[HN Gopher] PFAS ban affects most refrigerant blends
       ___________________________________________________________________
        
       PFAS ban affects most refrigerant blends
        
       Author : doener
       Score  : 94 points
       Date   : 2023-03-02 16:32 UTC (6 hours ago)
        
 (HTM) web link (www.coolingpost.com)
 (TXT) w3m dump (www.coolingpost.com)
        
       | empyrrhicist wrote:
       | While we were waiting for a contractor to replace our failing AC
       | and furnace, he had to come back like four times to recharge the
       | system (supply chain issues getting the new unit). Now I wonder
       | how much refrigerant we were unintentionally breathing, and how
       | much PFAS we were bio-accumulating during that time.
        
         | ben7799 wrote:
         | If you read that article carefully you probably don't have PFAS
         | in your system. It would have to have been replaced in the last
         | 10 years to possibly have it.
         | 
         | The older stuff had HFCs/CFCs but didn't have PFAS.
         | 
         | I am in the same situation. My system has had to be recharged
         | every 2 years or so but has not failed yet. Overall we're
         | talking very small amounts leaked on mine.
        
         | LazyMans wrote:
         | I wouldn't worry about it, these gasses are included in the
         | blanket PFAS classification, but they are fundamentally
         | different and thus non-toxic. r134a, a common refrigerant, and
         | likely what your system uses if it's less than 10 years old, is
         | used in inhalers.
        
           | rootusrootus wrote:
           | > r132a, a common refrigerant
           | 
           | Are you thinking R134A? IIRC, R132A theoretically exists but
           | nobody makes it. And R134A is an automotive refrigerant. Most
           | residential systems in the last 10 years likely use R410A
           | (which is itself a mixture of R32 and R125). That is getting
           | phased out and generally replaced with plain R32, as far as I
           | know.
        
             | martijnvds wrote:
             | R32 is also on its way out, and new units here in Europe
             | tend to come with R290 (propane)
        
               | jabl wrote:
               | That's interesting, a had an AC unit installed 2 years
               | ago (in Europe), and then many units were marketed as
               | using the new R32 instead of the traditional R410A.
               | 
               | Now that I look at the website of the company that did
               | the installation, it seems all their AC models now use
               | R32.
        
               | rootusrootus wrote:
               | I have heard a lot about R290 but at least in the US, I
               | am not seeing much of a push to go there. R32 is an A2L
               | refrigerant and (according to the article) isn't affected
               | by the PFAS ban. In the US at least it looks like the
               | main choice for the future, at least in the near term.
        
             | LazyMans wrote:
             | Sorry, 134a yes
        
             | a1371 wrote:
             | Then why are they banning R134A as the article says?
        
               | akira2501 wrote:
               | Glaxosmithkline loves it when they do this, it allows
               | them to create a new propellant forumlation, and then
               | that allows them to put basic asthma medication back on
               | patent.
               | 
               | And the current R134a patents are just set to expire.
               | Inhalers which should cost $5/ea are set to be $90/ea
               | again.
               | 
               | This is the same thing they did when CFC were banned and
               | they switched from CFC to R134a. This is a medication
               | that should have been off patent decades ago, but due to
               | this "trick", it almost certainly never will be.
        
       | kragen wrote:
       | at some point this kind of luddism will become self-defeating; we
       | can only hope that it doesn't engulf the whole human race
       | 
       | this is banning the safest refrigerants, forcing either a switch
       | to dangerously inflammable refrigerants or to systems without
       | refrigeration
        
         | VLM wrote:
         | The meta goal of greenwashing means you can't use Peltier
         | coolers as it would take insane amounts of power to replace a
         | condensing fridge, like dedicated circuit 15 amps. They're very
         | inefficient... if you're burning coal. What if you're not
         | burning coal?
         | 
         | Consider this loophole... imagine a crappy anti-green energy
         | wasting Peltier cooler connected to a solar panel. Half the day
         | it chills down to -70C and then all night long it slowly warms
         | up to -50C until sunrise. Probably the bottom quarter of the
         | fridge is a giant ice block with fans blowing on it when the
         | fridge above warms up, whereas the cooling is solar and below
         | and is on full blast whenever the sun is up.
         | 
         | Minor problem is now you're dumping 1500 watts of heat into
         | your kitchen whenever the sun's up. Nice in the winter, not so
         | much in the summer. And some idiot is going to gain access to
         | the cold-sink to "chill their vodka" and end up with frostbite
         | when they touch the -70C sink. And good luck periodically
         | defrosting that beast. But, in general, its not an overly crazy
         | idea.
        
