[HN Gopher] Solid-State Battery Has 2x the Energy-and No Anode
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       Solid-State Battery Has 2x the Energy-and No Anode
        
       Author : rbanffy
       Score  : 162 points
       Date   : 2023-03-31 09:38 UTC (13 hours ago)
        
 (HTM) web link (spectrum.ieee.org)
 (TXT) w3m dump (spectrum.ieee.org)
        
       | mabbo wrote:
       | Lithium ion batteries set the standard because they have an
       | acceptable level of all the key metrics: energy storage by
       | weight; energy storage by volume; discharge rate; charging rate;
       | production costs.
       | 
       | Every single one of these big breakthrough announcements touts
       | how great this new tech is- in just one or two particular
       | metrics.
       | 
       | The problem is that Li-Ion batteries are just barely acceptable
       | in all of those metrics. No new battery is going to replace them
       | unless they can match Li-Ion in every metric and beat them in at
       | least one.
        
         | dheera wrote:
         | Those are only a few metrics. Li-ion is not fantastic in (a)
         | charging cycles and battery depletion or (b) fire safety.
         | 
         | It also depends a lot on use case; for example, for home
         | electricity storage (like a PowerWall) I would gladly give up
         | energy density for safety. If there's some battery tech that
         | can handle 50000 charge cycles and completely non-flammable but
         | weighs 100 tons and has 10% of the energy density of Lithium,
         | I'd gladly make that trade. Maybe build part of the building
         | out of it.
        
           | megaman821 wrote:
           | How often will you fully cycle a home battery? At 100 cycles
           | a year it would take 50 years to deplete a 5,000 cycle
           | battery down to 80%. Another 50 years before it was 50%.
           | There is no way the casing would be fully intact and the
           | electronics even be functioning after that long.
           | 
           | Current LFP batteries should last multiple decades as a home
           | battery. The already have low flammability. The price is
           | getting more affordable. They could just be part standard of
           | a home electric system in a decade or two, like a whole-home
           | surge protector.
        
             | dheera wrote:
             | > The already have low flammability.
             | 
             | Low rates of spontaneous thermal runaway, sure, but they
             | still are extremely flammable if externally ignited or
             | physically damaged. A house fire that could otherwise be
             | put out might turn into a full disaster. An earthquake that
             | physically damages the battery pack could cause a fire that
             | would have otherwise not happened. A flood or minor tsunami
             | might allow for early evacuations and most lives saved, but
             | now the entire town is on fire instead of just water
             | damaged, if every house has a massive lithium pack in their
             | basement.
        
           | eknkc wrote:
           | I guess LTO is right there at the moment. Even LiFePo4
           | batteries are a lot more safer than Li-Ion ones. From what
           | I've seen, I would gladly have a LTO pack in my house.
        
         | phkahler wrote:
         | Actually, energy storage by weight is not as big a deal for
         | electric cars. Regenerative braking can recover most of a
         | vehicles kinetic energy, which is where the weight dependent
         | energy goes. This is why several hybrids get better fuel
         | economy in city driving than highway, the biggest losses are
         | due to aero which increases nonlinearly with speed.
         | 
         | Otherwise yes, it's important to find something better without
         | sacrificing on any of those metrics.
        
           | subarctic wrote:
           | >Regenerative braking can recover most of a vehicles kinetic
           | energy
           | 
           | I used to think that was the case, but then i think i read
           | somewhere that it only recovers 20% of the kinetic energy.
           | Can't find it anymore though
        
             | satiric wrote:
             | It depends a lot on how you drive. If you do a lot of hard
             | braking, the car will have to use a lot of friction
             | braking. If you slow down more gradually, the car can just
             | use regen which is gonna be pretty efficient.
        
             | magnuspaaske wrote:
             | As with anything else it depends what you optimise for and
             | at the most basic level the car uses the engines to
             | accelerate at all speeds but might need to use break pads
             | at slow speeds.
        
             | feifan wrote:
             | I've seen data showing ~70% recovery on a Model 3, but I
             | also can't find the source :/
        
             | hutzlibu wrote:
             | It is basic physic.
             | 
             | There is all the time friction of air and the road. You can
             | never recover that.
             | 
             | And in rare cases where you actually can recover energy, at
             | non emergency slowing down, it is probably indeed in that
             | ballpark, wich is something(especially in city with stop
             | and go), but not very high or much. With very high tech,
             | you can increase that number a bit, but not worth the
             | effort. Electric cars need good batteries and every
             | improvement there is good.
        
             | mikeyouse wrote:
             | Like OP mentioned, the efficiency of recovery varies by
             | speed but is generally in the 65%-80% range for total
             | round-trip (the system captures ~80% of the kinetic energy
             | but with round-trip losses, you only get ~80% of that
             | energy to propel the car).
             | 
             | Maybe you're thinking of the total range boost provided by
             | regen braking? That's often shown to be roughly 20% via
             | studies;
             | 
             | https://sci-hub.se/10.1109/vppc.2011.6043109
             | 
             | > _Simulations show that the energy reduction of the
             | vehicles under test can be more than 20% by applying
             | regenerative braking._
             | 
             | It's an older study, but they show the regen efficiency at
             | 60% for the EcoTruck and 70% for the bus.
        
           | [deleted]
        
           | PragmaticPulp wrote:
           | Heavier cars are more dangerous in collisions.
           | 
           | The extra weight of a big battery requires a bigger frame to
           | carry it, bigger suspension, wider tires, and so on.
           | 
           | I'm not really happy that some of these monster EVs are
           | approaching 10,000lbs with fast 0-60 times. It's like a
           | kinetic missile that can reach a momentum capable of
           | obliterating your average 3000lb compact car in under 5
           | seconds.
        
             | lazide wrote:
             | That is pretty much the definition of moving the goal
             | posts?
        
               | TaylorAlexander wrote:
               | Actually if I follow the conversation, the first person
               | said "storage density matters". The second person said
               | "actually it does not because the energy gets recovered".
               | The follow up said "actually there are other reasons why
               | weight is a problem."
               | 
               | So the first person never set goal posts around
               | efficiency, that was an assumption by the second person.
               | The first person could always have meant that the
               | collision risks from heavier vehicles are higher, while
               | the second person misunderstood their meaning. No moving
               | of goalposts here.
        
               | jgtrosh wrote:
               | There can be multiple reasons for heavy cars to be bad.
               | Additionally, extra heavy cars wear roads much faster.
               | 
               | It's nice to have a way of recuperating energy but it
               | doesn't solve everything.
        
               | _a_a_a_ wrote:
               | They didn't say it solved everything
        
         | DennisP wrote:
         | Here are the specs on the Amprius silicon-anode battery,
         | currently shipping in low volume:
         | 
         | https://amprius.com/products/
         | 
         | That's better on all the metrics you listed except cost, which
         | it doesn't mention. Whatever their current cost is, it should
         | drop significantly once they complete their factory in 2025.
         | 
         | https://amprius.com/facility/
         | 
         | Most of the battery is standard lithium-ion, the anode is a
         | drop-in replacement.
        
           | tromp wrote:
           | It mentions lasting for 200-1200 cycles, which (besides a
           | suspiciously large range compared to Li-ion's 500-1000
           | cycles) is not better on all mentioned metrics.
        
             | DennisP wrote:
             | The above comment didn't mention cycles but I should have
             | said "similar or better." Cycles are comparable, seems
             | likely it's just more sensitive to poor management. With
             | about twice the capacity, fewer cycles are more tolerable
             | anyway.
             | 
             | In any case, this looks like a very practical battery with
             | serious advantages over lithium-ion.
        
             | ksec wrote:
             | If you have double the energy capacity and the same cycle.
             | Your phone will also last roughly double the time at the
             | same energy usage. That is probably good enough for most
             | things.
        
             | Kye wrote:
             | If it's like Li-Ion, that's _full_ discharge and charge
             | cycles, not every top off. So if these batteries are
             | sufficiently higher capacity, it might make up for the
             | difference. 200+ charges is enough if each charge lasts 2x
             | longer or more.
        
