[HN Gopher] Webb Discovers Methane, Carbon Dioxide in Atmosphere...
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       Webb Discovers Methane, Carbon Dioxide in Atmosphere of K2-18B
        
       Author : wfurney
       Score  : 166 points
       Date   : 2023-09-11 15:04 UTC (6 hours ago)
        
 (HTM) web link (www.nasa.gov)
 (TXT) w3m dump (www.nasa.gov)
        
       | fritzo wrote:
       | Paywalled paper:
       | https://www.nature.com/articles/s41550-019-0878-9
       | 
       | Preprint: https://arxiv.org/abs/1909.05218
       | 
       | Figure 2 pp. 14 of the preprint shows much more plausible error
       | bounds on the curve fit. That press release "best fit" curve is
       | merely an artist's conception.
        
         | V1ndaar wrote:
         | Nope, that is the old paper about Hubble measurements of the
         | same planet.
         | 
         | The preprint of the Webb based paper is here [0] from here [1].
         | 
         | [0]: https://stsci-opo.org/STScI-01HA2G716KS9YGAGVY1WBVFJ8Y.pdf
         | 
         | [1]: https://webbtelescope.org/contents/news-
         | releases/2023/news-2...
        
       | sgt101 wrote:
       | Gosh - imagine that place!
       | 
       | I wonder how old this world is, and how stable its enviroment
       | is/has been. Complex animal life took 3.5 bn years to emerge on
       | Earth, of course that's a meaningless data point by itself but
       | intuitively for this place to have an ecosystem or complex life
       | it needs to be old.
       | 
       | Still, even without this what a wonderful and weird environment.
        
         | unsupp0rted wrote:
         | > Complex animal life took 3.5 bn years to emerge on Earth,
         | 
         | How certain are we it took that long (the first time)?
        
           | tracedddd wrote:
           | Not certain at all, it's based on last universal common
           | ancestor estimates(LUCA) and supported by (lack of) fossil
           | record.
        
             | wolverine876 wrote:
             | > it's based on last universal common ancestor
             | estimates(LUCA) and supported by (lack of) fossil record.
             | 
             | I thought the Cambrian Explosion's fossil record was pretty
             | sizeable - in fact, it's named after the place where the
             | fossil layer was first discovered. I didn't know it was
             | related to a common ancestor. Are you thinking of something
             | else or am I missing something major?
        
               | edgyquant wrote:
               | Yes but we're talking about before the Cambrian
        
             | no_wizard wrote:
             | Its _possible_ there is a good explanation for why there
             | would be no strong fossil record[0] for an advanced
             | civilization preceding us.
             | 
             | >When it comes to direct evidence of an industrial
             | civilization--things like cities, factories, and roads--the
             | geologic record doesn't go back past what's called the
             | Quaternary period 2.6 million years ago. For example, the
             | oldest large-scale stretch of ancient surface lies in the
             | Negev Desert. It's "just" 1.8 million years old--older
             | surfaces are mostly visible in cross section via something
             | like a cliff face or rock cuts.
             | 
             | While I think its highly unlikely (I mean less than
             | 0.00001% possible) the means in which we would could even
             | detect it are complicated
             | 
             | [0]:
             | https://www.theatlantic.com/science/archive/2018/04/are-
             | we-e...
        
           | delta_p_delta_x wrote:
           | The fossil record. There is little evidence of very complex
           | animal life before about 541 million years ago, which is when
           | the Cambrian explosion begun.
        
             | no_wizard wrote:
             | When you say very little, do you mean none, or there is
             | some questionable evidence?
             | 
             | I'm genuinely curious
        
               | dudinax wrote:
               | Before "modern" life evolved in the pre-cambrian era,
               | there was the Ediacaran life forms that were complex
               | multicellular life, but died out millions of years before
               | the Cambrian explosion.
               | 
               | https://en.wikipedia.org/wiki/Ediacaran_biota
        
             | TheBlight wrote:
             | Given the surface of the planet is such a dynamic
             | environment, I wonder how much evidence we should expect
             | even if it did exist.
             | 
             | See also: https://www.scientificamerican.com/article/could-
             | an-industri...
        
