[HN Gopher] "Off switch" makes explosives safer
       ___________________________________________________________________
        
       "Off switch" makes explosives safer
        
       Author : Someone
       Score  : 77 points
       Date   : 2023-03-21 16:07 UTC (6 hours ago)
        
 (HTM) web link (physics.aps.org)
 (TXT) w3m dump (physics.aps.org)
        
       | Animats wrote:
       | Safe until filled with water is probably not that useful. Water
       | is everywhere and things in military use tend to get wet.
       | 
       | There are binary explosives now, where both components are
       | nonexplosive by themselves. Those are used commercially, for road
       | work and such.
        
         | exabrial wrote:
         | Ah, yes, but think those olive drab steel Ammo Cans. These are
         | a simple, cheap, tried-and-true tested method of preserving
         | military supplies; heat proof, water proof, dust proof,
         | (somewhat) nuke proof, biological proof, and fire proof.
        
         | londons_explore wrote:
         | Depends how it's designed. If it needs to be drenched to be
         | explosive, then simple drains holes at the bottom keep it safe.
         | 
         | Plug the holes and fill with a hose when you want to use it.
        
           | andrewflnr wrote:
           | Yeah, damp or drizzle isn't going to activate these, if I'm
           | understanding them correctly. If anything, I was wondering at
           | first how they were going to deal with air bubbles (but I
           | suspect they're fine as long as there aren't too many).
        
         | tomatotomato37 wrote:
         | I believe this is more intended for civilian (mining,
         | demolition) or combat engineering explosives than it is for
         | actual armaments, where having to have lots of watertight
         | storage available to store your low density explosives isn't
         | that big of a concern.
        
         | nullc wrote:
         | > where both components are nonexplosive by themselves.
         | 
         | in plenty of binary explosives the components are explosive,
         | but less so and even harder to set off.
        
       | chillingeffect wrote:
       | Those are the names of Javascript libraries right?
        
       | EamonnMR wrote:
       | Water has a tendency to get into places it's not supposed to. I'd
       | hate for a roof leak to cause a warehouse explosion.
        
         | etskinner wrote:
         | Presumably there would be more safeguards in place than just
         | the water. All the safeguards that currently exist could still
         | be used.
        
       | exabrial wrote:
       | > They used a 3D printer to produce......
       | 
       | Wow really upping the pucker factor in one of my favorite
       | hobbies.
        
         | flangola7 wrote:
         | You wouldn't download a shaped charge
        
         | smilespray wrote:
         | Tip: Don't heat the print bed when printing with TNT.
        
           | jabl wrote:
           | I recently read about the Oppau disaster
           | (https://en.wikipedia.org/wiki/Oppau_explosion ), where the
           | workers were getting bored with using pickaxes to break up a
           | huge pile of compressed ammonium sulfate and ammonium
           | nitrate, and decided to use dynamite to loosen it up. What
           | could possibly go wrong?
        
             | jandrese wrote:
             | The crazy thing about that is they had broken up the
             | Ammonium Sulfate/Ammonium Nitrate mixture thousands of
             | times before the incident. It was incredible that they
             | managed to do so for as long as they did. All it took was
             | one day where the mixture wasn't mixed very well and
             | everyone dies. An industrial version of Russian Roulette.
        
               | Xylakant wrote:
               | It was considered safe at the time because the mixture is
               | usually not very sensitive. Hindsight is 20/20.
        
               | renewiltord wrote:
               | Famous saying in Safety Engineering: everything that can
               | go wrong will go right most of the time.
        
           | nibbleshifter wrote:
           | Its melt castable and not the easiest thing to get going, so
           | you probably _could_ print with it.
           | 
           | Probably would also give you megacancer.
        
           | wongarsu wrote:
           | Apparently TNT melts at 80degC. If we are to believe [1],
           | liquid TNT is quite sensitive while confined, and gets more
           | sensitive the hotter it gets, but if allowed to flow it's
           | actually very difficult to set off. Autoignition happens at
           | about 265degC, according to [2], and again according to [1]
           | temperature doesn't play a major role in the sensitivity of
           | solid TNT.
           | 
           | So I guess don't heat the print bed too much, and if you do
           | make sure the TNT can flow freely until it solidifies again,
           | and you should be fine.
           | 
           | Edit: and as nibbleshifter suggests, you could print with it
           | given these parameters, just be careful with the TNT in the
           | hotend.
           | 
           | 1: https://www.cdc.gov/niosh/mining/userfiles/works/pdfs/itas
           | s....
           | 
           | 2: https://www.govinfo.gov/content/pkg/GOVPUB-C13-36e8df81dfe
           | 03...
        