           | ilyt wrote:
           | No, it is utterly terrible solution, as even the worst
           | refrigerant beats peltier coolers.
        
             | VLM wrote:
             | My point is even the best refrigerant powered by coal or
             | even "rando outlet power on average" is less green than the
             | worst Peltier cooler powered by a solar panel. So as per
             | OPs original claim that if we ban every chemical more
             | hazardous than distilled water we can have no refrigeration
             | is not entirely true, we can in theory redesign the entire
             | system around not using any refrigerants.
             | 
             | It would be an environmental disaster if not powered by
             | solar, or maybe wind, of course, but it would technically
             | work.
        
           | kragen wrote:
           | i agree that tecs are a plausible solution for some
           | applications, and i have in fact lived in a house with a
           | small tec-driven refrigerator, but phase-change energy
           | storage or tces are more viable solutions to the daily energy
           | storage problem than the sensible-heat energy storage
           | approach you suggest, among other things because the large DT
           | you suggest would entail an absurdly large stack of tecs
           | 
           | you can solve the waste heat problem by putting the tecs
           | outside and running a coolant loop through the wall, filled
           | with brine or propylene glycol; in the case of pces, the
           | chilled coolant from the tecs freezes the ice inside your
           | kitchen, in the ice reservoir which is used to cool the
           | icebox
           | 
           | tces systems (not to be confused with tecs) can be driven
           | directly by solar heat rather than through pv
           | 
           | however, i am not convinced that tecs are a viable
           | alternative to vapor-compression refrigeration in general
        
         | smt88 wrote:
         | Banning harmful substances isn't luddism. What do you think
         | luddism is? What is the harm of this ban?
        
           | dsfyu404ed wrote:
           | You know why these substances exist right? Because the prior
           | substances were cutting a hole in the ozone layer. And at the
           | time the new-then substances weren't proven bad yet.
           | 
           | And those ozone eating substances themselves came about
           | because the prior refrigerants were more flammable or
           | poisonous and the then-new substances were not yet proven
           | bad.
           | 
           | It's an endless game of whack-a-mole.
        
             | slackdog wrote:
             | > _You know why these substances exist right? Because the
             | prior substances were cutting a hole in the ozone layer._
             | 
             | Refrigeration may end up back where it originally started
             | (before freon even), using ammonia. Ammonia is somewhat
             | dangerous on a local level (you don't want an ammonia leak
             | in your house..) but AFAIK it doesn't eat up ozone and the
             | local hazard is something that can be mitigated with the
             | right sort of product design.
        
               | labcomputer wrote:
               | > Ammonia is somewhat dangerous on a local level
               | 
               | Like saying that the Ohio train disaster may cause lung
               | irritation, that quite undersells the problem.
               | 
               | Ammonia refrigeration is inherently dangerous and has
               | been banned from domestic refrigerators for a long time
               | for good reason. Some regulations are written in blood.
        
               | slackdog wrote:
               | I think it could be possible to use ammonia in domestic
               | refrigerators safely if appropriate measures were taken.
               | Particularly, require that refrigerators be installed
               | with vent pipes leading from a tamper-resistant enclosure
               | straight to the outside. Such vents would be similar to
               | those used in waste plumbing to protect people from toxic
               | sewer gasses like hydrogen sulfide:
               | https://en.wikipedia.org/wiki/Drain-waste-vent_system
               | 
               | But jabl is probably right and something like propane
               | would make more sense.
        
               | jabl wrote:
               | I don't think we'll see ammonia used in domestic
               | refrigeration. Industrial use, sure.
               | 
               | I think what we'll see for domestic refrigerants
               | (refrigerators, AC, heat pumps) is hydrocarbons like
               | propane or butane (already a reality for refrigerators in
               | most of the world), and in some cases CO2.
        