               | Rebelgecko wrote:
               | There's quite a few fossils showing single-celled
               | organisms from 3+ billion years ago. I imagine if more
               | complex life existed the fossils could've survived
        
         | svachalek wrote:
         | Single cell life appeared on Earth almost instantly after the
         | planet cooled down enough to allow it. I don't think it's clear
         | that any progress was being made over the next few billion
         | years. One day the right mutation happened and boom, fancy life
         | everywhere. With our data sample of one, I don't think it's
         | clear if it was extraordinarily bad luck it took that long to
         | happen, or extraordinarily good luck it ever happened at all.
        
       | skywal_l wrote:
       | Seems to be down. This page seems to work:
       | https://webbtelescope.org/contents/news-releases/2023/news-2...
        
       | bayesianbot wrote:
       | 404 not found, did they maybe remove the article for some reason?
        
       | [deleted]
        
       | biggestlou wrote:
       | I'm still looking for intelligent life on _this_ planet
        
       | [deleted]
        
       | nickhalfasleep wrote:
       | Scientists using Webb may be able to present some surprisingly
       | strong evidence that we are not the only life bearing planet in
       | the galaxy.
        
         | jug wrote:
         | Yeah, not sure about the sensitivity, if it's particularly good
         | conditions here but at least this data set looks like it gives
         | remarkably little room for false positives and quite highly
         | detailed. I thought it would push JWST a bit harder but this
         | looks promising. Even a novice can read out the evidence for
         | various molecules in that graph? So, if only we'd find an
         | exciting result soon!
        
       | jncfhnb wrote:
       | Suppose a planet like this had non intelligent megafauna life.
       | How could we detect this?
        
         | dudinax wrote:
         | One way is to build bigger telescopes and hope its not too
         | cloudy.
        
           | floxy wrote:
           | "Direct Imaging of an Exoplanet with a Solar Gravity Lens (1
           | Km Resolution)":
           | 
           | https://arxiv.org/abs/1802.08421
           | 
           | ...and an excellent video on the topic:
           | 
           | https://www.youtube.com/watch?v=NQFqDKRAROI
        
       | CodeL wrote:
       | [flagged]
        
       | perihelions wrote:
       | What an unintuitive and sketchy-looking Bayesian model. They only
       | have 11 chemicals in the database they're matching that messy IR
       | spectrum against: 6 reasonable ones, and 5 bullshit ones that are
       | only there because theory papers suggested that they'd be
       | biomarkers of alien life. And, fit to just those 11 chemicals,
       | the best-fit includes one of the bullshit ones (dimethyl sulfide,
       | (CH3)2S).
       | 
       | https://stsci-opo.org/STScI-01HA2G716KS9YGAGVY1WBVFJ8Y.pdf
       | 
       | Is this approach, like, sane? I'm not a Bayesian statistics
       | expert.
        
       | Jeff_Brown wrote:
       | In case you wondered too, this is 124 light-years from us.
        
         | Aachen wrote:
         | Wow, that's really close so far as these things go. With the
         | nearest star being 4ly, this can be reached with essentially
         | the same tech level if we'd want to visit that with a rover or
         | generational ship one day
        
           | BoiledCabbage wrote:
           | What's also crazy is if we did send a rover over there to
           | hunt for life, and they found it, we'd have to wait 125 years
           | to hear the result.
           | 
           | We all sit around knowing to listen to the skies sometime in
           | October of 2185 to hear if the rover found life within the
           | first month of its landing.
           | 
           | If we ever send a team to live there, we'd hear broadcasts of
           | their lives from 125 years prior. A real portal in time - so
           | cool.
        
