[HN Gopher] Watching Paint Dry: The unexpectedly interesting sto...
       ___________________________________________________________________
        
       Watching Paint Dry: The unexpectedly interesting story of car
       coatings
        
       Author : rwmj
       Score  : 121 points
       Date   : 2023-05-23 15:40 UTC (7 hours ago)
        
 (HTM) web link (edconway.substack.com)
 (TXT) w3m dump (edconway.substack.com)
        
       | Gupie wrote:
       | Strange seeing "duco premier email a froid" in the vintage
       | poster! I assume it is vintage? Anyone know what "email" means in
       | this context?
        
         | ShakataGaNai wrote:
         | https://www.1stdibs.com/furniture/wall-decorations/posters/o...
         | 
         | " Cellemail le premier email a froid Francais / Cellemail the
         | best French cold enamel "
         | 
         | So, I think it's french for enamel? Based on that link.
        
       | tomcam wrote:
       | As an old-timer, I can tell you that modern automotive paint is
       | off the charts gorgeous end of a quality that would have looked
       | like alien technology in the 1970s. One color you will see
       | frequently is a metallic red that consists of the red pigment
       | with fine metal particles that give it a deep glimmer. 30 years
       | ago the only way you could get that was a very expensive coding
       | process that required 10, 12, 20 layers of paint. Now anyone can
       | get it on their Corolla for little or no markup.
       | 
       | Another piece of trivia is that Fender, the guitar company, has
       | often used automotive paints for its guitars. The reason is not
       | just availability and durability, but that it accurately tracks
       | recent color trends.
        
         | csours wrote:
         | There's a red tintcoat that's just amazing. It's red basecoat
         | with a red tinted clearcoat. So much depth, I feel like I could
         | wade through it.
        
         | supportengineer wrote:
         | The red paint on recent Mazdas specifically - I stop and stare
         | every time.
        
           | tomcam wrote:
           | YES
        
           | danzk wrote:
           | Mazda Soul Red is what's called a "Candy Color". It's
           | achieved with a translucent red layer applied over a base
           | color layer. It's rare for an OEM to offer a color like this
           | because the thickness the coating is applied changes the
           | color and It's much more difficult to achieve a consistent
           | color.
        
         | greenthrow wrote:
         | Fender only followed car color trends in the late 50s and early
         | 60s. After that they went their own way (including natural wood
         | bodies and many "interesting" color choices of the 70s.)
         | 
         | Most Fender guitars sold today are still in those "custom" Duco
         | colors from the late 50s and early 60s. (The standard
         | Stratocaster was a burst color and the standard Telecaster was
         | butterscotch or blonde. Any of the Duco car colors back then
         | was a "custom" option for an additional charge.)
        
           | tomcam wrote:
           | I interviewed their #2 guy for a radio show a few years ago
           | and he's the one who gave me that info. In fact, they follow
           | lots of other color trends--right up to and including women's
           | shoes (not joking). I called him out on it and he said, "Do
           | you have any better ideas?" and that shut me up really fast.
        
       | photochemsyn wrote:
       | Great article, I agree that _" the influence of the chemical
       | industry on modern products is astoundingly important, yet it's
       | one of the least appreciated and most rarely told stories in the
       | modern industrial pantheon."_
        
       | legitster wrote:
       | There's so much more detail you can go into in this stuff.
       | 
       | Before the Model T assembly line in 1916, most manufacturers did
       | something like 6 or 7 coats by hand because it was such thin,
       | slow drying varnish. And to get that nice shiny enamel surface we
       | are used to with hand brushes, they had to alternate the
       | direction of the brushstrokes between every coat as well as sand
       | it. In addition to time, this is a huge QC issue.
       | 
       | Part of the magic of the all-black Model T is that you can just
       | dip parts that can be dipped, Japan parts that can be Japanned,
       | and pour paint on parts that cannot. At final assembly they will
       | all be matched up together without any mismatching paint jobs.
       | 
       | And we cannot understate how magical the introduction of
       | asphaltum and naptha were to the paints. This was still pretty
       | new technology then and the precursor to our modern petrochemical
       | derived paints and even plastics. You could get thicker coats
       | that dried faster. So paint could just be poured on and the
       | surface tension would smooth the surface perfectly. And they were
       | more durable because they produced a more flexible coat.
       | 
       | One of the innovations of the Dodge Brothers (that Ford later
       | copied) was that by using more metal body components, not only do
       | you save on labor (working with wood is much more skilled than
       | running a metal press) but that metal can withstand the much
       | faster oven-baked finishes.
        
