[HN Gopher] The semiconductor industry hinges on a quartz factor...
       ___________________________________________________________________
        
       The semiconductor industry hinges on a quartz factory in North
       Carolina
        
       Author : speckx
       Score  : 104 points
       Date   : 2024-03-25 16:24 UTC (6 hours ago)
        
 (HTM) web link (www.tomshardware.com)
 (TXT) w3m dump (www.tomshardware.com)
        
       | chasil wrote:
       | There have been past articles on this subject.
       | 
       | 2009:
       | https://throughthesandglass.typepad.com/through_the_sandglas...
       | 
       | 2013: https://siliconmountain.wordpress.com/2013/10/29/ultra-
       | pure-...
       | 
       | 2018: https://www.wired.com/story/book-excerpt-science-of-ultra-
       | pu...
       | 
       | 2019: https://www.bbc.com/future/bespoke/made-on-earth/how-the-
       | chi...
        
       | nerpderp82 wrote:
       | Goldman Sachs should buy them out.
        
         | whycome wrote:
         | Nah. Morgan Stanley. Diversification. They're the ones that
         | bought all the Chicago parking meters.
        
           | nerpderp82 wrote:
           | Ideally it would be a private equity, so they would be immune
           | from reporting obligations.
        
           | jimbob45 wrote:
           | https://en.wikipedia.org/wiki/Chicago_Parking_Meters
           | 
           | for those not in the know. Chicago basically sold all revenue
           | from their parking meters to Saudi Arabia for the next 75
           | years. Not basically, that is exactly what happened.
        
             | lukan wrote:
             | "Chicago basically sold all revenue from their parking
             | meters to Saudi Arabia for the next 75 years."
             | 
             | According to your wiki link, only 25% are owned by a Saudi
             | Arabian company. The rest is mostly US.
             | 
             | Or is Morgan Stanley owned by Saudi Arabia now?
        
               | jimbob45 wrote:
               | TL;DR: it's complicated[0]. Also, you're right - I'm
               | mistakenly conflating SA with the UAE.
               | 
               | [0]https://www.reddit.com/r/chicago/comments/164hefi/comm
               | ent/jy...
        
             | shtack wrote:
             | Similarly the Canadian province of Ontario leased it's only
             | toll highway for 99 years to an international group, for an
             | amount it currently earns in tolls every ~2 years. Fun.
        
               | MadnessASAP wrote:
               | You're missing the bigger picture though. By doing so
               | they managed to look like they had balanced the budget in
               | an election year. That's what really matters here.
        
               | quickthrowman wrote:
               | Earns, or receives in revenue?
               | 
               | 'Earns' implies net profit after all expenses (including
               | operations and maintenance), which I find hard to believe
               | in this specific case.
        
             | selectodude wrote:
             | Abu Dhabi isn't in Saudi Arabia.
        
             | dragonwriter wrote:
             | The UAE is a completely different country than Saudi
             | Arabia, the article doesn't mention Saudi Arabia at all, it
             | claims that the sovereign wealth fund of the Emirate of Abu
             | Dhabi in the UAE indirectly owns ~25% of the company that
             | bought the parking revenue, and the article's total of
             | direct ownership claims adds up to 123.408%, which is
             | somewhat improbable and calls into question the other
             | ownership claims.
        
             | HarHarVeryFunny wrote:
             | Interesting - paid $1.15B and currently up $0.5B with 60
             | years to go, so the meters are generating $1.65B per 15
             | years, which'll be $8.25B (assuming no price increases)
             | over the 75 years.
             | 
             | If you do the math, going from $1.15B to $8.25B in 75 years
             | is only a 2.66% annual rate of return.
             | 
             | I wonder if the Saudi's saw this as a good investment, or a
             | good PR deal ?
        
               | lotsofpulp wrote:
               | Why assume no price increases? Also, parking meters in a
               | car centric region seem like they would be closer to
               | government bonds than equities in terms of risk profile,
               | so the return would need to be compared to something like
               | that.
        
