[HN Gopher] Cement recycling method could help solve one of the ...
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       Cement recycling method could help solve one of the big climate
       challenges
        
       Author : timthorn
       Score  : 131 points
       Date   : 2024-05-23 18:03 UTC (4 hours ago)
        
 (HTM) web link (www.cam.ac.uk)
 (TXT) w3m dump (www.cam.ac.uk)
        
       | gnabgib wrote:
       | There was some discussion yesterday [0] (21 points, 4 comments)
       | 
       | [0]: https://news.ycombinator.com/item?id=40446764
        
       | dr_dshiv wrote:
       | Incredible! They use a massive arc furnace (used for steel
       | recycling) to recycle concrete. They suggest that solar power
       | could power the arc furnaces, resulting in zero emission
       | concrete. As concrete currently constitutes 7.5% of anthropogenic
       | carbon emissions, this tech could make a big difference.
       | 
       | Arc furnaces are crazy energy intensive. But if solar power keeps
       | doubling every 2 years, we will very soon have way more power
       | than we know what to do with (at certain times in the day). Arc
       | furnaces are a good way to suck up the negative electricity spot
       | prices!
        
         | tempestn wrote:
         | Often the problem with using excess solar capacity is that the
         | capital cost of the thing that would use it (desalination
         | plants are one example) is so great that it's not cost
         | effective to leave them idle at other times of the day. Any
         | idea whether that would be the case with these arc furnaces as
         | well?
        
           | ahi wrote:
           | IANAMetallurgist. Arc furnaces for steel making already rely
           | on cheaper off peak power, so utilization is already a
           | factor.
        
             | s1artibartfast wrote:
             | I didn't think they varied their use pattern by time of
             | day.
             | 
             | They might rely on cheaper power to lower the average cost
             | make financial sense, but that is a different than soley
             | utilizing excess power.
             | 
             | If they cant rationalize the opex running 8 hours a day,
             | there is still a problem. My understanding is that many of
             | these plants cant even shut down and be restarted.
        
               | kragen wrote:
               | the normal kind of arc furnaces are shut down many times
               | a day; it's a batch process, not a continuous one
        
               | s1artibartfast wrote:
               | Do they operate 24/7?
               | 
               | Even if it is batch process, going from 24 hours to 8
               | hours is like tripling plant cost vs productivity.
        
               | colechristensen wrote:
               | You may be thinking of aluminum plants which can't be
               | shut down and restarted without significant damage, but
               | they are indeed still throttled up and down. In that case
               | it's electrochemistry at high temperatures to strip the
               | oxygen off of aluminum. If it gets cold the apparatus
               | gets damaged, but it can be throttled down a significant
               | percentage.
        
               | avianlyric wrote:
               | Arc furnaces tend to be first in line to voluntarily
               | shutdown to deal with grid instability, or projected
               | power shortages. Network operators will basically pay
               | them equivalent amount of money as they would to buy
               | electricity, if the furnace operator is happy to shutdown
               | at a moment's notice.
               | 
               | After, to a power grid, removing large loads are
               | functionally equivalent to adding additional generation.
               | So if you're operating an arc furnace, and can shutdown
               | quickly (which arc furnaces can), then grid operators
               | will pay you for _privilege_ of being able to shut you
               | down at moments notice, and then pay even more for the
               | electricity you're not consuming, if the grid is forced
               | to call upon that additional "capacity" due other issues
               | on grid.
               | 
               | I'm not sure if arc furnaces today vary their usage in
               | direct response to variable electricity prices through
               | the day, rather than only acting as emergency ballast to
               | be jettisoned in an emergency. But I would be very
               | surprised if they didn't, they're a large enough load
               | that they'll have coordinate the usage with their local
               | grid, and large enough that shifting the usage pattern to
               | avoid high cost peaks would save them a very material
               | amount of money.
        
