[HN Gopher] Wind-to-hydrogen production reaches deep water
       ___________________________________________________________________
        
       Wind-to-hydrogen production reaches deep water
        
       Author : mfiguiere
       Score  : 68 points
       Date   : 2023-06-10 14:41 UTC (8 hours ago)
        
 (HTM) web link (spectrum.ieee.org)
 (TXT) w3m dump (spectrum.ieee.org)
        
       | DropPanda wrote:
       | The article states that the capital investment cost of an
       | electrolyzer and pipeline is lower than that of a cable and a
       | substation. But what if you want electricity? If you include a
       | fuel cell and grid connection at the end of the pipeline, is the
       | capital investment cost still lower?
       | 
       | Edit: A fair comparison needs to keep the electrical power input
       | to the grid constant. This means the calculation needs to account
       | for both the losses in conversion to and back from hydrogen, as
       | well as that offshore electrolysis would be able to make use of a
       | greater share of the power during peak wind turbine output.
       | 
       | I want to see the math, not only an opaque claim of lower cost
       | when one set of infrastructure delivers electricity and the other
       | delivers hydrogen.
        
         | scythe wrote:
         | >If you include a fuel cell and grid connection at the end of
         | the pipeline, is the capital investment cost still lower?
         | 
         | You wouldn't, though. If you are going to convert hydrogen back
         | to electricity, it makes the most sense to do it where that
         | electricity is hardest to obtain by any other method -- say, an
         | off-grid research station in the Yukon or something.
        
       | goethes_kind wrote:
       | Once you build enough wind and solar, energy itself become cheap
       | and one is then more concerned with how to store and transmit
       | that energy. That's why hydrogen makes sense despite the inherent
       | conversion inefficiencies.
        
         | api wrote:
         | Grid scale storage and aviation are the two areas where
         | hydrogen seems to make sense to me. With the former you get
         | around the problem of having to build absurd numbers of
         | batteries and the material cost of that by using water as a far
         | cheaper working material. With the latter you have an
         | application where unlike cars minimizing weight per kWh is
         | absolutely critical. The fact that there aren't all that many
         | airports would also make deployment of hydrogen filling
         | infrastructure much easier.
         | 
         | I don't see hydrogen for cars unless we got a gigantic
         | Eisenhower scale infrastructure build out commitment. There is
         | already a power grid so the infrastructure problem for EVs is
         | way easier to solve.
        
           | goethes_kind wrote:
           | I agree that those are the two and the many industrial use
           | cases that use hydrogen directly are the most promising
           | areas. I think it might be plausible to see hydrogen creep
           | into other market sectors once it already serves a purpose
           | and the infrastructure is already built for use in
           | grid/aviation/steel...etc. Because it is so scalable, we
           | might find it easy to ramp up production and then end up
           | using it other markets sectors.
        
         | Valgrim wrote:
         | Compared to other fuels, what are the advantages of hydrogen?
        
           | rawgabbit wrote:
           | From
           | https://royalsociety.org/-/media/policy/projects/climate-
           | cha....
           | 
           | "Heavy-duty road vehicles Hydrogen fuel cells or hydrogen-
           | derived fuels offer a low-carbon alternative for heavy-duty
           | vehicles, for which batteries do not currently have the
           | energy density to offer a long-range solution. "
           | 
           | "One niche market for hydrogen fuel cells is forklift trucks.
           | These currently outnumber hydrogen cars, with around 30,000
           | in use. Fuel cell forklifts are suited to warehouse use
           | because refuelling is simple, and the vehicles emit no air
           | pollutants32"
           | 
           | "Synthetic fuels. A range of synthetic fuels for multiple
           | uses can be made via the Fischer Tropsch process, reacting
           | captured CO2 with hydrogen. These could potentially provide a
           | lower carbon drop-in fuel alternative for the aviation fleet
           | as well as an option for trucks or ships"
           | 
           | "Ammonia is denser and only requires compression to 10 times
           | atmospheric pressure or chilling to -33degC6 . Ammonia
           | storage is mature because of its widespread use as a
           | feedstock for mineral fertilisers. "
           | 
           | "For transport, China is aiming to produce one million
           | hydrogen fuelled vehicles and 1,000 refuelling stations by
           | 2030, the same goals as California3, 55. South Korea's
           | roadmap is aiming to produce six million FCEVs and roll out
           | 1,200 refilling stations by 2040."
        
