[HN Gopher] Iron fuel shows its mettle
       ___________________________________________________________________
        
       Iron fuel shows its mettle
        
       Author : mfiguiere
       Score  : 139 points
       Date   : 2023-06-23 14:48 UTC (8 hours ago)
        
 (HTM) web link (spectrum.ieee.org)
 (TXT) w3m dump (spectrum.ieee.org)
        
       | j-a-a-p wrote:
       | Looks like the same thing as Form Energy provides. They are
       | selling plants at MW level (article is about a small brewery at
       | kW level)
       | 
       | https://formenergy.com/
        
         | olau wrote:
         | Form Energy is a bit light on details, but it looks like they
         | are using a water based electrolyte, add oxygen, get electric
         | power and rust when discharging, then add electric power and
         | get iron and oxygen when charging.
         | 
         | The project mentioned here is setting the iron powder on fire
         | and need to use a steam turbine to get electric power out of
         | it. So different tech.
        
           | j-a-a-p wrote:
           | > _Our first commercial product is an iron-air battery
           | capable of storing electricity for 100 hours at system costs
           | competitive with legacy power plants._
           | 
           | https://formenergy.com/technology/battery-technology/
           | 
           | But yes, I was triggered with iron alone, but they both seem
           | to burn iron. There is a whole industry of flow batteries
           | emerging also.
        
       | howlin wrote:
       | I don't really understand why iron is being considered over
       | aluminum. Is aluminum production from ore too complex compared to
       | iron? I would have to imagine burning metallic aluminum produces
       | much more energy per gram.
        
         | chewbacha wrote:
         | My gut is to assume that aluminum isn't as viable because it
         | does _not_ oxidize as readily as iron does.
        
         | samus wrote:
         | Aluminium production is complex and might be less efficient per
         | kilogram than iron production. Also, compared to iron there are
         | no known processes to employ hydrogen, which can be had from
         | green-ish sources, in aluminium production.
        
       | Tade0 wrote:
       | > "Places that have excess energy could make iron, and others can
       | buy it. This way, you could commodify renewable energy so it can
       | be globally distributed without the need for transmission lines.
       | Metals can solve a big problem in the renewable energy
       | transition: long-duration energy storage."
       | 
       | My gut feeling is that transmission lines would still be cheaper.
       | That being said long-term storage seems to be the value
       | proposition here.
       | 
       | In my corner of the world coal is still frequently used to heat
       | homes during winter. A single house uses around 4-6 tonnes of the
       | stuff each season. This heap of coal takes a significant amount
       | of space.
       | 
       | If my back of the napkin calculations are correct, the energy
       | equivalent in iron dust would be half the volume. Of course
       | there's the issue of weight - about 5x that of coal, but perhaps
       | the cost of moving all that iron could be somewhat mitigated by
       | having a rust reprocessing plant in the neighbourhood.
        
         | elil17 wrote:
         | Transmission is expensive if you're running a line to somewhere
         | without a lot of demand. Something like this could be a
         | relevant solution for anything in remote locations.
        
         | chasil wrote:
         | "Altiro gets around this problem by adding a little natural gas
         | to ignite the iron powder when the boiler first starts up."
         | 
         | You will also need a very specialized furnace, and supplies of
         | CH4.
        
           | samus wrote:
           | The demand for natural gas is probably minuscule compared to
           | the total heat output of a burning cycle. Also, thanks to the
           | war in Ukraine, demand for natural gas might decline in the
           | long term if European countries switch to alternative,
           | hopefully greener, energy sources.
        
           | Tade0 wrote:
           | I suppose it's not more complicated than an LPG system in a
           | car, which fires up on gasoline and switches to gas only
           | after warm-up.
           | 
           | My Uber today was a Corolla hybrid and at one point I heard
           | the telltale clunk of the LPG system engaging. Apparently you
           | can have that on a hybrid as well.
        
         | ben_w wrote:
         | Yeah.
         | 
         | Article says energy density of 11.3 kWh/litre.
         | 
         | WolframAlpha says using that for all global electricity for a
         | day is 33e9 kg iron:
         | http://www.wolframalpha.com/input/?i=2%20TW%20%2A%201%20day%...
         | 
         | Some estimates I did a while back and then wrote up nicely with
         | ChatGPT said a global power grid would use about x100 that much
         | iron: https://github.com/BenWheatley/Studies-of-
         | AI/blob/main/Globa...
         | 
         | So the cut off between them is that if you use this for more
         | than about four (/eight) months, the grid was cheaper.
         | 
         | That said, while I personally love the idea of a global grid,
         | geopolitics rather than technical merit is likely to be the
         | dominant constraint for any solution, as everything[0] is cheap
         | enough that cost doesn't matter.
         | 
         | Also, possibly still useful for shipping? Possibly? I assume
         | they'd prefer synthetic oil, but I don't claim any real
         | knowledge, that's just my uninformed guess.
         | 
         | [0] Well, almost everything -- concrete-based gravity batteries
         | produce too much CO2 so they're expensive with current
         | production methods just in a non-monetary sense, and antimatter
         | production is so inefficient it's not viable, but those are the
         | only two exceptions I know about.
        
         | fnordpiglet wrote:
         | Iceland has absurd amounts of spare energy. So they bring in
         | ships full of bauxite and refine it into aluminum blocks then
         | load it back on the ship. Aluminum is refined by electrolysis,
         | so it's a perfect way to export their excess electricity.
         | 
         | That's stocking btw that it takes 4 tons of coal per year per
         | house. That's an absurd amount.
        
           | euroderf wrote:
           | I'm a serious PITA about recycling aluminum. I have this
           | mental image of vast quantities of bauxite and energy being
           | tossed out whenever an aluminum container (or bit of foil) is
           | not recycled. But I don't have any firm numbers.
        
             | Tagbert wrote:
             | According to:
             | https://www.lehighcounty.org/Departments/Solid-waste-
             | managem....
             | 
             | "About 65 % of America's aluminum is currently recycled."
             | That's pretty good. Much better than most materials.
        
           | caseyohara wrote:
           | It's not that absurd. One ton of coal produces ~25 million
           | BTUs. That's about the same output as a cord of oak or
           | hickory, which weigh about 2 tons per cord. And most people
           | that heat their home exclusively by burning wood use about
           | 5-6 cords per year.
        
         | [deleted]
        
         | _hypx wrote:
         | Pipelines of liquid or gaseous fuels is pretty much always
         | going to be the cheapest solution for energy transmission. This
         | fact will inevitably lead to people investing in some kind of
         | green chemical. If not hydrogen, then likely something made
         | from hydrogen like ammonia or methanol.
         | 
         | It's not actually clear if transmission lines are cheaper.
         | Ships and trains can carry a lot of mass. For an energy dense
         | fuel, this can be cheaper. Then again, this idea needs you to
         | carry things in both directions, both the iron and the iron
         | oxide. That may doom this idea to being too expensive.
        
           | lll-o-lll wrote:
           | How many posts about hydrogen being the best and only hope
           | have you made here?
           | 
           | I can't recall it all now, but my understanding was that if
           | you take the entire chain from production to storage to
           | consumption of hydrogen, it's pretty much an unworkable
           | engineering problem. "The closest thing to a vacuum, other
           | than a vacuum" was one memorable quote. Happy to be shown to
           | be wrong.
        