               | kragen wrote:
               | i went to a hotel with an ammonia refrigerator in the
               | kitchen a couple of weeks ago
        
               | oliveshell wrote:
               | Yeah, ammonia is very common in industrial refrigeration,
               | especially big specialized systems that need tons and
               | tons of refrigerant, as illustrated by this famous
               | accident in which 30,000 lb. of the stuff was released:
               | 
               | https://www.csb.gov/millard-refrigerated-services-
               | ammonia-re...
        
               | kragen wrote:
               | this was a 60-liter fridge with 117 grams of ammonia in
               | it in the kitchen of the hotel suite
        
             | FourHand451 wrote:
             | I don't think any of this is alarming. Nor a reason we
             | should stop trying to solve new problems as we learn of
             | them.
        
               | dsfyu404ed wrote:
               | I'd rather be exposed to the known-known of propane
               | refrigeration in my consumer devices (car, window unit,
               | refrigerator, mini-split, etc) than risk exposure poorly
               | understood chemicals to reduce the chances of a
               | refrigerant fire from one tiny decimal per capita per
               | lifetime to a slightly smaller tiny decimal per capita
               | per lifetime.
        
             | mustacheemperor wrote:
             | It sounds like an endless march of gradual forward
             | progress, since each generation of refrigerants has been
             | less destructive that the one before.
        
         | dymk wrote:
         | How do you feel about leaded gas?
        
           | kragen wrote:
           | leaded gas should be limited to extremely low-volume
           | applications, because it's enormously harmful
           | 
           | this regulation is more like banning unleaded gas
        
             | hadlock wrote:
             | There are better octane boosters, the only reason lead was
             | used was because it was marginally cheaper.
        
             | dymk wrote:
             | But it's not like unleaded gas. Evidence has been mounting
             | that PFAS are the modern 21st century's lead, hence bans
             | like this.
        
               | kragen wrote:
               | privacy invasion and this kind of discourse are the 21st
               | century's lead
               | 
               | there are pfas that are pretty bad but the refrigerants
               | in question are not among them
        
           | DoneWithAllThat wrote:
           | Snark doesn't do anything but virtue signal.
        
             | kragen wrote:
             | i think it's a reasonable question directed at clarifying
             | their understanding of my position
             | 
             | or anyway a person who wanted to clarify their
             | understanding of my position could very reasonably ask that
             | question
        
           | nordsieck wrote:
           | > How do you feel about leaded gas?
           | 
           | I think it should be banned.
           | 
           | Sadly, aviation has enough political muscle that they're
           | still allowed to use it. Which is amazing to me, given lead's
           | extremely harmful effects.
        
             | cypress66 wrote:
             | Do you really think the people flying their small cessna
             | with 100LL have so much political muscle? I strongly doubt
             | so.
        
               | jeffbee wrote:
               | It's not the pilots alone, it is also the piece-of-shit-
               | airplane industry which employs a handful of people here
               | and there, enough to have a little suction in Congress.
        
               | jabl wrote:
               | Also GA is, in the end, a relatively small-scale
               | activity, so leaded avgas isn't much of a public health
               | hazard like leaded automotive gas was back in the day.
               | More of an occupational hazard for people working on and
               | flying those planes, and higher maintenance requirement
               | on the engines.
               | 
               | Hopefully they can manage to roll out G100UL at scale so
               | 100LL can finally die. And then that final TEL plant on
               | the planet can be shut down for good.
        
               | r00fus wrote:
               | Let's not forget those small airports where nearby
               | residents are at higher risk due to leaded avgas. That's
               | why small airports have been forced to close.
               | 
               | Get rid of leaded avgas and we can have less municipal
               | airports closures.
        
               | slackdog wrote:
               | The general aviation industry is protected because it's
               | part of the pilot training pipeline, and that is
               | important because airplanes (both commercial and
               | military) have a great deal of importance to governments.
               | About 5% of the American GDP is attributed to commercial
               | aviation. Compare that figure to the number of deaths
               | caused by leaded avgas, and you don't need conspiracy
               | theories to explain the outcome.
        