           | analog31 wrote:
           | In addition to its use as a fuel, it's also a chemical
           | feedstock, perhaps notably for the production of ammonia. In
           | fact, wind-to-ammonia production would be a cool thing.
           | Synthetic ammonia for fertilizer, produced via the Haber-
           | Bosch process, sustains more than half of the world's animal
           | population.
           | 
           | A lot of ideas for reducing our carbon footprint depend on
           | the dream of getting methane out of the fertilizer business.
        
           | Gwypaas wrote:
           | See the hydrogen ladder for what can use synthetic fuels
           | compared to hydrogen as a feedstock.
           | 
           | https://www.linkedin.com/pulse/clean-hydrogen-
           | ladder-v40-mic...
        
           | alex_duf wrote:
           | Doesn't release CO2 or methane during production and use
        
             | Krssst wrote:
             | Depending on how it is produced. Electrolysis is fine but
             | steam methane reformating is the cheapest method and emits
             | CO2. (https://en.m.wikipedia.org/wiki/Hydrogen_production)
        
           | goethes_kind wrote:
           | What other fuels? All green/synthetic fuels depend on
           | hydrogen and as such I consider them the same technology.
        
             | ianai wrote:
             | Pulls oxygen in from the atmosphere and outputs energy plus
             | water. Just have to make the hydrogen generation/transport
             | emission free.
             | 
             | My question is whether storing hydrogen and the
             | complications therein are mitigated. I just don't know my
             | modern material science/manufacturing enough.
        
               | funnymony wrote:
               | If you have some time: https://youtu.be/Zklo4Z1SqkE
               | (Sabine Hossenfelder)
               | 
               | If I remember video correctly, summary would be: not yet
        
               | [deleted]
        
               | ianai wrote:
               | Seen it, she's taking pot shots at hydrogen. I'd be more
               | interested in hearing how it works in established
               | applications now and relevant to the article.
        
           | dmbche wrote:
           | Easy to produce, doesn't go bad, somewhat light, can be
           | produced on site.
           | 
           | You lose quite a bit of energy making the hydrogen (around
           | 50% I think) but the claimed positives make this not that
           | problematic. If it's possible to create a lot of energy
           | somewhere remote, making hydrogen there and shipping the
           | hydrogen out can be a good idea. Also making hydrogen when
           | there is unused electricity and storing it for further use
           | when energy is not available (night, winter)
           | 
           | There are many other drawbacks - I'm no expert.
        
             | goethes_kind wrote:
             | The drawbacks are as follows. To convert hydrogen back into
             | electricity you need to either use a gas turbine or a fuel
             | cell.
             | 
             | Fuel cells are expensive, so you have capital cost
             | problems. Additionally fuel cells have problems providing
             | variable power output. For this reason you often couple the
             | system with a battery.
             | 
             | Gas turbines running on hydrogen have some engineering
             | challenges. In particular the gas turbine technology needs
             | to be re-engineered because hydrogen burns differently from
             | natural gas. Secondly NOx emissions are an issue that needs
             | to be addressed.
             | 
             | Moreover, if one is to store and transport hydrogen as a
             | gas or a liquid, the infrastructure is more challenging
             | than with a natural gas pipeline. If one is to further
             | convert hydrogen into a synthetic fuel, you get additional
             | conversion losses.
        
               | dmbche wrote:
               | Thanks for the explanation, clear and to the point.
        
               | bwanab wrote:
               | Wouldn't the cost of fuel cells come down, as happened
               | with PV, once they are mass produced? Or, is there some
               | inherent high cost to them?
        
               | jgamman wrote:
               | currently use a lot of rare metals like platinum. inc vol
               | of fuel cells will drive up price of fairly inelastic
               | supply of rare metals. or require step change in
               | anode/cathode catalysts to cheaper metals
        
               | dmbche wrote:
               | I think it's inherent from the danger of hydrogen and I
               | imagine it's extremely reactive, it might interact with
               | most materials used to hold it.
        