             | _hypx wrote:
             | Because it is instrumental to solving to climate change.
             | The better question is why are people unwilling to take the
             | problem seriously?
             | 
             | Your understanding is the result of years of FUD against
             | it. People really need to understand that they have been
             | lied to repeatedly on this subject. If you have a basic
             | grasp of engineering, you should understanding that it is
             | literally made by running electricity through water. It is
             | an incredible simple idea that you can even do at home. And
             | since hydrogen is already being used in a vast number of
             | industrial and chemical processes, it should be clear that
             | there could not be any fundamental technical challenges
             | that haven't been solved.
        
         | SmooL wrote:
         | > My gut feeling is that transmission lines would still be
         | cheaper
         | 
         | Transmission lines are great for moving electricity, but only
         | if there's demand for that electricity _right now_. Otherwise,
         | you have to store it - which is a problem, because battery tech
         | right now isn't great (or rather, it's not good enough for
         | grid-scale requirements) . This iron powder could be thought of
         | as a "battery". It might be harder to move than compared to a
         | transmission line, but it's _stored_ energy and can be redeemed
         | at a later time.
        
           | rootusrootus wrote:
           | > not good enough for grid-scale requirements
           | 
           | Is that still true? Aren't there a number of very successful
           | grid battery installations now? And given the steady decline
           | in battery costs, it ought to just get better and better.
        
             | dgacmu wrote:
             | Batteries are amazing for short term supply / grid
             | stabilization. They can supply massive current on very
             | short notice. But the cost per kilowatt hour is still
             | painfully high if we're talking about more than a handful
             | of hours. Fortunately, it's still headed downward.
        
             | xyzzyz wrote:
             | There are successful grid battery installations, but as far
             | as I know, there are no _grid-scale_ battery installations.
             | Existing installations have really small capacity, and are
             | only used for things like demand smoothing. The only energy
             | storage solution deployed at scale is pumped hydro storage.
        
               | gpm wrote:
               | For anyone wondering
               | 
               | List of pumped-storage hydroelectric power stations
               | https://en.wikipedia.org/wiki/List_of_pumped-
               | storage_hydroel...
               | 
               | List of (non-hydro) energy storage power plants https://e
               | n.wikipedia.org/wiki/List_of_energy_storage_power_p...
               | 
               | Largest battery plants in particular: https://en.wikipedi
               | a.org/wiki/Battery_storage_power_station#...
               | 
               | "Really small capacity" here apparently means "roughly 4
               | hours of discharging as fast as possible".
        
           | hankman86 wrote:
           | But isn't that the point of transmission lines - match supply
           | and demand? Given a large enough region, there is going to be
           | a place where renewable electricity can be produced. Case in
           | point being offshore wind turbines where there are almost
           | always strong winds to spin these. Moving this electricity to
           | where it is consumed is a huge issue though. Existing power
           | grids were created with centralised power stations in mind,
           | which are usually located close to where the electricity will
           | be needed.
        
             | SmooL wrote:
             | Yes, but transmission lines can only go so far, and you
             | still lack the ability to arbitrage over time instead of
             | just spatially. E.g. from a solar power POV, it's night
             | everywhere in a given region at the same time.
        
           | cogman10 wrote:
           | > or rather, it's not good enough for grid-scale requirements
           | 
           | I disagree with this point. LFP batteries are cheap, high
           | density, and have huge cycle life. The big drawback of LFPs
           | is manufacturing is just starting to ramp up on them. That
           | is, they aren't available.
           | 
           | LFPs just came out of patent protection last year and you are
           | already starting to see them everywhere. The biggest problem
           | with LFPs today is demand is outstripping supply.
        
             | baybal2 wrote:
             | [dead]
        
             | concordDance wrote:
             | Got any numbers here?
        
               | cogman10 wrote:
               | For LFPs at the moment we are looking at 100->150/kwh of
               | storage. [1]
               | 
               | Cycle life is around 3000->10000 cycles depending on how
               | deep the cycles are (more shallow cycles, longer battery
               | life). [2]
               | 
               | Note: Cycle life is about how long it takes for a battery
               | to lose 20% of it's capacity. That doesn't mean you can't
               | still use it.
               | 
               | [1] https://www.fastmarkets.com/insights/the-ev-battery-
               | chemistr...
               | 
               | [2] https://www.powertechsystems.eu/home/tech-
               | corner/lithium-iro...
        
               | Retric wrote:
               | They're cheap enough for EV's, but the big number here is
               | you can get 10,000+ charge/discharge cycles. Predictions
               | are near term ~2c/kWh grid storage looks realistic which
               | completely changes the economics of the electricity grid.
               | (As in whatever you pay for the electricity to charge the
               | batteries you need to charge 2 more cents/kWh at
               | discharge to break even.)
               | 
               | Pair with renewables and not only is nuclear and coal
               | looking obsolete but even natural gas is uneconomical at
               | current prices. Of course the economy reacts as you start
               | to bring this stuff online which means wholesale natural
               | gas prices could fall quite a bit etc. You also need
               | enough wind/solar/hydro to actually charge the batteries,
               | but that doesn't seem to be an issue either.
        
             | ac29 wrote:
             | Assuming LFP means Lithium Iron Phosphate (LiFePO4)?
             | 
             | Not sure how to reconcile "they aren't available" with
             | "starting to see them everywhere".
             | 
             | They're great batteries (especially compared to lead acid)
             | and at least in small quantities, they have been widely
             | available for years.
        
             | coryrc wrote:
             | If we're using renewables, we need seasonal shifting, so
             | cycle life doesn't matter at one cycle per year.
             | 
             | You could build nuclear to supply your winter power, but
             | then you're overbuilt for summer and don't need any
             | renewable. Or you could store heat directly in the ground
             | like that Alberta pilot project, heat collectors on the
             | roofs all summer drive the heat underground, pump it back
             | out all winter.
             | 
             | Or our current plan, pretend to be "green" by spending
             | money on solar while increasing coal usage and no feasible
             | plan to replace space heating.
        
               | bryanlarsen wrote:
               | We don't need seasonal storage. The sun still shines in
               | the winter, unless you're in the Arctic circle. We can
               | use over building, production diversity, interconnection
               | and short term storage instead. Or just use natgas
               | peakers for the last 1% and call a 99% solution good
               | enough.
               | 
               | If we had reasonably priced seasonal storage we'd use it,
               | but we don't need it.
        
       | wongarsu wrote:
       | > "You can think of iron fuel as a clean, recyclable coal," says
       | Bergthorson.
       | 
       | I was under the impression that basically all naturally found
       | iron is in the form of iron oxide. Which means you first have to
       | put in energy to reduce it to pure iron, to then burn it and turn
       | it back to iron oxide. That's much closer to what a battery does,
       | or hydrogen, than it is to coal.
       | 
       | I imagine it's still useful in many applications since hydrogen
       | is a pain to store and transport.
        
       | hankman86 wrote:
       | Or you just use the iron to build more towers for wind turbines.
       | Or transmission lines to send renewable electricity to where it
       | is needed.
        
         | samus wrote:
         | There is no shortage of iron, while this is another way to make
         | usage of abundant renewable energy. Especially when at the
         | destination actually heat is required. Apart from that, neither
         | wind turbines nor more transmission lines help with the problem
         | of making excess energy available for _future_ use.
        
