[HN Gopher] Plasma reactors could create oxygen on Mars
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       Plasma reactors could create oxygen on Mars
        
       Author : rntn
       Score  : 62 points
       Date   : 2022-08-16 19:37 UTC (3 hours ago)
        
 (HTM) web link (www.science.org)
 (TXT) w3m dump (www.science.org)
        
       | linuxftw wrote:
       | We're never going to colonize mars, every penny spent on mars is
       | wasted.
        
       | cryptodan wrote:
       | This is how DooM started.
        
       | colechristensen wrote:
       | Isn't there plenty of oxygen which could be much more simply
       | burned out of mars rocks? Place is covered with fine dust that's
       | almost entirely metal oxides. I'm thinking concentrated solar to
       | liberate the oxygen and produce a nice metal building material
       | that could be refined to base metals for all sorts of things.
        
         | hinkley wrote:
         | On earth a great deal of life's variety happens at the
         | boundaries, such as in tidal zones and estuaries. There are no
         | oceans on Mars but there is also very little atmosphere. I
         | suspect we will want to engineer our oxygen producing equipment
         | to make estuaries and tidal zones for atmosphere, where there
         | is either a steady stream of atmosphere, or daily pulses that
         | push life to adapting to temporary deficits and surpluses of
         | resources.
         | 
         | Later on that could be accomplished just by routing the exhaust
         | down into the canyons, but early on that may have to go through
         | greenhouses, which either vent above a certain pressure or
         | aren't quite hermetically sealed.
        
         | ortusdux wrote:
         | I've always thought this was the obvious choice. I wonder what
         | the logistical issues are. As a bonus, you get pure iron as a
         | byproduct, which would be worth it's weight in gold as a
         | building and additive manufacturing resource.
        
           | colechristensen wrote:
           | If you just roast common Martian soil you don't just get iron
           | but many metals mixed together (the three mars landers tested
           | and got pretty similar results at a high level)
        
         | nickpinkston wrote:
         | That's my intuition too, though given's gene-h's citation [1]
         | in this thread, there may be an interesting analogy between
         | water evaporation and reverse osmosis, as the proposed tech
         | creates a plasma and the oxygen diffuses through a membrane
         | (like osmosis tech). We know that reverse osmosis is the more
         | efficient tech compare to evap, so who knows.
         | 
         | [1] https://aip.scitation.org/doi/10.1063/5.0098011
        
       | PaulHoule wrote:
       | "Method X could create oxygen on (Moon|Mars)" headlines drive me
       | nuts.
       | 
       | Before we sent astronauts to the moon successfully we discovered
       | the hard way that astronauts are likely to die if they breathe
       | pure O2.
       | 
       | https://en.wikipedia.org/wiki/Apollo_1
       | 
       | Future Apollo missions mitigated the danger of fires by being
       | really careful about the materials in use, but that's not a good
       | answer for long term missions, particularly if the astronauts are
       | going to conduct industrial activities such as in-situ resource
       | utilization.
       | 
       | If you want to make breathing gas on Mars, O2 covers 20% of it,
       | the rest of it is going to be an inert gas like Nitrogen, Argon,
       | Helium or SF6.
       | 
       | Of course every method of producing O2 in space works by
       | separating O from something else and the "something else" is
       | likely to be useful, such as H2, C, Al, etc.
        
         | mpweiher wrote:
         | Apollo continued to use pure oxygen once in space, even after
         | the Apollo 1 fire.
         | 
         | https://www.popsci.com/why-did-nasa-still-use-pure-oxygen-af...
        
         | teraflop wrote:
         | That seems like an extremely pedantic complaint.
         | 
         | Sure, the breathing gas for a crewed mission or habitat would
         | need to include an inert gas as well as oxygen. But oxygen is
         | consumed during respiration and the inert gas isn't, so oxygen
         | will be needed in much larger quantities, so in-situ production
         | is a much more pressing problem.
        
           | PaulHoule wrote:
           | You are probably recycling the CO2 from the astronauts breath
           | which is easier than cracking it from the air. Also many
           | practical breathing systems (especially for spacesuits) leak
           | some of the inert gas for cooling and other purposes.
           | 
           | The real thing you'll need O2 for is an oxidizer for fuel but
           | of course you need to make fuel too.
           | 
           | If you are interested in making anything interesting such as
           | large plastic sails or small biospheres nitrogen is the big
           | missing piece of the puzzle right now in the moon, mars and
           | asteroids.
        