             | coffeebeqn wrote:
             | How do you get the rover there? It would take thousands of
             | years. Or maybe millions of years? With the current tech
        
               | NoMoreNicksLeft wrote:
               | Orion drives can get up to some respectable fraction of
               | the speed of light. Just need a billion or so 1-kiloton
               | nukes. No biggy. No worries about sneaking up on them and
               | startling them either.
        
               | floxy wrote:
               | "Roundtrip Interstellar Travel Using Laser-Pushed
               | Lightsails"
               | 
               | https://citeseerx.ist.psu.edu/viewdoc/download?doi=10.1.1
               | .10...
        
             | jandrese wrote:
             | Even worse if we are still limited by Newtonian dynamics it
             | will take thousands of years for a probe to reach there.
             | The rocket equation is a harsh mistress. In practical terms
             | we will never visit that world without completely upending
             | physics as we know it.
        
               | holoduke wrote:
               | We just need a 1g rocket. Will take only a few days to
               | get there. Life on earth will be 1000 years ahead once we
               | are back though.
        
               | jandrese wrote:
               | The problem is when you work out the math on rocket that
               | can sustain 1G for multiple days with any Earthly isp you
               | realize the math just doesn't work. Even if you go nuts
               | and plug in a number like 1 million seconds (our best
               | chemical rockets are more like 450 seconds) for the isp
               | it is still nowhere close to feasible using only the mass
               | of our solar system.
               | 
               | As long as you are stuck flinging mass out of the back of
               | your rocket to accelerate you don't get to go anywhere
               | outside of our solar system.
        
             | polishdude20 wrote:
             | 2185? Not 2273?
        
           | hungryforcodes wrote:
           | We'd need some fast tech for sure. However, what is also
           | interesting is that the light from it is only 124 years old.
           | So the planet is still very similar today probably.
        
       | wfurney wrote:
       | https://web.archive.org/web/20230911143418/https://www.nasa....
        
       | v8xi wrote:
       | In Nick Lane's Oxygen: The Molecule that Made the World, he talks
       | about the importance of both methane and carbon dioxide and how
       | they exist at the extremes of a complex metabolic oxidation-
       | reduction cycle. Methane stores a lot of chemical energy in its
       | C-H bonds which can be burned directly, or metabolized through
       | repeat oxidation events to ultimately form CO2, which plants
       | utilize with the help of the sun to form more CH bonds before
       | ultimately breaking down into methane again. Hence, an exoplanet
       | with both molecules in its atmosphere is a promising candidate in
       | the search for life.
        
         | behnamoh wrote:
         | I wonder what life looks like on a planet which is over 8 times
         | more massive than the Earth. Do animals have spines at all on a
         | planet with almost 8g gravity? Does life even get to evolve
         | into complex systems like animals under this much gravity? How
         | about plants? Do they grow up or spread out instead?
         | 
         | If one day we get a visitor from this planet, they'll jump on
         | our planet the same way human astronauts jumped on the Moon.
        
           | alexpotato wrote:
           | The book Dragon's Egg has a species living on a neutron start
           | with millions of G's
           | 
           | https://en.wikipedia.org/wiki/Dragon%27s_Egg
        
           | joshlemer wrote:
           | It would be really cool to run an experiment like this. Have
           | some population of rats living in a large enclosure that is
           | held in a large centrifuge for decades and see how they
           | evolve.
        
           | [deleted]
        
           | fmobus wrote:
           | I think 8g would be pretty hard to escape from, at least with
           | chemical rockets.
        
             | ericbarrett wrote:
             | Earth's surface gravity is really on the edge of what's
             | feasible for chemical rockets; IIRC the limit is around
             | 1.4g. Though as other commenters have mentioned, it's
             | possible to have a much more massive planet that's also got
             | a larger radius and thus has comparable surface gravity.
             | 
             | Some fun trivia--the planet Kerbin from Kerbal Space
             | Program is the opposite case. It has a radius of 600km,
             | versus Earth's 6378km, but is exactly 1 Earth g on the
             | surface. This implies it's over 10x as dense.
        
