[HN Gopher] Organic Syntheses (2023)
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       Organic Syntheses (2023)
        
       Author : divbzero
       Score  : 22 points
       Date   : 2024-01-22 05:34 UTC (1 days ago)
        
 (HTM) web link (www.science.org)
 (TXT) w3m dump (www.science.org)
        
       | WhatsTheBigIdea wrote:
       | It's so good to hear about a scientific organization that is
       | doing excellent, repeatable, high quality work. I wonder how they
       | are compensated/incentivized?
        
         | awjlogan wrote:
         | _OrgSyn_ was /is the absolute gold standard, and partly why I
         | ended up quitting academic organic chemistry. A key metric in
         | organic chemistry is yield, ie. how much of A turns into B. Top
         | journals generally required 15+ examples of yield >85-90% for a
         | new reaction (unless it was _really_ novel). Reference that
         | 90%+ figure against the typical _OrgSyn_ yield and you 'll be
         | wondering what a stressed out PhD with limited analytic support
         | knows that a team of real process chemists doesn't.
         | 
         | Process chemistry is not a glamourous field, so people submit
         | their results for at least some recognition and the journal
         | editors replicate the procedures in their own labs
         | independently. Their stipulation is that the single most
         | expensive reagent cannot be more than $500.
        
         | murphyslab wrote:
         | Everything noted by awjlogan is correct in my experience. To
         | add to the question of incentive, Organic Syntheses is a non-
         | profit corporation since its inception. It's worth reading the
         | organization's history page:
         | 
         | https://www.orgsyn.org/history.aspx
         | 
         | Regarding compensation, the model employed for reproduction of
         | experiments is that students associated with the Board of
         | Editors are paid to carry out the checking process:
         | 
         | > Junior checkers (students associated with members of the
         | Board of Editors) now receive an honorarium for their efforts.
         | This change recognizes the more complex and sophisticated
         | procedures that now appear in these volumes. Also, because of
         | the greatly increased cost of chemicals involved in the
         | checking process, checking editors are now reimbursed for their
         | costs; it is no longer reasonable to expect their own
         | departments to absorb these expenses.
         | 
         | The incentives here are so different from a typical chemistry
         | journal in part because Organic Syntheses is not engaging in a
         | race to publish as many articles as possible, nor is it aiming
         | for novelty. They publish about 20-30 procedure papers each
         | year, which would be comparable to a single issue at any other
         | chemistry journal. The subjects are well-trodden areas, but
         | often in need of greater detail than is provided in a typical
         | report.
        
         | philipkglass wrote:
         | The original incentive was the outbreak of World War I, which
         | cut America off from the previously-dominant European suppliers
         | of organic chemicals. This is the first part from the lengthier
         | history linked below:
         | 
         |  _Prior to 1914, the industrial production of organic chemicals
         | in the United States was very limited both in the number of
         | compounds and quantities. ... Most organic compounds were
         | imported from Europe; research chemicals for use in
         | universities and industrial laboratories were imported from
         | Germany (Kahlbaum 's Chemicals), Great Britain (Boots Ltd.),
         | and France. There were only a few small scientific supply
         | houses that distributed small amounts of imported chemicals.
         | Indeed, organic research in universities and industry was
         | limited to a few schools and very few companies. In 1914, the
         | outbreak of the war in Europe led to embargoes, blockades, and
         | destruction of shipping, which meant that chemical supplies in
         | the United States were quickly exhausted. ... Since all the
         | industrial plants and laboratories were in use, the chemistry
         | staff at the universities began to increase their "student
         | preps" to make chemicals needed for research. Clarence G.
         | Derick of the Chemistry Department at the University of
         | Illinois in Urbana, actually initiated "Summer Preps" with
         | about five students in 1914 before the war started. In the
         | summer of 1915, Ernest H. Volwiler, a graduate student, joined
         | Derick's prep group and was placed in charge during 1916 and
         | 1917. Oliver Kamm, a member of the teaching staff after 1915,
         | also helped in the prep work._
         | 
         | http://www.orgsyn.org/history.aspx
         | 
         | The war was also the beginning of organic chemistry for many
         | American chemical businesses. The one I read about most
         | recently was Hooker Electrochemical, which started making
         | materials for high explosives and dozens of other things during
         | the war. Originally it only manufactured sodium hydroxide and
         | bleach. There's a long company-commissioned hagiography
         | (nonetheless containing a lot of fascinating historical
         | information) available here:
         | 
         | "Salt & water, power & people: a short history of Hooker
         | Electrochemical Company"
         | 
         | https://babel.hathitrust.org/cgi/pt?id=mdp.39015070160174&se...
         | 
         | To me, Hooker is most notable for its contributions to the
         | Manhattan Project and the development of hafnium-free zirconium
         | used in the first pressurized water nuclear reactors. To most
         | people, it's probably most notable (if known at all) for the
         | chemical waste it left buried in Love Canal. It was absorbed
         | into Occidental Petroleum in the 1960s and no longer exists as
         | a separate entity. The history linked above encapsulates a lot
         | of the changes in American chemical businesses between the
         | World Wars even if this company is gone.
        
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