           | mrguyorama wrote:
           | Using electricity to run a heat pump will beat combustion in
           | efficiency, and that only becomes way more true when the
           | energy source starts as electricity being sunk into creating
           | a synthetic fuel.
        
       | jokoon wrote:
       | At that rate, there should be an encyclopedia dedicated to all
       | projects that can be described as greenwashing.
       | 
       | I think it's a new strategy to "drown the fish", by flooding the
       | media with "green" technologies just to pretend to say "we heard
       | you, we are going to change the world with green new things" only
       | to save more time until everybody realize each of those new
       | projects are just not viable. The air travel sector seems to be
       | rife with this.
       | 
       | Who could have guessed that snake oil could work in something as
       | serious as the energy sector, I'm really surprised it's getting
       | so low.
       | 
       | I'm going to be brutally honest, but you even hear people from
       | first world countries playing the poverty card when you tell them
       | they should stop driving alone in a 1 ton vehicle, and it seems
       | sobriety and de-growth will have to convince those people that
       | fossil fuels are a privilege, not a right.
       | 
       | I can bet that we are going to see people sabotaging cars, gas
       | stations and refineries pretty soon if nothing is done. Greta
       | Thunberg will be 25 soon and a whole generation will not tolerate
       | more lies.
        
         | Slava_Propanei wrote:
         | [dead]
        
         | elihu wrote:
         | 1 ton vehicles would actually be an improvement on the status
         | quo, at least in the U.S. where a "small" car is usually more
         | like 3,000 to 4,000 pounds.
         | 
         | Also, if self driving becomes wide-spread and successful, we're
         | going to start seeing a lot of zero-occupant cars on the road,
         | most likely bringing the average vehicle occupancy below 1.
        
         | Animats wrote:
         | Yes. See "blue hydrogen", "grey hydrogen" (from natural gas),
         | "black hydrogen" (from coal), "turquoise hydrogen" (from
         | methane)...[1]
         | 
         | [1] https://www.weforum.org/agenda/2021/07/clean-energy-green-
         | hy...
        
         | unwind wrote:
         | Okay, but it would be more helpful if you provided some actual
         | arguments against the technology.
        
           | cyberax wrote:
           | It's another "use energy/hydrogen to create a fuel"
           | technology.
           | 
           | This one creates a very inconvenient fuel: iron powder. It
           | can't be efficiently piped, and it needs some very strange
           | technology to make it burn in controlled conditions. And you
           | cannot use it for gas turbines or piston-based engines.
           | 
           | At this point, if you have hydrogen, you can just use it to
           | produce methane that has none of these problems. Or maybe
           | ammonia if we ever get catalysts working at mild conditions.
        
         | concordDance wrote:
         | While it's very true that greenwashing is a thing, bans on
         | fossil fuels are not the right approach. You need sin taxes
         | that account for the cost of the externalities instead. A CO2
         | tax is sensible, "degrowth" is a horrific thing that will kill
         | billions.
        
           | nyc_data_geek1 wrote:
           | Done correctly, degrowth need not lead to billions of deaths.
           | We desperately need to restructure our economic systems and
           | societies to account for the reality that infinite economic
           | growth on a finite world is not possible, realistic or
           | desirable. If we do so, we can minimize the bleeding.
           | 
           | If we fail to, billions will die on hothouse Earth
           | regardless.
        
             | Slava_Propanei wrote:
             | [dead]
        
       | CoastalCoder wrote:
       | It would be fun if our next major technology stage is the "iron
       | age".
        
       | MagicMoonlight wrote:
       | Comparing petrol with iron based on volume rather than weight
       | seems highly misleading. I'm assuming that actual energy density
       | is much worse with iron right?
        
       | obblekk wrote:
       | > 0.3% of the Iron-oxide becomes nanoparticles which cannot be
       | converted back into Iron.
       | 
       | At that rate, 50% of the initial iron will be gone in 333 cycles
       | of iron -> iron oxide -> iron.
       | 
       | This a hard type of energy source to reason about:
       | 
       | 1. It's not a pure fuel and acts like a battery most of the time,
       | but it's also not renewable
       | 
       | 2. Iron is extremely abundant on Earth, but it requires mining
       | and processing to extract
       | 
       | 3. Iron oxide in nanoparticle size would likely be a pollutant
       | and hazardous to human health, not something that will break down
       | quickly and harmlessly.
       | 
       | The high fuel density and low explosiveness may make it a good
       | use case in some niches, but I imagine it's actually more
       | scalable and healthy to burn jet fuel and reproduce it from
       | renewable powered carbon capture, where density is needed.
        
         | umvi wrote:
         | > The nanoparticles are not emitted in the atmosphere but
         | captured in a HEPA filter.
         | 
         | If that's true, your point #3 is moot. And if the nano
         | particles can be captured by a filter, maybe we could design
         | filters specifically for iron oxide nano particles that would
         | allow the nano particles to be extracted
         | 
         | > but I imagine it's actually more scalable and healthy to burn
         | jet fuel and reproduce it from renewable powered carbon
         | capture, where density is needed.
         | 
         | You're saying capture carbon from CO2 and turn it into
         | kerosene? I tried googling around and everywhere I look it
         | seems like this is currently _way_ more difficult than
         | renewable iron fuel (https://www.planet.veolia.com/en/how-
         | produce-kerosene-co2).
        
           | a3w wrote:
           | Cherry-picking the fuel for jets example makes sense, since
           | somehow we don't expect aviation to transition completely to
           | airscrews.
           | 
           | As for the disposal of HEPA filteres loaded with air-stable
           | inorganics, that still is pollution, only the kind of waste
           | you store safely, and if not give people cancer, but highly
           | localized so.
        
         | jerf wrote:
         | To a first approximation, Earth is a big ball of iron, so
         | losing 50% of the iron in 333 cycles doesn't seem like that big
         | a deal. Getting more iron is an energy issue rather than an
         | availability issue.
         | 
         | I'm also somewhat concerned about the nanoparticle's effect on
         | living things. It is likely that it is only a question of local
         | exposure, as in general once they get out they should still
         | rust in some relatively short period of time, and as Earth is
         | the aforementioned big ball of iron, a bit of rust in the
         | environment is quite unlikely to hurt anything because if it
         | could hurt a thing that thing would already be dead, but
         | locally nanoparticles would be something weird and I could see
         | breathing them could be problematic. It is also entirely
         | possible that it is safe up to surprisingly absurd levels too
         | (your body is familiar with iron, and while there are toxic
         | doses of iron you're not getting to them with nanoparticle
         | exposure any time soon), it would just be something that would
         | need some study.
        
           | marcosdumay wrote:
           | > once they get out they should still rust in some relatively
           | short period of time
           | 
           | Nanoparticles of iron _oxide_ are already rust.
           | 
           | There is certainly some inorganic phenomenon that will turn
           | it into normal, aggregated rust. It probably requires water
           | and some time.
           | 
           | But those particles sound like the kind of thing that will
           | stay for years on the atmosphere, and contaminate every
           | living thing. And yeah, they are probably safe in some
           | surprisingly large amount, so whatever direction it goes, we
           | will only know after we start doing it.
        
             | mrguyorama wrote:
             | Maybe then we could stop putting iron filings in children's
             | cereal as a supplement.
        