       | 1970-01-01 wrote:
       | >They all use electrodeposition and most of them use robots to do
       | most of the car spraying. They are gradually beginning to explore
       | replacing their gas ovens with electric ones to reduce the carbon
       | emissions at plants.
       | 
       | Toyota's electrodeposition and prep process can be seen here:
       | 
       | https://youtu.be/DLav5xRvWUo?t=269
        
       | mhb wrote:
       | > These days, where we use enormous ovens to cure and dry car
       | coatings, it is comfortably the most energy intensive and carbon
       | intensive parts of making a car.
       | 
       | I guess so if you don't count what it takes to make aluminum and
       | steel.
        
         | csours wrote:
         | It would be better phrased as "most ... intensive part of an
         | automotive assembly plant". Generally, the only big thing that
         | assembly plants actually manufacture is the body (including
         | painting the body)
         | 
         | Once production was shut down at my plant because it was too
         | cold and the natural gas company said they had to use the gas
         | for residential customers.
        
         | yread wrote:
         | a friend (a paint engineer) believes there are massive energy
         | savings to be had from the painting (baking). He was shocked to
         | see how wasteful the process is in automotive plants compared
         | to his other clients. All because the paint has to be perfect
         | and last long
        
       | [deleted]
        
       | linksnapzz wrote:
       | The paint shop at a modern car assembly plant can be 50% of the
       | square footage under the roof, and cost 50% of the outlay, so
       | half a billion for a new one at least.
       | 
       | The change from VOC-borne to water-based paints was also a big
       | deal for the environment. The lacquers did a good job, but
       | imagine living in a neighborhood where several tons of toluene or
       | acetone was being evaporated into your air every hour. In places
       | like LA, this process was a _huge_ contributor to smog in the
       | 1960s /70s.
        
         | sokoloff wrote:
         | On the other hand, at least the early water-base painted cars
         | were prone to premature rusting, which has its own
         | (distributed) ecological impact. My W210 Mercedes was
         | mechanically great the day I sent it to the scrapper for
         | excessive rust through on the rockers and underbody structure.
         | Hundreds of thousands of car met such an earlier than otherwise
         | demise.
        
           | linksnapzz wrote:
           | Glad you liked yours; the 210s and 220s and the original MLs
           | were the nadir of Mercedes value-engineering when it came to
           | many things, and rustproofing was certainly one of them.
        
         | geepytee wrote:
         | You should tour any of the Tesla factories, this is not the
         | case.
        
           | linksnapzz wrote:
           | I'm pretty sure the cost is still a large part of the plant
           | budget, as well as the floorplan.
           | 
           | Also, Tesla isn't all automakers.
        
             | hef19898 wrote:
             | And Tesla is famous for trying things evrybody else knows
             | are either stupid or just don't work economically when it
             | comes to manufacturing cars. They sell it pretty well so,
             | usually as some groundbreaking innovation of sorts, one
             | that miraculiosly justifies the over hyped shares and cars.
             | 
             | Not that Teslas are bad cars, far from it, but tue delta
             | between perception and substance is larger than anything
             | German "Premium" OEMs could have ever dreamed of.
        
         | danzk wrote:
         | Acetone is not considered to be a VOC.
         | 
         | https://en.wikipedia.org/wiki/VOC_exempt_solvent
        
         | csours wrote:
         | I used to work in an automotive paint shop. When our exhaust
         | scrubber (burner) went down, we had to stop painting cars. We
         | had a 'budget' of VOC exhaust per year. I don't know when that
         | went in, I imagine in the 80's or 90's.
         | 
         | We switched to water based paints in 2013 and that really
         | helped with the VOC.
        
           | dghughes wrote:
           | Take care of yourself!
           | 
           | My neighbour was a car painter for decades he died of
           | dementia. My Dad and grandfather had a house painting
           | business in the 1960s/1970s using leaded paint for most of
           | that time. Both Dad and my grandfather died of lung diseases.
        