           | panick21_ wrote:
           | Amprius technology will not magically drop in price as much
           | as people think. Some manufacturing methods don't just scale
           | and become cheap.
           | 
           | Their large facility planned is still tiny in terms of
           | battery factories.
           | 
           | This will remain an expensive niche product.
        
             | DennisP wrote:
             | No small company is going to suddenly build a gigafactory.
             | But 5GWh, if they manage it, is not _that_ small. One of
             | Tesla 's gigafactories is 37GWh.
        
         | brightball wrote:
         | The only one that I'm actively monitoring is this one because
         | it handles the other metrics AND gives a path forward to rapid
         | charging, which is the core requirement to displace liquid
         | fuels. IMO any battery advance that doesn't address rapid
         | charging is going to fall to the wayside for exactly the reason
         | you stated.
         | 
         | https://www.forbes.com/sites/michaeltaylor/2021/05/13/ev-ran...
        
         | cryptoegorophy wrote:
         | As well as battery charge cycles
        
           | infogulch wrote:
           | And shock tolerance, and temperature tolerance, and i/o
           | efficiency
        
           | scythe wrote:
           | Particularly relevant for this particular battery, because
           | the authors seem to think it's impressive that they had 80%
           | capacity retention after 50 cycles. No, I didn't forget a
           | zero. That's 50, not 500 or 5000. It may be an improvement on
           | other Li-metal anodes, but it's still orders of magnitude
           | away from being stable enough for practical use.
           | 
           | I'm not sure if the paper is open access or if my library is
           | automatically logging me in again, but the cycling behavior
           | is shown in Figure S18 of the Supporting Information here,
           | page 12:
           | 
           | https://onlinelibrary.wiley.com/action/downloadSupplement?do.
           | ..
        
         | Tagbert wrote:
         | Lithium ion batteries are not a single technology and are not
         | static. There are periodic changes that improve the batteries
         | in various dimensions. They are constantly evolving. At the
         | same time, it is perfectly feasible for EVs to switch to
         | alternate chemistries a construction methods. Individual
         | vehicles might not switch but a manufacturer could switch their
         | product line to start using sodium or sulphur or whatever new
         | chemistry comes along.
         | 
         | This Ars story talks about the ongoing improvements to battery
         | tech... https://arstechnica.com/science/2021/05/eternally-five-
         | years...
        
           | cptskippy wrote:
           | You're right and so is the OP.
           | 
           | Lithium based batteries of varying chemistries collectively
           | in space that few other battery chemistries overlap.
        
         | uoaei wrote:
         | Different battery designs and chemistries are appropriate for
         | different applications. I don't care about how much a battery
         | weighs if it never moves, for example.
        
           | bluGill wrote:
           | True (within limits), but the largest use of batteries is
           | batteries that move. Utility scale power storage is the only
           | significant use of battery that doesn't move. (there are
           | others, but they are not probably large enough to develop a
           | battery for, and so will be stuck with whatever they can get
           | from the other markets)
        
             | sanderjd wrote:
             | Yes, but stationary energy storage is itself a large use
             | case.
             | 
             | There are also different performance profiles within EVs,
             | where different tradeoffs might make sense. Though, like
             | you, I'm somewhat skeptical that any non-lithium
             | chemistries will break through in that space.
        
           | mabbo wrote:
           | I'm of two minds on this.
           | 
           | On the one hand, you're right that for different applications
           | having different metrics can be acceptable. Sure, a battery
           | for your home that never moves can be heavy and large and
           | that's okay.
           | 
           | But then you have to consider the economics of production.
           | How many of those batteries will you make? What will the
           | factory for them cost to build? And what would it cost
           | instead to just make a bunch more Li-Ion batteries at the
           | existing factory instead?
        
             | tasty_freeze wrote:
             | Your logic makes sense if there is only one battery
             | factory. But there are and will be many.
        
               | Retric wrote:
               | Economies of scale still apply with multiple factories
               | because you need someone to design and build the
               | equipment used at each of them.
        
           | alkonaut wrote:
           | The powerwall use case will only grow when people get solar
           | panels and when rural areas in countries lacking power
           | infrastructure eletrify. But while that use case doesn't care
           | as much about weight, bulk, charge rate and % capacity as car
           | batteries, in return they are very sensitive to cost and the
           | market will (depending on how cheaply recycling can be done)
           | likely be filled with used car-batteries with degraded
           | capacity.
           | 
           | If you invent a battery that is 2x as large and heavy as
           | current vehicle batteries but half the cost, then you might
           | think you would be able to sell them for stationary storage,
           | _but_ you are then competing with the price of second hand
           | vehicle batteries which may well be half price already.
        
             | sorenjan wrote:
             | One drawback of using lots of lithium batteries in your
             | home is that they might experience thermal runaway and burn
             | your house down. Not having to worry about that should have
             | some additional value.
        
               | RRRA wrote:
               | Most new solar installations now use LiFePO4 which
               | apparently is much safer on that runaway side...
        
               | BirAdam wrote:
               | Also way better cycle life, but the density is slightly
               | lower.
        
               | sorenjan wrote:
               | That's good, but is that what's used in "used car-
               | batteries with degraded capacity"?
        
               | samtho wrote:
               | Used car batteries are conventional unsealed, lead-acid
               | batteries. Lithium-iron-phosphate (aka LiFePO4, LFP)
               | batteries is a different battery chemistry altogether. It
               | is touted as the answer to a deep-cycle, lithium-based
               | electrical storage that the traditional lead acid
               | batteries occupy.
        
               | xsmasher wrote:
               | I think they mean used EV batteries - EV batteries that
               | are at the end of their useful life in cars.
        
               | samtho wrote:
               | That makes more sense.
        
         | Feloevo wrote:
         | There is already a car which uses two battery technologies in
         | parallel.
         | 
         | This would also allow you to configure or offer cars optimized
         | for the climate they are being used.
         | 
         | I personally also see those news more in 'im 5-10 years' we
         | will have something much better than now.
        
           | kungito wrote:
           | Which car? You cannot drop something like this without a
           | source
        
             | Feloevo wrote:
             | Can't find it on the fly.
             | 
             | I read about it a few month back but ev battery and types
             | etc. Shows a lot of other topics.
             | 
             | Might have been Tesla when they announced the other cell
             | type.
        
             | raddan wrote:
             | I'm sure this is not what the poster meant, but in fact
             | most EVs and hybrids use multiple battery technologies in
             | parallel. For example, a Chevy Bolt has a lithium ion
             | battery to power the drivetrain and a conventional lead-
             | acid battery for the accessories. My old Prius had a NiMH
             | battery for the drivetrain and a lead-acid battery for
             | accessories.
        
               | londons_explore wrote:
               | A lead acid battery is just a holdover from the way every
               | car used to have one for the accessories, and unless you
               | want to redesign all the accessories, it's easier to have
               | a 12v-14v circuit just for that.
               | 
               | And before you say "oh, but they could just use a voltage
               | converter from the high voltage battery", they need to
               | consider that some accessories use hundreds of amps
               | briefly (eg. the power steering - that makes for an
               | expensive voltage converter), and the car still needs to
               | operate lights and stuff while the high voltage battery
               | is offline (eg. after an isolation fault).
               | 
               | For all of the above reasons, the lead acid battery is
               | still there, even though a clean sheet design would never
               | have one.
        
               | entropicdrifter wrote:
               | My Hyundai Ioniq hybrid has a 12v section of the Li-ion
               | battery that can be charged off of the hybrid battery
               | while the car is off with the press of a button so that
               | the car never needs to be jump-started unless the entire
               | hybrid battery is dead.
        
               | rbanffy wrote:
               | > For example, a Chevy Bolt has a lithium ion battery to
               | power the drivetrain and a conventional lead-acid battery
               | for the accessories.
               | 
               | This seems like an odd choice - unless you already bought
               | a supply of lead-acid batteries for the next 50 years or
               | so.
               | 
               | I've read about a car using supercapacitors in the
               | regenerative brakes to capture energy at high current
               | and, then let it trickle back into the main batteries (or
               | drivetrain) at levels that won't damage it.
        