             | ben_w wrote:
             | > recycling the CO2 from the astronauts breath
             | 
             | It's literally exactly as difficult as cracking out from
             | the air, because breath is in fact made from air.
        
               | sigstoat wrote:
               | being extremely generous, and assuming he meant "martian
               | atmosphere" when he said "air", it _might_ be a bit more
               | challenging (depending on your process and what you've
               | got available) to convert the CO2 at 0.095 PSI into O2,
               | than it would be to pull the CO2 out of ~14.7 PSI human
               | exhalations and convert it to O2.
               | 
               | seems like the kind of thing where there is a bunch of
               | engineering that could be productively done.
        
             | MichaelCollins wrote:
             | CO2 needs to be scrubbed/vented out of the breathable
             | atmosphere. Even if there is abundant of oxygen anyway, too
             | much CO2 will make people feel dizzy and confused, cause
             | splitting headaches, increased heart rated, reduced senses,
             | and eventually death. CO2 can't take the place of inert
             | nitrogen in a breathable atmosphere, that much CO2 in the
             | air just isn't compatible with human life.
        
         | MichaelCollins wrote:
         | A major contributing factor to the Apollo 1 fire was they
         | didn't merely have a pure oxygen atmosphere, but a
         | _pressurized_ pure oxygen atmosphere. Pressurized above 1
         | atmosphere, for testing purposes. In space they would have
         | operated with a substantially lower pressure; I believe about 1
         | /5th of atmospheric pressure. A low pressure pure oxygen
         | environment is still a fire hazard relative to regular air with
         | the same partial pressure of oxygen, but it's not nearly as
         | dangerous as a pressurized oxygen atmosphere.
        
       | basicplus2 wrote:
       | What would they do with all that toxic CO??
        
         | fnordpiglet wrote:
         | Huff it to get high
        
           | lovemenot wrote:
           | Assume you were thinking of nitrous oxide N2 O.
           | 
           | C O is deadly when inhaled
        
         | LeifCarrotson wrote:
         | Toxic to who or to what?
        
         | PaulHoule wrote:
         | Make organic chemicals. See 'C1 chemistry'. CO is one of my
         | favorite substances to get in designing chemical factories in
         | space.
        
       | jscipione wrote:
       | There's a heck of a lot more CO2 in Venus' atmosphere than there
       | is in Mars'.
        
       | John23832 wrote:
       | Great. Now let's deal with the carcinogenic soil.
        
       | jmyeet wrote:
       | Two things:
       | 
       | Producing materials from other materials such as extracting
       | oxygen from various compounmds is ultimately an energy problem.
       | Better processes might reduce the ultimate cost by reducing the
       | capital cost or reducing the running cost. For example: we can
       | make hydrocarbons from the atmosphere. It's just uneconomic
       | because of the energy cost.
       | 
       | The energy source itself presents issues. If you need a $50
       | billion fusion reactor that takes 20 years to build and a
       | thousand people to maintain then that's a problem to bootstrap on
       | Mars.
       | 
       | I personally believe that on Mars, much like on Earth, the future
       | is solar. Solar has a lot of benefits on places like Mars. It's
       | the only form of power generation that reduces electricity
       | directly rather than boiling water and turning a turbine.
       | 
       | So mars still has the two big problems it always has had:
       | 
       | 1. It's further from the Sun so solar is less effective. This
       | just increases the cost of energy, ultimately. Of course,
       | there'll occassionally be a months-long dust storm that'll stop
       | you producing any power or just a shorter one that covers all
       | your panels in dust; and
       | 
       | 2. What are you going to do with this oxygen? You're going to be
       | living underground because living above ground exposes you to
       | radiation and the Martian surface itself is toxic (eg
       | perchlorates). If you're living underground anyway, why are you
       | living on Mars instead of the Moon?
       | 
       | Mars just makes zero sense to colonize.
        
         | [deleted]
        
       | [deleted]
        
       | smm11 wrote:
       | Let's put Arnold on it.
        