             | outworlder wrote:
             | > Sadly, aviation has enough political muscle that they're
             | still allowed to use it.
             | 
             | Does it? GA is a shadow of its former self.
             | 
             | There's already a substitute. But it's precisely how small
             | general aviation has become that's stifling the transition.
             | The volume of avgas made today is already pretty small,
             | compared to other gas users, and there's ony a handful of
             | plants that can make it. Then there's all the small
             | airfields with existing avgas pumps.
             | 
             | Without a big push, it will take time. The fastest way
             | would be with a carrot; the stick can come later.
        
       | StillBored wrote:
       | Is it time to admit that maybe the problem with r22 and some of
       | the other CFC's were that people were using them as propellants
       | for hairspray/etc, as canned air, and any number of industrial
       | processes (packing peanut manufacture) that was basically blowing
       | it into the atmosphere and the lack of regulations requiring
       | refrigeration units to be repaired/leakchecked before pumping
       | more refrigerant into them?
       | 
       | It seems pretty clear that the fairly short lived damage they
       | cause to a renewable resource (ozone) would largly be a non issue
       | given modern refrigerant regulations. While the advantages make
       | them pretty much the best in any number of areas.
        
         | TheJoeMan wrote:
         | You are following the explanation for the bans as they are
         | told.
         | 
         | R134a was introduced in the 90's, and in 2010's it conveniently
         | is named bad at the same time the patent runs out.
         | 
         | So the savior was the 4x as expensive R1234yf, introduced 2012.
         | Don't worry that it's flammable.
         | 
         | Here we are 10 years after R1234yf, it's time to explain why it
         | can't be used anymore!
        
       | inportb wrote:
       | > R152a also falls outside the PFAS definition.
       | 
       | Oh, so it might be possible to use the contents of "canned air"
       | gas dusters as refrigerant.
        
         | CamperBob2 wrote:
         | Yep. Turn one of those cans upside down and spray it, and
         | you'll see how that works very quickly.
        
       | [deleted]
        
       | iosono88 wrote:
       | [dead]
        
       | londons_explore wrote:
       | Whats wrong with R600a (isobutane)?
       | 
       | It can provide heating/cooling suitable for nearly all usecases
       | in homes, offices and retail (ie. -100C up to +150C).
       | 
       | It isn't awful for the environment if vented (no ozone depletion,
       | greenhouse effect less bad than driving your car a few miles if
       | you vent a fridge/freezer).
       | 
       | Yes, it is flammable... But in typical quantities in a fridge
       | (perhaps 60 grams), it's hard to do too much damage.
       | 
       | It is also cheap, easy to lubricate, unpatented, made by many
       | suppliers and efficient.
       | 
       | I really don't understand why anyone would want to use anything
       | else....
        
         | akira2501 wrote:
         | Every flammable refrigerant I've seen is usually in a
         | completely sealed system. There is no way to maintain them
         | unless you completely vent the system and add ports yourself,
         | manufacturers don't seem to want the liability and many
         | governments force the issue by code anyways.
        
           | londons_explore wrote:
           | You typically need to completely vent the system for any
           | maintenance on a refrigeration system anyway, if only for the
           | fact it is important to weigh the amount of refrigerant (too
           | much and you could get slugging, which is very expensive to
           | fix).
           | 
           | I think lack of ports is simply to save money - in the
           | factory it's just as easy to fill once and crimp the system
           | closed.
        
             | akira2501 wrote:
             | > You typically need to completely vent the system for any
             | maintenance on a refrigeration system anyway
             | 
             | On residential/small systems where it's commonly used
             | today, sure. For larger systems this is not true. You're
             | typically going to have a receiver and a valve you can use
             | to store the charge entirely in the receiver. Then you can
             | work on the system without having to dump or capture that
             | charge.
             | 
             | It also allows you to have additional cooling circuits, so
             | you're starting to see this incorporated into smaller
             | commercial designs for the additional cooling efficiency.
             | 
             | > I think lack of ports is simply to save money
             | 
             | They're required to be hermetically sealed in the US by IEC
             | and in most Pacific Island countries by law where they're
             | more commonly used in residential applications.
        