               | _aavaa_ wrote:
               | Don't forget:
               | 
               | - it has an abysmal energy density per unit volume, even
               | as a liquid. E.g. if you used to need 1 tanker or
               | gasoline, you'll need 18 tankers of compressed hydrogen
               | for the same energy content.
               | 
               | - compressing and liquifying it is much more expensive
               | and challanging that natural gas. See this fun little
               | challange [0]
               | 
               | - there are currently no odorants available for use in
               | hydrogen (the thing that gives natural gas it's smell).
               | All the available ones either react with hydrogen or
               | poison your fuel cell
               | 
               | - it's flame is essentially invisible and incredibly hot
               | 
               | - it has an explosive range from 4-75% (natural gas for
               | example is 5-17%)
               | 
               | [0]:
               | https://en.m.wikipedia.org/wiki/Spin_isomers_of_hydrogen
        
               | somewhat_drunk wrote:
               | I was a project engineer in a hydrogen fuel cell research
               | lab for a few years.
               | 
               | To add to this, hydrogen also:
               | 
               | - is the smallest molecule; as such is very difficult to
               | contain
               | 
               | - embrittles and degrades most steels
               | 
               | - is ignited by a miniscule amount of energy, such as
               | static sparks
               | 
               | - has a terribly rapid flame front, which means big boom
               | when it does ignite
               | 
               | Everyone has seen the consequences of pilot lights going
               | out while owners are on vacation. House fills with
               | natural gas, fridge compressor kicks on, ignites gas,
               | house explodes. A house filled with hydrogen would not
               | only destroy the house containing it, but the houses next
               | to it as well, and it would be _much_ more likely to
               | ignite due to its much lower ignition energy.
               | 
               | I do not trust contractors to install hydrogen piping,
               | and I do not trust homeowners to maintain their hydrogen
               | sensors. I would NEVER live in a building that had
               | hydrogen stored (as in a vehicle tank) or piped inside.
               | There are simply too many ways for that scenario to go
               | wrong, and if it does go wrong, it goes wrong in a very
               | bad way.
        
               | dmbche wrote:
               | Would it be reasonable to reserve hydrogen for electric
               | plants then? Bringing power from far away and burning the
               | hydrogen to power locals?
        
               | dmbche wrote:
               | I hadn't realised the flame was invisible. It's
               | terrifying to me, after seeing ethanol fires on racecars.
        
               | _aavaa_ wrote:
               | It is! NASA and firefighters had the broom test [0].
               | 
               | Walk with a broom in front of them if they thought there
               | might be a hydrogen fire. If the broom suddenly burst
               | into flames, they knew they had a problem.
               | 
               | [0]: https://spinoff.nasa.gov/spinoff1997/ps1.html
        
               | ikekkdcjkfke wrote:
               | If you have an accident at a filling station it will go
               | boom real loud
        
             | Etrnl_President wrote:
             | [dead]
        
           | credit_guy wrote:
           | In the particular case discussed here hydrogen just wins
           | hands down. You can easily generate hydrogen at sea, but you
           | can't bring a floating chemical plant to make other fuels.
           | The alternative to send electricity via cable was also
           | considered:                 > For offshore wind producers,
           | meanwhile, Lhyfe projects that adding electrolysis and a
           | hydrogen pipeline to shore will reduce the cost of delivering
           | their energy as wind parks move further offshore. "A hydrogen
           | production plant plus pipeline is five to ten times cheaper,
           | as an investment, than an electric substation plus a cable,"
           | says Le Berre.
        
           | _aavaa_ wrote:
           | Why do we need fuels? We have electricity that we need to use
           | later. Going electricity -> fuel -> electricity is a
           | necessarily lossy process.
        
             | allannienhuis wrote:
             | As an example: transportation. More specifically,
             | airplanes. Energy density is a bigger factor for some uses
             | than others.
        
               | _aavaa_ wrote:
               | Anything but the longest flights will end up electric,
               | and everything else can go biofuels. No need for a
               | hydrogen-centered Rube Goldberg machine.
               | 
               | And if biofuels cost is a concern, synthetic fuels will
               | be out of the question.
        