               | HarHarVeryFunny wrote:
               | I just meant the math assumes no price increases. I'd
               | have to guess that there are some agreed-upon price
               | increases in the deal (2.66% too unattractive), and I see
               | there was a recent failed lawsuit by Chicago drivers
               | protesting high prices (downtown $7/hr), so they probably
               | have gone up.
        
             | 0cf8612b2e1e wrote:
             | I don't live there any more and that still makes my blood
             | boil. I especially loved the politicians who voted in favor
             | and claimed they did not have time to read the legislation.
             | "I'm not corrupt, just incompetent"
        
         | tivert wrote:
         | > Goldman Sachs should buy them out.
         | 
         | And sell it to China for a tidy profit.
        
       | sethammons wrote:
       | The quartz being formed when Africa and North Carolina were one
       | and pressed up against one another is really neat. Similar, NC is
       | the only major source in the US for emeralds for the same reason.
        
       | hn_throwaway_99 wrote:
       | These types of articles/pronouncement always tend to make a
       | connection that is nearly never warranted. That is, the article
       | quotes this tweet that says "The modern economy rests on a single
       | road in Spruce Pine, North Carolina. The road runs to the two
       | mines that is the sole supplier of the quartz required to make
       | the crucibles needed to refine silicon wafers." But the first
       | sentence doesn't really follow from the second.
       | 
       | That is, even if all the silicon wafers are made from this quartz
       | from NC today, it's not really because that is the only possible
       | option, it's because that quartz is the highest quality that can
       | be procured at a relatively low price. But if that factory and
       | quarry went away tomorrow, I have no doubt that the worldwide
       | semiconductor industry would quickly adjust to a different quartz
       | supplier.
       | 
       | I think it's still a very cool factoid, but the subtext that "the
       | whole world economy 'hinges' on a teeny NC town" is false.
        
         | chasil wrote:
         | This is addressed at the end of the article.
         | 
         | "...Mollick makes it clear in his social media thread that,
         | yes, fully synthetic techniques are available to create
         | similarly pure quartz. However, any sudden closure or
         | interruption of the mining at Spruce Pine would likely cause
         | "pretty catastrophic" disruption (and extra expense) for a few
         | years as the industry scales up manufacturing."
         | 
         | I understand that 25% of all neon production was coming out of
         | Mariupol, Ukraine (and another 25% out of Odessa) prior to the
         | war. It would be interesting to see how the industry coped with
         | a 50% loss of supply.
         | 
         | https://www.reuters.com/technology/exclusive-ukraine-halts-h...
        
           | hn_throwaway_99 wrote:
           | Even then, I disagree with the characterization in that last
           | sentence.
           | 
           | When billions (trillions?) of dollars are on the line, people
           | and organizations tend to move with a degree of urgency not
           | seen in the normal course of business.
        
             | MenhirMike wrote:
             | I agree that it wouldn't be catastrophic, but we just saw a
             | semiconductor shortage during COVID. For a lot of us end-
             | users, that mainly meant that we couldn't get a Raspberry
             | Pi, but it did affect some industries where a lot of Micro-
             | controllers (including simple 8-bit AVRs) and even stuff
             | like ADC/DACs weren't available at all or only for way
             | jacked up prices for a while. I think the automotive
             | industry also suffered from that despite all their money
             | because they couldn't just swing a magic wand to make a
             | chip foundry appear in their backyard.
             | 
             | But in the end, everything was fine because as you say,
             | eventually everyone is going to move.
        
               | TylerE wrote:
               | It doesn't sound like this would cause any short term
               | pain really, just make it harder to spin up new capacity.
        
               | dopylitty wrote:
               | Was everything fine in the end?
               | 
               | We would probably never hear about it if for a completely
               | made up example an extra 10k people died because some
               | medical device was being made without some microprocessor
               | that made it more effective or reliable.
               | 
               | It's possible for things with large scale effects to have
               | large impacts without it becoming well known by people
               | not working in the affected industry or directly
               | impacted.
        