           | wheels wrote:
           | Gravity is only about 1.25 g, according to Wikipedia. Density
           | matters. The earth and Saturn have about the same surface
           | gravity.
        
           | [deleted]
        
           | lovecg wrote:
           | Note that 8 times more massive doesn't mean it has 8 times
           | surface g, unless it's exactly the same radius as the Earth.
           | If the planet is larger you're further away from the center
           | of gravity.
           | 
           | For example, the Earth is 10 times more massive than Mars,
           | but only has 2.6 times surface g.
        
           | watersb wrote:
           | I wonder how much of an outlier we may be, shuffling around
           | on dry land, when most of the biosphere of our planet is in
           | the ocean.
           | 
           | Higher gravity certainly means higher pressure gradient, more
           | pressure per vertical meter of ocean. And high pressure
           | affects protein structure.
           | 
           | It's life, but not as we know it.
        
           | littlestymaar wrote:
           | In addition to what others have said about the fact this
           | planet doesn't have 8g at its surface, at 8g you could still
           | have many lifeforms that exists on earth, but only the small
           | ones. Gravity grows roughly as the cube of your size (because
           | your volume does), but bones resistance only get n2 (because
           | it's the surface that counts), so the bone resistance /
           | weight ratio is inversely proportional to your size.
        
           | jdblair wrote:
           | The classic sci-fi "Mission of Gravity" explores what life
           | would be like on a rapidly rotating planet where one
           | experiences 3g at the equator and 700g at the poles.
           | 
           | https://en.wikipedia.org/wiki/Mission_of_Gravity
        
             | everyone wrote:
             | Thanks for that! I need a new novel to read, just
             | downloaded it!
        
           | colechristensen wrote:
           | As others have mentioned it wouldn't be 8 g. Life would be
           | smaller. There would be speed differences. A lot of optimums
           | and limits depend on how volume scales against area. Like the
           | biggest terrestrial animals are limited a characteristic
           | dimension (height or length) _x_ being proportional to femur
           | area _x^2_ being proportional to mass _x^3_. Mass grows
           | proportional to x^3, femur strength (area) grows proportional
           | to x^2, so you have a limit on how big a thing can be when
           | you run out of available femur strength.
           | 
           | Higher gravity means this upper limit will be smaller. All
           | sorts of similar scaling things will change optimum points
           | for structural and energy reasons.
        
           | 0xfaded wrote:
           | Assuming roughly comparable density to earth, the surface
           | gravity would only be 2g
        
           | thelittleone wrote:
           | Perhaps they're gas like.
        
           | gizmo686 wrote:
           | Gravity is more relevant for land based life. However, we
           | know from Earth that complex life can evolve in oceans.
        
           | pdonis wrote:
           | The planet's surface gravity is not 8 g. Surface gravity goes
           | like mass over radius squared, and the planet's radius is 2.6
           | times Earth's, so the surface gravity will be 8 / (2.6)^2, or
           | only about 1.2 times that of Earth.
        
             | adolph wrote:
             | That is if density remains constant. If the planet were 8x
             | mass but with same radius, gravity would be 8 g, or 8 x
             | 9.795 m/s^s.                 Earth mass:       5.97x10^24
             | kg, 6378.137 km yields 9.795 m/s^2            8x mass:
             | (8x5.97)x10^24 kg, 6378.137 km yields 78.36 m/s^2
             | 
             | All calculations: https://www.wolframalpha.com/input?i=surf
             | ace+gravity+calcula...
        
               | pdonis wrote:
               | _> That is if density remains constant._
               | 
               | No, the calculation I made did not assume constant
               | density. I just used the direct Newtonian formula for
               | surface gravity and plugged in the known mass and radius
               | of the planet. (You could also use that known mass and
               | radius to calculate the average density. But you don't
               | need to do that to calculate the surface gravity.)
               | 
               |  _> If the planet were 8x mass but with same radius_
               | 
               | But we know it isn't. We know the planet's radius is 2.6
               | times the Earth's radius. That's stated in the article.
        