       | S_A_P wrote:
       | Could the same thing be used to remove carbon dioxide from
       | earth's atmosphere?
        
         | Johnny555 wrote:
         | The reaction described in the article says that it strips an
         | oxygen molecule from carbon dioxide, creating carbon monoxide.
         | 
         | CO typically only lasts for a few months in the atmosphere, but
         | only because CO molecules react with oxygen, forming CO2.
         | 
         | So I think no, this could not be used to sequester CO2 from the
         | atmosphere.
        
       | eggy wrote:
       | Douglas Quaid discovered this in the 1990s on Mars!
        
       | trhway wrote:
       | SpaceX will need to split CO2 into CO and O2, H2O into H2 and O2,
       | combine the firsts into methanol and pour all this into the
       | Starship tanks for the Earth bound trips. That means that they
       | will probably bring nuclear reactor(s) there (my hope though is
       | that Musk will decide to do to fusion that he had already done to
       | EV, space, etc.). O2 for humans will be just a noise (also
       | greenhouses for food production will probably generate O2 enough
       | for humans).
        
         | tsimionescu wrote:
         | > my hope though is that Musk will decide to do to fusion that
         | he had already done to EV, space, etc.
         | 
         | Fusion power doesn't need the kind of incremental advances and
         | smart marketing that Musk's companies have benefitted from, it
         | needs huge fundamental advances in science and engineering.
         | 
         | That said, by the time anyone actually tries to establish any
         | kind of base on Mars, we may well have figured fusion (my money
         | is still on ITER's follow-ups, the DEMO plants, being the first
         | to actually do anything, in 2050 at the earliest). Musk's
         | "plans" for Mars are just part of his pretty smart marketing /
         | outright lying to bolster his companies.
        
           | systemvoltage wrote:
           | Although something tells me that Fusion would be a solved
           | problem in about 18 months if we were in a wartime and have
           | all hands on the deck. I am joking only slightly.
        
           | trhway wrote:
           | >Fusion power doesn't need the kind of incremental advances
           | and smart marketing that Musk's companies have benefitted
           | from, it needs huge fundamental advances in science and
           | engineering.
           | 
           | It is systems engineering - take the available science and
           | engineering and combine into an actually working thing. That
           | is exactly what we need with fusion today.
        
             | JumpCrisscross wrote:
             | > _take the available science and engineering and combine
             | into an actually working thing_
             | 
             | This doesn't describe the present situation. For example,
             | high-temperature superconducting magnets open design space
             | which simply didn't exist a decade or two ago.
        
         | elihu wrote:
         | Nuclear has the problem that you somehow need to hoist a
         | reactor from the Earth into space, and putting nuclear
         | materials makes a lot of people nervous. (What happens if the
         | rocket launch fails and scatters radioactive debris?)
         | 
         | An alternative is to gather the reactor fuel on Mars, but that
         | sounds like a difficult undertaking.
         | 
         | I think the expectation is that the energy needed to make
         | methane on Mars will be provided by a lot of solar panels.
         | 
         | (I would be curious to know how the math works out. For
         | instance, if you send a Starship fully loaded with solar panels
         | to Mars and spread them out on the ground, how long will it
         | take those solar panels to gather enough energy to make enough
         | methane to return the rocket to Earth? Is it one year? 10
         | years? 100 years?)
        
           | trhway wrote:
           | The amount of highly enriched U and Pu that has already been
           | put into space is at least several hundred of kilograms
           | across at least 10+ of launches. And reliability of SpaceX
           | launches is highest in history of human space programs.
           | 
           | My bet is on nuclear vs solar as the nuclear is the next
           | rocket engine type after chemical and will loose the
           | dependency on launch windows and shorten the trip time.
        