               | MenhirMike wrote:
               | It's a good point - I was more talking about society as a
               | whole, since we didn't collapse. And we wouldn't collapse
               | if some Quartz mind in North Carolina closes either.
               | 
               | But yes, on an individual level, it can be severe. Like
               | the employees of car manufacturers who lost their jobs
               | because they couldn't make cars for a while because they
               | didn't have the chips needed.
        
             | tedsanders wrote:
             | Even with billions on the line, semiconductor shortages can
             | take years to resolve.
             | 
             | Consider the 2020-2023 chip shortage, which hit automakers
             | especially hard. When COVID19 struck in 2020, car sales
             | plunged by 30%-90%, inducing many automakers to cancel
             | future chip orders. Then when demand rebounded unexpectedly
             | quickly, automakers found that there were not enough chips
             | to buy, nor enough available manufacturing capacity to make
             | them.
             | 
             | This shortage of chips was severe. Every major automaker
             | (including Toyota,Volkswagen, Daimler, Ford, Honda, and GM)
             | were forced to idle manufacturing plants. In 2021 alone,
             | the chip shortage reduced auto production by ~11 million
             | vehicles, costing an estimated $210B in auto revenue(!). In
             | response, the White House convened 3 summits and signed the
             | CHIPS and Science Act of 2022.
             | 
             | Building extra semiconductor manufacturing tools takes
             | years. Even in late 2022, lead times of various tools were
             | as high as 24-30 months, and lead times of some chips were
             | still over 100 weeks.
             | 
             | Literally hundreds of billions of dollars of automotive
             | revenue (tens of billions of profit) were sitting as a
             | prize to anyone who could make some extra chips for
             | automakers. And this is a relatively "easy" task -
             | automotive is only a small ~10% slice of the semiconductor
             | market, and doesn't even need the leading edge technology
             | nodes, where production is even more bottlenecked. Yet even
             | with this massive prize of billions of dollars, the
             | industry couldn't match this demand in under 3 years. It's
             | not for lack of skill or effort -- these companies have
             | hundreds of thousands of employees, a large fraction with
             | advanced degrees -- but simply because the modern
             | semiconductor supply chain is fantastically complex.
             | 
             | When designing a supply chain, cost trades off against
             | resilience. If you minimize cost (e.g., single sourcing
             | crucibles from the lowest cost provider), you lose
             | resilience (e.g., it may take you months to recover from
             | that single source going offline unexpectedly).
        
               | chasil wrote:
               | One easy way for the automakers to solve their problems
               | would be to exploit Moore's law, and move all of their
               | designs to a 28nm planar node of transistor production
               | (which are somewhat more durable than the smaller FINFET
               | nodes).
               | 
               | Because many of them were still at 180nm (or higher),
               | they wasted the silicon material with a much larger die
               | size.
               | 
               | Spend the money to stay current. Nobody is going to mass-
               | produce vacuum tubes for you overnight.
        
               | Retric wrote:
               | I think the automotive chip shortage actually shows the
               | opposite of what you think it does. The industry largely
               | shut down, a global pandemic causing massive shipping
               | issues for a huge range of components hitting a complex
               | industry focused on just in time supply chains and
               | complex logistics combined with poor forecasting of
               | demand resulted in a _12% reduction in output over a
               | year._ Which then quickly caught back up.
               | 
               | That's so wildly far from catastrophe it's laughable,
               | economic swings frequently have larger impacts on car
               | sales. The pandemic hurt the automobile industry less
               | than several others, companies didn't fail, and things
               | quickly caught back up.
               | 
               | So yes disruptions mean a temporary reduction in output
               | and possibly a significant period catching up, but
               | suggesting it would take an industry years to deal with X
               | issue just doesn't line up with how companies actually
               | behave.
        
               | chasil wrote:
               | As I understand it, the "legacy" production capacity that
               | the automobile manufacturers canceled/forfeited was
               | (re)sold to other customers. When car sales picked up,
               | the order books were full and there were were no
               | immediately-available fabs.
               | 
               | The foundries did not appear to have as substantial of a
               | downturn.
        
             | hgomersall wrote:
             | Small correction: billions on the line over the time period
             | of the current generation of CEOs' tenures.
        