             | Gibbon1 wrote:
             | This is one of the reasons I believe 'base load' demand is
             | more fungible than people assume.
             | 
             | I think in California 6% of electricity demand is pumping
             | water. I'm almost willing to go on record and say that's
             | the California Aqueduct and the actual number is higher.
             | Okay I'm going to look.
             | 
             | https://www.ppic.org/publication/water-and-energy-in-
             | califor...
             | 
             | > The water system uses approximately 20% of the state's
             | electricity and 30% of its natural gas for business and
             | home use, according to data from 2001--accounting for more
             | than 5% of California's greenhouse gas emissions.
        
               | samatman wrote:
               | Did you miss the stat directly underneath that?
               | 
               | > _Heating and other energy-intensive water uses in homes
               | and businesses make up almost 90% of water-related energy
               | use, while treatment, pumping, and conveyance of water
               | and wastewater account for the rest._
               | 
               | That's 2% for everything which isn't heating water.
               | Pumping is some smaller fraction of that.
        
               | abakker wrote:
               | you are right. The thing that is interesting is that
               | pumping loads overall take a lot of the grid's energy,
               | it's just that most pumps are refrigeration loads, not
               | water transport.
        
               | avianlyric wrote:
               | Great thing about heating water, is that it stays hot
               | after you've heated it.
               | 
               | Water heating is basically the poster child for "demand-
               | response" technologies. You can easily heat your water a
               | few hours earlier than normal with basically no
               | consequences to the user. But you need to get reasonable
               | smart about modelling people water usage, as people don't
               | tend forget or forgive a cold shower.
        
           | kragen wrote:
           | i didn't know what ahi said (that minimills already depend on
           | cheap off-peak power) but intuitively i would expect an arc
           | furnace to be pretty cheap compared to the power it uses;
           | it's just a water-jacketed chamber lined with castable
           | refractory with a lid with three big carbon electrodes
           | lowered through it, and all of those are cheap materials and
           | low-precision (tight tolerances won't withstand white-hot
           | flaming steel for long). the machinery is large and heavy,
           | but only in proportion to the volume of material it
           | processes. the electrical energy consumption, on the other
           | hand, is comparatively enormous
           | 
           | (admittedly maybe the capex for running the power lines to
           | the facility is significant, but in the same proportion to
           | the cost of the energy used as running transmission lines
           | anywhere else)
           | 
           | there's a nice video illustrating the process at
           | https://www.youtube.com/watch?v=T1CJ5NPW8MU. don't be
           | alarmed, the part that looks like a major industrial accident
           | is just what happens normally when they turn it on. a more
           | detailed documentary with explanations, though unfortunately
           | of an atypically large arc furnace, is in
           | https://www.youtube.com/watch?v=eZRuVEfxIVI
           | 
           | in that particular case they say it runs 24/7
        
         | abdullahkhalids wrote:
         | The important thing here is that it only recycles concrete.
         | Most of the 7.5% emissions are from new concrete constructions
         | - new roads and new buildings - as we increase the total
         | concrete in use. Very little is from old buildings/roads being
         | destroyed and then replaced by something else.
         | 
         | This will make a small dent in the 7.5% at scale.
        
           | marcosdumay wrote:
           | Once you solve energy producing and handling, 100% of the
           | remaining is composed of tiny little problems.
           | 
           | This one is large enough for several companies to make a
           | living. What means it's large enough to care about.
        
           | s1artibartfast wrote:
           | I dont understand your point. Are you saying there isnt
           | enough recyclable concrete to meet the demand for new
           | construction?
           | 
           | If we create half as much concrete waste as demand, that 7.5%
           | could drop by half.
        
             | trimethylpurine wrote:
             | Home Depot seems to suggest that old concrete is already in
             | high demand. If we need it for roads and we can't get it
             | because concrete is more valuable, now we have to go find
             | road building materials. Is the manufacture of road
             | building materials cleaner than concrete?
             | 
             | https://www.homedepot.com/c/ah/how-to-dispose-of-
             | concrete/9b...
        