           | dylan604 wrote:
           | The gravity question is one I've pondered myself as a thought
           | exercise. There's been discussions on how far up a plant can
           | draw water as the defining limit to how tall a tree could
           | grow. Some discussions as well on how tall an animal could
           | grow based on how high blood could be pumped up. Which is a
           | direction different from the structural support and sizes
           | that I find interesting.
        
         | julienchastang wrote:
         | Thanks for the book recommendation. Added to reading list.
        
       | lofaszvanitt wrote:
       | 120 light years away. Time to get the ufo tech out already.
        
         | 7373737373 wrote:
         | Unfortunately humanity has not yet understood the potential
         | that is out there, and is too busy fighting over the limited
         | one here on Earth.
        
         | no_wizard wrote:
         | is _Faster Than Light_ travel even possible? I 'm asking in a
         | serious way.
         | 
         | I have always read that its impossible, at least within our
         | current knowledge.
         | 
         | the only semi-plausible theory I've ever heard is that
         | Blackholes might one day yield some way of traveling quickly
         | across the universe but nobody has shown anything substantiated
         | around that or anything else.
        
           | coldpie wrote:
           | FTL travel being impossible is basically the one thing where
           | I completely irrationally reject the science :) It's just too
           | depressing for me to accept. There's gotta be a loophole.
           | There's just gotta be...
        
           | svachalek wrote:
           | There's no realistically plausible solution I've ever heard
           | of, that is, ones that don't require millions of years of
           | setup and entire stars worth of energy production. But that's
           | with our current understanding of physics. While our current
           | models seem nearly perfect and therefore nearly complete,
           | there was a time they thought that about Newtonian physics.
           | Perhaps some detail we need to understand dark matter or dark
           | energy could spring the whole field wide open again.
        
           | lofaszvanitt wrote:
           | The ufos have to come from somewhere, right?
        
             | coldpie wrote:
             | Yeah, flawed lenses and windows, and unreliable witnesses.
             | No need for FTL there.
        
           | NoMoreNicksLeft wrote:
           | It's quite simple really. All we need is fast-as-light
           | technology.
           | 
           | If you get in a ship and travel to Alpha Centauri at the
           | speed of light, the travel seems instantaneous to you. But
           | the people you leave behind think you've been gone 8 years
           | when you return.
           | 
           | So instead, I propose that when the ship launches, we also
           | propel the rest of the universe in the opposite direction
           | _also at the speed of light_. Then, when the astronaut is
           | scheduled to return, we propel the entire universe _at the
           | speed of light_ back to its original location.
           | 
           | All of reality undergoes time dilation. And the trip is
           | basically instantaneous for all involved+.
           | 
           | + Note: This form of FTL is mildly costly in regards to
           | energy expenditure.
        
       | ZunarJ5 wrote:
       | This feels like a big deal. The website seems to be getting
       | hammered as it is working on and off.
        
         | willis936 wrote:
         | What makes it feel like a big deal? Carbon, oxygen, and
         | hydrogen are extremely abundant. Those molecules are relatively
         | low energy combinations of the elements. I would be surprised
         | to not find them in the atmospheres of big rocky planets.
        
           | bilekas wrote:
           | Apperantly it seems to be the presence of " dimethyl sulfide
           | ". It seemingly only produced, on earth at least, by life. So
           | using us as a baseline it seems pretty interesting.
           | 
           | > DMS is generated by the degradation of
           | dimethylsulfoniopropionate, which is present in many species
           | of marine algae and plants, including dinoflagellates and
           | coccolithophores
        
             | ZunarJ5 wrote:
             | Yes, this is it!
        
             | JackFr wrote:
             | After getting sucked in by the phosphine on Venus hype, I
             | refuse to get hurt again. . .
        
