[HN Gopher] Smaller, cheaper flow batteries throw out decades-ol...
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       Smaller, cheaper flow batteries throw out decades-old designs
        
       Author : mfiguiere
       Score  : 91 points
       Date   : 2023-01-28 17:21 UTC (5 hours ago)
        
 (HTM) web link (spectrum.ieee.org)
 (TXT) w3m dump (spectrum.ieee.org)
        
       | LeanderK wrote:
       | > They remain costly, though, with a capital cost of around US
       | $800 per kilowatt-hour, more than twice that of lithium-ion
       | batteries.
       | 
       | I was surprised by this! Since this is not commercialised on a
       | broad scale, I would have thought that the cost is nowhere near
       | competitive. Twice seems very close. How close are we to
       | introducing flow-batteries at a competitive price?
        
         | vlovich123 wrote:
         | > Liu estimates that the tubular design should cut the cost of
         | flow-battery power modules by roughly half. Plus, all the
         | components in the cell are off the shelf, and scaling up the
         | reactor cell design should be easy, since it is based on a
         | commonly used design in the chemical industry.
         | 
         | So if this research pans out it sounds like very close. This
         | isn't a new concept and it's mature so the probability of
         | continuing savings is less than traditional battery
         | technologies (eg there's new kinds of batteries coming out that
         | are cheaper and more energy dense than lithium ion). However,
         | at grid scale this may have additional advantages beyond pure
         | cost that make it attractive still.
        
           | LeanderK wrote:
           | I can't imagine this is more mature then lithium ion
           | batteries, or traditional batteries in general. They are
           | everywhere in my apartment but afaik flow batteries are not
           | used yet.
        
             | neltnerb wrote:
             | I agree, especially on the industrial design and
             | manufacturing side. The concept has exited for ages, and I
             | love decoupling power and energy density for all kinds of
             | reasons (though I'm sure standard batteries are just tuned
             | perfectly enough in large facilities that it's no big
             | difference).
             | 
             | But the big cost reductions don't happen because an idea is
             | mature, they occur because they're being produced at large
             | enough scale that lots of people have spent time and energy
             | on all of the thousand tiny things that individually reduce
             | the cost. The stuff in this article is borderline just
             | industrial design and they're talking a 3x change in
             | footprint?
             | 
             | There has to be lots of other low hanging fruit... we're
             | still improving lithium battery electrodes and each
             | improvement really does improve them. The same will be true
             | for flow batteries if they ever get made at enough scale.
        
         | pfdietz wrote:
         | I find that number dubious, since the per-kWh cost of flow
         | batteries should be low: just make the tanks larger.
        
           | uluyol wrote:
           | It sounds like the energy capacity and power output can be
           | scaled independently of one another. But as this article is
           | meant for a wide audience, I think they simplified the
           | discussion by making some assumptions about the desired power
           | output per kWh stored.
           | 
           | Not unreasonable. The details are always in the research
           | paper after all.
        
       | oconnore wrote:
       | > showed that the battery had a charge densities of about 1,322
       | watts per liter of electrolyte and a discharge density of about
       | 306 W/L
       | 
       | Isn't the relevant measurement energy density (Wh/L) rather than
       | power (W/L)? I guess there's some limit on the power generated by
       | a given volume of the battery, but in practice it seems like the
       | main question is how big the tank has to be per MWH/KWH, rather
       | than how big the power module has to be to convert that back to
       | energy over the duration of the discharge period.
        
         | LeanderK wrote:
         | (I know nothing about batteries or chemistry) I think this
         | research only focuses on power generation, the device where you
         | combine the liquids to get energy. Changing the energy density
         | means changing the type of liquid, I assume, which this
         | research is just not about.
         | 
         | I understand it as analogous to a ICE, where you have the fuel
         | and the motor. But with flow batteries you can also go in
         | reverse to create fuel from energy. The research featured here
         | is about the motor but if you need a different energy density
         | you have to change the type of fuel since that's how the energy
         | is just stored in huge tanks.
        
         | amluto wrote:
         | No. From the article:
         | 
         | > Liu and colleagues focused on redesigning the power module
         | 
         | A flow battery separates the _power_ portion (the electronics,
         | electrodes, pumps, etc) from the _energy_ portion (tanks,
         | fluid). Which is not so amazing for a car or a UPS where you
         | want tens of minutes to a few hours of charge or discharge
         | time, but is potentially great for grid use, where a discharge
         | time of days to months is useful.
        