               | allannienhuis wrote:
               | the question I'm replying to was about why the need for
               | fuels at all, not specifically Hydrogen. I'm not big on
               | hydrogen. I like the ideas around ammonia based fuels.
               | Biofuels have other environmental costs that concern some
               | people. Synthetic fuels could serve a purpose, but yes
               | energy cost has to be really low for that to make sense.
               | But they might be the only viable option in some cases.
               | 
               | Obviously costs change the demand side of the equation -
               | it may be that we wind up with very expensive airfare,
               | and have a lot more somewhat slower modes (say high-speed
               | rail) that can more easily use the cheaper energy forms.
        
               | goethes_kind wrote:
               | You are betting on a 20x improvement in mass energy
               | density of batteries for that to become realistic. That
               | would probably require entirely new chemistries and while
               | I am not going to rule it out, there is really no good
               | reason to believe that it will happen either. Hydrogen
               | powered flight is on the other hand only a matter of
               | incremental improvements. It is already feasible today.
        
               | _aavaa_ wrote:
               | Damn straight I am: https://www.energy.gov/eere/vehicles/
               | articles/fotw-1234-apri...
               | 
               | Ain't no incremental improvement going to improve the
               | density of a gas or a liquid. On top of that you talk of
               | energy per mass, but what kills you for flights is also
               | volume.
               | 
               | Hydrogen power flights are not feasible today. Even
               | hydrogen busses are struggling to operate, to say. I
               | thing of trains.
               | 
               | For starters you'll need hydrogen at any and all possible
               | destinations (plus any nearby airports if you're
               | diverted) since nobody is going to buy a plane that will
               | likely get stranded.
               | 
               | Then:
               | 
               | 1. Hydrogen's energy/volume is far too low.
               | 
               | 2. You can't store it in the empty space in the fuselage
               | due to pressure vessel geometry requirements.
               | 
               | 3. You need heaters and coolers and all sorts of extra
               | parts to operate something hydrogen power (hint: a
               | hydrogen car is just an electric car with a small battery
               | and a while separate hydrogen system frankesteined
               | ontop).
               | 
               | 4. Going back to that volume, you'll need to store the
               | hydeogren tanks inside the main fuselage, where the
               | volume required is going to either eat into your
               | available volume for cabin or cargo. OR, you're gonna
               | need a bigger cross-section, which will increase your
               | drag.
               | 
               | To top all that off. Nobody is using green hydrogen.
               | They're using hydrogen made directly from methane (or god
               | help us coal). This hydrogen has more GhG emissions
               | associate with it than the methane it's made from.
               | Hydrogen itself also has a GHG impact since it will
               | interfere with the processes occurring that remove other
               | GHGs.
        
               | goethes_kind wrote:
               | The bottom line is, the batteries that you would need do
               | not exist yet. You just have faith that your
               | extrapolation holds true. I cannot comment on that either
               | way, because there is no way to tell when battery energy
               | densities will stop improving.
               | 
               | Synthetic kerosene is a technology that we have today and
               | imho the most likely option because it is plug and play.
               | Otherwise one would have to work out many modifications
               | to fly directly on hydrogen, but that is also technically
               | possible today, if one wanted to do it that way.
        
               | theshrike79 wrote:
               | The biggest advantage of electric flight is the
               | maintenance interval. Electric engines need next to no
               | maintenance.
               | 
               | Jet engines need to be maintained pretty much after every
               | flight and that costs $$.
        
               | ianburrell wrote:
               | Any commercial flights over 500mi will be too far for
               | electric. There are a lot of regional flights that might
               | work as electric.
        
               | _aavaa_ wrote:
               | There will be some X mi limit that will slowly increase.
               | 
               | But the energy source that handles everything beyond that
               | is much more likely to be biolfuels than hydrogen (or
               | synthetics).
               | 
               | The cost it much better and the infrastructure is already
               | there.
        
               | ianburrell wrote:
               | Another good example is cargo ships. Making those
               | electric would be expensive and use a lot of cargo space.
               | Hydrogen is lower density than bunker fuel but better
               | than batteries. It should be possible to retrofit
               | hydrogen engines to existing ships unlike using kites.
        
               | uncertainrhymes wrote:
               | I don't have first-hand knowledge of this, but my
               | understanding is most cargo ships already have electric
               | engines to drive the propellers. The fuel is only there
               | to run the generators.
               | 
               | Fuel aside, might be less of a retrofit than we think.
        