       | [deleted]
        
       | swader999 wrote:
       | Nice to know we aren't the only ones struggling with CO2.
        
       | julienchastang wrote:
       | On this topic, I just finished reading "A Very Short Introduction
       | to Planetary Systems"[0] by Raymond T. Pierrehumbert. He devotes
       | a good portion of the book to exoplanet atmospheres. It is one of
       | the best science books I've read. Pierrehumbert really has a
       | knack for explaining complex material clearly and concisely. I
       | really recommend it.
       | 
       | [0] https://global.oup.com/academic/product/planetary-
       | systems-a-...
        
       | kaycebasques wrote:
       | It's mind-bendingly cool that people can figure out the
       | composition of an atmosphere without actually being close to that
       | atmosphere.
       | 
       | Had not heard of dimethyl sulfide before. That's a good keyword
       | to know.
        
         | julienchastang wrote:
         | From a single pixel of light! Indeed mind blowing.
        
           | treyd wrote:
           | That's somewhat misleading though. It's not really a pixel in
           | that there's much more information available than, basically,
           | 3 integers between 0 and 255. There's 4 instruments on the
           | telescope that collect 4 different chunks of IR spectra, and
           | there's very precise and granular intensity values for light
           | received around any given wavelength. Much more detail than a
           | "pixel" has in the typical sense we use them.
           | 
           | It's not a _lot_ of information, not nearly enough to
           | identify surface features on an exoplanet, but it 's very
           | useful data if you're trying to identify likely chemical
           | composition of bodies or how hot clouds of gas are.
        
         | dghughes wrote:
         | For emission spectroscopy has been a thing since 1859 when
         | Gustav Kirchhoff figured it out but for stellar emission
         | spectroscopy it was Joseph von Fraunhofer in early 1800s?
         | Although 1866, Pietro Angelo Secchi may have also discovered
         | stellar emission spectroscopy 1848.
         | 
         | An amazingly long time ago.
        
         | finite_depth wrote:
         | This is an easier problem than it probably seems. Atmospheres
         | are relatively low-density gas, which means they produce an
         | absorption spectrum - a chemical fingerprint that identifies
         | most atoms and molecules quite reliably. It's such a good
         | fingerprint that it was used to discover several chemical
         | elements, most notably helium (observed in the Sun's spectrum
         | before it was known on Earth).
        
       | cout wrote:
       | > These initial Webb observations also provided a possible
       | detection of a molecule called dimethyl sulfide (DMS). On Earth,
       | this is only produced by life. The bulk of the DMS in Earth's
       | atmosphere is emitted from phytoplankton in marine environments.
       | 
       | Given a sufficient quantity of reactants/reagents, could DMS be
       | produced via a natural process, or is this a sufficiently
       | unfavorable reaction that it's unlikely?
        
         | marcosdumay wrote:
         | I don't think anybody knows enough to tell you what kinds of
         | reactions happen on planet-wide environments without an
         | oxidizing atmosphere.
        
       | divbzero wrote:
       | > "Our ultimate goal is the identification of life on a habitable
       | exoplanet, which would transform our understanding of our place
       | in the universe," concluded Madhusudhan.
       | 
       | What sort of observation or measurement would allow us to
       | identify life on an exoplanet?
        
         | gus_massa wrote:
         | A lot of O2. As far as we know, the only source of a lot of O2
         | in the atmosphere are photosynthetic bacteria-like. So it will
         | be a clear sign of life.
         | 
         | There are some more subtle cases, like the one discussed in
         | this paper.
        
       | nofitty376 wrote:
       | That spectrum is so noisy. How can they infer the blue fit from
       | the (noisy) white points? The data look almost consistent with
       | flat (no detection). And even if there is a detection, it looks
       | like many other models could potentially fit the data...
        
         | fritzo wrote:
         | Right, show a posterior distribution not some hallucinated
         | point estimate.
        