           | philipkglass wrote:
           | Neon supply disruption started earlier with the Donbas war,
           | so companies were already adapting to the neon squeeze.
           | Approaches used include developing neon production capacity
           | outside of Ukraine, optimizing process control to reduce neon
           | consumption, and recycling neon gas that would formerly have
           | been vented to the atmosphere:
           | 
           | "Gigaphoton Announces Neon Gas Rescue Program" (2015)
           | 
           | https://www.businesswire.com/news/home/20150708005017/en/Gig.
           | ..
           | 
           | "Linde installs neon production facility at ASU in Texas"
           | (2016)
           | 
           | https://www.gasworld.com/story/linde-installs-neon-
           | productio...
           | 
           | "Noble gases and the shock of war: Laser and semiconductor
           | manufacturers adjust to price increases while securing supply
           | chains" (2023)
           | 
           | https://spie.org/news/photonics-
           | focus/mayjune-2023/supplying...
           | 
           | "Samsung to use recycled neon gas in chip manufacturing"
           | (2024)
           | 
           | https://www.kedglobal.com/korean-
           | chipmakers/newsView/ked2024...
        
         | pfdietz wrote:
         | Silicon wafers aren't made from that quartz; the crucibles in
         | which silicon is melted is. The wafers themselves are made from
         | metallurgical silicon that is subsequently converted to
         | trichlorosilane, then repeatedly distilled to remove
         | impurities, and then converted back to elemental silicon.
         | 
         | If we didn't have sufficiently pure quartz for the crucibles we
         | could oxidize some of that purified silicon back into silicon
         | dioxide and use that instead.
        
           | chasil wrote:
           | The first chemist who performed this process actually went to
           | a college near my house.
           | 
           | https://en.wikipedia.org/wiki/Carl_Marcus_Olson
        
             | selimthegrim wrote:
             | This wasn't first? -
             | https://news.ycombinator.com/item?id=39819030
        
         | csours wrote:
         | It's kind of like peak oil. It's the price, not the amount. So
         | 'peak oil' isn't completely wrong, it's just complicated.
         | 
         | ---
         | 
         | > I think it's still a very cool factoid, but the subtext that
         | "the whole world economy 'hinges' on a teeny NC town" --is
         | false.--
         | 
         | is oversimplified to the point of being misleading.
        
           | samatman wrote:
           | Peak oil is defined in terms of production. When total global
           | production decreases, the moment of maximum production will
           | be peak oil. Unless of course it's later exceeded, which
           | could easily happen.
           | 
           | Why this will happen, when this will happen, and what the
           | economic consequences will be, we can only speculate about.
           | But it's the amount, not the price.
        
             | Turing_Machine wrote:
             | You are correct, of course. However, most of those using
             | the "peak oil" scare tactic try to pretend that once "peak
             | oil" is reached, there will be a sudden and drastic drop in
             | oil production.
             | 
             | I think that's what the person you're responding to was
             | alluding to.
        
         | dist-epoch wrote:
         | Other similar articles:
         | 
         | - lithium from Chile
         | 
         | - phosphates from Belarus
         | 
         | - rare earths from China
        
         | notShabu wrote:
         | There is a similar fallacy that I've seen many engineers &
         | teams fall into. The occupy "critical" roles which without, the
         | whole chain would break and everything would fall apart
         | 
         | However often times the project only needs that one critical
         | role and can replace it fairly easily. (the on-ramp off-ramp
         | costs are lower than the cost of redundancy or other political
         | costs)
         | 
         | Ironically, "non-critical" roles can be more important from a
         | business narrative or core competency pov.
         | 
         | E.g. "the AI expert/team" leaving breaks the narrative of being
         | an AI company even if all they do is non-critical path
         | exploratory research. The inability to get new hires breaks the
         | narrative of a growth-company etc...
         | 
         | There is more leverage in being able to direct narrative energy
         | than in being nominally critical
        