               | Gwypaas wrote:
               | Not true. They use hyper optimized two stroke diesel
               | engines.
               | 
               | Cruise ships, RORO, off-shore supply ships and vessels
               | with similarly dynamic operating profiles have started to
               | use diesel electric.
               | 
               | Also starting to employ batteries to handle peak loads.
        
               | _aavaa_ wrote:
               | Bunker fuel is used because companies basically have to
               | pay to get rid of it. It's 3.5% sufur for crying out
               | loud.
               | 
               | The idea that the shipping companies would pay for a
               | premium gas like hydrogen is laughable.
               | 
               | Even with bunker fuel, fuel costs make up a large
               | percentage of shipping cost.
               | 
               | There's no way that's happening.
        
               | JumpCrisscross wrote:
               | > _an example: transportation. More specifically,
               | airplanes_
               | 
               | Biology found an efficient solution to storing energy
               | with hydrogen, and its hydrocarbons. I struggle to
               | imagine why hydrogen-powered planes are superior other
               | than on marketing merits.
        
             | jonnycomputer wrote:
             | I guess I have two answers.
             | 
             | First, it is not always most convenient or efficient to
             | produce energy where you use it, and electricity needs to
             | be generated relatively nearby where it is used, and
             | transit lines can be expensive to build. For example, deep
             | offshore wind seems to look like a more and more promising
             | option, but you need some practical way to get that energy
             | onshore.
             | 
             | Second, electricity is just not practical for some modes of
             | transportation; notably cargo ships and airplanes. And
             | these represent significant CO2 and other pollution
             | emission sources.
             | 
             | Also, hydrogen is a chemical feedstock with plenty of uses
             | besides as a source of energy.
        
             | Etrnl_President wrote:
             | [dead]
        
           | legulere wrote:
           | All other fuels depend on hydrogen when producing from
           | electricity and have a lower efficiency. Ammonia as a fuel is
           | difficult to handle. Carbohydrates like natural gas or
           | e-fuels depend on carbon capture which is still very
           | expensive/inefficient and they also burn much more dirty
           | emitting particulate matter.
           | 
           | There are also some disadvantages of hydrogen though: Low
           | volumetric density makes transport in anything but pipelines
           | much less efficient compared to carbohydrates. That includes
           | fuel tanks which makes hydrogen for aeroplanes unlikely. Also
           | there's no existing infrastructure compared to existing oil
           | and gas infrastructure.
        
         | BiteCode_dev wrote:
         | I'm a proponent of investing in solar and wind energy, but it
         | will be only cheap because we build solar panels and wind
         | turbines using fossil and nuclear fuel.
         | 
         | Oil and urnanium have a miraculous energy density, and can be
         | easily transported.
         | 
         | It's good we build alternative capabilities while we have cheap
         | energy, but we should not forget why we can.
        
           | hkt wrote:
           | I don't really see the point of remembering this. More
           | salient perhaps is the behaviour of the oil companies: their
           | cover ups of climate science and pollution, their lobbying,
           | their massive, massive subsidies and their (frankly cruel)
           | profiteering.
           | 
           | It'll be good that they're gone, when they're gone, and may
           | we never have to rely on such morally unsound people or
           | technology ever again.
        
             | BiteCode_dev wrote:
             | Well, it's important because if we want to transition, we
             | need a strategy and we need people to understand it.
             | 
             | If you can't understand energy density, you may be under
             | the impression we can go 100% renewable right now.
             | 
             | But we can't sustain our current life-style with them
             | today.
             | 
             | Also if you think oil companies are going to disappear
             | after we migrated, you are going to be disappointed if you
             | don't understand the role they play in systems.
        
           | epistasis wrote:
           | > only cheap because we build solar panels and wind turbines
           | using fossil and nuclear fuel.
           | 
           | This is not logical. We are building solar panels and wind
           | turbines with fossil fuels becuase that's the energy source
           | we have now, now becuase they are cheap.
           | 
           | Once we have enough energy from solar and wind, that energy
           | will be cheaper than fossil fuels, and that input to their
           | production will be cheaper, reducing the cost of wind
           | turbines and solar panels further.
           | 
           | Fossil fuels have been made obsolete for most use cases, and
           | we are building the industrial capacity to replace them as
           | fast as we possibly can.
           | 
           | If you don't believe me, check out what the world is
           | deploying for new electricity production. _Especially_ in
           | profit driven markets like Texas ' ERCOT. Outside of ERCOT,
           | most of the grid decisions are smoky-room deals with lots of
           | corruption, and there fossil fuels tend to have a huge leg
           | up, since more expensive electricity means a higher profit
           | level for the utility.
        