             | Arrath wrote:
             | There are to this day many an explosive product that is
             | cast by pouring molten explosive material into the shell.
             | In some cases, poured by hand from jugs.
             | 
             | Steady!!!
        
             | dsfyu404ed wrote:
             | Would be pretty cool to be able to order custom shapes
             | SendCutSend style. Would be real useful in demolition and
             | construction settings in cases where you don't do enough of
             | a specific job to buy or rent expensive non-explosive
             | equipment to do it.
        
               | TylerE wrote:
               | That's easy with plastic explosive. It's a putty like
               | consistancy. It's explicitly designed to be sized and
               | shaped in the field.
        
       | loufe wrote:
       | I work as a drilling and explosives engineer at an active mine. I
       | don't see the value-add here, to be honest. Modern explosives
       | management (in a mining context) is extraordinarily well managed.
       | ANFO (ammonium nitrate fuel oil) which is the dominant explosive
       | type is so hardy that you can hold a flame to it or shoot it with
       | a firearm and you will not succeed in detonating it. 3-stage
       | explosives systems (detonator-->booster-->ANFO) is a fantastic
       | way of managing risk. Detonators cannot set off ANFO, the booster
       | is required middle step.
       | 
       | I won't pretend to have studied the phenomenon, but the only
       | undesired detonations I've heard of so far in my career have all
       | been a result of detonators inadvertantly set off. The latest
       | examples I know of being wireless electric detonators (which are
       | being phased out as they're inferior to electronic
       | detonators,which offer more protection) set off because of
       | malfunctioning devices emitting the required radio waves, yikes!
       | The explosion in Beirut can hardly be considered in the same
       | category as that was an explosion of explosive precursor,
       | effectively unrelated.
       | 
       | I'm struggling to understand what the target market for this type
       | of innovation is. Is it bulk transport of explosive materials
       | between the manufacturer (like Orica or Dyno-Nobel) and
       | individual mine sites? That part is already extremely safe. You'd
       | need specialized equipment at each mine to mix the water back in,
       | with maintenance and calibration requirements. There's no way
       | this could be between the surface and the holes into which the
       | explosives are loaded, for so many reasons. I also wonder about
       | the consistency and quality of the resulting product, the balance
       | for these explosives is already such a tuned and precise.
        
       | killjoywashere wrote:
       | Ah, Los Alamos, exactly what I though. What this really is, is an
       | external manifestation of the eternal struggle between the
       | military, which wants the weapons to detonate on time every time,
       | and the safety-minded engineers and politicos who would rather
       | eat an occasional fail than start a nuclear war. The safety
       | people being the engineers tend to keep finding new ways to be
       | safe and applying them without necessarily securing the DoD's
       | permission, but they don't always work out the way the engineers
       | intended. For a period of time, there was a piece of cobalt tape
       | on Trident missile warheads that would ensure they fizzle unless
       | removed. Except the adhesive dried up and then the release force
       | exceeded the torque of the motor intended to remove the tape, so
       | something like 75% of the Trident missiles were duds for years.
       | 
       | Read Eric Schlosser's Command and Control. Absolutely
       | fascinating.
        
         | XorNot wrote:
         | > who would rather eat an occasional fail than start a nuclear
         | war.
         | 
         | A nuclear detonation on allied territory that originates from
         | your own weapons isn't going to cause a nuclear war. The point
         | at which a nuclear warheads needs to explode is "when it's
         | about 1km above it's target". The war is already _happening_ if
         | it got anywhere near there.
        
         | perihelions wrote:
         | I can't find anything on Google about cobalt tape or Trident
         | missiles -- but there was a cadmium wire in the W47 warhead,
         | the one for Polaris missiles, which has a story very similar to
         | yours:
         | 
         | - _" Because the test ban prohibited the testing needed for
         | inherently safe one-point safe designs, a makeshift solution
         | was adopted: a boron-cadmium wire was folded inside the pit
         | during manufacture, and pulled out by a small motor during the
         | warhead arming process. Unfortunately, this wire had a tendency
         | to become brittle during storage, and break or get stuck during
         | arming, which prevented complete removal and rendered the
         | warhead a dud. It was estimated that 50-75% of warheads would
         | fail. This required a complete rebuild of the W47
         | primaries.[7]"_
         | 
         | https://en.wikipedia.org/wiki/W47?useskin=vector#Reliability...
        