             | csours wrote:
             | Yea, everyone in that shop was a little crazy, but we were
             | never sure which way the causality pointed.
        
       | eig wrote:
       | For those of us who would like a little more depth in the history
       | and chemistry of automotive paints (and more images/videos too),
       | there's a great video essay by New Mind on youtube:
       | 
       | https://www.youtube.com/watch?v=b_hgPinCZks
       | 
       | I was quite surprised at how important paint actually was to car
       | production.
        
       | csours wrote:
       | I used to work in an automotive paint shop. Another point of
       | interest:
       | 
       | There's a limit on the number of tries you have to "repair" the
       | paint job, because the vehicle has to go through the oven again
       | to bake the coatings. The trips through the oven affect more than
       | just the paint. Some panels are filled with foam; there's
       | internal sealant and glue, and external sealant. All of those
       | things don't really love being baked too long. For the shop I
       | worked in, we got 2 tries to repair.
       | 
       | The main limit on repairs though? The windshield. Windshields are
       | glued in with specialized urethane 'caulking'. They have to stick
       | to the paint, and the paint has to stick to the body. That is
       | only certified reliable with less than 5 trips through the ovens
       | (in my shop).
       | 
       | ---
       | 
       | Paint is the hardest thing to get right in the whole assembly
       | process, because there are so many process variables. Temperature
       | and humidity (dew point) are the biggest besides the actual paint
       | mix, but there's also unexpected problems from every direction.
       | Our solvent paint process (pre-2013) was very vulnerable to
       | siloxane (silicone) lubricants. Someone in IT applied some
       | lubricant to a label printer and ruined hundreds of paint jobs.
       | Livestrong bracelets also ruined at least a hundred paint jobs.
       | Someone did weekend work on the roof? Congratulations on your
       | dust quality spill (spill means a bunch of problems).
       | 
       | All of the parts of the paint have to work together, and that
       | includes things that you don't think are paint. The body is just
       | dumb metal, right? Of course not. The metal panels have oil on
       | them in stamping, and they MUST stay oiled right up to the point
       | where the body takes it's first bath. If too much of the oil has
       | evaporated, then you start getting corrosion, and in many cases
       | you won't be able to tell until the vehicle gets to the customer.
       | 
       | ---
       | 
       | Paint shops have the most complicating routing of any part of
       | automotive assembly. The electronic quality and build data has to
       | be synchronized with the physical process, and that data package
       | can be updated by several different systems. Then either IT or OT
       | (operational technology) can make a routing decision, or an
       | individual can use a key switch to manually change routing. "Why
       | did this vehicle go here" is not a straightforward question to
       | answer sometimes.
        
         | bluGill wrote:
         | > The metal panels have oil on them in stamping, and they MUST
         | stay oiled right up to the point where the body takes it's
         | first bath.
         | 
         | I toured an assembly line a few years ago. The guide told us
         | that in the 1970s they had teams of people watching iron/steel
         | prices, when they thought the prices where at the low they made
         | a massive order of all iron that factory would need for the
         | next few years. When the factory when to just-in-time (sometime
         | in the 1980s or 1990s) they couldn't do that anymore - but they
         | also got to get rid of all the equipment to de-rust all that
         | stored iron: since every raw material was shipped out as a
         | final assembly in a week there was no time for significant rust
         | to form and so they avoided a lot of problems.
        
           | csours wrote:
           | JIT assembly has SO many non-obvious implications. I had not
           | heard of this one, thanks.
        
         | geepytee wrote:
         | You were painting bodies with windshields already bonded onto
         | them? Seems like a good idea to adhere windshields after paint.
        
           | singleshot_ wrote:
           | I got the feeling they were in an auto body shop, where the
           | paint might be trashed and the windows might be fine.
        
           | csours wrote:
           | Nope, the windshields go on top of the paint, but the
           | requirements for the windshield affect the paint process.
        
         | EvanAnderson wrote:
         | Thank you for this comment. I enjoy hearing about intricacies
         | of engineering processes-- particularly those that sound "easy"
         | on the surface.
         | 
         | This gives me a deeper appreciation for cars with plastic body
         | panels. I also wonder if DeLorean Motor Company took any of
         | this into account when they designed the DMC-12 with stainless
         | steel body panels.
        
