[HN Gopher] Researchers claim first functioning graphene-based chip
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       Researchers claim first functioning graphene-based chip
        
       Author : Brajeshwar
       Score  : 229 points
       Date   : 2024-01-19 14:52 UTC (8 hours ago)
        
 (HTM) web link (spectrum.ieee.org)
 (TXT) w3m dump (spectrum.ieee.org)
        
       | causal wrote:
       | If I'm reading this correctly, this would more accurately be a
       | graphene wafer, right? There are no circuits on this thing, it's
       | just a sheet of graphene, right? Still remarkable if so, just not
       | what I would call a "functioning chip".
        
         | OnACoffeeBreak wrote:
         | I only scanned the article and the paper, but the paper linked
         | in the article talks about the researchers characterizing
         | performance of a MosFET.
        
         | gwill wrote:
         | yea, looks like the author doesn't understand the difference
         | between a semiconductor and a chip.
         | 
         | the researchers said "functioning semiconductor".
        
         | deepsquirrelnet wrote:
         | Likely single devices patterned from a epitaxially grown
         | graphene layer. It would be a functioning transistor --- or set
         | of transistors, albeit not terribly useful as single devices.
         | Typically they would pattern the devices with large metal
         | landing pads to drop probes onto, and perform characterization
         | from there.
        
         | idiotsecant wrote:
         | The difference is just engineering once the material science is
         | there.
        
       | kaptainscarlet wrote:
       | This could be the breakthrough that could miniaturized AI more
       | powerful.
        
         | programjames wrote:
         | This is still years away from mass production. The process
         | takes hours at very high temperatures to make a single layer.
        
           | givinguflac wrote:
           | Nope, it takes about an hour for one layer.
           | 
           | FTA: "Then a high-frequency current is run through a copper
           | coil around the quartz tube, which heats the graphite
           | crucible through induction. The process takes about an hour."
        
       | dylan604 wrote:
       | Having a title for anything with "Researchers claim..." is such a
       | red flag that I don't even want to click the link. I've been
       | burned too many times. I know that fire is hot, I don't need to
       | touch it again to find out. I'm a quick study, and after the 10th
       | time, it took hold
        
         | colordrops wrote:
         | Speaking of graphene, I've been hearing about its miraculous
         | powers for years. Are there any practical applications yet?
        
           | theragra wrote:
           | It is used in industrial uses widely, for composites with
           | greater durability, strength etc
        
           | theragra wrote:
           | Also, for fun, search for nano tape. I think it is using
           | carbon nano structures, close relatives of graphene
        
           | dotnet00 wrote:
           | I'm not sure if they're available on market already, but I
           | recall that graphene Li-ion batteries are being seen as a
           | decent near term upgrade, with the production issues of
           | graphene reduced because they don't need large sheets of it.
        
         | bogtog wrote:
         | Isn't it notable that the article is at least acknowledging
         | this uncertainty?
        
       | bee_rider wrote:
       | The manufacturing process seems quite friendly compared to the
       | (albeit, local) ecological nightmare that is Si.
       | 
       | It sure is hard to compete with half a century of Si advancement,
       | though. Especially given how many STEM-brains get attracted to
       | software instead, nowadays...
        
         | varispeed wrote:
         | > Especially given how many STEM-brains get attracted to
         | software instead, nowadays...
         | 
         | It's just common sense. You won't earn decent money at
         | semiconductor company and given the niche, you will be
         | sentenced to whims of one or two (if you are lucky) companies
         | operating in your region. If you find that your employer
         | doesn't treat you well, you cannot exactly leave and bootstrap
         | your own chip making business.
         | 
         | Software is more democratised and you have much better chances
         | to grow wealth of your family in that area. Although corrupt
         | regulators are doing their best to pull as many ladders as they
         | can to limit ways workers can go their own way (like changed
         | IR35 legislation in the UK that massively limits how small
         | service based business can operate).
        
           | bee_rider wrote:
           | I agree that the market has shifted in a way that we're all
           | individually making the rational decision by going into
           | software, but it still seems like a shame.
        
           | mindentropy wrote:
           | It is simple. If the Govt wants to support the semiconductor
           | industry provide proper worker protections. It should know
           | that the a few companies would have cartel like power and
           | exploit their employees.
        
             | idiotsecant wrote:
             | Its rare that nuanced problems have simple solutions. The
             | problem is not that evil employers are oppressing helpless
             | employees, at least not entirely. The problem is that
             | making physical things requires physical infrastructure and
             | investment at a massive scale. Things move slowly and
             | barrier to entry is high. Conditions like that are going to
             | cause a slower, less transferrable skill set just because
             | few entities are willing to take the capital risk to
             | develop that infrustructure so fewer entities exist.
             | 
             | Contrast that with software where you and I could go start
             | a business _now_ and potentially unseat a major player
             | somewhere with enough talent and dedication.
             | 
             | Its obvious which one is going to have more mobile
             | employees.
        