           | wl wrote:
           | Yeah, looks like boron coated cadmium tape. The relevant
           | excerpt from _Command and Control_...
           | 
           | > To avoid the embarrassment of relying on a Los Alamos
           | design, Teller used Livermore's new core but added a
           | mechanical safing device to it. A strip of cadmium tape
           | coated with boron was placed in the center of the core.
           | Cadmium and boron absorb neutrons, and the presence of the
           | tape would stop a chain reaction, making a nuclear detonation
           | impossible. During the warhead's arming sequence, the tape
           | would be pulled out by a little motor before the core
           | imploded. It seemed like a clever solution to the one-point
           | safety problem--until a routine examination of the warheads
           | in 1963 found that the tape corroded inside the cores. When
           | the tape corroded, it got stuck. And the little motor didn't
           | have enough torque to pull the tape out. Livermore's
           | mechanical safing device had made the warheads too safe. A
           | former director of the Navy's Strategic Systems Project
           | Office Reentry Body Coordinating Committee explained the
           | problem: there was "almost zero confidence that the warhead
           | would work as intended." A large proportion of W-47 warheads,
           | perhaps 75 percent or more, wouldn't detonate after being
           | launched. The Polaris submarine, the weapon system that
           | McNamara and Kennedy considered the cornerstone of the
           | American arsenal, the ultimate deterrent, the guarantor of
           | nuclear retaliation and controlled escalation and assured
           | destruction, was full of duds. For the next four years,
           | Livermore tried to fix the safety mechanism of the W-47,
           | without success. The Navy was furious, and all the warheads
           | had to be replaced. The new cores were inherently one-point
           | safe.
        
         | jabl wrote:
         | > the military, which wants the weapons to detonate on time
         | every time
         | 
         | Well, the military sure is also concerned about avoiding non-
         | intentional detonations due to accidents or by being hit by
         | enemy fire. E.g. the IMX series of explosives that have
         | apparently started to replace TNT and Comp B in some
         | applications.
         | 
         | https://en.wikipedia.org/wiki/IMX-101
        
           | KptMarchewa wrote:
           | As we've seen in Ukraine, sensitive munitions kill a lot of
           | tank, IFV and artillery crews.
        
         | bell-cot wrote:
         | You might want to read a bit about the design of WWII-era
         | conventional bombs, or WWI-era artillery shells, or magazines
         | in sailing ships, or ...
         | 
         | Militaries that have wanted to _win_ (vs. blow themselves up)
         | have been laboriously working to make sure that explosives do
         | not explode when they shouldn 't for _centuries_.
        
           | TylerE wrote:
           | They're pretty good at it, too.
           | 
           | You can set RDX (the explosive in C-4) on fire, and it'll
           | burn, not explode. Even small arms fire won't trigger it.
        
       | Kon-Peki wrote:
       | If such a thing can be scaled and made reliable, the implications
       | are staggering.
       | 
       | Imagine ammunition that fits in existing firearms and is fully
       | self-contained, mixing into a viable round only when entering the
       | chamber. And then made "smart", such that it can be geofenced and
       | therefore refuse to mix near schools or stadiums or government
       | buildings, etc.
       | 
       | If this becomes _possible_ , then all traditional ammunition may
       | become legislated or litigated out of existence.
        
         | runnerup wrote:
         | Ammo is really really safe as it is. Ammo doesn't accidentally
         | go off. The modifications you're talking about would go on the
         | gun, not the ammo.
        
           | mrguyorama wrote:
           | That "gun digitally safed" concept was tried before and
           | pretty roundly rejected. Even electrically ignited primers
           | were a market failure. Gun people are more paranoid than even
           | InfoSec researchers when it comes to tech in their toys. If
           | you truly believe your guns are for self defense, it makes a
           | little more sense.
        
             | xoxxala wrote:
             | Forgotten Weapons on YouTube has a video on the Armatix iP1
             | "smart" pistol, the technology behind it, it's development
             | and why it was a commercial failure.
        
             | GravitasFailure wrote:
             | I haven't heard of any electrically ignited primers that
             | made it to market, but every attempt that's gone through
             | military trials have had abysmal reliability.
        
               | gao8a wrote:
               | See Remington EtronX
               | https://www.youtube.com/watch?v=8qP6Q9ZEsEo (but it
               | obviously was a commercial failure)
        
               | GravitasFailure wrote:
               | Interesting. I missed that one.
        
         | ThrowawayR2 wrote:
         | It's a little surprising to see all these replies with none of
         | them mentioning that this discovery applies to high explosives,
         | which aren't used in small arms ammunition. Ammunition uses
         | propellants, which burn quickly (deflagration) but not as
         | quickly as high explosives (detonation); the latter would burst
         | the firearm. Therefore this discovery is unlikely to have any
         | relevance to small arms ammunition.
        