             | NegativeLatency wrote:
             | Save money, and force consumers to buy a new one when it
             | breaks
        
         | elil17 wrote:
         | I'm not an expert in refrigerant selection but you've missed
         | many critical aspects of a refrigerant: we care about
         | viscosity, density, thermal conductivity, etc. because these
         | all impact the energy efficiency of the system.
        
         | zbrozek wrote:
         | Several light hydrocarbons seem like perfectly good
         | alternatives. Propane is another one. And there's also quite a
         | lot of use of ammonia for refrigeration as well. It's not clear
         | to me why these simpler, non-chlorinated, non-fluorinated
         | compounds are so grossly undesirable that we keep chasing more-
         | complex alternatives.
         | 
         | Is it really that people are simply horribly afraid of their
         | flammability?
        
           | VLM wrote:
           | People are scared of the sealed container explosion.
           | 
           | An external butane leak would be about as harmful as a
           | leaking cig lighter.
           | 
           | Internal leak? A perfect mixture of butane and air the size
           | of fridge would certainly take out a wall, maybe an entire
           | house if it knocks out a load bearing wall.
           | 
           | The worst part about the internal explosion is its almost
           | certain to happen when the owner is standing right in front
           | and opens the door and the light kicks on along with maybe
           | anti-frost heaters or whatever else is in there.
           | 
           | I have seen some ideas proposed such as using the "smart" in
           | a smart fridge for good not evil and locking the door if the
           | system pressure drops below "X". Much more likely the "smart"
           | in a smart fridge will never be permitted to be used for
           | anything other than advertising and marketing, which is sad.
           | 
           | Energy content of hydrocarbons is about the same (to one sig
           | fig or less LOL) and just one gram of gasoline can blow a
           | piston rod clean thru an engine block under perfectly bad
           | conditions (already shattered bearings, etc) so a couple
           | hundred grams under worst possible case in a confined sealed
           | fridge could take out a house, most likely.
           | 
           | (Edited to add: I have a better analogy: A perfect
           | stochiometric mix of air and diesel the size of my coffee cup
           | can blow the engine head clean off a diesel engine, IIRC
           | that's how one of the brothers who invented the Diesel engine
           | died in a lab accident a century ago. And that was just a
           | little coffee cup sized engine cylinder. So imagine a sealed
           | container the size of a fridge instead of a coffee cup...
           | that'll take out a house for sure... neighbors will
           | "probably" live but I wouldn't bet on it...)
        
             | zbrozek wrote:
             | Yet we plumb methane in houses all the time. Also, at least
             | for HVAC, it's perfectly reasonable to keep all of the
             | refrigerant outdoors and use water as a heat transfer
             | medium to the interior.
        
               | amluto wrote:
               | And it's not a great idea, especially given the
               | proliferation of appliances that burn it in room air.
               | 
               | And methane has the convenience property of being less
               | dense than air. I'm not sure, but I expect that the
               | heavier hydrocarbon gasses might be more likely to
               | accumulate indoors.
        
             | ajb wrote:
             | I get your point, but we already have methane pumped to our
             | houses. Are these worse?
        
               | VLM wrote:
               | Yes, sealed container vs open air. If we stored natgas in
               | scuba tanks that could get exciting... ironically there
               | are people considering powering auto engines with
               | compressed natgas... must be very exciting in a fire LOL.
        
             | ilyt wrote:
             | locking might not even be necessary, just power off the
             | device if pressure of refrigerant drop.
             | 
             | Having some way to ventilate the gas (so you don't just get
             | "a box full of flammable gas" situation on slow leak)
             | without reducing performance too much might help also
        
             | gabereiser wrote:
             | I had an internal explosion of my gas grill. I apparently
             | forgot to turn the gas off so it filled the chambers under
             | the grill plates and when I went to light it, it sent the
             | top and the grill plates through the lanai and 40ft into
             | the air. I lost my eyebrows for a few months.
        