               | xxs wrote:
               | The 12v lane is ubiquitous, and standardized. Supercaps
               | are inefficient when it comes to storage per weight and
               | volume, discharge rate too.
               | 
               | Both lead acid and supercaps are not even remotely
               | comparable to the main liion battery, they're
               | suppliments, and not interesting ones
        
               | briffle wrote:
               | It could be great if you were a car manufacturer that
               | already had an existing, very large supply chain for
               | lights, dashboard, powered window motors, and other
               | accessories, that were already 12 volt.
        
               | sorenjan wrote:
               | Tesla switched from lead-acid to 12V lithium ion their S
               | and X models in 2021. James May had some issues with his
               | Tesla when the 12V battery went flat.
               | 
               | https://insideevs.com/news/546087/tesla-
               | liion-12v-auxiliary-...
               | 
               | https://youtu.be/NsKwMryKqRE
        
               | jandrese wrote:
               | Tesla is also switching to 48V for the accessories.
        
               | dreamcompiler wrote:
               | This was the best news I heard at Tesla investor day. It
               | should simplify and cut the cost of the in-cabin wiring.
               | 
               | When Sandy Munro interviewed Elon Musk a couple of years
               | ago he said "Why are you still using 12v stuff in the
               | cabin?"
               | 
               | Musk's answer was that the automotive supply chain was
               | entirely geared around 12v equipment and they had to take
               | advantage of that to get to market quickly.
               | 
               | I'm glad those days are almost over.
        
               | robocat wrote:
               | Isn't there a whole trucking supply chain geared around
               | 24 Volts?
        
               | Retric wrote:
               | This is a classic, it isn't broken don't fix it
               | situation.
               | 
               | Many laptops had both a lithium ion battery and a watch
               | battery used to keep the bios and an internal clock
               | running after the battery died.
               | https://www.makeuseof.com/tag/why-does-my-motherboard-
               | have-a...
        
               | Someone wrote:
               | That was a bit of a necessity. Users wouldn't want their
               | clock to reset when they swapped batteries, and you
               | couldn't be sure the machine was connected to a time
               | server to set the time at boot.
        
               | JohnClark1337 wrote:
               | [dead]
        
               | panick21_ wrote:
               | I don't think that is what this person is talking about.
               | Yes having an extra lower voltage battery is totally
               | normal and every EV either has a led acid or an
               | additional smaller LiIon battery.
               | 
               | Having multiple chemistries in one battery pack is of
               | course possible, but I don't any car who is actually
               | doing that.
        
       | moron4hire wrote:
       | I didn't see any mention of sustained discharge rate. I mean,
       | pretty much any battery will put out about as much current as you
       | ask of it. But that comes with heat scaling problems and heat
       | dramatically effects capacity. So at what kind of discharge rate
       | are they seeing "72% higher capacity by weight than Li-Ion," and
       | how does it compare to _typical_ Li-Ion usage?
        
       | 1970-01-01 wrote:
       | >They explored coating its copper current collector with
       | ultrathin lithium-activated tellurium. The aim was to control the
       | way in which lithium metal spread across or "wetted" the copper.
       | They found this new coating helped lithium metal deposit and
       | dissolve from the copper current collector in a thin uniform
       | layer.
       | 
       | Wikipedia: With an abundance in the Earth's crust comparable to
       | that of platinum (about 1 ug/kg), tellurium is one of the rarest
       | stable solid elements.
        
       | AtlasBarfed wrote:
       | 2x the density of.... what? ? "commercial lithium ion batteries"?
       | 
       | Watt-hours per kg, and watt-hours per liter.
       | 
       | And with all solid state, have they solved scaling production
       | beyond a small demonstration cell? It is now a known investment
       | "con" to create a solid state cell that appears to kick the tar
       | out of conventional cells and then try to get funded to "solve
       | production". I lost count of how many companies were doing this.
       | 
       | This is an embarrassing article from an engineering organization
       | website.
       | 
       | What appears to be happening is that solid state will simply be a
       | distraction technology. Sulfur chemistries (medium/long term) and
       | prosaic unsexy LFP and sodium ion (short term) will drive the
       | true revolution in electrification of transportation and grid
       | storage.
       | 
       | Solid state may produce usable use cases around laptops / phones
       | / etc at some point, and who knows, solid state sulfur may become
       | a thing eventually, but what's really needed from batteries now
       | is scale and cost.
       | 
       | The 200 wh/kg LFP (230+ on the roadmap/12-24 months away!) and
       | 150 wh/kg sodium ion (180-200 wh/kg on roadmap) going into mass
       | production are the big revolution in batteries. That is a non-
       | cobalt/nickel LFP battery that can do 400 mile cars, and a sodium
       | ion battery that should drop to 40$/kwh costs that can do a 300
       | mile car, and the roadmap should further upgrade/cheapen those
       | chemistries.
       | 
       | The 150 wh/kg sodium ion battery should mean 250-350 mile range
       | city cars that are significantly cheaper than ICE drivetrains can
       | achieve. It is tranportation for 3-4 billion people that won't
       | use fossil fuels.
       | 
       | LFP should eventually be able to do the medium range electric
       | semi truck. Sulfur chemistries should enable or better a long
       | haul semi, but sulfur chems are probably 8-12 years from mass
       | production (I really hope I'm wrong and it is sooner though)
        
       | RivieraKid wrote:
       | I think the best measure of real-world battery improvement would
       | be a chart of iPhone / Macbook battery densities over time. My
       | guess is that there's been little improvement over the last 10
       | years.
        
         | xbmcuser wrote:
         | This is according to CHATGPT so in terms of density you are
         | probably correct though in terms of reliability speed of
         | recharging there probably are improvements
         | 
         | iPhone 5: Dimensions: 51 x 39 x 3.6 mm (2.01 x 1.54 x 0.14 in)
         | Capacity: 1440 mAh Voltage: 3.8 V
         | 
         | iPhone 5s: Dimensions: 51 x 39 x 3.8 mm (2.01 x 1.54 x 0.15 in)
         | Capacity: 1560 mAh Voltage: 3.8 V
         | 
         | iPhone SE (1st generation): Dimensions: 51 x 39 x 3.95 mm (2.01
         | x 1.54 x 0.16 in) Capacity: 1624 mAh Voltage: 3.82 V
         | 
         | iPhone 6: Dimensions: 66.4 x 51.8 x 3.8 mm (2.61 x 2.04 x 0.15
         | in) Capacity: 1810 mAh Voltage: 3.82 V
         | 
         | iPhone 6s: Dimensions: 65.6 x 51.7 x 3.8 mm (2.58 x 2.04 x 0.15
         | in) Capacity: 1715 mAh Voltage: 3.82 V
         | 
         | iPhone 7: Dimensions: 73.1 x 32.4 x 5.2 mm (2.88 x 1.28 x 0.20
         | in) Capacity: 1960 mAh Voltage: 3.8 V
         | 
         | iPhone 8: Dimensions: 74.5 x 26.6 x 6.9 mm (2.94 x 1.05 x 0.27
         | in) Capacity: 1821 mAh Voltage: 3.82 V
         | 
         | iPhone SE (2nd generation): Dimensions: 67.3 x 40.9 x 3.73 mm
         | (2.65 x 1.61 x 0.15 in) Capacity: 1821 mAh Voltage: 3.82 V
         | 
         | iPhone X: Dimensions: 88.9 x 32.5 x 3.25 mm (3.5 x 1.28 x 0.13
         | in) Capacity: 2716 mAh Voltage: 3.81 V
         | 
         | iPhone XS: Dimensions: 87.16 x 32.61 x 2.96 mm (3.43 x 1.28 x
         | 0.12 in) Capacity: 2658 mAh Voltage: 3.81 V
         | 
         | iPhone XR: Dimensions: 76.0 x 30.8 x 3.25 mm (2.99 x 1.21 x
         | 0.13 in) Capacity: 2942 mAh Voltage: 3.81 V
         | 
         | iPhone 11: Dimensions: 90.0 x 31.9 x 3.25 mm (3.54 x 1.26 x
         | 0.13 in) Capacity: 3110 mAh Voltage: 3.83 V
         | 
         | iPhone 12: Dimensions: 81.5 x 32.4 x 4.1 mm (3.21 x 1.28 x 0.16
         | in) Capacity: 2815 mAh Voltage: 3.83 V
         | 
         | iPhone 13: Dimensions: 84.5 x 30.9 x 5.7 mm (3.33 x 1.22 x 0.22
         | in) Capacity: 3095 mAh Voltage: 3.83 V
        
           | slaw wrote:
           | from iPhone 13 to iPhone 5. volume increased 2.08 times and
           | capacity increased 2.15 times.
        