           | onlyrealcuzzo wrote:
           | > so losing 50% of the iron in 333 cycles doesn't seem like
           | that big a deal.
           | 
           | Where does the Iron go??? It's not like Fission or Fusion is
           | happening, right?!
        
           | rsaesha wrote:
           | >Earth is a big ball of iron.
           | 
           | No it's not.
           | 
           | Inside the crust both Si and Al are more common.
           | 
           | There is plenty of Fe, which is all in oxide form. Mining and
           | processing required.
        
         | proto-n wrote:
         | Is iron oxide magnetic in nanoparticle size? Because if it is,
         | then we can probably very efficiently filter it before
         | releasing it into the atmosphere.
        
           | idiotsecant wrote:
           | Even if it isn't we are very good at filtering materials from
           | exhaust gasses. Something like a wet electrostatic
           | precipitator is probably overkill, but would do the job
           | without having to care about magnetic properties.
        
           | nabla9 wrote:
           | Traditional methods or their combination: wet scrubber,
           | electrostatic precipitator or bag filters will do the job.
        
           | juujian wrote:
           | The article mentions a HEPA filter.
        
             | sudhirj wrote:
             | That's still a mess, if the particles are magnetic a magnet
             | will be a way cleaner and more effective filter.
        
           | thsksbd wrote:
           | iron oxide magnetic properties depend on its oxidation state,
           | temperature and particle size.
        
             | 13of40 wrote:
             | Not sure why this is dead, but AFAIK magnetism in iron and
             | steel is dependent on "domains" of iron molecules that are
             | aligned in a crystal structure so the magnetic effect isn't
             | just scattered to all directions. That's why some kinds of
             | stainless steel aren't magnetic - the adulturant elements
             | break up the crystal structure. In this case I think the
             | question would be whether these particles are big enough to
             | form a "domain" and become magnetic.
        
               | thsksbd wrote:
               | [dead]
        
               | pixl97 wrote:
               | If the output is iron oxide, no it is only very very
               | weakly magnetic.
        
         | jjk166 wrote:
         | The nanoparticles can't be converted back to iron in this
         | process, but they can still be turned back into iron by other
         | processes. No system is truly closed loop, but this is more
         | closed loop than any other energy-to-fuel system.
         | 
         | You need to extract the feedstocks for any energy-to-fuel
         | system. Iron is cheap and simple to extract, compared to say
         | carbon from the atmosphere.
         | 
         | The nanoparticles do not get released to the environment.
         | Emissions from burning carbon based fuels also include
         | pollutants that are hazardous to human health.
        
           | idiotsecant wrote:
           | > Emissions from burning carbon based fuels also include
           | pollutants that are hazardous to human health.
           | 
           | Which _do_ get released into the environment in quite large
           | quantities!
        
         | mirekrusin wrote:
         | Can't you just make pulsating/spinning magnet to capture it?
        
         | juujian wrote:
         | Might be possible to create a completely closed system to
         | address the loss?
         | 
         | I am more concerned/confused by the fact that they use hydrogen
         | to reduce the iron. That seems like a very convoluted process,
         | why not use the hydrogen generate heat instead? Yes, it has
         | much lower density, but it has advantages to make up for it,
         | for instance the fact that you don't need to worry about
         | evaporation, leakage, filters, all that at all.
        
           | PaulHoule wrote:
           | Hydrogen is devilishly hard to transport and store. Hydrogen
           | packs a lot of energy per gram, but the density is so low.
           | You need a huge tank if you compress it as a gas, you can
           | liquefy it but the density is still not great, it takes a lot
           | of energy, and you have to deal with this:
           | 
           | https://en.wikipedia.org/wiki/Spin_isomers_of_hydrogen
           | 
           | freshly liquefied hydrogen contains a lot of stored energy in
           | that form which will be released over time and cause quite a
           | bit to vaporize, for long term storage you have to release
           | that energy.
           | 
           | Thus people have looked at all sorts of schemes for storing
           | hydrogen such as absorbing it in metals like palladium, metal
           | hydrides, chemical carriers such as ammonia, methane, etc.
        
             | kaliszad wrote:
             | Sodium would be a much better proposition. With NaOH, you
             | can create a closed cycle. The electrolysis of NaOH is the
             | well known Castner process, a consumable metal anode fuel
             | cell with sodium is also well known (expired Patent:
             | US3730776A by Lockheed) More details and overlap with other
             | approaches: https://orgpad.com/s/5BfLP-cxj-7
             | 
             | Sodium has higher energy density (3.5 kWh/L) than liquid
             | hydrogen, there is no energy needed to store it and no
             | catalyst is needed for the fuel cell because sodium is so
             | reactive with water. The fuel cell is rather easy to
             | construct (I know somebody, who has done it in a garage).
             | NaOH solution is very caustic but also neutralizes well
             | naturally without long term effects at least in comparison
             | to crude oil that seems to be the better proposition. And
             | of course sodium is everywhere, where NaCl - table salt is.
        
       | cmrdporcupine wrote:
       | _"it's more efficient to produce iron from hydrogen gas than to
       | produce liquid hydrogen. So iron powder as fuel is more expensive
       | than gaseous hydrogen but cheaper to produce and move across the
       | oceans than liquid hydrogen."_
       | 
       | He's saying liquid _hydrogen_ , but I gotta wonder if the the
       | real story here is an attempt to deal with moving the energy in
       | _natural gas_ , since the liquified natural gas story is so
       | shitty (expensive facilities, etc.) and pipelines are politically
       | and logistically difficult.
       | 
       | I would not be surprised to see this turned into a "burn/process
       | natural gas (in North America etc) to produce the iron 'fuel'.
       | Ship the iron by train or boat & skip building pipelines and
       | tankers and LNG facilities." Which gets us no further on the
       | climate change front, but answers certain current European (esp
       | German) ... political / economic ... problems.
        
       | SamPatt wrote:
       | Requiring natural gas to work makes me a bit skeptical. They
       | don't indicate how significant the nat gas component is, but if
       | prices are low, it will be much simpler and cheaper to just use
       | the gas itself.
        
       | FrustratedMonky wrote:
       | Doesn't this seem like we are just going to use up iron supplies.
       | Iron would then become a used up commodity and drive up prices.
       | Just like when Corn was used for ethanol, the side effect was
       | driving up corn prices, and raising food prices. This could use
       | up Iron, and then impact a ton of stuff.
       | 
       | EDIT
       | 
       | Missed this: "This can later be reduced--that is, the oxygen can
       | be stripped away--back into iron powder. "You can think of iron
       | fuel as a clean, recyclable coal," says Bergthorson."
       | 
       | So guess it's all good.
        
         | RajT88 wrote:
         | The iron mining biz would probably expand, pushing prices down.
         | 
         | Iron is just everywhere. I can go out in my back yard and find
         | rocks which contain ore.
        
         | bioemerl wrote:
         | Iron is one of the most abundant elements on earth, but also we
         | aren't going to be burning it like we do fuels now. Instead we
         | would produce pure iron using green power and oxidize it back
         | to it's natural state for energy in a cycle.
         | 
         | Imagine loading an iron rod into your car, driving for a while,
         | and then when you get into the gas station you dump a pile of
         | rust off and buy a fresh iron bar.
        