             | robertlagrant wrote:
             | It's not worker protections that will help. They will just
             | end up incentivising industry to move elsewhere. The
             | problem is it's too hard to set up competitors. Competitors
             | are what raise employees' standards of living, far higher
             | than vote-winning legislation.
        
           | ngneer wrote:
           | This is right. The flip side is that having many talented
           | software engineers renders each one slightly more
           | dispensable. You want to find the right Goldilocks niche. Not
           | too rare that mobility is limited, but not too prevalent that
           | compensation suffers.
        
             | tyre wrote:
             | As a hiring manager, I can confidently say that we are
             | nowhere close to saturated with talented software
             | engineers.
        
               | agumonkey wrote:
               | so the niche is in training ? :D
        
               | throwaway22048 wrote:
               | Yes, I earn 3x more doing training than myself or any of
               | my senior SWE colleagues/friends. Think 1500 EUR daily
               | rate instead of 500 (in Central Europe).
        
           | burnished wrote:
           | Yep! When I was in school and learning about semiconductors I
           | was so interested that I went to the library for further
           | reading and dropped by the physics department to ask
           | questions, purely for my own edification. But I chose to
           | pivot towards software due to the career prospects.
        
           | soitgoes511 wrote:
           | Won't earn decent money? Have you ever worked for a big semi
           | company? I have and that is simply not true. Niche, maybe...
           | But, they did not skimp high performers regarding wage.
           | Believe it or not, there are plenty of good software
           | positions in semiconductors too..
        
         | crotchfire wrote:
         | Just wait until they scale it up and commercialize it; the
         | nightmare will return.
         | 
         | The sad fact is that nasty and exotic chemicals provide ways to
         | make many manufacturing processes cheaper and run large
         | batches. When you're pushing the limits of _everything_ and the
         | stakes are high, you can 't really take them off the table.
        
       | programjames wrote:
       | Where did they claim to make a chip? It seems to be just a single
       | epigraphene layer.
        
         | jacquesm wrote:
         | 'just'?
        
           | robertlagrant wrote:
           | A chip is a lot harder than a wafer, and a chip is what's
           | claimed.
        
             | jacquesm wrote:
             | From nothing at all to a wafer of a new material is a giant
             | step compared to the step from a wafer to a chip.
        
       | photochemsyn wrote:
       | Full research article:
       | 
       | https://arxiv.org/pdf/2308.12446
       | 
       | They did make a proof-of-concept device: "The electrical
       | properties of the SEG were measured by characterizing a
       | fabricated top-gated SEG FET."
        
       | ngneer wrote:
       | Trouble is always with scaling and equipment. Unless one uses the
       | existing infrastructure, low chance of success.
        
         | px43 wrote:
         | I also think that a fundamental issue with using carbon for
         | compute is that we don't actually have a lot of it, and what we
         | do have we largely need for all that organic chemistry that
         | keeps us alive.
         | 
         | For reference, carbon makes up about 0.18% of the earth's mass,
         | whereas silicon makes up 27.7%. The moon basically has zero
         | carbon, and the regolith is 20% silicon.
        
           | AdamH12113 wrote:
           | Far more of the silicon (from sand) goes into concrete and
           | glass, though. And it's not like we're short on hydrocarbons.
           | From what I can gather, the total yearly worldwide production
           | of concrete is tens of billions of metric tons, fossil fuels
           | are billions of tons, and silicon is millions of tons --
           | barely a blip on the radar.
        
       | mthcalixto wrote:
       | Graphene is the future and Brazil is the largest country that has
       | this resource, it could be the best country in the world.
        
         | dtx1 wrote:
         | Isn't graphene just carbon?
        
         | ur-whale wrote:
         | I thought Graphene was just a form of Carbon, and mostly
         | produced from regular carbon through some sort of process.
         | 
         | Are you saying Graphene can be found in nature?
        
         | binarymax wrote:
         | Graphene (https://en.m.wikipedia.org/wiki/Graphene) is
         | manufactured from carbon. You don't pull graphene out of the
         | ground, you manufacture it in a lab.
        
           | neuronexmachina wrote:
           | I've been playing too much Dyson Sphere Program lately, my
           | first thought was "you just need to combine graphite and
           | sulfuric acid in your chemical plant": https://dyson-sphere-
           | program.fandom.com/wiki/Graphene
           | 
           | Looks like that's sort-of a real thing?
           | https://www.americanscientist.org/article/mass-producing-
           | gra...
           | 
           | > Researchers at Rutgers University are making sheets of
           | graphene out of ordinary graphite flakes and some sulfuric or
           | nitric acid.
        