           | csours wrote:
           | Plastic panels are a whole bucket of issues in themselves. As
           | far as I know, the color matching plastic panels are painted
           | using a different process. That means the the front and rear
           | fascia (bumper) of your vehicle are painted in a different
           | plant (usually) from the rest of the vehicle. The colors have
           | to match to a very high degree.
           | 
           | And yes, that's a big reason why they went with stainless.
           | Stainless steel does corrode, just much less visibly than
           | regular steel. It also has different physical properties like
           | work hardening etc. It's also VERY expensive. Salty napkin
           | math says $10,000 more for the Cybertruck.
        
             | EvanAnderson wrote:
             | > Plastic panels are a whole bucket of issues in
             | themselves. As far as I know, the color matching plastic
             | panels are painted using a different process.
             | 
             | I was thinking about "molded-in color" panels like the old
             | Pontiac Fiero. That makes sense, though, re: painted
             | plastic panels. They'd be a whole different ballgame and
             | there's, I'm sure, interaction between the paint chemistry
             | and the plastic chemistry that's probably pretty hairy.
        
           | buildsjets wrote:
           | The DMC-12 had stainless steel body panels, but it had a
           | plain ol' carbon steel frame (designed by Lotus and similar
           | in design to the Esprit) with an epoxy coating, and they have
           | NOT fared well over the years. You can buy a new-build
           | stainless frame for it, it only costs as much as a new
           | regular car.
           | 
           | https://deloreanindustries.com/8-1-0-stainless-frame/
        
             | hef19898 wrote:
             | Same with old Land Rovers, people belive they don't rust
             | being all aluminium. Chassis are steel, and those rot. Plus
             | some other bits and pieces. New galvanised chassis are
             | available, getting the body mounted is the fun bit so.
        
         | akiselev wrote:
         | That sounds fascinating and complicated. I scratched my car a
         | few years ago and decided I wanted to DIY a chameleon paint job
         | instead of taking it to the shop (the car is worth less than
         | the paint job if I pay retail). I've been slowly acquiring all
         | the gear I need like a forced air respirator and sprayers.
         | 
         | I was wondering how realistic that really is to DIY or if I'm
         | kidding myself. Sound like even if I rented a stall in a paint
         | shop for a few weeks, I won't have the time to finesse the
         | technique to get a good end product, especially with how much
         | more finicky I understand the chameleon paint to be.
        
           | csours wrote:
           | My understanding about chameleon paint is that it's very hard
           | to match if it's not all painted at once. I think the
           | difficulty may depend on your expectations for the final
           | product.
        
             | akiselev wrote:
             | Yep from what I've read I'll have to do the full body in a
             | single shot after spending several hundred man hours
             | sanding down the old paint job and prepping the surface.
             | I'm hoping in Southern California's weather I won't have
             | much problem with rust between the prep and actual
             | painting.
             | 
             | I don't care so much about getting the matching perfect -
             | "it was my first time" is a perfectly cromulent excuse in
             | my social circles - but I do want the paint job to be good
             | enough so that I'm not redoing it every year or two (I hate
             | sanding). What should I exepct?
        
               | csours wrote:
               | I don't think I can help much more, sorry. The shop I
               | worked in was completely automated and worked on new
               | builds. In most ways, it's much harder to do a one-off
               | repaint of an assembled vehicle.
               | 
               | Only advise I can give is to get some cheap paint and
               | some kind of panels and start practicing.
        
         | crazygringo wrote:
         | This is fascinating, thanks. Can you elaborate more on how the
         | label printer and Livestrong bracelets ruined paint jobs? Was
         | it something they emitted through the air? How would that be in
         | concentrations to affect the paint job, what would happen to
         | the paint?
        
           | csours wrote:
           | Silicone oils caused the paint to "run away", like putting
           | soap in a greasy pot.
           | 
           | Droplets were enough to cause problems - there's no hiding
           | problems on a car's paint job and customers are VERY
           | demanding.
        
             | _tom_ wrote:
             | So it was workers wearing the bracelet that caused the
             | problem, not end customers?
        
           | danzk wrote:
           | Silicone has very low surface tension, imagine water on a non
           | stick pan. If paint encounters a droplet of silicone it will
           | shrink back on itself and form a hole around the
           | contamination.
        