           | klyrs wrote:
           | > E.g. "the AI expert/team" leaving breaks the narrative of
           | being an AI company even if all they do is non-critical path
           | exploratory research.
           | 
           | I find myself in this position (but, not AI). That sole
           | researcher doesn't just have "narrative" power. I make
           | prototypes which are fleshed out into products by more
           | capable engineers. Without me, the team is a bunch of
           | engineers with great intuition on engineering and some
           | familiarity with my niche -- but not the depth of knowledge
           | required for keen intuition. The result would be either
           | stagnation, or very inefficient research as an engineer
           | attempts to step into the research role, hoping to
           | accidentally rediscover decades of specialized knowledge.
           | 
           | An AI company without an AI just won't be able to execute at
           | the pace of an AI company with that expert. And likewise, us
           | niche experts don't go far without a solid engineering team
           | to back us up.
        
         | Simon_ORourke wrote:
         | > I think it's still a very cool factoid, but the subtext that
         | "the whole world economy 'hinges' on a teeny NC town" is false.
         | 
         | Let them have their mistaken day in the sun, I've no doubt that
         | the market would adjust pretty quickly rather than, you know,
         | stop making semiconductors forever if this place disappeared
         | off the map.
        
         | joe_the_user wrote:
         | There's a whole school of "Industry X is totally dependent on
         | far flung facility Y" journalism. ("your cellphone depends on
         | coltan from African wars" from a few years back is the worst
         | offender - not that people shouldn't be concerned with such
         | wars but concern should be based on a reasonable lens).
         | 
         | That said, the world has experienced quite a few supply chain
         | disruptions in recent years and a big factor is large-scale,
         | highly capitalized enterprises wind-up preferring situations of
         | not producing at all to situations of increasing or continuing
         | production at a lower profit rate for an emergency situation.
         | (I remember covid vaccine production was limited by drug
         | companies unwillingness to invest in new gene printing
         | machines, US hospitals didn't buy US made masks because neither
         | the mask manufacturer would make/accept short-term contracts at
         | temporarily higher prices, etc. We all whine about AMD's
         | unwillingness to compete directly with Nvidia with a Cuda-clone
         | system).
         | 
         | Which is say, yes markets generally take risks into account but
         | some amount of fragility seems to be a risk markets are willing
         | to pay.
        
         | pradn wrote:
         | We don't have the vocabulary to separate two ways people use
         | "critical": "required for something's functioning", and "not
         | substitutable".
         | 
         | A tire is critical to a car's functioning, but there's plenty
         | of brands to choose from if one tire company goes bust. Ofc,
         | substitutability is a matter of degree - cost/time.
        
         | dylan604 wrote:
         | This comment reads like someone that has already forgotten
         | about the supply chain nightmare of the past couple of years.
         | Yeah, And, So to the idea that other suppliers _can_ , _could_
         | , _might_ be available.
         | 
         | How long does it take to suddenly have those suppliers ramp up
         | their production to the same levels? How long does it take for
         | a new shipper to be found from that new location? How long does
         | it take to make any changes to the processing because it's the
         | same but different as far as what is coming in?
         | 
         | Switching to a new vendor when you're comparing shopping at
         | Walmart, Target, Amazon is not any where close to the same
         | thing as receiving raw material from a new vendor for an
         | industrial process.
        
         | Terr_ wrote:
         | > I think it's still a very cool factoid, but [...] is false.
         | 
         | Technically, that falsehood is what _makes_ it a factoid, since
         | it resembles-but-isn 't a fact, just like how a spheroid is not
         | a true sphere, a meteoroid/asteroid isn't a true meteor/star,
         | an android/gynoid isn't a true man/woman, and almost every
         | other _-oid_ word out there.
         | 
         | Now, there are some philistines out there who claim that
         | popular misuse means the "correct" definition of factoid has
         | changed recently... But either way, I still find it amusing
         | that everyone agrees that "A factoid is a small fact" is itself
         | a factoid.
        
           | bl0rg wrote:
           | Thank you. Have a great day.
        
         | rstuart4133 wrote:
         | Yes. It's not like similar factories haven't suddenly stopped
         | production elsewhere:
         | 
         | https://www.spglobal.com/commodityinsights/en/ci/research-an...
         | 
         | It was uncomfortable for a while, but the world didn't end.
         | Supply chains adjusted pretty quickly.
        