         | aldonius wrote:
         | Maybe not in specs, but what about in specs per dollar? Surely
         | there's been enough computer battery production over the last
         | decade for Wright's Law to have an effect.
        
       | ngrilly wrote:
       | Why is it called anode-free when it still has a copper collector
       | with a special coating? Yes, they removed the graphite, but they
       | didn't remote the entire "anode". Or is it because the collector
       | and the coating are not technically considered as an electrode?
        
         | danbruc wrote:
         | Technically speaking you can not get rid of the anode unless
         | you also get rid of the cathode as anode and cathode switch
         | places between charging and discharging. It is just by
         | convention that in case of batteries the role while discharging
         | is used, I would guess carried over from non-rechargeable
         | batteries, but the anode would better be called the negative
         | electrode.
        
           | pbhjpbhj wrote:
           | A battery with no poles would be a curious beast!
        
         | _nalply wrote:
         | I wondered about that too then I realized what an anodeless
         | battery would really, literally mean: if you charge it, you
         | pump electrons into it, so it gets somewhat electrically
         | negative, and if you discharge it, you let the electrons flow
         | out of it. To be pedantic, this is not really anodeless, this
         | would be just a battery having only one electric contact
         | switching roles between a cathode and an anode.
         | 
         | Then I started to wonder: what if this really could be done? I
         | am afraid not, because you need two contacts to create a
         | potential difference, don't you?
        
           | skupig wrote:
           | I think (?) that would work as long as your circuit is more
           | negatively charged than your battery and has enough
           | capacitance to keep current flowing- you just have to
           | discharge it later. Maybe with a second, negatively-charged
           | battery...
        
         | malfist wrote:
         | Forgive me if my EE knowledge is old and rusty, but isn't an
         | anode required for a battery to function? You have to be able
         | to harvest a voltage differential, and to do that you must have
         | an anode and a cathode.
         | 
         | Perhaps they meant there wasn't an anode that gets degraded by
         | use?
        
         | ndsipa_pomu wrote:
         | I initially thought this was an early April Fool's joke in a
         | different time zone to me. It does sound to me like they're
         | replacing the traditional anode with a different anode.
        
           | eurekin wrote:
           | They missed the opportunity to go "anodeless", like with the
           | serverless
        
           | ngrilly wrote:
           | Sounds the same to me. A copper sheet coated with a thin
           | layer of lithium-activated tellurium instead of a thicker
           | layer of graphite. Not trying to diminish their achievement,
           | but I don't understand the anode-less claim.
        
       | chimen wrote:
       | Surprised how "dead" this industry is. I remember having Lithium-
       | Ion batteries since I was in high school which was more than 20
       | years ago (and some Li-Po until then). Everything is leaps and
       | bounds since then but not the batteries. Seems like a massive
       | disconnect to me but I'm no chemist or researcher in this field.
        
         | jackmott42 wrote:
         | Lots of fields have run into fundamental physical limits that
         | pause progress. Rocketry is another. In the 1950s we pretty
         | much figured out how to throw gas out the back as fast as
         | possible, and so not much has happened since that improves
         | rocket performance. We did finally figure out how to reuse a
         | bit of the rocket affordably though so that has been nice.
         | 
         | similarly airplanes stopped getting faster because we hit the
         | point where the atmosphere starts melting you to death, and not
         | much can be done about that.
         | 
         | battery chemistry is hardly dead though, since 20 years ago
         | there have been all kinds of improvements in different
         | directions. Just no big leaps. But the little improvements add
         | up.
        
           | reisse wrote:
           | > similarly airplanes stopped getting faster because we hit
           | the point where the atmosphere starts melting you to death,
           | and not much can be done about that.
           | 
           | While I agree with your point in general, have to nitpick
           | here. Thermal protection is mostly solved problem by now
           | (think Space Shuttles and other reentry vehicles). Commercial
           | airplanes stopped getting faster because they hit a sweet
           | spot between speed and fuel consumption. Military airplanes
           | are stuck because hypersonic aerodynamics is very hard and
           | different from subsonic/sonic/supersonic ones.
        
           | londons_explore wrote:
           | Rocketry progress stopped because world governments cut back
           | funding dramatically in the 1960's, and private demand for
           | rocket launches isn't much.
           | 
           | Aeroplanes stopped developing because the whole industry is
           | now highly regulated. The barrier to getting a new type of
           | plane/engine design to market is beyond what pretty much all
           | startups are capable of. That's why we still fly some planes
           | like cessna designed in the 1960's, back when regulation was
           | more lax.
           | 
           | I don't think either rockets nor planes are anywhere near
           | fundamental physical limits if we took away the 'human'
           | limiting factors.
        
         | ben-schaaf wrote:
         | Energy density is ~8 times higher than in 2008 at 1/10th the
         | price. That's more progress than we've made in single-core
         | performance in the same timeframe.
         | 
         | Sources:
         | 
         | https://www.energy.gov/eere/vehicles/articles/fotw-1234-apri...
         | 
         | https://www.iea.org/data-and-statistics/charts/evolution-of-...
         | 
         | https://mlech26l.github.io/pages/2020/12/17/cpus.html
        
           | eutectic wrote:
           | Any idea why utiliy-scale is so much more expensive than
           | automotive?
        
             | Schroedingersat wrote:
             | Fire control, temperature control, chemical safety systems,
             | daily 2-3C (half hour to 20 minute) charge and discharge
             | rates, industrial grid scale high voltage grid forming
             | inverters. And finally, the auto-makers got to the front of
             | the queue for raw materials before prices spiked (and the
             | ones that do both just take the profit).
             | 
             | Expect more consistent prices in Q3 2023 once the end of
             | the lithium bubble works its way through the system.
        
           | AtlasBarfed wrote:
           | That has to be an astroturfer that posted that comment.
        
           | leoc wrote:
           | Did you mean 'more progress'?
        
             | ben-schaaf wrote:
             | Yes I did.
        
         | lm28469 wrote:
         | 2000 li ion batteries are the same as modern li ion batteries
         | the same way a Volkswagen golf 4 is the same as a golf 8, aka
         | they're not
        
         | windowsrookie wrote:
         | It's definitely not "dead". As commented above me, there have
         | been massive improvements.
         | 
         | 20 years ago laptops had two hours of battery life. Today a
         | MacBook has 20+ hours of battery life. Obviously many
         | components have become more efficient, but battery improvements
         | have also contributed to that large increase in battery
         | capacity.
        
           | ben-schaaf wrote:
           | The iBook G3 had a 45Wh battery which is only slightly less
           | than a M2 air, and barely under half of the maximum you can
           | take on a plane. Battery development has led to smaller,
           | lighter and cheaper batteries in laptops but not really to an
           | increase in capacity.
        
             | Anarch157a wrote:
             | Because Apple realised that a thin and small laptop sells
             | better than a chunky one. Make a Mac Book the sane size as
             | the iBook G3 and you could have a week's worth of battery.
             | 
             | But then you wouldn't be allowed to carry it on a plane.
             | The limitation is not tecnological, is regulatory.
        
             | londons_explore wrote:
             | Many laptops now are 99.6 Watt hours.
             | 
             | The 100Wh battery limit means they have little incentive to
             | further improve battery technology. Any increased storage
             | capacity wouldn't be legal to fly with, so all it could do
             | is make the laptop very slightly thinner or lighter.
        
         | empyrrhicist wrote:
         | Compare a power tool battery from any of the major brands from
         | 20 years ago to the ones today. It's still lithium, but real
         | performance is night and day.
        
