 metric tons of aluminum
       | oxides injected into the mesosphere..._
       | 
       | On the scale of the planet, that's incredibly tiny. 17 metric
       | tons of aluminum oxide can be made by oxidizing a cube of
       | aluminum about 1 meter on a side. The catalytic action must be
       | incredibly potent!
       | 
       | Wolfram helpfully tells me that the mass of the mesosphere is on
       | the order of 10^12 tons, so that's on the order of parts per
       | trillion.
        
         | shadowgovt wrote:
         | It's tiny, but it may be enough if the wind currents are
         | concentrating it, as happened with CFCs doing away with the
         | ozone layer over the South Pole.
        
       | yourMadness wrote:
       | Is there even an estimate of the impact on ozone in the paper?
       | 
       | You don't need a science paper to end up with "letting satellites
       | burn up in the atmosphere results in burned satellite dust in
       | atmosphere", do you?
        
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       (page generated 2024-06-13 23:01 UTC)