           | neolefty wrote:
           | Some societal implications:
           | 
           | * Kids playing with iron filings sounds a lot safer than kids
           | playing with gasoline. "Don't leave your magnets in the fuel
           | tank; it clogs up the lines!"
           | 
           | * The gasoline party scene in Zoolander would need to be
           | reconsidered.
        
         | Arubis wrote:
         | If we have to pick a natural resource to exploit for fuel, iron
         | is a good choice:
         | https://en.wikipedia.org/wiki/Abundance_of_the_chemical_elem...
        
       | GlibMonkeyDeath wrote:
       | Sounds like one of the least efficient energy storage ideas I've
       | heard in a long time, I wonder how this is getting funded? Hmm,
       | let's check to see who is behind this...the founding professor
       | https://www.tue.nl/en/research/researchers/philip-de-goey/ is a
       | fellow/awardee of the Combustion Institute, gets funding from
       | ERC, etc. OK, so I guess all that European taxpayer money won't
       | spend itself, and if you have a hammer blah blah nails...
       | 
       | Meanwhile, stationary class (i.e. relatively poor energy density)
       | iron air batteries are making commercial progress. https://pv-
       | magazine-usa.com/2023/06/12/form-energy-to-deploy...
        
         | volkl48 wrote:
         | > Meanwhile, stationary class (i.e. relatively poor energy
         | density) iron air batteries are making commercial progress.
         | https://pv-magazine-usa.com/2023/06/12/form-energy-to-deploy...
         | 
         | Also seems worth mentioning ESS. https://essinc.com/
         | 
         | They're a bit further along (scaling up from low-volume
         | production, some installs in the wild) with a different
         | approach to the use of iron (flow batteries).
        
           | scythe wrote:
           | ESS should not be mentioned except as an example of how prone
           | the green news cycle is to fraud. As I detailed last year,
           | their claims are highly dubious:
           | 
           | https://news.ycombinator.com/item?id=31430227
           | 
           | (previously I misspelled the last name of Sri Narayanan as
           | "Narayan", for which I belatedly apologize)
           | 
           | And that prediction was substantiated when they were subject
           | to a class-action shareholder lawsuit in February involving a
           | fabricated customer which was actually a subsidiary:
           | 
           | https://www.bloomberg.com/press-releases/2023-03-10/the-
           | law-...
           | 
           | The other shoe has yet to drop, but I suggest that any
           | battery company without publications should be considered
           | with appropriate salinity.
        
         | Animats wrote:
         | Yes, this is a strange approach. Separate iron from iron oxide,
         | which is energy intensive. That's what blast furnaces did, or
         | do, and it's a messy and energy-intensive process. Burn iron to
         | get heat and iron oxide. Repeat.
         | 
         | Are there numbers on the energy efficiency and costs of this
         | process? This seems very strange. Batteries are above 90%
         | round-trip efficiency now. This has to be lower.
        
           | chasil wrote:
           | According to the source below, aluminum has higher energy
           | density than iron (23.5kWh/L versus 16.7kWh/L).
           | 
           | The entry for iron in the link below is also higher than the
           | iron energy density reported in the parent link (11/3 kWh/L).
           | 
           | https://onlinelibrary.wiley.com/doi/full/10.1002/ente.202000.
           | ..
           | 
           | Of course, aluminum used in this way is the classic thermite
           | reaction; I conjecture that the iron reaction is also.
           | 
           | https://en.wikipedia.org/wiki/Thermite
        
       | thescriptkiddie wrote:
       | > Iron oxide can also be reduced to iron using hydrogen
       | 
       | > Altiro gets around this problem by adding a little natural gas
       | 
       | This is transparently just green washing from the fossil fuel
       | industry. There is no way that this will be an efficient energy
       | storage mechanism and it definitely won't be carbon neutral.
       | Developing cost-effective methods to produce steel from iron ore
       | without the use of coke (coal) is important, but if you want to
       | do that just do that.
        
         | samus wrote:
         | The natural gas is used to help starting and stabilizing the
         | flame. Actual use of natural gas is probably negligible to the
         | total output of the process.
        
       | scythe wrote:
       | Similar proposals have been made previously, particularly for
       | boron, which has ten times the energy density of iron, and yet
       | similar low combustibility:
       | 
       | http://www.eagle.ca/~gcowan/boron_blast.html
        
       | bbojan wrote:
       | The elephant in the room are, as always, nitrous oxides (NOx).
       | 
       | Whenever you burn something in a nitrogen atmosphere, NOx are
       | created. They contribute to acid rain and the formation of smog,
       | and are a trigger for asthma.
        
         | samus wrote:
         | While certainly being an issue, they are a far smaller problem
         | than emissions of greenhouse gases by fossil power sources. It
         | is a greenhouse gas itself, but most human emissions come from
         | agriculture. Moreover, there are technologies to reduce the
         | emission of NOx'es from burning processes.
        
       | rcme wrote:
       | Is iron oxide really that much more volumous than iron? In terms
       | of capturing the iron oxide, why couldn't this be run in a sealed
       | container with a valve that allows oxygen in? This doesn't work
       | for hydrocarbons because the volume of CO2 is orders of magnitude
       | greater than the volume of fuel, but does iron oxide have the
       | same issue?
        
         | MauranKilom wrote:
         | I vaguely remember that continuous processes are strongly
         | preferred over batch processes. Especially for such things as
         | "provide energy".
        
       | rfreytag wrote:
       | I assume they are using renewable energy to reduce naturally-
       | occurring iron oxide.
       | 
       | When the iron is burnt are they going to do with pure oxygen?
       | Otherwise they'll get pollutants like nitrogen dioxide, possibly
       | ozone. And the 0.5% not burnt will also become a pollutant unless
       | carefully removed in some smokestack scrubber.
       | 
       | Or is this 'burning' to occur some kind of iron fuel cell? How
       | would they liquidize the iron which is quite heavy?
       | 
       | Lastly, iron is heavy. Moving reduced iron could be expensive and
       | dangerous.
       | 
       | Still, if sufficiently close to the renewable source this could
       | provide much needed load leveling for intermittent sources.
        
         | samus wrote:
         | The article assumes the viability of a hydrogen-driven process
         | to reduce the iron. The intention is to establish a circular
         | economy of reducing iron oxidized by burning it in the proposed
         | fashion.
         | 
         | The byproducts from burning iron are no more noxious than
         | burning fossil fuels, possibly less so. Filtration technologies
         | exist as well.
         | 
         | Of course this technology would have to compete with other
         | technologies to make use of excess renewable energy, like
         | liquid hydrogen storage and transport (which it has several
         | advantages over), iron-based battery technologies, or green-
         | produced carbon-based fuels. I guess it makes the most sense in
         | applications where heat instead of electricity is required.
        
           | _hypx wrote:
           | > Of course this technology would have to compete with other
           | technologies to make use of excess renewable energy, like
           | liquid hydrogen storage and transport (which it has several
           | advantages over), iron-based battery technologies, or green-
           | produced carbon-based fuels. I guess it makes the most sense
           | in applications where heat instead of electricity is
           | required.
           | 
           | I'm going to come out and say those competing technologies
           | are vastly more plausible and viable.
        