             | seaal wrote:
             | Always nice when games introduce you to real life concepts.
             | Shout out to Greg Tech: New Horizons, often leading me down
             | a wikipedia rabbit hole.
        
             | klyrs wrote:
             | Even if you could just magically make a reel of graphene
             | with this graphite+sulphuric acid recipe, it wouldn't help
             | one bit in chip fabrication. You need to build things layer
             | by layer; there's only one place where a bulk material is
             | used, and that's the substrate.
        
         | r3d0c wrote:
         | lol.. unless brazil is the only country in the world with
         | carbon, this is absolutely not true
        
         | neuronexmachina wrote:
         | Assuming you mean graphite (which can be used in graphene
         | production), it looks like Turkey might have even more
         | reserves. China, Madagascar, and Mozambique also have pretty
         | significant graphite reserves:
         | https://www.statista.com/statistics/267367/reserves-of-graph...
        
         | wigster wrote:
         | its made out of sellotape/scotch tape and pencils! ;-)
        
         | cassiogo wrote:
         | I belive you are thinking about Niobium and not Graphene
        
         | dudeinjapan wrote:
         | Brazil is the world's third largest producer of graphite,
         | behind China and Mozambique. Our current most reliable graphene
         | production methods start with graphite and exfoliate it into
         | single layers of graphene.
        
         | moffkalast wrote:
         | Even if that were true, countries where most of the wealth is
         | dug or pumped from the ground are the worst places to live
         | because it can all be be easily extracted by foreign companies
         | who pay a cut to the dictator directly and the people have
         | nothing to threaten the laughably rich autocrat with.
        
       | margorczynski wrote:
       | The question is can this be as effectively processed and
       | miniaturized as silicon. Still as someone pointed out they've
       | already produced a transistor based on it and the claim is the
       | same processes used for silicon can be used here so I sure hope
       | it works out.
        
         | mcshicks wrote:
         | Silicon based chips rely on oxide and metal layers to connect
         | the transistors. Not clear to me from the article how that
         | would work for graphene based devices. This was also an issue
         | for GaAs based chips. From the Wikipedia article on GaAs
         | 
         | "The second major advantage of Si is the existence of a native
         | oxide (silicon dioxide, SiO2), which is used as an insulator"
        
         | EasyMark wrote:
         | Yep, we have much faster switching semiconductors than silicon
         | based ones, but that is like 10% of the deal; there is also
         | miniaturization techniques, fab equipment, engineer/scientist
         | expertise in the subject, conductor/semiconductor/insulator
         | layers & interfaces, and oh so much more. It's nice to hear
         | about advancements outside the regular silicon ecosystem but
         | it's a tough row to hoe to push silicon aside for a "better
         | material". It's probably going to have to be a revolutionary
         | advantage (100x?) improvement over current tech to move to a
         | new tech stack.
        
           | dotnet00 wrote:
           | Since density with Si is approaching a wall soon and thus a
           | switch in materials likely to end up being necessary at some
           | point in the next 2-3 decades anyway, I feel like rather than
           | being immediately revolutionary, all that'll end up mattering
           | is where the theoretical limits are. After all, at that
           | point, you need to retool and retrain anyway.
        
         | moffkalast wrote:
         | Even if it can't, ridiculously high current mosfets without
         | heatsinks FTW.
        
       | throwbadubadu wrote:
       | > The outcome is transistors capable of operating at terahertz
       | frequencies, offering speeds 10 times as fast as that of the
       | silicon-based transistors used in current chips.
       | 
       | Why? We are single digit gigahertz, so terahertzes should be ~
       | 100 times faster?
        
         | daveFNbuck wrote:
         | We're at single digit gigahertz for an entire chip, not a
         | single transistor.
        
         | AdamH12113 wrote:
         | The clock frequency is single-digit gigahertz. But digital
         | signals have to propagate through multiple layers of logic
         | gates, so the transistors have to switch much faster.
         | 
         | At a glance, the article doesn't make it clear whether the
         | "terahertz" speed refers to switching frequency or gain
         | bandwidth (fT). You can definitely get transistors with fT in
         | the hundreds of gigahertz range right now.
        
         | mtlmtlmtlmtl wrote:
         | Not an EE, but my guess is that current transistors can likely
         | operate at a much higher clock rate than current chips.
         | 
         | The problem is that when you pack them together, they get far
         | too hot to permit dennard scaling to reach the limits of the
         | individual transistor.
        
           | tux3 wrote:
           | This one's not because of heat, but because signal had to go
           | from the beginning of a stage, through several transistors,
           | to the end of the stage
           | 
           | So the transistors switch fast individually, but the speed of
           | the chip is limited by the slowest path in any stage, where
           | you wait for every transistor on the path in series
        
             | mtlmtlmtlmtl wrote:
             | Ah, right, thanks for correcting me.
        