       | perihelions wrote:
       | Tangentially, this looks like a seriously unpleasant neighbor to
       | live next to:
       | 
       | - _" Dozens of dead fish have died and are washing up on the
       | banks of the North Toe River after a reported hydrofluoric acid
       | leak at a Spruce Pine quarry, state officials say."_
       | 
       | https://wlos.com/news/local/dozens-of-fish-in-north-toe-rive...
       | 
       | - _" Officials told people who live within four miles of the
       | plant to evacuate their homes because of the fire."_
       | 
       | https://www.blueridgenow.com/story/news/2008/11/30/spruce-pi...
        
         | avalys wrote:
         | The global semiconductor manufacturing industry, and all of
         | modern society, on the one hand...
         | 
         | Dozens of dead fish on the other. Dozens!
        
           | perihelions wrote:
           | I mean, there were also children playing in the hydrofluoric
           | acid spill.
           | 
           | - _" Tuesday, moms Katrina Benfield and Nikki Bennett
           | returned to the river with their children. They said they had
           | all been swimming in the North Toe about 4 p.m. when they
           | began to see dead fish float around them and wash ashore."_
           | 
           | - _" "I'm not happy at all," Benfield said. "I had my
           | children in here. They fish, we eat the fish.""_
           | 
           | - _" Bennett said everyone got out of the water as soon as
           | they saw the dead fish."_
           | 
           | - _" "My daughter actually picked one up and said the scales
           | looked like they had been burnt," she said."_
           | 
           | ~
           | 
           | - _" Cecilia McCool, 15, said her eyes began to sting and she
           | began to feel light-headed while swimming in the river
           | Sunday. Within 10 minutes, she said she began to see the fish
           | floating and told friends and family to get out of the
           | river."_
        
             | greenavocado wrote:
             | Hydrofluoric acid (HF) is a highly corrosive and dangerous
             | substance that can pass through the skin and into the
             | bones. There are many things wrong with it that make it
             | different from other common acids like sulfuric acid.
             | 
             | Penetration: Unlike other acids that cause immediate pain
             | and visible burns on the skin, hydrofluoric acid can
             | penetrate the skin quickly without causing immediate pain
             | or visible damage.
             | 
             | Skin damage: Once absorbed through the skin, hydrofluoric
             | acid continues to cause deep tissue damage, which may not
             | be immediately apparent.
             | 
             | Bone and joint damage: Hydrofluoric acid has a high
             | affinity for calcium and can cause decalcification of the
             | bones, leading to severe bone damage and potentially fatal
             | electrolyte imbalances. It can also cause joint damage and
             | pain.
             | 
             | Systemic effects: If left untreated, hydrofluoric acid
             | poisoning can lead to systemic effects such as hypocalcemia
             | (low blood calcium levels), hypomagnesemia (low blood
             | magnesium levels), and hyperkalemia (high blood potassium
             | levels), which can cause cardiac arrhythmias and death.
             | 
             | Treatment: Immediate treatment is crucial for hydrofluoric
             | acid exposure. Calcium gluconate gel is typically applied
             | to the affected area to neutralize the acid and prevent
             | further damage. In severe cases, intravenous calcium and
             | magnesium may be necessary to treat systemic effects.
             | 
             | The Occupational Safety and Health Administration (OSHA)
             | has established a permissible exposure limit (PEL) for
             | hydrofluoric acid at 3 ppm (parts per million) as an 8-hour
             | time-weighted average (TWA) concentration. The National
             | Institute for Occupational Safety and Health (NIOSH)
             | recommends an even lower exposure limit of 3 ppm as a
             | ceiling limit, not to be exceeded at any time.
        
               | fy20 wrote:
               | Thanks ChatGPT!
        