           | goethes_kind wrote:
           | Well, fossil fuels are indeed very convenient. However I
           | disagree that they are/were cheap. The costs are just hidden.
           | I mean, that's the whole point we are having to replace them.
        
             | hkt wrote:
             | Here's a thought: if Russia didn't have a market for its
             | oil and gas, would anyone be on the hook for war materiel
             | in Ukraine?
        
               | epistasis wrote:
               | This is pretty far afield from the current conversation,
               | but I think that there would be far far more support for
               | Ukraine if Russia didn't have massive amounts of fossil
               | fuels. Russia's ability to withhold them is a source of
               | economic and political power.
        
               | hkt wrote:
               | It is absolutely related to the current conversation,
               | though - fossil fuels as diplomatic leverage. Russia's
               | economy couldn't support the war without trade in fossil
               | fuels either.
        
       | usrusr wrote:
       | Still needs mooring? What i want to see are swimming
       | hydrolyzer/hydrogen transport units that sail the oceans under
       | wind power, driving a hydrogenerator turbine as they go that
       | powers hydrolyzer and compressor. They'd go wherever weather
       | models predict favorable conditions, cruise up and down those
       | waters on a net stationary beam reach course until the storage is
       | filled. Might want to leave some capacity for the return trip
       | harvest. Then they return home, or to whatever port has the best
       | offersvfor selling hydrogen and buying maintenance.
        
         | jonnycomputer wrote:
         | Would be moored more or less the same way deep-sea oils rigs
         | are. The main difficulties, as I understand it, is the unique
         | stresses and forces of the turbine on platform stability. I can
         | see why an image of these moving back and forth is appealing,
         | it will almost certainly make more sense to have dedicated
         | craft responsible for it (even if they were not fixed to the
         | ground). The very sorts of stability you need would work
         | against it being an efficient transport.
        
       | jonnycomputer wrote:
       | I recommend a listen to this series
       | 
       | https://gwec.buzzsprout.com/1229717/11455756-hydrogen-series...
        
       | [deleted]
        
       | Brian_K_White wrote:
       | hydrogen is almost as bad as batteries for storage, distribution,
       | and portable use. Worse in a lot of ways. Even if it were totally
       | free.
       | 
       | Maybe it can be a component of an artificial hydrocarbon, but
       | unless the carbon were sourced from the air it wouldn't be a
       | cycle and wouldn't be any better for the environment.
        
         | jillesvangurp wrote:
         | It's much worse than batteries for energy storage. With
         | batteries you get most of the energy back at least. Converting
         | electricity to hydrogen and back to electricity, the losses are
         | much steeper. Which makes it not ideal for that kind of thing.
         | There are lots of battery chemistries at this point; the round
         | trip is well over 90% efficient with most of them. With
         | hydrogen there are a lot of lossy steps, generating it, storing
         | it, transporting it, transforming it back, etc. Batteries are
         | produced at large scale now. Hundreds of gwh per year. Soon
         | twh. Green hydrogen production is orders of magnitude away from
         | that.
         | 
         | A good reference is Michael Liebherr's hydrogen ladder. It
         | organizes hydrogen use cases by their economical viability.
         | Some of the least economical things you can do with it is using
         | it for transport or heating. It just doesn't make any sense to
         | do that; there are cheaper ways to do those things. The more
         | economical things at the top are a combination of things we
         | already use lots of (grey) hydrogen for such as fertilizer
         | production and other industrial processes and a few things like
         | steel production and other industrial processes that currently
         | rely on burning fossil fuels. For each of those producing the
         | hydrogen close to where it is consumed is key. There are plenty
         | of economical uses for hydrogen. More than enough that
         | bothering with the low yield uneconomical use cases just
         | doesn't make sense. Just cleaning up the existing uses of grey
         | hydrogen is actually a massive project by itself.
         | 
         | Because of it's physical properties, transporting and storing
         | hydrogen is costly and technically challenging. It takes up a
         | lot of space. In liquid form it's almost 3x the volume of
         | liquid methane. And to get it to that state, you have to cool
         | it to a few degrees above absolute zero. Keeping it in that
         | state also costs energy. You typically get that by boiling some
         | of it off. Same with methane of course but liquid methane is a
         | lot warmer so the need to boil it off is a lot smaller.
         | Converting hydrogen to methane or other fuels is of course
         | possible but also not free. Every energy conversion you
         | sacrifice double digit percentages of energy. The more
         | conversions, the less economical sense it makes.
        