       | Tade0 wrote:
       | Solid state might share the fate of Betamax.
       | 
       | There was a post a while ago about a small scale battery
       | manufacturer named Amprius, which reported 500Wh/kg batteries:
       | 
       | https://news.ycombinator.com/item?id=35276709
       | 
       | Thing is, the company is producing 450Wh/kg batteries NOW and
       | they're planning on scaling up their manufacturing capacity to
       | 5GWh:
       | 
       | https://www.convertingquarterly.com/ConvertingQuarterly/Indu...
       | 
       | This solid state news piece is exiting, but the real revolution
       | is happening in the background, with LFP achieving decent
       | densities without sacrificing cost or longevity and silicon anode
       | batteries reaching large-scale commercialization as we speak.
        
         | ngrilly wrote:
         | Some applications still require higher energy densities than
         | what LFP can provide. Are you saying silicon anodes are more
         | promising than solid state for those applications?
        
           | panick21_ wrote:
           | LFP cathodes and silicon or 'solid state' aka lithium metal
           | anodes are not incompatible.
        
           | Tade0 wrote:
           | My position is as follows:
           | 
           | -LFP wins on price where it fits the use case, so grid
           | storage, current-gen EVs.
           | 
           | -Silicon anode competes for market share with solid-state in
           | areas where LFP can't, namely aerospace and next-gen EVs or
           | even aviation, should they ever reach 1kWh/kg. The former has
           | easily a decade lead considering that they're already selling
           | packs and the latter exists largely in the lab or on paper.
           | 
           | I also believe even 400Wh/kg at pack level is already good
           | enough to be a serious proposition as replacement for
           | internal combustion in land transportation, provided pricing
           | is adequate.
        
             | ngrilly wrote:
             | I totally agree with your position on LFP, and about 400
             | Wh/kg being enough to unlock some applications.
             | 
             | But I'm not fully convinced on silicon anodes versus solid
             | state. Yes, energy density is very promising, but I
             | understand capacity fade is still a huge problem due to
             | silicon volume expansion/reduction while
             | charging/discharging?
        
               | Tade0 wrote:
               | That's the problem they've solved here using nanowires -
               | the cells have a 200-1200 cycle life depending on
               | operating conditions - I suppose the range is so wide
               | because of the temperature range - -30degC - 55degC. It's
               | not surprising to see cells degrade fast at the hotter
               | end of this spectrum.
               | 
               | For EVs they advertise cells with no less than 410Wh/L,
               | 4C rate of discharge.
        
               | naasking wrote:
               | Is there still a fire risk with LFP? From my
               | understanding, solid state batteries have a large safety
               | advantage here because of this.
        
               | Tade0 wrote:
               | Yes - LFP still uses a flammable, liquid electrolyte -
               | usually ethylene carbonate.
               | 
               | That being said LFP survives the nail penetration test
               | without causing a fire, so it's considerably safer than
               | the usual alternatives.
        
         | danbruc wrote:
         | 5 GWh in what time? Gigafactory 1 was at 30 GWh per year in
         | 2019 and they planned to ramp up to 54 GWh, according to
         | Wikipedia. So probably per year? Which would make their
         | production capacity 570 kW. Also according to Wikipedia, a
         | production of 35 GWh per year which is 4 MW was estimated to
         | require 300 MW of energy input.
        
           | Feloevo wrote:
           | Energy input can be green.
           | 
           | If not now, at least doable.
        
           | seszett wrote:
           | What is the point of comparing 300 MW energy use for
           | production with 35 GWh/year (which is technically 4MW indeed)
           | new battery capacity though?
           | 
           | These are technically the same units, but they don't measure
           | the same things.
        
             | danbruc wrote:
             | I find that comparison quite interesting with respect to
             | the energy intensity of producing lithium ion batteries. A
             | factory that can produce two oil barrels per hour or seven
             | 60 liter gasoline tanks per hour or will also produce 35
             | GWh storage capacity per year and would probably not
             | consume anywhere close to 300 MW in the process.
        
             | IshKebab wrote:
             | They measure comparable things. The ratio is how many times
             | you would have to discharge the battery to output enough
             | energy to manufacture the battery. It's the capacity
             | independent measure of embodied energy. An important
             | metric.
        
           | Tade0 wrote:
           | > Which would make their production capacity 570 kW.
           | 
           | I understand where you got this number, but I would rather
           | stick to units which are easy to interpret.
           | 
           | Yes, 5GWh per year or 570kW - in a sense.
        
         | jillesvangurp wrote:
         | You are right. The company you mention is focusing on the
         | aviation industry. Drones and light airplanes. Weight matters a
         | lot there. To the point where saving weight is worth a lot to
         | manufacturers.
         | 
         | Basically every kilo you save is more useful load and range.
         | It's also a very conservative market. Most of the planes in the
         | process of being certified, or already certified (like the
         | Pipistrel trainer) are using batteries that are quite
         | unimpressive in terms of wh/kg. That's because the technology
         | is typically at least half a decade old by the time a plane
         | gets through the certification process.
         | 
         | Manufacturers can't just switch battery supplier without
         | triggering a lot of re-certification activity and most of them
         | would have locked in their supplier many years ago; long before
         | even starting the certification process.. It's their next
         | models that are being designed now that would get something
         | that is state of the art now. Like this battery. We won't see
         | those in the market until 6-7 years from now.
         | 
         | The exception to this is probably going to be experimental
         | aircraft. I think that should become a growth market pretty
         | soon. A 500wh/kg battery of say 100kwh would weigh about 200
         | kilos, give or take. That should get you some usable range and
         | be light enough to put in a small plane. And it would put a
         | nice little dent in the cost of what used to be a 100$
         | hamburger flight. Fuel cost is high and planes use a lot of it.
         | 5-10 gallons per hour typically. And combustion engine
         | maintenance on planes is very expensive. All that goes away
         | with battery electric. Servicing becomes a lot simpler, less
         | moving parts that can break and the few remaining ones last a
         | lot longer.
         | 
         | Irresistible for a lot of private pilots, I would imagine. This
         | is a market that doesn't currently exist but I don't think it
         | should take long for people to start experimenting with battery
         | electric.
        
           | gpm wrote:
           | Manned airplanes are a conservative market, I would imagine
           | that unmanned drones are not? Especially cheap consumer ones?
        
           | MrsPeaches wrote:
           | Who's the current market leader on EV private pilot planes?
        
             | jillesvangurp wrote:
             | Cessna I guess.They bought Pipistrel recently. There are a
             | few companies getting closer to production with various
             | planes and drones. But realistically, I think volume sales
             | is still a few years out.
             | 
             | Companies like Amprius scaling their high end battery
             | production (like they announced recently) is interesting
             | though.
        
               | darksaints wrote:
               | Cessna didn't buy Pipistrel, Textron did. Maybe that's
               | being pedantic, but Cessna has zero development going on
               | in the electric plane space, and Pipistrel still runs
               | almost completely independent of the other brands in
               | Textron's portfolio.
        
             | rch wrote:
             | No idea who the technology leader might be, but I hear
             | about Joby most frequently.
        
         | jackmott42 wrote:
         | EVs are already very heavy, and when the model 3 switched to
         | LFP it got even heavier. This mass has lots of subtle
         | consequences that aren't always appreciated. Like accelerated
         | tire wear (which Tesla owners notice after they buy) and
         | increased particulate pollution from that, increased road wear,
         | increased danger to pedestrians and cyclists, etc.
         | 
         | So, I'm less excited about LFP. There are a number of ideas in
         | the works that might double the energy density over the current
         | leading lithium ion chemistries and if any of them work out its
         | going to unlock a lot a things that don't quite work yet like:
         | 
         | 1. light weight sports car EVs (like a miata) 2. EVs that can
         | tow things or carry 4 mountain bikes on road trips 3. Some
         | aircraft 4. EVs that can do a track day for a reasonable amount
         | of time 5. EVs that are lighter than ICE counterparts rather
         | than heavier
        
           | Feloevo wrote:
           | Independent of this, this also gives more and.better options
           | for the energy grid in general.
           | 
           | And economy of scale: if we can produce it, the chance that
           | we can scale it might only be a question of few years.
        