             | elihu wrote:
             | The safety risk isn't necessarily an insurmountable
             | obstacle; I could imagine the U.S. government being more
             | likely to approve sending a nuclear reactor into space if
             | it was NASA that was asking as opposed to a private
             | company, but either way it's more of a political problem
             | than a technical one.
             | 
             | Nuclear rocket engines are tricky. Nuclear reactors don't
             | actually work very well in space because there isn't any
             | convenient way to get rid of the excess heat. A vacuum is a
             | very good insulator, so usually your only option is just to
             | radiate it away as infrared light.
             | 
             | With a rocket there's another option which is to transfer
             | all the heat to the reaction mass you're expelling out the
             | back of the ship. That sounds like a hard engineering
             | problem though.
             | 
             | Using a reactor on the Mars surface is a lot more
             | straightforward because you can use the local air and
             | ground to transfer heat. And since Mars is so cold, you
             | might even get better steam generator efficiency there than
             | on Earth, where the ambient temperatures are higher.
             | 
             | One of the hopes with fusion is that if it pans out it
             | might be reasonable to send a fusion reactor to Mars since
             | you wouldn't need to send radioactive fuel rods. In fact,
             | maybe the first practical fusion reactors will be used on
             | Mars before they're used in more than a demonstrative
             | capacity on Earth because they fit a very specific need,
             | there are barriers to using the alternatives, and cost per
             | kw/h isn't the most important constraint.
        
           | alex_young wrote:
           | There are plenty of nuclear reactors already in space. The
           | Voyager probes are famously powered by radioisotope
           | thermoelectric generators, and even the Perseverance lander
           | mentioned in the article is powered by one. Full list here: h
           | ttps://en.wikipedia.org/wiki/List_of_nuclear_power_systems_..
           | .
        
             | aqme28 wrote:
             | Those are much much smaller than the nuclear reactors that
             | parent comment is talking about. A totally different beast.
        
               | elihu wrote:
               | Interestingly the biggest reactors (mostly 2kw and a few
               | 5kw) were deployed by the Soviet Union. Presumably they
               | just didn't care about the safety risks.
               | 
               | The risks weren't purely theoretical either. They had one
               | nuclear-powered satellite that re-entered over Canada.
               | 
               | https://en.wikipedia.org/wiki/Kosmos_954
        
           | PaulHoule wrote:
           | On mars you have a day not too different from ours and solar
           | looks attractive. On the moon you really need nuclear because
           | the night lasts two weeks. It is so bad people are thinking
           | about reversing O'Neills idea and microwave beaming power
           | from the Earth to the Moon.
        
           | rdevsrex wrote:
           | Couldn't we just use low enriched uranium for that? And as
           | long as you aren't actively powering it up on takeoff, even
           | in an accident, how radioactive would it be?
        
       | somecommit wrote:
       | Should we blast a giant hole into Mars?
       | https://www.youtube.com/watch?v=RnRzsQOZSfQ
        
         | bambax wrote:
         | Interesting. So maybe the asteroid that killed the dinosaurs
         | was an alien attempt to make earth habitable for them.
        
           | knodi123 wrote:
           | And it worked. And we are them. Cue intro theme music....
        
         | elihu wrote:
         | That was sort of how C.S. Lewis imagined Mars in Out Of The
         | Silent Planet, before we really had a good idea of what Mars
         | was really like. Most of the planet was unlivable without an
         | air supply, but the valleys trapped enough air for plant and
         | animal life to thrive.
         | 
         | If one were to make a hole like the one described in the video,
         | I wonder how much that would affect the atmospheric pressure on
         | the rest of Mars?
        
       | Taniwha wrote:
       | mmmm O2+2CO great to breathe ..... to be useful they're going to
       | n eed something that separates out ALL the carbon monoxide
        
       | gene-h wrote:
       | Here's a link to the paper which this article is about:
       | https://aip.scitation.org/doi/10.1063/5.0098011
       | 
       | Using plasmas is interesting for ISRU because they may work at
       | Mars ambient atmospheric conditions. I'm quite surprised that
       | this plasma reactor approach is more energy efficient than the
       | solid electrolysis technique used by the MOXIE experiment.
        
       | vlovich123 wrote:
       | Needing to lift all the materials into space from Earth seems
       | energy intensive. On the other hand, maybe we'll have fusion-
       | based rockets in the future where the energy cost to escape
       | Earth's gravity well isn't as important. You'll still have
       | potentially two planets worth of needs to support. I know that
       | the various space companies are looking at asteroid capture. I
       | wonder if it makes sense to just smash some of those into Mars
       | before it's inhabited. Yes it potentially destroys scientific
       | data but that risk can be managed vs the benefit of having
       | easily-accessible building materials on Mars to build large-scale
       | industrial equipment / housing if we get serious about colonizing
       | Mars.
        
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