             | foota wrote:
             | Out of curiosity, how long are these paths generally?
        
               | jiggawatts wrote:
               | Low single digit millimeters for current chip designs.
               | 
               | One reason that clock speeds are going above 5 GHz these
               | days is that chips are getting smaller. That means
               | shorter signal propagation distances.
        
               | tux3 wrote:
               | So, when I talked about the length of the path in number
               | of transistors, I oversimplified a bit. The length of the
               | path would be measured in nanoseconds (or even
               | picoseconds).
               | 
               | That number depends not just on the number of
               | transistors, but also on the routing delay (are the
               | interconnect wires between transistors long or short? How
               | high is the resistance/capacitance?), and a lot of low-
               | level details of the fabrication process that are
               | extremely not public
               | 
               | But say you buy a brand new CPU and it's clocked at 5
               | GHz, you can easily get a rough estimate of how long the
               | critical path is, since 1/5GHz = 0.2ns
               | 
               | What you can't easily get is the speed of the transistors
               | or the number of transistors in the critical path, that
               | info is not public, and you could only make a very rough
               | guesstimate.
        
         | deepnotderp wrote:
         | Single transistor level frequency is different than chip level
         | frequency.
         | 
         | Each clock stage has many layers of transistors
        
         | itcrowd wrote:
         | For digital computers, clock speeds are single digit GHz. For
         | analog circuits, ~100 GHz is achievable in silicon. E.g.,
         | automotive radar chips, communication systems etc.
         | 
         | This THz comment relates to analog circuits, which is
         | supposedly around a factor 10 higher with this new tech.
         | 
         | If you want to learn more, read about Fmax and Ft of
         | transistors.
        
       | johntb86 wrote:
       | Previous discussions:
       | https://news.ycombinator.com/item?id=38912240 and
       | https://news.ycombinator.com/item?id=38878780
        
       | ajb wrote:
       | Buries the lede a bit? Near the end is "Conventional GFETs
       | [graphene transistors] do not use semiconducting graphene, making
       | them unsuitable for digital electronics requiring a complete
       | transistor shutdown. [...] the SEC [material] developed by his
       | team allows for a complete shutdown, meeting the stringent
       | requirements of digital electronics."
       | 
       | As far as I heard before, this was the problem with graphene
       | transistors, they had a nonlinear response but did not shut down
       | the current flow, making them not useful for digital logic, only
       | analog circuits. But, it's a while since I read about this so
       | maybe someone else already achieved this before.
        
         | j16sdiz wrote:
         | That's the "bandgap" thing mentioned in the article. They
         | exists, but very unreliable.
        
         | singularity2001 wrote:
         | Semi analog transistor would be perfectly fine for AI
         | operations though? ( matrix multiplication, sigmoid, tanh etc )
        
       | LAC-Tech wrote:
       | oh very cool. I remember hearing about graphene in inorganic
       | chemistry 101 and thinking it that was the neatest thing in the
       | world. That and carbon nanotubes.
       | 
       |  _De Heer says that it will take time to develop this technology.
       | "I compare this work to the Wright brothers' first 100-meter
       | flight. It will mainly depend on how much work is done to develop
       | it."_
       | 
       | Something to look forward to!
        
       | foota wrote:
       | It's amusing to think about something like a several thousand
       | (probably more like billions?) transistor graphene based chip
       | outdoing a trillions transistor behemoth.
       | 
       | I don't know if that's possible in reality though, since things
       | like cache space are important regardless of your clock speed and
       | there's no point in being able to do fast logic if you can't pipe
       | in enough data.
        
       | foota wrote:
       | Are there any niches for super high speed chips that it isn't
       | possible to fill with silicon based chips? Would there ever be a
       | niche for a small company making handfuls of them, or would it
       | only be feasible at scale?
        
         | Jweb_Guru wrote:
         | Sure. Network switches for example have a pretty insatiable
         | supply for processing speed.
        
       | RecycledEle wrote:
       | > This heating step is done with an argon quartz tube in which a
       | stack of two SiC chips are placed in a graphite crucible,
       | according to de Heer. Then a high-frequency current is run
       | through a copper coil around the quartz tube, which heats the
       | graphite crucible through induction.
       | 
       | So they use a tube furnace?
       | 
       | > "The chips we use cost about [US] $10, the crucible about $1,
       | and the quartz tube about $10," said de Heer.
       | 
       | Tube furnaces do not cost $10 except when you build it yourself
       | and do not count the thousands of dollars of equipment you have
       | sitting around.
        
         | uSoldering wrote:
         | They are talking about the price of consumables in the process.
         | You also need a building and electricity and employees and a
         | whole bunch of other stuff you can infer via deduction.
        
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