           | wffurr wrote:
           | Wh/Kg is the relevant metric to optimize though. Whether it's
           | LFP or solid state doesn't matter. If that company is
           | building higher density LFP batteries, that addresses every
           | concern you mention.
        
             | jackmott wrote:
             | [dead]
        
           | ericpauley wrote:
           | I'll know we've made it when you can buy a 1000kg EV Miata.
        
           | newZWhoDis wrote:
           | > increased danger to pedestrians and cyclists, etc.
           | 
           | Why do seemingly so people here understand clipping
           | functions?
           | 
           | The lethality of a pedestrian-vehicle collision with a
           | 4,000lb vehicle at 60MPH and a 400,000lb vehicle at 60MPH are
           | both 1
           | 
           | In practical terms, the additional weight of an EV has zero
           | effect on pedestrian collision lethality, whereas something
           | like bumper design would.
        
             | AlotOfReading wrote:
             | I'm not sure why clipping functions are relevant, because
             | the probability of death isn't 100% even for semis hitting
             | pedestrians at highway speeds. It's actually more like
             | 80-90%. There's still quite a bit of long tail for higher
             | speeds beyond that as well. SUVs and other "heavy" consumer
             | vehicles are somewhere in the 75% range at comparable
             | speeds, while sedans are down around 65% mortality. Feel
             | free to find your own numbers, but I'm using [1]. Vehicle
             | weight and size clearly have a significant effect on
             | mortality even at high speeds.
             | 
             | However, not all collisions are at highway speed. Most
             | collisions are at relatively low speed, where weight is an
             | even more significant factor in the energy involved. There
             | are tradeoffs you can make between weight contributed by
             | safety equipment (e.g. bumpers), but to a large extent
             | those tradeoffs are mandated by regulations rather than
             | consumers or OEM engineers.
             | 
             | [1] https://www.moneygeek.com/insurance/auto/analysis/pedes
             | trian... [2] https://www.nber.org/digest/nov11/vehicle-
             | weight-and-automot...
        
               | meatmanek wrote:
               | Vehicle mass matters a lot in vehicle-to-vehicle
               | collisions, where the energy and momentum of each vehicle
               | is going to change a lot, but when a car collides with a
               | person, the car's momentum is barely affected, because
               | the car is already significantly more massive than the
               | person. A 20x mass ratio is already practically infinite.
               | 
               | In a direct collision between a moving 1000kg car going
               | 10 m/s and a stationary 50kg person, the person will end
               | up moving somewhere between 9.5 m/s (perfectly inelastic
               | collision) and 19.05 m/s (perfectly elastic). The car
               | will end up moving 9.5 m/s (perfectly inelastic) and 9.05
               | m/s (perfectly elastic).
               | 
               | In a direct collision between a moving 10000kg car going
               | 10 m/s and a stationary 50kg person, the person will end
               | up moving 9.95 m/s (perfectly inelastic) and 19.90 m/s
               | (perfectly elastic). The car will end up moving somewhere
               | between 9.95 m/s (perfectly inelastic) and 9.90 m/s
               | (perfectly elastic).
               | 
               | Even though we 10x'd the weight of the car, we only
               | increased the velocity of the person after impact by
               | about 5%, and energy imparted on the person by about 10%.
               | 
               | I suspect vehicle size (or rather, the size/shape of the
               | front of the vehicle) has way more effect on pedestrian
               | survivability than the weight of the vehicle. SUVs and
               | trucks will impart the force of impact directly to your
               | torso and head, and then subsequently run you over.
               | Sedans hit you in the legs and then roll you over the top
               | of the vehicle.
        
             | GaryNumanVevo wrote:
             | Higher curb weight correlates with longer breaking
             | distances
        
           | seppler wrote:
           | Before my Model 3, I had a BMW M3. Curb weights were the same
           | (2009 BMW M3 vs 2018 Model 3 LR RWD). Even comparing a 2020
           | Model 3 AWD vs. a 2020 BMW M3, curb weights are about the
           | same (~4000lbs).
        
       | Heston wrote:
       | "...the problem they face going through cycles of discharging and
       | recharging in a stable way."
       | 
       | They suffer from poor wearing like almost all new battery
       | technologies. Until that's solved they aren't useful.
        
         | lonk11 wrote:
         | The article is about a solution to make lithium metal anode
         | more stable. They discovered a coating that prevents the
         | formation of dendrites, which are the cause of short cycle life
         | of previous attempts at lithium metal anodes.
        
       | [deleted]
        
       | ashish10 wrote:
       | Isn't this what Quantumscape is already betting on ?
        
         | Phurist wrote:
         | Yeah, Isn't that what engineers in the Skunksworks at Mutual
         | Polydynamics were already working on in scope of the SANS ICS
         | HyperEncabulator?
        
         | AtlasBarfed wrote:
         | Hey, remember them? They were right on the verge of production
         | allegedly while the shorters were "outing" them?
         | 
         | I've heard nothing about them for a solid 16 months, so I'm
         | guessing the shorters were right.
         | 
         | Solid State batteries appear pretty easy to crank out a
         | demonstration cell with lots of density advantages over the
         | production cells, and handwave away the scaling of production
         | as a detail resolved in investment. There are a solid dozen
         | companies I've seen with that basic approach.
         | 
         | None of the solid state companies appear close to scaling
         | production.
         | 
         | Likely the sulfur chemistries will beat them to market with far
         | superior material cost and density and scalability. Solid state
         | still has a good opportunity in cell phones / laptops / etc,
         | which is a big market, but the real play in batteries is grid
         | storange and tranportation, which will dwarf phones/laptops by
         | several orders of magnitude in volume.
        
           | panick21_ wrote:
           | The never even claimed to have their first medium scale
           | production facility before 2024 and only then going into
           | medium scale production. Their first real factory isn't
           | planned until later this decade.
           | 
           | Not sure where people got the idea that they claimed they are
           | on the verge of large scale production.
           | 
           | They were on a little bit more then lab scale production.
        
       | solarkraft wrote:
       | > Still, although this research may solve one critical problem
       | with anode-free all-solid-state lithium batteries, a great deal
       | of development is needed to actually bring them to market
       | 
       | Always.
       | 
       | I'm happy they found something that might perhaps some day become
       | real, but it's going to stay irrelevant for years and may never
       | happen. Unless you _really_ care about minor scientific
       | discoveries (rather than things that are directly going to
       | influence industies related to energy storage), there 's not much
       | to see here.
       | 
       | No, we're not all going to have Aluminium-Air batteries in our
       | cars next year. The hype around this stuff reminds me of the one
       | around fusion reactors. Just around the corner. Sure, dude.
        
       | amelius wrote:
       | How do you get the energy out when it has no anode?
       | 
       | Title seems a bit weird for an IEEE audience ...
        
       | gt565k wrote:
       | I read an article somewhere that discusses how Toyota has the
       | most battery patents out of any company and also owns most of the
       | solid state patents and are actually working on commercializing
       | solid state batteries for vehicles.
       | 
       | The point I think the article was trying to make is that while
       | everyone is focused on lithium ion, Toyota was biding it's time
       | and getting ready to one-up everyone with solid state batteries
       | and vehicles with double the range.
        
         | _trackno5 wrote:
         | Please share that article if you can find it. Sounds like an
         | interesting take!
         | 
         | I honestly don't get the criticism Toyota has been getting
         | recently. I think their decision to not go all in on just
         | electric vehicles makes sense, especially for countries where
         | it is highly unlikely that full EV will be a reality in the
         | next decade.
        
           | MontyCarloHall wrote:
           | >I honestly don't get the criticism [Toyota] has been getting
           | recently. I think their decision to not go all in on just
           | electric vehicles makes sense
           | 
           | Because for a while it seemed they were going all-in on
           | hydrogen fuel cell vehicles, a technology that makes little
           | technological (and even less practical) sense.
        