           | 7952 wrote:
           | I was reading about the hydrogen projects around Teeside in
           | the UK. You have existing hydrocarbon infrastructure,
           | industrial customers, offshore storage, spare land, and an
           | existing grid connection to the wider grid and renewables.
           | This proximity makes the economic case work as there are
           | opportunities to buy and sell in one place.
           | 
           | Also, efficiency becomes far less important if the source
           | energy is cheap and the sold hydrogen is expensive. If the
           | margins are high enough you can afford to waste energy.
        
             | jillesvangurp wrote:
             | True, it's just that that excludes any use cases where that
             | hydrogen competes directly with renewable electricity. When
             | the choice is using the electricity to charge a battery to
             | drive a truck, or convert the electricity to hydrogen
             | transport it half way around the world after first
             | compressing and cooling it and while boiling off double
             | digit percentages to keep it cool and then transporting it
             | by road to a fueling station (in gas form by now stored at
             | 300 bar), putting it in a truck and then running it through
             | a fuel cell .... you get my point. No sense whatsoever.
             | Unless you ignore all the inefficiencies. The vast majority
             | of road transport is going to be powered by batteries.
             | Including 100+ ton road trains in Australia. Because that
             | already happened.
             | 
             | Green hydrogen production will eventually happen at scale.
             | As you say, it's way too valuable for that not to happen.
             | But the caveat with that is that using it for uneconomical
             | / low value things doesn't make much sense. Why waste an
             | expensive resource on stuff like that when there are much
             | more valuable things you can do with it.
             | 
             | At the top of the ladder are things like industrial and
             | chemical processes, long haul aviation via e-fuels
             | generated from hydrogen, etc. Sticking it in the ground in
             | order to burn it in order to boil water and drive a
             | generator would be closer to the bottom. You could do it
             | technically but there are a gazillion other ways to store
             | and generate energy. Likewise using it for road transport
             | is just madness. And forget about replacing methane with
             | hydrogen to heat your home.
        
             | _aavaa_ wrote:
             | "Existing hydrocarbon infrastructure"
             | 
             | The fact that it exists does not mean that it's fit for
             | purpose. Hydrogen gas has very different material
             | requirements, you can't simply put it into those pipes.
             | 
             | "If the source energy is cheap and the sold hydrogen is
             | expensive"
             | 
             | Except a) the energy is not cheap (nor is the equipment
             | required to make and transport the hydrogen).
             | 
             | And b) who is going to buy this expensive hydrogen when
             | they could instead use a cheaper alternative which is much
             | more efficient (direct electricity cation)?
        
         | dghughes wrote:
         | Hydrogen can be stored as a metal hydride. More of it can be
         | stored in the same volume compared to liquid hydrogen.
        
           | _aavaa_ wrote:
           | And how much equipment, energy, and time does it take to
           | convert it back to a gas?
        
         | Etrnl_President wrote:
         | [dead]
        
         | credit_guy wrote:
         | I don't know why you are saying that. Batteries are expensive.
         | To recoup the capital expense you need to charge and discharge
         | them daily (so you can buy the electricity cheap and sell it
         | expensive and you get a profit). If you want to use them for
         | long term storage, then you buy cheap electricity in the
         | summer, sell it for a profit in the winter, do the same each
         | year, and find out in a few years that you are broke.
         | 
         | With hydrogen, the storage is cheap. We already store natural
         | gas in tanks. We can switch to hydrogen. Maybe hydrogen will
         | leak more, but 1. hydrogen is not a greenhouse gas and 2. the
         | square-cube law tells you that for large tanks you don't really
         | care about leakage.
         | 
         | I don't think we will find an alternative to hydrogen for long
         | term storage of electricity.
        