           | gumby wrote:
           | > for grid use, where a discharge time of days to months is
           | useful.
           | 
           | Not sure I know the use case for a duration of that length.
           | It's possible today with pumped hydro, but I don't think it's
           | used in that mode.
           | 
           | The DoE's "long duration storage earthshot" effort is loking
           | for 10+ hours, which makes more sense:
           | https://www.energy.gov/eere/long-duration-storage-shot
        
             | michaelt wrote:
             | A zero-carbon northern Europe that replaced all gas heating
             | with heat pumps would benefit from being able to store
             | electricity during the warm summer months, to power heating
             | in the cold winter months.
             | 
             | There are other options, of course - new nuclear plants,
             | importing renewable power from countries with better
             | weather, huge numbers of wind turbines, and so on - but
             | cost-effective long-term power storage would address some
             | issues if it was available.
        
             | jfoutz wrote:
             | The standard reply to any sort of gravity storage is
             | "geography and land availability". I don't find that
             | argument compelling enough to dismiss gravity storage
             | outright, but I'll admit Oklahoma is pretty darn flat.
             | 
             | Chemical storage could be a big win when a mountain isn't
             | readily available. Or the land is too expensive to use for
             | power storage.
        
           | mgerdts wrote:
           | Why wouldn't it be good for cars? It seems a fluid exchange
           | could recharge the car, limited by how fast you can pump out
           | the discharged fluid and pump in charged fluid.
           | 
           | I have no idea whether there are containment or environmental
           | challenges that make this especially hard.
        
             | hinkley wrote:
             | It's going to depend on the details. In a power substation
             | space and weight are fairly flexible. In a vehicle they
             | matter quite a bit. If you can build a flow battery that
             | rivals solid state batteries for weight and volume, you've
             | made an improvement because the fluid is swappable in ways
             | that batteries are not. Batteries meant to move will move
             | in a crash. Fixed batteries tend to stay put but complicate
             | road trips.
             | 
             | In a UPS the tanks and valves and pumps are new points of
             | failure, as the other responder states. In a car they are
             | many times more complicated than electric vehicles, yes,
             | but still less complicated than ICE vehicles by far. Your
             | heater has more moving parts. Hell, the emissions control
             | gear is probably more complex than the entire drivetrain of
             | the electric vehicle.
        
             | randall wrote:
             | That sounds like moving to a non solid state situation,
             | right? One of the big benefits, imo, is removing as many
             | moving parts from a car, not reintroducing them.
        
               | mgerdts wrote:
               | Surely it is more complicated. It may be able to serve
               | the goal of eliminating fossil fuels from the car while
               | not getting the full simplicity of (not really) solid
               | state batteries we have today.
               | 
               | It would seemingly also allow you to carry around 50
               | miles of juice when you are running around town and bump
               | up to 400 miles of juice when you are taking a road trip.
               | This really only makes sense if the car is able to
               | recharge the juice.
               | 
               | Maybe a new hybrid model (not gas electric hybrid) could
               | emerge. The base (say 50 mile) capacity is solidish state
               | like we have today and a flow battery range extender
               | could be filled with fluid when the extended range is
               | needed. This would make it so the car wouldn't need to
               | charge the fluid, if that helps.
        
               | jacobn wrote:
               | Being able to "refuel" quickly is a pretty big plus, so
               | in the balance it could still be better to accept some
               | moving parts in exchange for that.
               | 
               | And it's easy to imagine retrofitting a gas station to
               | all of a sudden have charged electrolyte instead of gas,
               | but I'm sure that has all sorts of additional
               | complexities that I know nothing about... ;)
        
               | jccooper wrote:
               | Probably adds two low-pressure low-volume pumps. Which is
               | more, but not a large increase in complexity for a car.
               | The driver's seat probably has more moving parts.
        
         | imtringued wrote:
         | A smaller charger/discharger simply costs less which lets you
         | buy more electrolyte. This is especially relevant for smaller
         | installations.
        
         | marcosdumay wrote:
         | The article is about the size of the ion-exchange element, so
         | I'd guess no, it's not supposed to be Wh/l.
         | 
         | If you want the storage density, you can look by the battery
         | chemistry. But I'm not sure the article got this one right, or
         | else the researchers didn't actually work on flow batteries and
         | that part is only speculation.
        
         | [deleted]
        
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