       | jacknews wrote:
       | This makes no sense to me.
       | 
       | Iron/steel production is one of the largest individual sources of
       | co2 emissions and uses a lot of energy.
       | 
       | And then to just burn it back into iron ore for energy - At best
       | you'll only get back the energy you expended to refine it in the
       | first place.
       | 
       | Assuming they are burning scrap, it would surely be better to
       | melt it down and recycle it as steel.
       | 
       | As energy storage, it may well have more energy per liter than
       | gasoline, but it weighs many times more. There are surely better
       | options - even in the same category, eg aluminium?
        
         | neolefty wrote:
         | True, if we're getting it the traditional way.
         | 
         | Fortunately, iron oxide can be reduced using hydrogen. In the
         | article, they conclude that the system cost of shipping iron
         | and iron oxide back and forth from an electrolysis facility
         | (presumably from renewables) is lower than using hydrogen
         | directly as a fuel.
        
       | OrbitalPewPew wrote:
       | Imagine thinking that a material stars can't use for fuel is one
       | that makes sense as a "renewable energy source." These idiots
       | need to go back and take undergraduate thermodynamics.
        
         | skyechurch wrote:
         | You can't extract energy from iron by nuclear fusion, which is
         | how stars "burn" fuel, but this is a chemical process, Fe + O2
         | => (some Fe&O compound) + energy.
        
         | JoeAltmaier wrote:
         | Confusing chemistry with fusion there.
        
           | OrbitalPewPew wrote:
           | [flagged]
        
         | thsksbd wrote:
         | Stars cant use Fe's _chemical_ energy because they 're too hot
         | and the entropy of not being bound to O2 is too high. (And Fe
         | is a trace element).
         | 
         | No one is talking about using Fe as fuel in a nuclear reactor,
         | or (even though the article muddles this) as a primary source
         | of chemical energy.
         | 
         | Its a battery. A heavy, big battery.
        
         | __MatrixMan__ wrote:
         | Skipping class to play with thermite was, in retrospect, an
         | educationally sound decision.
        
       | AlbertCory wrote:
       | There's an experiment in here where Theodore Gray "burns" iron:
       | 
       | https://www.youtube.com/watch?v=NMJtieqVUc4
       | 
       | I hosted this. Getting permission from the Building department to
       | have fire indoors was lotsa fun.
        
         | __MatrixMan__ wrote:
         | The lecture looks interesting, but if you want to skip to the
         | burning stuff part: https://youtu.be/NMJtieqVUc4?t=2587
         | 
         | I learned that stainless steel burns the hard way. You can use
         | stainless steel scrubby pads as a heat sink to vaporize DMT in
         | a contraption called "the machine". Naively, I thought steel
         | wool would work instead of the scrubby pad. It doesn't. The
         | fibers are too small and it ignites--pretty much exactly the
         | opposite of what you want in a vape.
        
           | AlbertCory wrote:
           | Pro tip: do Show Transcript to skip around a YT video. Find
           | the words you want, then click it.
        
       | PaulHoule wrote:
       | See also
       | https://en.wikipedia.org/wiki/Chemical_looping_combustion
        
       | scottLobster wrote:
       | And just like articles about hydrogen, no mention of the
       | extraction/distribution supply chains needed or the
       | costs/emissions involved. Nope, just focus on our fancy (ZERO
       | EMISSION) generator and ignore how the inputs are actually
       | produced.
       | 
       | It has the energy density of coal, only unlike coal it requires
       | both mines as well as smelters/processing facilities to produce
       | the iron powder. So this can only work if we build out twice the
       | infrastructure that coal currently enjoys, with all the costs and
       | emissions therein.
       | 
       | I'm so tired of breathless scientific reporting of
       | "breakthroughs" that ignores any and all economic context. Or,
       | like this article, treats it as a side issue to be addressed with
       | literally one sentence.
        
         | VadimPR wrote:
         | We are already using the most economically viable option. The
         | trouble is that it's not sustainable long term. The solution
         | then will not be the most economical one.
        
           | scottLobster wrote:
           | Right, but from an emissions standpoint this is a bad idea
           | too. You not going to create an emission-free iron
           | mine/processing supply chain any time soon. This just moves
           | the emissions up the chain and would take decades to build
           | out. It might be just as bad as coal in terms of emissions at
           | the end of the day, and marginally better at best.
           | 
           | Solar, Wind, more/better batteries and nuclear are our best
           | paths forward if we want to take the immediate action we need
           | to take. If crap like this gets traction we'll just have a
           | greenwashed future where all the coal and natural gas plants
           | will be gone, but global emissions will still be high and
           | power will be many times more expensive. Maybe then people
           | will start to do math.
           | 
           | Back when I was in college the Environmental Science majors
           | were a joke because the chemistry classes they took senior
           | year were the same classes the Chemical Engineers took
           | freshman year. I thought my university just had a crappy
           | environmental science program, but after reading a number of
           | articles like this one I'm thinking it might be a more
           | pervasive issue.
        
             | wolverine876 wrote:
             | Then the issue is with the chemical engineers, who haven't
             | learned the waste, counterproductiveness and foolishess of
             | dismissing other ideas, viewpoints and people. It's a
             | vicious cycle - it greatly limits their ability to learn
             | what they don't already believe, or deal with challenges to
             | their ideas. The only solution is to give no validity to
             | such dismissals.
             | 
             | I was taught that, in part, by a fed-up engineering
             | professor.
        
           | wolverine876 wrote:
           | > We are already using the most economically viable option.
           | 
           | Arguably we always are doing that, by definition. Investment
           | is spending money on current non-optimal returns in exchange
           | for much greater returns later.
           | 
           | If an investment had guaranteed success; if it had no flaws,
           | then it would already have been made. There is nothing
           | flawless in this world - not you or me, not Facebook or
           | Messi, not oil or iron or renewables or nuclear.
        
           | _hypx wrote:
           | The second most economically viable option is basically going
           | to be hydrogen in some way. Either made from renewables or
           | nuclear power, possible natural sources if they exist in
           | quantity. That is why you hear about it so much.
           | 
           | But this fact causes large scale confusion on all sides. For
           | those invested in the existing system, this is a threat. But
           | for those who think it will be some other kind of green
           | technology, this means admitting they were betting on the
           | wrong horse the whole time.
        
         | eddyzh wrote:
         | It is not an energy source. It is a (battery) energy storage
         | solution that can scale. Meant to support renewables use at
         | night/ low sun/low wind periods. And not on hourly scale like
         | normal batteries but on year scale on plant level.
         | 
         | Like in an energy plant. That during the day when there Is
         | surpluses they generate iron powder from ironoxide and cheap
         | electricity. And when there is no surplus they burn the iron
         | powder to irononoxid. And they can both be stored at unlimited
         | scale on a heap.
        