           | carnot wrote:
           | [dead]
        
           | SoftTalker wrote:
           | Ammonia is quite toxic. Some bad outcomes from leaky ammonia
           | air conditioning in the past. Ok for industrial chillers with
           | good leak detection systems.
        
             | VLM wrote:
             | Texas state code requires machine rooms for ammonia systems
             | to get 30 air exchanges per hour, same state building code
             | requires houses to be under 1/3 air exchanges per hour.
             | 
             | I'm a little fuzzy about the later, pretty sure about the
             | former, and most people don't have the privilege of living
             | in Texas (not sure if I'm kidding or not?), but it
             | demonstrates the safety issue that ammonia cooling needs
             | about a hundred times as much ventilation as a normal
             | kitchen. And insert the usual quotes about building codes
             | being written in blood so they aren't demanding a hundred
             | times the ventilation just for fun.
        
         | nigrioid wrote:
         | Flammable refrigerants are no joke:
         | 
         | https://www.youtube.com/watch?v=A169-s4KHFQ
        
         | amluto wrote:
         | For better or for worse, people like to pump refrigerant
         | through pipes in buildings, and flammability can be a problem.
         | Also this requires a lot of refrigerant.
         | 
         | One can separate the refrigeration part and the moving-heat-
         | around part, though, by using good old H2O in pipes. Water is
         | non-flammable, non-ozone-depleting, cheap, and has zero GWP. It
         | can be a bit messy if a large amount spills indoors, though.
        
       | loeg wrote:
       | Do the remaining alternatives work, and are they excessively
       | expensive?
       | 
       | > Laboratory test equipment and centrifuges would receive a
       | 12-year exemption as no alternatives are currently available.
       | 
       | Oh, so there are no remaining alternatives that work in these
       | applications.
        
         | arsome wrote:
         | Hydrocarbons work quite well and are (comparatively) minimal
         | impact on climate change. There's been some paranoia about
         | fires, particularly in automotive applications but it's
         | actually a quite small amount needed to do the job.
        
           | mschuster91 wrote:
           | The problem are large building air conditioning systems,
           | grocery store chillers and industrial machines - they contain
           | an awful lot of coolant and are _very_ expensive to replace
           | which means they tend to last for decades.
        
             | throw_away1525 wrote:
             | Ammonia (another dead simple molecule/process) is used in
             | these services quite often, as far as I know.
        
               | jabl wrote:
               | From what I understand, at least here in Europe CO2 has
               | been common in recent supermarket and similar
               | installations.
        
             | amluto wrote:
             | One can buy large building air conditioners that use water
             | to move heat around. There will still be refrigerant
             | somewhere in the system, but there won't be long
             | refrigerant pipes anywhere.
             | 
             | I don't know how popular these are. I have seen multiple
             | condo buildings with a water source heat pump in each unit.
             | The usual suspects (Mitsubishi, Daikin, etc) have hydronic
             | systems with outdoor heat pumps on their websites. Chiltrix
             | markets a small-building solution.
        
         | rsync wrote:
         | Why do centrifuges need refrigerant?
        
           | kazinator wrote:
           | You probably have to sometimes spin biological materials that
           | have to be kept cool.
        
           | rleigh wrote:
           | Because they are temperature-controlled and contain a
           | refrigeration unit.
           | 
           | In biological and medical applications, you might want to
           | have the samples kept cool for stability. You'll transfer
           | them from a fridge or on ice into the cooled centrifuge and
           | back again after you've spun it down. Since in these big
           | units the rotor is often a big hunk of anodised aluminium, it
           | also helps maintain temperature stability.
        
         | kube-system wrote:
         | There are a lot of alternatives that are cheap and perform
         | well... but many of those have other safety concerns.
         | 
         | Some common examples are hydrocarbons or ammonia:
         | https://en.wikipedia.org/wiki/Natural_refrigerant
        
         | spqr0a1 wrote:
         | Ethane (R-170) is a fine low-temperature refrigerant for lab
         | equipment. The performance characteristics are at least as good
         | as halocarbon refrigerants. The main drawback is flammability
         | but propane has a similar concern and is already widely used in
         | residential refrigerators and similar size systems.
        