               | s1artibartfast wrote:
               | I dont think that suggests there is a high demand for
               | used concrete. It does however highlight the fact that
               | there may be insurmountable transportation and handling
               | costs for recycled concrete.
               | 
               | It is hard to imagine it being cost effective to
               | transport it to recycling centers.
        
         | 3abiton wrote:
         | What's the catch
        
         | mechhacker wrote:
         | Nuclear has a large heat source (or can make a large heat
         | source instead of converting to electric first) to do a lot of
         | things like this.
        
           | Animats wrote:
           | Nope. Nuclear isn't hot enough. Only about 315degC at the
           | output end. Electricity, though, has no thermodynamic upper
           | limit on what temperature can be generated.
        
           | bruckie wrote:
           | Is there a cost effective way to move that heat to where it
           | could be used?
           | 
           | Nuclear reactors can produce very high temperatures, but in
           | most reactors the heat is moved to turbines using water. Are
           | there ways to move the heat at the high temperatures required
           | to melt steel? (AFAIK, even molten salt is too cold.)
        
         | seventyone wrote:
         | How does this address the emissions of concrete's curing
         | process? There's no way you can have "zero emission concrete".
         | I've seen proposed additives that will reduce the emissions
         | during the curing process but that chemical reaction is going
         | to have to happen regardless.
        
           | bobfromhuddle wrote:
           | Concrete absorbs co2 while curing. It's the calcination
           | process, where we heat limestone up until the co2 burns off,
           | that has unavoidable emissions. Since this concrete is
           | recycled, that's already happened.
        
         | logtempo wrote:
         | It's math time, let's look what wikipedia say about electric
         | arc furnace:
         | 
         | - 1.44 gigajoules (0.4MWh) is required for 1 ton of steel. In
         | theory.
         | 
         | - 300T of steel needs 132 MWh, and a "power-on time" (the time
         | that steel is being melted with an arc) of approximately 37
         | minutes.
         | 
         | ---- wikipedia end -----
         | 
         | From https://ourworldindata.org/grapher/electricity-prod-
         | source-s...: total world electricity from renewable was
         | 10,700TWh in 2021. 11,600 TWh in 2023.
         | 
         | 1.5 billions (metric) tons of crude steel were produced in
         | 2023. 30% of it by electric power.
         | 
         | ------------------------
         | 
         | (A) Let's assume that 20% of those 30% already come from
         | renewable (which is not the case, anyway). 30x20% is 6%. It
         | means 24% of the 1.5 billions tons are looking for renewable.
         | 
         | It means 360 millions of tons needs its green energy.
         | 
         | It means we need to find 360 millions x 0.4MWh = 144 TWh.
         | 
         | If we don't assume (A), we get 152 TWh.
         | 
         | It means we need to dedicate ~1.5% of renewable worldwide
         | energy to replace 24% of crude steel "e-production". In
         | theory...
         | 
         | We observed +5% of renewable energy production worldwide. If we
         | wanted to make the steel *production* go green (1.5*3.33 = 5%),
         | in theory it could be possible in one year...in theory.
         | 
         | Tbh, I expected a more crazy conclusion. I'm quite sure the
         | number is off by more than 10% though. But even if it was off
         | by 100%, it would mean it's possible in 2 years.
         | 
         | On a side note: it's useless anyway if those 5% are not coming
         | with a decrease of 5% of coil&gas consumption. Which is not
         | what's happening...
         | 
         | Feel free to redo the math, I can make a mistake!
        
         | Hooray_Darakian wrote:
         | > But if solar power keeps doubling every 2 years, we will very
         | soon have way more power than we know what to do with
         | 
         | How soon is soon to you?
         | https://www.eia.gov/todayinenergy/detail.php?id=50357
        
       | ben_w wrote:
       | Nice, this was one of the bigger things I have on my "I hope
       | someone knows how to solve this" pile.
        
         | mandibeet wrote:
         | What else is in that pile?
        
           | dylan604 wrote:
           | Creating clean energy with fusion, desalinating salt water
           | for near limitless clean water, reducing plastic use, curing
           | cancer and on and on and on
        
             | ant6n wrote:
             | Black holes, portals, FTL, electoral reform...
        