           | V1ndaar wrote:
           | Check out the paper and not a PR piece [0].
           | 
           | [0]: https://stsci-
           | opo.org/STScI-01HA2G716KS9YGAGVY1WBVFJ8Y.pdf
        
         | bigbillheck wrote:
         | > How can they infer the blue fit from the (noisy) white
         | points?
         | 
         | By having a detailed model, and modern probabilistic
         | techniques:
         | 
         | The planet's terminator is modelled as a plane-parallel
         | atmosphere in hydrostatic equilibrium, with uniform chemical
         | composition. The chemical abundances and pressure-temperature
         | (P-T) profile are free parameters in the model. The retrieval
         | framework follows a free chemistry approach, whereby the
         | individual mixing ratio of each chemical species is a free
         | parameter.... Our canonical model comprises of 22 free
         | parameters overall: 11 corresponding to the individual mixing
         | ra- tios of the above chemical species, 6 for the P-T profile,
         | 4 for the clouds/hazes and 1 for the reference pressure Pref ,
         | defined as the pressure at a fixed planetary radius of 2.61
         | R[?]. The Bayesian inference and parameter estimation is
         | conducted using the MultiNest nested sam- pling algorithm
         | (Feroz et al. 2009) implemented through PyMultiNest.
         | 
         | (Sections 2.4 and 3.1 from https://stsci-
         | opo.org/STScI-01HA2G716KS9YGAGVY1WBVFJ8Y.pdf)
         | 
         | > And even if there is a detection, it looks like many other
         | models could potentially fit the data...
         | 
         | Name three.
        
           | gus_massa wrote:
           | Can I help the GP?
           | 
           | In the paper they analyze 3 models, "no offset", "offset" and
           | "offsetx2". It's strange that they get better fit for CO2 and
           | CH3 en the "offsetx2" model, but in that model the DMS
           | disappears. So there it at least one model.
           | 
           | Also, they analyze common molecules like CO2, CH4, H2O, NH3
           | and biologically interesting molecules like CH3-S-CH3 (DMS),
           | HCN, CH3-Cl. From the discussion in the paper it looks like
           | the CH3- part is important, so I'd like to see a brute force
           | search with everything that is in
           | https://en.wikipedia.org/wiki/Atmosphere_of_Titan and has a
           | methyl group, like CH3-CCH, CH3-CN. My Chemistry and
           | Astronomy is no so good, so I'd like to add CH3-OH, CH3-NH2,
           | CH3-SH, CH3-CHO and a few more from https://en.wikipedia.org/
           | wiki/List_of_interstellar_and_circu... I removed the ones
           | that are big or has too many oxygen (like CH3-COOH).
        
         | gus_massa wrote:
         | [I'm not an expert is spectroscopy, but let me guess.]
         | 
         | The bump at 4.3um looks real, and it seams to be an standard
         | absorcion of CO2. https://www.quora.com/Does-CO2-absorb-all-
         | infrared-frequenci...
         | 
         | The bump at 1.2, 1.4 and 2.4um looks real. I found this showing
         | a peak for CH4 at 2.325um.
         | http://www.astrochem.org/data/CH4H2O.php
         | 
         | [Sorry for the sources, but I'm not an expert is spectroscopy.]
         | 
         | My guess is that they assumed something like
         | 
         | a% * CH4 + b% * CO2 + c% * H2O + others
         | 
         | and get the best fit for a%, b%, c%, ... using the white
         | points. Later, using these numbers they draw the blue line.
         | 
         | The peak for DMS is not clear for my untrained eye, so I can't
         | guess what they did there. (Perhaps it's just the best fit.) It
         | would be nice to see the a graph of the blue line they guessed
         | with DMS and a superimposed red line with and atmosphere with
         | an alternative atmosphere where the DMS is replaced with
         | something uninteresting (N2? H2O? More CH4? I have no idea what
         | is uninteresting here.)
        
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