           | sidewndr46 wrote:
           | There was at one point some research done on seeing if
           | artillery could replace propellants with high explosive. From
           | what I understand it concluded that is was completely
           | impractical.
        
         | LawTalkingGuy wrote:
         | Liquid propellant could be useful in varying the amount used
         | per shot. In some large guns (ship guns mainly) you put bags of
         | propellant in the gun and you're limited to whole bags. If you
         | need a half bag you have to vary your aim to get the desired
         | target. It sounds very difficult but might be worth it for
         | space savings and for not having explosive ammo laying around.
         | 
         | As for making guns stop working in certain places, why wouldn't
         | crime just target those places? My walk home passes malls, a
         | school, government buildings, and two stadiums. Why would I
         | accept a defensive tool that didn't work most of the time?
         | 
         | If we make gun ownership too onerous we risk people ignoring
         | the law altogether - after all the risk of being injured is
         | more serious than being caught defending yourself - which would
         | increase the black market and aid criminals.
        
         | vkou wrote:
         | 1. Why would you install all this into the ammo, rather than
         | the gun? Any mechanically-inclined idiot with a garage workshop
         | can make his own ammo.
         | 
         | 2. Guns are a political problem, not a technological problem.
         | If you want to reduce gun violence, ban handguns. If you want
         | to reduce mass shootings, ban handguns and semi-automatic long
         | guns. If you want to stop a dedicated idiot with a garage
         | workshop from building his own pipe shotgun that he will use to
         | execute an MLM cult leader, you can't, he's going to do that
         | regardless.
        
           | idiotsecant wrote:
           | I'm not sure banning semi-automatic weapons is an effective
           | way to stop mass shootings. California has one of the most
           | restrictive semi-automatic weapon bans in the country and it
           | has one of the higher rates of mass shootings. That seems to
           | be pretty good evidence that this policy is restricting
           | people who care about the law from possessing these weapons
           | and not the people actually committing the crimes.
        
             | vkou wrote:
             | California's surrounded by 49 other states, most of which
             | have no such restrictions, and does not have any border
             | controls with any of them.
             | 
             | The formula of access changes substantially when you don't
             | have opportunities for jurisdictional arbitrage.
             | 
             | Criminals don't sit in a pentagram and magick weapons up
             | out of thin air, they source them (legally and otherwise)
             | from legitimate owners. A few of them are also legitimate
             | owners, who choose to use them for crime.
        
             | TylerE wrote:
             | If you really want to do something good, don't ban semi-
             | autos, or long guns at all.
             | 
             | Make it way harder to get a pistol. That's what's used in
             | the vast majority of murders.
             | 
             | Those two mass shootings in California earlier this year?
             | Both pistols.
             | 
             | I also think that concealed carry should generally be
             | banned for most civilians, and open carry legal.
             | 
             | My views on guns tend to generally annoy both sides...
        
               | RajT88 wrote:
               | I won't go so far as to say I'm on your side, but it's a
               | valid way of looking at the issue. It's the statistical
               | approach - target the biggest part of the problem.
               | 
               | IIRC handguns are used in 75% of firearm deaths from all
               | causes (homicide, suicide, accidents).
        
               | nullc wrote:
               | > IIRC handguns are used in 75% of firearm deaths from
               | all causes (homicide, suicide, accidents).
               | 
               | kind of a distorted figure there because suicide
               | dominates by a wide margin, and gun availablity doesn't
               | change the suicide rate. e.g. when controlling for
               | latitude you get similar suicide rates in places without
               | guns, people just use different means.
        
         | throwanem wrote:
         | That would require a battery, a GPS chipset, and either a
         | sizable database or a cellular radio, in the base of every
         | cartridge.
         | 
         | I'm pretty sure ammo makers aren't shaking in their boots on
         | this one.
        
           | TylerE wrote:
           | You could probably do it with something like Bluetooth LE in
           | the bullet. You'd need some sort of base station, worn on a
           | belt loop or something.
           | 
           | Binary explosives certainly exist so it should be in theory
           | possible. Not sure how well they "scale down" though, and I
           | don't know if any have a blast velocity low enough to be
           | workable. I'm not a gun guy, really, outside of my interest
           | in naval warfare. 16" shells have slightly different design
           | params though.
           | 
           | Actually, thinking about it more would the barrel act like a
           | faraday cage?
        
       | A4ET8a8uTh0 wrote:
       | Loved the read. I know I am on a list somewhere now, but I don't
       | care. This is what HN is all about. Interesting knowledge.
        
       ___________________________________________________________________
       (page generated 2023-03-21 23:01 UTC)