             | darknavi wrote:
             | > desalinating salt water for near limitless clean water
             | 
             | Don't forget the free salt!
        
       | sandworm101 wrote:
       | >>The Cambridge researchers found that used cement is an
       | effective substitute for lime flux
       | 
       | So they can only "recycle" this concrete as a substitute
       | ingredient during steel making? That cannot scale. We would have
       | to start making epically more amounts of steel in order to
       | process even 1% of the concrete that we would want to recycle.
        
         | j2bax wrote:
         | Is there a reason they couldn't just reuse the same steel over
         | and over just to process the cement at scale?
        
           | sandworm101 wrote:
           | Lime is used to remove impurities from the melt. So I imaging
           | they would have to re-add those impurities each time. I doubt
           | that would be energy-efficient.
        
           | dylan604 wrote:
           | The industries in the Steel Belt liked your post
        
           | bell-cot wrote:
           | Very likely no - so long as electrical power is free-ish.
           | Because if they aren't actually producing X units of steel
           | along with Y units of cement in each batch, then they'll have
           | to pay for the whole thing out of just the cement sale
           | revenues.
        
         | zharknado wrote:
         | No, they sub it for lime flux, which had the side effect of
         | reactivating the cement (makes "clinker"), which can then be
         | used again in new concrete.
         | 
         | Pretty cool hack!
        
       | adolph wrote:
       | Seems like the "big if feasible" part is reducing concrete to
       | hydrated cement paste.
       | 
       | From actual paper:
       | https://www.nature.com/articles/s41586-024-07338-8
       | 
       |  _Recovered cement paste (RCP) is not commercially available at
       | scale at present. . . . The value of the improved recovered
       | aggregates is not at present high enough to cover the extra cost
       | of processing, so RCP is currently landfilled. However, the know-
       | how and the technologies required to produce RCP at scale exist.
       | [22]_
       | 
       | 22. Thermomechanical beneficiation of recycled concrete
       | aggregates (RCA):
       | https://www.sciencedirect.com/science/article/pii/S095006182...
       | 
       | The cited paper does not support the assertion that tech to
       | recycle concrete into RCP exists. The paper discusses removing
       | adhered mortar (AM) from recycled concrete aggregate (RCA).
        
       | mandibeet wrote:
       | Cement production is a significant contributor to global carbon
       | dioxide emissions. Amazing that the development of effective
       | cement recycling methods is in process.
        
       | magicalhippo wrote:
       | Another way is to build stuff that doesn't have to be torn down
       | after 10 years. Quite a lot of large concrete buildings in town
       | have been torn down less than 20 years, some just 10.
       | 
       | Seems quite wasteful, surely there's a better way with some
       | planning and foresight.
        
         | hcarvalhoalves wrote:
         | ... or already build planning for tear down. Steel and wood.
        
           | magicalhippo wrote:
           | Yea that's what I was thinking of. Either switch materials or
           | build with future use in mind.
           | 
           | We've recently gotten a fairly large wooden tower[1] here in
           | Norway, will be interesting to see how it fares in this
           | regard.
           | 
           | [1]: https://www.architecturaldigest.com/story/worlds-
           | tallest-tim...
        
             | card_zero wrote:
             | Nice. That's only 5 feet shorter than the (steel-framed)
             | Flatiron Building.
        
       | onlypassingthru wrote:
       | It may not be a panacea, but using busted up chunks of concrete
       | in gabions is a great way to re-use an otherwise worthless
       | material. For those who don't like the aesthetic of _post-
       | industrial wasteland_ , just use the concrete chunks in the
       | interior of the gabion and put the pretty rocks on the exterior
       | faces so that no-one will ever know your beautiful gabions are
       | filled with demolition debris.
        
         | ksenzee wrote:
         | But the point of the article is that used concrete is no longer
         | a worthless material, because it can now be recycled, which
         | avoids the huge carbon impact of manufacturing new concrete.
        
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