           | xxpor wrote:
           | >widely used in residential refrigerators and similar size
           | systems.
           | 
           | Not in the US (because of the flammability), unless
           | something's changed very recently.
        
             | xenadu02 wrote:
             | > Not in the US (because of the flammability), unless
             | something's changed very recently.
             | 
             | I don't know when it changed but R-290 (propane) is allowed
             | up to 13oz. My ice maker uses it. I believe it must also be
             | sealed without service ports both to prevent leaks and
             | prevent anyone from connecting normal A/C service equipment
             | to the system. Service requires emptying the system then
             | brazing service ports onto the fill pipes (which are left
             | much longer than normal for this purpose).
        
             | akira2501 wrote:
             | In commercial applications you'll see R-290. It's often
             | used in low temperature applications, like ice cream
             | display freezers. I've seen them in gas stations and pizza
             | shops quite a bit.
        
             | thaeli wrote:
             | In the last few years, the US has finally started allowing
             | small appliances containing limited quantities of flammable
             | refrigerants.
        
             | jabl wrote:
             | USA is kind of the exception. In much of the rest of the
             | world, propane or butane are the norm in domestic
             | refrigerators.
        
               | xxpor wrote:
               | Most of the world doesn't build their residential
               | buildings out of light wood frame :/
        
               | scythe wrote:
               | A fuel-air explosion will not be contained by a
               | _reasonable_ amount of concrete or masonry. The real
               | safety lesson is to control sources of ignition and
               | prevent the buildup of released gases.
        
               | slackdog wrote:
               | If your house is on fire, you best GTFO no matter what
               | kind of refrigerator you have.
               | 
               | American homes have plenty of propane/natgas appliances
               | anyway, so what difference does one more make?
        
               | xxpor wrote:
               | People usually store their propane tanks outdoors.
        
               | hn8305823 wrote:
               | Notably, Propane has almost identical refrigeration
               | characteristics to R-22, so it was an easy drop-in
               | replacement for systems designed for R-22 when that was
               | banned.
        
               | _a_a_a_ wrote:
               | I don't see why, they're hardly less flammable
        
           | RobotToaster wrote:
           | From personal experience things using propane refrigerant
           | seem to make a high pitched noise, I'm not sure if that's a
           | property of the refrigerant or how devices using it are
           | built.
        
             | dsfyu404ed wrote:
             | There's no "reason" propane has to be louder but most
             | propane refrigeration systems are used in industrial or
             | cost-conscious applications where making the equipment
             | quiet is less of a priority. When designing pumps it takes
             | a non-trivial amount of engineering effort to ensure that
             | the bulk of the noises emitted are above/below human
             | hearing range.
        
         | jrimbault wrote:
         | Magnetic refrigeration seems (to a complete layman) to show
         | promise.
         | 
         | https://en.wikipedia.org/wiki/Magnetic_refrigeration
        
           | hadlock wrote:
           | I remember reading about this in Popular Science in high
           | school. Residential refrigerators powered by this technology
           | by 2006! Twenty years after that magazine article I haven't
           | seen any substantial progress towards a commercial product.
        
           | sargun wrote:
           | I for one, hope that someone figures out a way to make this
           | cost effective.
           | 
           | I think thermoacoustic coolers are another promising
           | solution.
        
           | scythe wrote:
           | The problem with most alternative refrigerant technologies
           | (magnetocaloric, electrocaloric, thermoelectric) is the same:
           | the temperature deltas tend to be rather small, at best 25 C.
           | That is roughly the thermal performance of the recently
           | published "ionocaloric" cooling system; 20 C is very good for
           | a magnetic system. For air conditioning, a delta of 25 C will
           | just do (assuming outdoor temperature below 50 C!), but heat
           | pumps may need to cross temperature gaps of 40 C or more.
        
       | chicob wrote:
       | PFAS are harmful, both to the environment and humans, so the
       | transition to safer alternatives is commendable.
       | 
       | The fact that this ban seems to fit the specific blend of a
       | particular company, however, casts some doubts on how this
       | process was conducted. Specially in a time when demand is
       | projected to increase considerably.
        
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