               | greenavocado wrote:
               | Please, this is not ChatGPT! (If nothing else the math is
               | actually correct, something LLMs suck at)
               | 
               | The average volume of water in one square kilometer of a
               | river basin can vary greatly depending on the specific
               | characteristics of the basin, such as its topography,
               | geology, climate, and land use. Factors like
               | precipitation, evaporation, infiltration, and water
               | abstraction also play significant roles in determining
               | the water volume within a basin.
               | 
               | However, to provide a rough estimate, we can use the
               | concept of average runoff depth. Runoff depth is the
               | average depth of water that would cover the entire basin
               | if all the water flowing through it in a given time
               | period were evenly distributed across the basin's
               | surface.
               | 
               | In the United States, the average annual runoff depth
               | varies widely, ranging from less than 0.1 inches (2.54
               | mm) in some arid regions to more than 40 inches (1,016
               | mm) in some humid regions. For this example, let's assume
               | an average annual runoff depth of 20 inches (508 mm).
               | 
               | To calculate the volume of water in one square kilometer
               | of the basin, we can use the following formula:
               | 
               | Volume = Area x Average runoff depth
               | 
               | Given:
               | 
               | Area of the basin = 1 square kilometer = 1,000,000 square
               | meters Average annual runoff depth = 20 inches = 0.508
               | meters Volume = 1,000,000 m2 x 0.508 m = 508,000 m3
               | 
               | This means that, on average, one square kilometer of this
               | hypothetical river basin would contain about 508,000
               | cubic meters of water annually. However, it's essential
               | to note that this is a highly simplified estimation, and
               | actual water volumes can vary significantly depending on
               | the specific characteristics of the basin and the time
               | period considered.
               | 
               | The North Toe River has an approximate basin area of
               | 2968.7 km2
               | 
               | 2968.7 km2 x (508000 m3/km2) / m3 = 1,508,099,600 m3 of
               | water
               | 
               | Given:
               | 
               | Target concentration = 3 ppm = 3 mg/L
               | 
               | Volume of water = 1,508,099,600 m3
               | 
               | Concentration of concentrated HF = 48% w/w (weight by
               | weight) = 480,000 mg/L (assuming the density of 48% HF is
               | approximately 1 kg/L)
               | 
               | Step 1: Convert the volume of water from cubic meters to
               | liters. Volume of water = 1,508,099,600 m3 =
               | 1,508,099,600,000 L
               | 
               | Step 2: Calculate the mass of HF needed to reach the
               | target concentration. Mass of HF = Target concentration x
               | Volume of water Mass of HF = 3 mg/L x 1,508,099,600,000 L
               | = 4,524,299 kg
               | 
               | Step 3: Calculate the volume of concentrated HF needed.
               | Volume of HF = Mass of HF / Concentration of HF Volume of
               | HF = 4,524,299 kg / (480,000 mg/L / 1,000,000 mg/kg) =
               | 9,425,623 L
               | 
               | Therefore, approximately 9,425,623 liters of 48%
               | concentrated hydrofluoric acid would need to be added to
               | the entire river basic to reach a concentration of 3
               | parts per million.
               | 
               | If the affected area is 1 km out of the 118.4 km length
               | of the river, this would require in a spill of approx.
               | 79,600 liters of 48% concentrated hydrofluoric acid to
               | reach a concentration of 3 parts per million.
               | 
               |  _What I don 't understand at all is how this is possibly
               | an accident. It is hard to release such quantities of
               | hydrofluoric acid by accident._
        
               | TylerE wrote:
               | US environmental laws and industrial safety enforcement
               | are basically a farce.
        
               | greenavocado wrote:
               | Not true, there is a significant improvement relative to
               | 1969, the end of an era where a river in Ohio caught on
               | fire 11 times between 1869 and 1969.
        
               | TylerE wrote:
               | That doesn't contradict what I said. If you get a 65 on
               | the test instead of a 30, your score significantly
               | improved, but you still flunked.
        
               | greenavocado wrote:
               | You can't quantify the improvement in these terms because
               | you yourself don't have a way to measure it.
               | 
               | Edit because I can't reply:
               | 
               | What is abundantly clear is the main areas with severe
               | problems with water pollution today are Africa and the
               | Indian Subcontinent: https://ourworldindata.org/clean-
               | water
        
               | TylerE wrote:
               | It's pretty clear from the number of ongoing current
               | catastrophes (PFAS, more recently BPA, cities with lead
               | pipes) that what we're doing now isn't enough. Can we
               | start from that as a point of agreement?
        