       | wlesieutre wrote:
       | That's a lot of work to paint 80% of new cars in the most boring
       | colors possible
        
         | nicenewtemp84 wrote:
         | I worked in car sales for a decade.
         | 
         | If you like model xyz, and you like red, but we only have it in
         | Silver, you'll probably buy it.
         | 
         | If you like model xyz, and dislike vibrant colors (very
         | common), you won't buy the red one we have.
        
           | wlesieutre wrote:
           | It's true, if I weren't married I'd be getting Soul Red
           | Crystal. Gorgeous color. But it's not for everyone,
           | apparently.
           | 
           | And the blue option isn't available, so white is it. If they
           | had literally any non-red color we would've bought it, but
           | they didn't.
        
             | joezydeco wrote:
             | I have a deep blue crystal Mazda but I also lust for that
             | Soul Red color. It's amazing.
        
               | wlesieutre wrote:
               | Can't believe I'm paying $400 for white, but even with
               | that the overall price beats what I could get out of
               | another dealer 100 miles away where they had a deep
               | crystal blue on the lot. Beats paying thousands of
               | dollars of markups for literally nothing.
        
         | crazygringo wrote:
         | Then what's boring to you is clearly tasteful to the 80% of
         | people buying them.
         | 
         | I personally like to express my personality in other ways. The
         | last thing I want is a car screaming some garish hue.
         | Especially since I can do things like match clothes to my mood
         | and the season, but I can't get my car repainted every day or
         | every three months.
        
           | wlesieutre wrote:
           | It's not even really up to customers today, most people (me
           | included) will take whatever color is available as long as
           | it's not hideous. That's how I'm ending up with a white car
           | even though I'm not enthusiastic about it. I guess
           | manufacturers know that, so it's no problem for them to keep
           | cranking out the whites and grays.
           | 
           | Was talking to a Mazda salesperson recently and he was
           | complaining that the first five or six of the new CX-90s they
           | were being allocated are all white. Though looking at their
           | website they have some red and dark blue ones on the way now,
           | so maybe that was just the first production run.
        
             | crazygringo wrote:
             | It's still up to customers in the sense that car companies
             | are cranking out whites and grays because that's where the
             | most consumer demand is.
             | 
             | If people stopped buying white today, Mazda would stop
             | producing it tomorrow.
        
               | wlesieutre wrote:
               | I get that they do it because it's boring and
               | unobjectionable, but I stand by my original point that it
               | _is_ boring.
        
               | crazygringo wrote:
               | No, you're _projecting_ "boring" onto it. That's how you
               | feel about what they're buying, not how they feel.
               | 
               | I stand by my original point that it's _tasteful_.
               | Classic shades of white, gray, silver, and black are in
               | good taste, which is why people buy them. The buyers aren
               | 't saying "I want a boring color", they're saying "I want
               | a tasteful shade".
        
               | wlesieutre wrote:
               | Maybe we can agree that it's tastefully boring
               | 
               | At least it's not beige, which would only be boring
        
               | crazygringo wrote:
               | > _At least it 's not beige_
               | 
               | Ugh, if the 1990's are calling, tell them I'm not home!
        
               | wlesieutre wrote:
               | If you get a call from the 1990's tell Honda to bring
               | back cypress green pearl
               | 
               | Meanwhile at Mazda, I can see "zircon sand" working for
               | the CX-50, but I'm skeptical on the Miata
               | https://www.caranddriver.com/news/a41995585/2023-mazda-
               | miata...
               | 
               | Unless it's such a weird choice that it somehow
               | transcends boringness?
        
               | elzbardico wrote:
               | Bach's fugues are tasteful, french cuisine is good taste.
               | White and grey cars are just boring, the definition of
               | good taste for the unimaginative petite bourgeoisie, the
               | hallmark of conformity and middle-class sensitivity.
               | 
               | I have a grey car, but I am fully aware this is the case
               | just because I am a terminally boring middle-class
               | denizen, mass-produced, and absolutely non-remarkable for
               | history.
        
           | mhb wrote:
           | The gap between boring and garish is at least big enough to
           | drive a Mini Cooper through.
        
           | Swizec wrote:
           | > Then what's boring to you is clearly tasteful to the 80% of
           | people buying them.
           | 
           | Apparently this has to do with how the economy is doing. When
           | times are tough, people like boring car colors. Something
           | about ease of resale and broad palatability in car
           | dealerships.
           | 
           | https://www.cnbc.com/2020/09/22/most-cars-are-painted-one-
           | of...
        