           | Rygian wrote:
           | You seem to happily ignore the distribution costs, metal
           | embrittlement, sheer loss of efficiency and rest of factors
           | that make hydrogen a bad idea for almost any use where it's
           | not yet being used.
        
             | goethes_kind wrote:
             | So what is your better option? What alternative technology
             | has the potential to be used to store six months worth of
             | energy for an entire continent?
             | 
             | Nobody is saying that hydrogen technology is without its
             | problems, but it is feasibly scalable unlike anything else
             | I am aware of, and it is not some kind of mythical
             | vapourware that exists only in the form of CAD renderings.
        
               | ianai wrote:
               | Definitely another space where the anti/propaganda has
               | won the early game.
               | 
               | Is there somewhere to learn about the proper storage and
               | use of hydrogen?
               | 
               | I'd just add that for grid scale storage the hydrogen
               | probably doesn't have to go far from generation. That
               | probably resolves plenty of problems.
        
               | hutzlibu wrote:
               | "So what is your better option?"
               | 
               | Converting hydrogen into something more safe, like
               | ethanol or methanol. Fuel cells for those also exist, but
               | needs more research.
        
               | funnymony wrote:
               | Storing hydrogen is not the same as storing oil.
               | 
               | Over time, hydrogen damages the tank. (Which is
               | undesirable combo with "explosive gas when mixed with
               | air")
               | 
               | I would like some breakthrough in material sciences here.
        
               | legulere wrote:
               | Only if you don't use suitable materials:
               | 
               | > Steel with an ultimate tensile strength of less than
               | 1000 MPa (~145,000 psi) or hardness of less than HRC 32
               | on the Hardness Rockwell Scale is not generally
               | considered susceptible to hydrogen embrittlement.
               | 
               | https://en.wikipedia.org/wiki/Hydrogen_embrittlement
               | 
               | Gas storage facilities also generally use geological
               | structures which are not susceptible to hydrogen
               | embrittlement either:
               | 
               | https://en.wikipedia.org/wiki/Natural_gas_storage#Types
        
             | credit_guy wrote:
             | > metal embrittlement
             | 
             | You can't ship things in steel vessels overseas because
             | steel rusts in contact with water, especially salty water.
             | See what I did there?
             | 
             | > distribution costs
             | 
             | What about distribution costs? Hydrogen can replace natural
             | gas. Wherever you have a gas burning powerplant, you can
             | retrofit it to burn hydrogen. The tanks that store gas for
             | that plant can be modified to hold hydrogen. Whatever
             | distribution costs are incurred for natgas will be incurred
             | by hydrogen. Some will go up, some down, but not by orders
             | of magnitude.
             | 
             | > sheer loss of efficiency
             | 
             | As opposed to what? In a world powered by solar and wind,
             | you'll have times (lots of times) when you generate more
             | than you consume. The least efficient option is to just not
             | generate. Generating electricity and converting it to
             | hydrogen, and then the hydrogen back to electricity at a
             | later time may or may not be economically profitable. In
             | the cases where the economics will work out, people will do
             | that, where it won't people won't do it. But the economics
             | will always be against batteries for long term storage,
             | except if by some miracle batteries will get to be 100
             | times cheaper (not a mistake, 100).
             | 
             | Other chemical storage solutions (ammonia, methanol,
             | ethanol, lithium hydride) need one extra step that will be
             | very expensive. There are slight chances for one of those
             | to make sense, but my bet is that they won't. Why? Because
             | both Europe and Japan are betting very, very big bucks on
             | hydrogen.
        
           | scythe wrote:
           | >hydrogen is not a greenhouse gas
           | 
           | Well, at least, it's a much less bad one:
           | 
           | https://pdfs.semanticscholar.org/2901/7f35d70295af32860db77a.
           | ..
        
       | dmbche wrote:
       | This is so exciting that I had Freebird playing in my mind while
       | reading. This is so cool. Cheap, away from people, little
       | environemental risks.
       | 
       | I hope maintenance won't be a nightmare, I wonder what problems
       | seawater electrolysis plants run into!
        
         | tcfhgj wrote:
         | Environmental risk: hydrogen leaking and reducing the amount of
         | methane removed from the atmosphere
        
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