             | _trackno5 wrote:
             | For a while, but not the case anymore. They seem keen on
             | having a diverse set of offerings, with some EV and hybrid
             | cars. Yet the criticism continues
        
           | thatwasunusual wrote:
           | > Please share that article if you can find it. Sounds like
           | an interesting take!
           | 
           | I assume it's this one:
           | 
           | https://asia.nikkei.com/Business/Technology/Toyota-
           | secures-h...
           | 
           | It seems to behind a soft paywall, so here's the archive.ph
           | edition:
           | 
           | https://archive.ph/UWFCH
        
         | pjc50 wrote:
         | I'm not sure about Toyota, because up till now they've been
         | hydrogen evangelists and they don't have a great record on pure
         | battery EVs.
        
           | rowanG077 wrote:
           | Isn't that a given since the invest in solid-state?
        
             | speedgoose wrote:
             | Solid-state isn't going to fix the crazy high consumption
             | of their EVs.
        
           | gonzo41 wrote:
           | Well H2 is a hedge. It's a green-ish fuel and has potential
           | as a replacement to lng for japan.
           | 
           | but more power to toyota. can't wait to get an electric
           | hilux. hopefully it's cheap.
        
             | nordsieck wrote:
             | > Well H2 is a hedge. It's a green-ish fuel and has
             | potential as a replacement to lng for japan.
             | 
             | Is it though? Can't be a hedge if it doesn't really work
             | well fundamentally.
             | 
             | Although I'll admit to being largely ignorant of the
             | Japanese car market.
             | 
             | IMO, it'd be much more practical to invest in automotive
             | LNG tech and combine that with synthesizing LNG from the
             | atmosphere (or at least developing the tech to do so).
             | 
             | Practically, both H2 and LNG are both "dirty", since H2 is
             | made though natural gas reforming these days.
        
               | pbhjpbhj wrote:
               | Strikes me that H2 made from excess solar panel output,
               | at source, might become a thing. If you have enough solar
               | for your needs then you're over-producing when the sun is
               | at its peak. With feed in tariffs being low it makes
               | sense to use this -- and hydrogen vehicles are an option.
        
               | nordsieck wrote:
               | > Strikes me that H2 made from excess solar panel output,
               | at source, might become a thing.
               | 
               | Why is that better than putting it back into the grid
               | and/or putting it into a battery?
        
               | pjc50 wrote:
               | There's occasionally overproduction of renewables, which
               | is normally just curtailed (discarded) because it exceeds
               | grid demand.
               | 
               | The H2 for medium-term tank storage idea is not bad ..
               | except for the very high capital cost of electrolysis.
               | Without some means of making H2 that doesn't involve
               | tying up a chunk of platinum as a capital asset this is a
               | non starter economically.
        
               | Schroedingersat wrote:
               | Batteries are as yet inappropriate for long duration
               | swings over weeks or months that cycle only a few times a
               | year.
               | 
               | Better to compare it to thermal storage, PHES, simply
               | curtailing it or even virtual storage via hydro or w2e
               | (or hydrogen generation with no step where it is
               | converted back to electricity or motion). All of which
               | are more sensible than hydrogen for personal transport.
        
               | greggsy wrote:
               | H2 has the benefit of being much easier to store,
               | transport and transfer than batteries. It's able to be
               | stored in small containers and large vessels of any
               | shape. Batteries manufacturing is much more complex.
               | Electricity needs to be transferred from a power station
               | over wires, while hydrogen can be pumped into a vehicle
               | from a bulk source.
               | 
               | Sure H2 is dangerous, but so is LNG, and petrol for that
               | matter. 100+ years of accidents and safety controls means
               | that even a drunk person smoking at the pump can
               | (probably) fill their car up safely.
               | 
               | Japan has very poor carbon security, so LNG reforming
               | might come with its own challenges, but they could
               | generate it via electrolysis using nuclear or wind power,
               | or import ammonia from future mega producers like
               | Australia.
               | 
               | It's very likely that global demand in the transport
               | sector will tend towards H2, so they need to gear their
               | industry towards that market.
        
               | pjc50 wrote:
               | The bait-and-switch is that while green hydrogen _can_ be
               | made, it very rarely is, and when it is, it 's less cost-
               | effective than a battery electric solution. It's almost
               | always a Trojan horse for shifting carbon emissions away
               | from the tailpipe to a refinery where you can't see them
               | quite as obviously.
        
               | pbhjpbhj wrote:
               | If battery material costs go high (it they're otherwise
               | hard to come by) then it seems like hydrogen could find
               | its niche?
        
               | _hypx wrote:
               | That is no different than a battery car. You are just
               | shifting pollution to whatever is making your
               | electricity. And if anyone comes in and says "I spent
               | tens of thousands of dollars getting green electricity!"
               | then it should be obvious that the same level of spending
               | could make upstream hydrogen production vastly greener.
               | 
               | And no, it is not "less cost effective" because batteries
               | involve dramatically higher upfront production costs. The
               | argument is really just a troll argument and virtually
               | identical to the same arguments used against battery
               | cars.
        
               | greggsy wrote:
               | I think it's important to frame it within the
               | sociotechnical frameworks that nations are able to
               | operate under.
               | 
               | Introducing this technology will require incremental
               | changes across industry, infrastructure and communities.
               | Today, green hydrogen is out of reach for many economies.
               | Building H2 ecosystems, will almost certainly require
               | initial investment in brown/black hydrogen by burning
               | fossils fuels, which is currently under development in
               | Australia and Japan.
               | 
               | The transition to blue (renewable>LNG>H2) and eventually
               | towards green (renewables>H2O>H2) hydrogen will be slow
               | and _will_ take decades to achieve. Purple (nuclear)
               | hydrogen may be a next logical step for Japan.
               | 
               | It's simply not possible to replace everything everywhere
               | all at once. We should have gotten onto this two decades
               | ago, so we unfortunately have to make compromises that
               | seem cynical and small on the outset, but are still very
               | difficult to implement and gain consensus.
        
               | somewhat_drunk wrote:
               | Nah.
               | 
               | I worked as a project engineer in a hydrogen fuel cell
               | test lab for a few years. H2 is EXTREMELY hazardous. It
               | can be ignited by a miniscule amount of energy (i.e. a
               | tiny static spark will do it), and it has a very fast
               | flame front, which creates an extremely energetic
               | explosion. It's also the smallest molecule, so it's very
               | difficult to prevent leakage, and it embrittles and
               | degrades most steels over time. Additionally, proton
               | exchange membrane fuel cells (the most common kind) are
               | poisoned by anything NOT H2, so you can't add odorous
               | agents to H2 to easily detect leaks, like we do with
               | natural gas. H2's only non-dangerous characteristic is
               | its high buoyancy, which means it dissipates quickly in
               | outdoor environments, but in my opinion that is not
               | sufficient to offset all of its other dangerous
               | characteristics.
               | 
               | I would NEVER live in a building that had H2 stored
               | inside (as in, inside a vehicle tank) or pumped in it,
               | and I would definitely not trust the general public to
               | use it safely.
               | 
               | It also has to be stored at either incredibly high
               | pressures (as a gas) or incredibly cold temperatures (as
               | a liquid), neither of which are conducive to large-scale,
               | long-range transport.
               | 
               | But the worst part of H2 isn't how dangerous it is or how
               | impractical it is; the worst part of H2 is how incredibly
               | inefficient a hydrogen economy would be. See Paul
               | Martin's excellent summary of H2 for a thorough debunking
               | of the main H2 talking points.
               | 
               | https://www.linkedin.com/pulse/distilled-thoughts-
               | hydrogen-p...
        
         | ezconnect wrote:
         | They have always been conservative. They have the most reliable
         | hybrid in the market.
        