           | _hypx wrote:
           | The problem is that that is the same idea that people are
           | proposing with hydrogen energy storage systems. The
           | difference is that hydrogen works a lot like natural gas. You
           | can pipe it and fire up gas turbines with it. It is also
           | useful as a chemical feedstock in many industrial processes.
           | You can also use it to power vehicles, something that you
           | probably can't with this idea.
           | 
           | So in other words, this is a really crappy version of
           | something that already exists. I guess there are three
           | takeaways to be had:
           | 
           | 1) We still need large scale energy storage and it simply
           | cannot just be a pile of batteries. It really needs to be a
           | chemical system and it really has to be able to burn.
           | 
           | 2) But that always takes you down one road: Hydrogen or
           | something made from hydrogen. That's the only class of
           | chemicals that really works and doesn't involve carbon. This
           | causes a lot of conflict since it is definitely not many
           | people's favored energy storage idea. And since so much FUD
           | has been flung around for so long because of that, many
           | people have become convinced that this inevitability is
           | actually impossible.
           | 
           | 3) So you usually end up with two alternative ideas:
           | Something crazy like burning metals. I've heard of burning
           | boron too BTW. This particular proposal is a continuation of
           | that way of thinking. Probably they are all DOA ideas. And
           | the other is something akin to linking all of the grids
           | across world together with vast numbers of HVDC lines. But
           | this too is crazy, especially once you realize the sheer cost
           | and complexity of it all. Not to mention you are still
           | wasting oodles of energy since you have minimal energy
           | storage.
           | 
           | So eventually we end up in this cycle of one crazy idea being
           | proposed after another, and nothing of importance actually
           | being achieved.
        
         | pankajdoharey wrote:
         | This is another Aluminium Air battery, same concept different
         | metal. None of them considers splitting water is energy
         | intensive and inefficient. Another hydrogen fool cell category
         | fuel imo.
        
           | throwway120385 wrote:
           | Who cares if it's energy intensive or inefficient if our
           | other option for using the energy is to run it through a big
           | resistor or to not produce it in the first place? This is a
           | tool for repeatedly storing and releasing excess energy from
           | power plants that can't control their output in response to
           | grid conditions. Let's supposed for the sake of argument that
           | battery banks were prohibitively expensive in some
           | applications, and that hydroelectric storage was too damaging
           | to the local environment. In those cases, your only option is
           | to either dissipate any excess energy or to not produce it in
           | the first place.
           | 
           | What this does, then, is provide you an alternative storage
           | medium that is relatively inert until you want to use it. And
           | it provides you a simple self-sustatining scalable chemical
           | reaction that can be started by supplying some initial heat
           | and then goes on to produce even more heat steadily and
           | continuously until you run out of fuel.
        
       | photochemsyn wrote:
       | Seems like a niche technology, useful if you're sitting on tons
       | of scrap iron for example. I recall some proposals for using this
       | in long-distance cargo shipping instead of very dirty (and
       | fossil-sourced) bunker fuel, but even there synthetic diesel or
       | methane from atmospheric CO2 + water might be the more versatile
       | solution (and the overall mass of the iron required for say, a
       | trans-Pacific journey is an issue). See:
       | 
       | https://swzmaritime.nl/news/2020/02/27/why-iron-could-be-a-s...
       | 
       | > "A disadvantage of iron as a fuel for ships is the relatively
       | high specific mass of iron powder and the increase in the weight
       | of the iron oxide that is produced during combustion. As a
       | result, a ship will lie deeper and deeper during the voyage."
       | 
       | They seem to have a prototype in the works c. 2030.
        
       | wolverine876 wrote:
       | > It has an energy density of about 11.3 kilowatt-hours per liter
       | --better than gasoline.
       | 
       | How about per gram?
        
         | aredox wrote:
         | Sometimes volume is more important than mass (e.g. on a ship).
        
       | schwabacher wrote:
       | Is iron a potential replacement for coal in steel and cement
       | production?
        
         | adrianN wrote:
         | Making steel from ore using iron seems a bit weird. If you
         | already have a method to reduce the oxide, why not use it on
         | the ore?
        
         | wolverine876 wrote:
         | Steel in principle is iron + carbon.
        
         | droopyEyelids wrote:
         | it could be, but like other posters have mentioned, it takes a
         | lot of energy to mine and refine the iron so it'd be in a
         | usable state.
         | 
         | I think it's easiest to think of iron as another energy storage
         | medium that could ease the peaks of renewable energy, by taking
         | excess renewable energy to generate the iron, and oxidizing the
         | iron for energy generation during peak demand periods with low
         | renewable generation
         | 
         | It's like hydrogen in that way.
        
       | usrusr wrote:
       | I used to be very excited about the iron cycle when the first
       | news about that brewery appeared. But these days I wonder how
       | useful it really is, as an energy store? Won't it start oxidating
       | at room temperature unless kept in inert atmosphere? And if
       | that's a requirement, is it really that much less trouble than
       | plain H2 or some gaseous or liquid intermediate?
        
         | thsksbd wrote:
         | There's the kinetics of oxygen transport into a big pile of
         | iron powder. If that's not good enough, you can always
         | transport it in a closed container with a block of dry ice. You
         | don't even have to seal it, just change the chemical potential
         | of O2 in Fe.
        
         | moffkalast wrote:
         | The trouble level for H2 is reasonably high, so it could very
         | well be less.
        
         | csours wrote:
         | Yes, and gasoline will evaporate, natural gas will disperse,
         | etc. It's kept in a container until they burn it.
        
           | usrusr wrote:
           | Sure, but liquids and gases are routinely handled in vessels
           | with a maintenance interval of "never" on the inside, I'm not
           | so sure that could be transferred to a powder. But this might
           | be my lack of knowledge of existing processes in "powdery
           | industries" speaking, if those are solved problems there I
           | would not know.
           | 
           | Your mention of gasoline evaporating made me realize that
           | some of the iron oxidating is probably not all that bad, just
           | make sure that there's no ventilation continuously swapping
           | in fresh air. I guess I'm looking forward to the next iron
           | age!
        
             | csours wrote:
             | Handling iron particulate is well-established technology:
             | 
             | https://www.youtube.com/watch?v=PZHpeBubb_M
             | 
             | Note that this is about when it goes wrong, but also that
             | it is usually due to cost-cutting measures.
        
       | ermir wrote:
       | Iron is not widely available in nature as a ready-to-use element,
       | it must be processed into elemental iron, which takes a lot of
       | energy as input. Therefore this can't be really considered as
       | fuel, more like energy storage. You still need fossil fuels or
       | nuclear power to turn iron ores into iron, then you have iron
       | available for the process described in the article.
       | 
       | I'm not criticizing the process, but it's not accurate to call it
       | "fuel" like it could be the solution to replacing fossil fuels.
        
         | c0nsumer wrote:
         | The article says this. It wraps up with:
         | 
         | "If these problems can be overcome, you could use renewable
         | electricity to produce iron, store it as long as necessary,
         | transport it there and then burn it for power when needed, says
         | Bergthorson. "Places that have excess energy could make iron,
         | and others can buy it. This way, you could commodify renewable
         | energy so it can be globally distributed without the need for
         | transmission lines. Metals can solve a big problem in the
         | renewable energy transition: long-duration energy storage.""
        
           | intothemild wrote:
           | Sure you could use renewables to make iron. But that thought
           | process also extends to other methods too. You could use
           | renewables to make other non renewable fuels.
           | 
           | Why not just skip the middleman? Use renewables?
        
             | neolefty wrote:
             | They mention that with hydrogen. It's cheaper to _produce_
             | hydrogen but much harder to transport it. Fortunately,
             | hydrogen can reduce iron oxide, which turns out to be a
             | great complement. Their analysis is that the system cost of
             | burning iron and renewing it at electrolysis plants is
             | lower cost (and safer) than using hydrogen directly.
        