       | ughitsaaron wrote:
       | > The conventional wisdom is that Ford decreed that all Model Ts
       | should be black because that was the fastest-drying of all
       | colours
       | 
       | Is that actually the conventional wisdom?
        
       | emmelaich wrote:
       | These days people using vinyl wrap as well.
       | 
       | e.g. if you see a Tesla in other than white, red or blue, then
       | it's probably:
       | 
       | https://www.3m.com.au/3M/en_AU/p/c/films-sheeting/vehicle-wr...
        
       | dekhn wrote:
       | these innovations spread back into the normal paint world, I've
       | come across a number of things about modern paint that show it
       | was first developed for cars (and mostly GM/Ford). Automobile
       | primer is great for covering 3d prints.
        
         | ZeroGravitas wrote:
         | Masking tape being a notable example:
         | 
         | > By the early 1920s, two-toned cars were the rage, and that
         | created a major headache for the automotive industry. To craft
         | this duo-tone look, one portion of the car had to be masked off
         | while the other was painted. The problem was nobody knew how to
         | do this well. So automakers and auto body shops improvised.
         | They glued old newspapers to the body and windows with library
         | pastes, homemade glues or surgical adhesive tape. This helped
         | create a sharp demarcation between the two colors, but the
         | adhesives stuck so firmly that trying to remove them often
         | ruined the paint job.
         | 
         | > At the time, 3M primarily manufactured sandpaper and other
         | abrasives. One of Dick Drew's jobs was taking samples of
         | waterproof sandpaper (another 3M invention) to nearby auto body
         | shops for testing. One morning in 1923 he walked into one of
         | these shops and overheard "choicest profanity I'd ever known."
         | Yet another paint job was botched and the worker who'd done it
         | was furious. Drew had seen this occur on many other visits, but
         | this time he spoke up. He could, he said, produce a tape that
         | would end the painter's torment.
        
       | AlbertCory wrote:
       | There are actually videos on YouTube of watching paint dry, e.g.
       | 
       | https://www.youtube.com/watch?v=PLOPygVcaVE
       | 
       | 1.3M views! I found the plot a little thin (drum roll).
        
         | aidenn0 wrote:
         | I think you meant rim-shot, not drum roll?
        
         | david422 wrote:
         | Gonna watch that on 1.5x speed.
        
       | intrasight wrote:
       | Great article. Reminded me of this article about the mineral
       | "Fordite" that I recently read:
       | 
       | https://www.boredpanda.com/car-paint-deposits-fordite-detroi...
       | 
       | Many dozens or perhaps hundreds of "watching paint dry" cycles
       | results in some spectacular agate-like specimens.
        
       | doctorhandshake wrote:
       | Might be a little OT but I was hoping this would include more
       | discussion of the contemporary interplay between aesthetics and
       | paint chemistry / technology.
       | 
       | I know there are some interesting stories behind titanium dioxide
       | production, the use of which is critical to making paints vibrant
       | and opaque [1].
       | 
       | Further I have a pet theory that the recent trend in 'flat'
       | automotive paints (without the apparent depth and larger
       | suspended metallic flakes common in decades prior) has been
       | enabled by some kind of technical advance as well, not just a
       | change in consumer tastes, although I have no evidence to support
       | the idea [2]
       | 
       | [1] https://www.theverge.com/2014/3/6/5476904/china-stole-the-
       | co... [2] https://www.latimes.com/business/story/2023-03-07/la-
       | fi-car-...
        
         | notjulianjaynes wrote:
         | >Further I have a pet theory that the recent trend in 'flat'
         | automotive paints (without the apparent depth and larger
         | suspended metallic flakes common in decades prior) has been
         | enabled by some kind of technical advance as well, not just a
         | change in consumer tastes, although I have no evidence to
         | support the idea.
         | 
         | I've wondered about this as well. One theory I've had is that
         | older paints used lead based pigments which gave a glossier
         | finish, but are no longer used. I also do not have any concrete
         | evidence to support this aside from pointing out that
         | automotive paint was exempted from the 1978 (US) lead paint
         | ban.
        
       | [deleted]
        
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