         | panick21_ wrote:
         | Yeah so this is basically just repeating Toyota marketing. Yes
         | they have lots of patents, because they studied lots of stuff,
         | it does not mean they are in the lead of anything.
         | 
         | > while everyone is focused on lithium ion
         | 
         | Please remember that 'solid state' is just a marketing term.
         | The actual meaning when talking in terms of automotive battery
         | is 'lithium metal anodes'. So these are still lithium ion
         | batteries.
         | 
         | And lots of people are working on lithium metal anodes, and
         | have been for 50 years.
         | 
         | > Toyota was biding it's time and getting ready to one-up
         | everyone with solid state batteries and vehicles with double
         | the range.
         | 
         | That is certainty what Toyota marketing has been telling
         | people. But in reality scaling a new battery technology is
         | incredibly difficult and if these claims were actually true we
         | would see massive Toyota battery factory being build. When in
         | reality its incredibly low volume production stuff that might
         | show up in a few hybrids.
         | 
         | Also, 'solid state' isn't magically better then everything
         | else. You can hit the same density with silicon. There are 100s
         | of companies working on silicon and lithium metal anodes.
         | 
         | Toyota has announced some EVs but no actual product with these
         | magical batteries that they have. The reality is, nobody, not
         | Toyota best battery engineers know how difficult it will be to
         | scale production of these things to a massive gigafactory. And
         | if its not a massive gigafactory then its practically
         | irrelevant in the EV market.
         | 
         | So unless we actually see a massive gigafactory somewhere that
         | is dedicated to this type of battery, this is just marketing.
        
         | moogly wrote:
         | So are you saying this long game is why the anti-EV CEO Toyoda
         | Akio is stepping down tomorrow? (Read between the lines: being
         | ousted by the board).
        
           | panick21_ wrote:
           | In realty his successor is just as anti-EV.
        
         | datacruncher01 wrote:
         | I think that Toyota won't really go heavy into EVs until
         | batteries are more available. EV batteries are heavily
         | dependent on lithium availability which is limited by world
         | wide exploration limits. We are only able to mine enough to
         | make about 2 million Tesla equivalent cars per year, and that's
         | if none of it goes to phones other electronic devices. Toyota
         | sells that many vehicles alone each year. Until there is
         | something that can scale and still allow them to sell an
         | economical model, they won't go heavy into EVs.
        
           | dev_daftly wrote:
           | I mean, Toyota has said this themselves. Their view is that
           | making 1,000,000 hybrids is better than 1,000 evs because
           | most of an evs battery capacity is wasted on a daily basis.
        
         | horseRad wrote:
         | I remember when people said Toyota would sweep in and crush
         | EV:s with solid state batteries in 2020 (Even when they
         | despised EV:s).
         | 
         | https://techcrunch.com/2017/07/25/toyotas-new-solid-state-ba...
        
       | vrglvrglvrgl wrote:
       | [dead]
        
       | jagtongue wrote:
       | No fire risk? hmmm ... but still on lithium 25 years later. But
       | then again the recent advancements in solid-state battery
       | technology have led to twice the energy density of traditional
       | lithium-ion batteries as stated in this read, as well as
       | eliminate the need for a separate anode altogether. Think its
       | because it uses a lithium metal foil both as the anode and the
       | current collector. But i don't understand the science behind why
       | that would result in a more compact design.
        
       | Aardwolf wrote:
       | Nice, when can we use them for phones and laptops lasting 72%
       | longer and without fire risk?
       | 
       | Genuine question, because optimistic battery articles have been
       | popping up for decades, but here we are still with lithium ion in
       | practice.
        
         | jeffalyanak wrote:
         | News about news battery chemistry is interesting, but it's not
         | meaningfully correlated with our ability to produce practical
         | batteries at scale.
         | 
         | If there are existing manufacturing processes that can be
         | leveraged to build cells with this chemistry--and do so
         | economically--then commercialization could happen very rapidly.
         | 
         | Otherwise, it's likely to be filled away until future
         | manufacturing technology comes along, which may be "too late"
         | if even better or more economical options exist at that point.
        
         | jrockway wrote:
         | > here we are still with lithium ion in practice
         | 
         | Lithium ion batteries are actually amazing tech. I certainly
         | remember the world without them; laptops had an hour of battery
         | life, mobile phones were "car phones", everyone was running
         | around paranoid about the "memory effect", and electric cars
         | were an interesting curiosity always ten years away. Here we
         | are today with pocket computers that last for days and electric
         | cars buzzing around the city. In 30 years, some of this new
         | tech we read about will be widely adopted, but in the meantime,
         | it's not like things are that bad.
         | 
         | I think that electric airplanes will be the thing that new
         | battery technology unlocks.
        
           | ezconnect wrote:
           | It's not all batteries, the electronics got less power
           | hungry.
        
             | dougmwne wrote:
             | Drones are a good example of something that couldn't exist
             | with the old battery tech. Hobbyist RC aircraft always ran
             | on small fuel engines. And the laws of physics around
             | energy required to lift a craft are not changing anytime
             | soon.
        
               | ezconnect wrote:
               | I agree Lithium batteries can't be beat on power density
               | compared to other battery technology.
        
         | panick21_ wrote:
         | Lithium ion is not one thing.
         | 
         | The 'Lithium ion' from 10 years ago is very different from it
         | now. 'Lithium ion' is an umbrella term that contains lots of
         | things. Just as 'solid state' is not really what anybody is
         | talking about. What actually matters about 'solid state' is
         | lithium metal anodes. There are also companies who are doing
         | lithium metal anodes without being solid state.
         | 
         | If 'solid state' ever make it into the market, they will just
         | be the new 'Lithium ion'.
        
         | hgomersall wrote:
         | I have a genuine question too. I've never been worried about
         | phone battery life; I charge once a day and I almost never run
         | out, nor do I consciously conserve battery. Is worrying about
         | phone battery life a problem relevant to certain phones, or is
         | it a problem with usage styles?
        
           | RivieraKid wrote:
           | I have a Pixel 4a and it doesn't last a whole day if I use
           | the phone a lot.
           | 
           | So basically, if I wanted the freedom to have occasional
           | heavy-usage days, I would have to buy a larger, heavier
           | phone.
        
           | ibejoeb wrote:
           | It certainly depends on network quality. Do you stay mainly
           | in one area, or do you move around all day? I use my phone
           | for communication only--practically no browsing or app usage,
           | no games--and in some places I can get away with a full day,
           | others I need a recharge.
        
         | tomxor wrote:
         | If you read the article to the end it does actually offer
         | reasonable perspective on this, pointing out that there are
         | many other challenges left to solve before even getting to a
         | prototype scale. TL;DR It's a promising step in the direction
         | of solid state batteries.
        
       | akokanka wrote:
       | Research Vs Reality are quite often decades behind in physical
       | world.
        
         | jillesvangurp wrote:
         | Easy to forget that most car enthusiasts thought that Elon Musk
         | was a lunatic that was obviously going to fail about a decade
         | ago. And now he's basically dominating the car industry.
         | Lithium batteries did not exist until the nineties and did not
         | get practical for use in cars until about 15 years ago.
         | 
         | Research on solid state batteries has been ongoing since then.
         | E.g. Quantumscape founded in 2010. and is planning to start
         | small scale production next year. We'll see how successful they
         | are of course. You are right that it takes quite long to take
         | technology into production. But the counter argument is that
         | there are a few decades behind us with stuff that is now slowly
         | trickling into the market.
         | 
         | Double the energy sounds amazing. Until you ask the question
         | "double of what". Double of what's available in the market
         | right now (450 wh/kg, Amprius sells these in low volumes) would
         | be 900 wh/kg. That's perhaps not what they mean. The article is
         | infuriatingly hand wavy on what is being compared to what. Or
         | maybe they do. Hard to tell.
        
           | solarkraft wrote:
           | You're not wrong, but these articles keep selling it like the
           | market introduction is just around the corner. It never is.
           | They never mention that the battery almost always a huge
           | downside making it inviable for most applications. So I (and
           | probably many others) have grown disillusioned of news around
           | battery technology. Wake me up when pre-production units
           | reach independent testers. I don't care enough about this
           | stuff to follow the dozens of leads that appear what feels
           | like every week but never go anywhere.
        
           | panick21_ wrote:
           | Solid state (actually we talking about lithium metal anodes)
           | have been researched literally since 70s.
        
       | nmeofthestate wrote:
       | * goes straight to the HN comments before reading TFA, to find
       | out why this battery sucks *
        
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