             | kinnth wrote:
             | Renewables are exceedingly bad at storing energy for times
             | when sun or wind isn't blowing so you always need a mix.
        
               | red-iron-pine wrote:
               | That's not a wind or sun problem, that's a battery and
               | transmission problem.
        
             | slashdev wrote:
             | Because renewables are intermittent and unevenly located.
             | This could potentially solve those problems.
             | 
             | There could be a space for it. Or maybe batteries will just
             | always be better. Depends on the full costs of each and the
             | use case. Burning fuel to make electricity is pretty
             | inefficient, but burning fuel for heat compares better.
        
             | TheGeminon wrote:
             | I think this is likely more of an energy storage project,
             | rather than an energy production one (which seems to be the
             | stance the article takes).
             | 
             | At grid-level, battery tech is challenging, requiring
             | technologies like pumped storage that require particular
             | environments (e.g. damming a river) and can't really be
             | transported.
             | 
             | If this works out you could use excess solar during the day
             | to deoxidize the rust produced, and then run the iron
             | reactor overnight, or on cloudy, windless days.
        
               | dmix wrote:
               | How does that battery/production distinction work? How is
               | it a battery if it is consuming/burning a fuel? More as a
               | stable fallback or something?
        
               | wongarsu wrote:
               | Non-rechargeable batteries are also consuming a fuel. The
               | products just stay in the same enclosed container. Same
               | with rechargable batteries, just that there the process
               | is easily reversible.
               | 
               | It is a bit of a fuzzy distinction. Batteries are
               | typically simple chemical reactions that cause electrons
               | to move around. But viewed from the outside a hydrogen
               | fuel cell behaves the same; so why not call this one a
               | battery too (especially since the process is reversible).
        
               | samus wrote:
               | A useful distinction seems to be that batteries are solid
               | state and don't use high process heat, else something
               | would be seriously wrong. Of course, the underlying
               | reactions are probably very similar if you look at them
               | with a chemist's eye.
        
               | balaga01 wrote:
               | Well, if you can burn it to produce energy + spent fuel
               | 
               | and then put back energy in the spent fuel to make new
               | fuel again
               | 
               | then you have really a battery. That's how li-ion
               | batteries work. The issue is the efficiency: how much of
               | the energy you used to recharge the "battery" (iron) is
               | going to be available when you discharge (burn) it
        
               | dmix wrote:
               | Thanks that makes sense
        
             | balaga01 wrote:
             | Well, it ties into the storage issue that we see with
             | renewable. We still need energy when there is no wind at
             | night. Burning iron at night and regenerating during the
             | day could be a solution. It needs to prove that it can be
             | competitive with the other methods (compressed air, li-ion
             | batteries, flow batteries, molten salts, flywheels...).
        
               | intothemild wrote:
               | Thank you.
        
               | hn_throwaway_99 wrote:
               | > It needs to prove that it can be competitive with the
               | other methods.
               | 
               | I think the one thing is that iron storage would be a
               | potential _long term_ form of storage, while all those
               | other methods that you mentioned are really short term,
               | designed primarily just to deal with the daily peaks and
               | troughs of renewable production, but not as much the
               | "it's been completely overcast for 3 weeks" problem. The
               | only other form of storage I'm aware of that is also long
               | term like that is pumped water storage, and that is
               | obviously very geographically limited.
        
               | rsaesha wrote:
               | If using Fe why not iron batteries? Keep the redox,
               | remove the energy from the system via eletrical current
               | instead of low efficiency heat, boiler and steam engine
               | combo.
        
               | hn_throwaway_99 wrote:
               | Great point. Fe batteries are very new so I'm not aware
               | of the cost/benefit or if Fe batteries still slowly
               | discharge over time, but yeah in both cases you're just
               | oxidizing iron, so why not take the more direct route to
               | generate electrical current directly.
        
               | samus wrote:
               | There are also applications where the desired output is
               | heat, not electricity. In that case, iron fuel would be
               | useful.
        
           | kinnth wrote:
           | This is actually the same principle as BTC. High volume cheap
           | electricity is used to process random numbers and the value
           | is stored as BTC allowing it to be freely transferred once
           | first mined.
           | 
           | The green economics of this need some serious consideration
           | as i'd be really aware if you can reprocess it and get a
           | second reaction for less energy than it cost you to turn the
           | rust back into free iron metal.
        
             | jshorty wrote:
             | Not sure I agree, on one hand you have actual, physical
             | potential energy, on the other hand you have numbers on a
             | computer that could become worthless depending on
             | unpredictable economic factors.
        
             | cr__ wrote:
             | > the value is stored as BTC
             | 
             | What value? Where did any value originate in this process?
        
               | a3w wrote:
               | The maniacs who claimed that something had a price on a
               | market and cost to create claim that this means value was
               | created. From an ecological perspective, nonsense.
               | Economically, somewhat sound.
               | 
               | Misappropriated rare resources cause destroyed nature for
               | the reason that capitalism said it was sound.
               | 
               | Every joule can only be spent once, but and as long as
               | there is no moral coercion, there is a profit to be made
               | from pillaging it from the supply.
        
             | noodlesUK wrote:
             | There's a pretty big difference between BTC and a burnable
             | fuel. It is not possible to turn BTC back into electricity
             | directly, it is only possible to turn it into electricity
             | by first turning it into money, which then buys more
             | electricity (from any, renewable or non renewable) power
             | source. You can't ship someone a container of memory sticks
             | containing BTC and then they get power out of them without
             | burning more fuel or building more solar panels/other
             | renewables. The much better comparison would be hydrogen,
             | which can be produced using readily available water and
             | renewable electricity, shipped, then burned. The difference
             | is that hydrogen doesn't really produce much in the way of
             | by products when burned.
        
         | kumarvvr wrote:
         | If a power plant has sufficient store of Iron, with a complete
         | cycle, from burning iron to recovering iron, then it is no
         | longer a consumable.
         | 
         | I can imagine a solar plant, making iron in the day and burning
         | it in the night and essentially act as a base load plant, the
         | holy grail of renewable energy.
        
         | proto-n wrote:
         | But also don't underestimate how huge it would be if we could
         | store energy efficiently as elemental iron. E.g., produce it
         | using solar, burn it for grid energy. Of course that depends on
         | the efficiency of the whole process.
        
         | upofadown wrote:
         | The definition of the word "fuel" does not include the
         | requirement that it was originally found laying around in the
         | environment.
        
           | DontchaKnowit wrote:
           | Yeah but it pretty much requires that producing the fuel
           | requires less energy than the fuel provides, otherwise itd be
           | like trading a quarter for a dime.
        
       | bilsbie wrote:
       | GOOD Point by my wife. Could this be done with aluminum instead
       | of iron?
        
       | alex_young wrote:
       | If they require Hydrogen to complete the loop, you're going to
       | create a lot of CO2 in the process. 4% of H is produced using
       | renewables today: https://rmi.org/the-truth-about-hydrogen/
        
         | TSiege wrote:
         | Yes. "Green hydrogen" is largely vaporware at this point. The
         | majority of hydrogen we produce is from fossil methane
        
       | antisthenes wrote:
       | How/why is this better than molten salt energy storage?
        
         | eddyzh wrote:
         | You can store the oxidized iron on a heap outside indefinitely.
        
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