             | 4ad wrote:
             | This is pure propaganda, one of the many reasons HF is
             | really bad is because _it doesn 't hurt at all_, at least
             | in the beginning.
             | 
             | Environmental disasters are really bad by themselves,
             | adding propaganda on top only weakens the cause and makes
             | people in the know not care.
        
           | bigbillheck wrote:
           | Sounds like they should have the resources to make sure
           | they're not polluting.
        
           | greenavocado wrote:
           | Take this line of reasoning to an extreme and you have The
           | Ganges River.
        
             | selimthegrim wrote:
             | I'm still disappointed Wikipedia removed the addendum to
             | the article about "Louisiana Woman, Mississippi Man"
             | comparing the Mississippi River's water quality at the time
             | to the Ganges quantitatively.
        
         | TylerE wrote:
         | It's North Carolina. That's not even a Tuesday. We routinely
         | have spills that dump _millions of a gallons_ of concentrated
         | hog shit directly into our rivers. Most of those rivers are
         | also downstream of one of the major producers of PFAS.
        
       | lostlogin wrote:
       | I recently toured an MRI factory. They used 20 tons of quartz per
       | week to mix in with the epoxy resin that encases the gradient
       | coils. Its thermal stability makes it desirable.
        
         | perihelions wrote:
         | That makes sense: so the alignment doesn't shift as the
         | gradient coils operate and heat up, right? Those aren't the
         | superconducting coils, they have Ohmic heating.
        
           | lostlogin wrote:
           | No, not superconducting.
           | 
           | Body and gradient coils I believe. They get a lot of current
           | through them. 3x 200 amps at 2000 volts if I recall
           | correctly. They have cooling pipes too.
           | 
           | If a cable wiggles loose it's a big deal with that much power
           | in use, they start to smoke. Running that that current is a
           | large force on any connections.
        
       | heleninboodler wrote:
       | Fun fact, the quartz is used to make the big crucibles where the
       | silicon wafers crystallize by starting from a seed in the center
       | which is slowly drawn upward. My grandmother was a quartz
       | salesperson for GE for decades (they sourced their quartz from
       | this same company) and they make the crucibles. My grandma lived
       | in a place with a small yard and her garden was planted in these
       | very modern-looking quartz crucibles that were destined for
       | chipmakers but had some tiny flaw on the inner surface so they
       | couldn't be sold.
        
         | harikb wrote:
         | I was very confused initially because you talked about 'seed'
         | as well as a garden. Do you mean something like this? [1]
         | 
         | [1] https://en.wikipedia.org/wiki/Czochralski_method
        
           | heleninboodler wrote:
           | Yes, exactly.
        
         | jonah wrote:
         | That's neat!
         | 
         | My uncle gave me a bunch of large electrical insulators from
         | the old high-tension transmission lines heading West from
         | Hoover Dam. They make great yard ornaments.
        
         | samatman wrote:
         | Quartz singing bowls have historically been sourced from flawed
         | crucibles. I don't know if that's still true exclusively or
         | even primarily. Just always thought it was cool.
        
       | Animats wrote:
       | There's a competitor in Drag, Norway.[1]
       | 
       | There was a startup in Australia that was going to mine ultra-
       | high quality quartz.[2] No site updates since 2021.
       | 
       | [1] https://www.thequartzcorp.com/location/drag
       | 
       | [2] https://ultrahpq.com
        
       | exabrial wrote:
       | Interesting, I wonder if this if this is the same geological
       | source of quartz that makes a bunch of the gulf coast beaches
       | really white.
        
       | jacknews wrote:
       | SCR - SIBELCO on euronext in case anyone wants to the follow the
       | pump.
        
       | a_vanderbilt wrote:
       | Local mines also produce the materials used to make nuclear
       | weapons, which on more than one occasion has led to anti-
       | proliferation protests in Asheville.
        
       | idunnoman1222 wrote:
       | If this is true, they should charge more.
        
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