[HN Gopher] Scientists discover new "origins of life" chemical r...
       ___________________________________________________________________
        
       Scientists discover new "origins of life" chemical reactions
        
       Author : geox
       Score  : 86 points
       Date   : 2022-07-29 14:09 UTC (8 hours ago)
        
 (HTM) web link (www.scripps.edu)
 (TXT) w3m dump (www.scripps.edu)
        
       | wrycoder wrote:
       | Keto acids[0] are a primary precursor.
       | 
       | [0] https://en.m.wikipedia.org/wiki/Keto_acid
        
       | gilleain wrote:
       | What looks like the main (?) reaction (from the graphic on
       | https://www.nature.com/articles/s41557-022-00999-w) :
       | 
       | R-C(=O)COO -- (CO2, "NH3", CN-, H2O) --> R-Hydantoin (?) -->
       | aminated amino acid --> alfa-amino acids
       | 
       | where R = {H, CH3, CH2COO}.
       | 
       | (ps : Apologies to any chemists reading this...)
        
         | gilleain wrote:
         | Oh ok, looks like this is called the
         | https://en.wikipedia.org/wiki/Bucherer%E2%80%93Bergs_reactio...
         | - mentioned in the abstract.
        
       | yuan43 wrote:
       | > After their success using cyanide to drive other chemical
       | reactions, Krishnamurthy and his colleagues suspected that
       | cyanide, even without enzymes, might also help turn a-keto acids
       | into amino acids. Because they knew nitrogen would be required in
       | some form, they added ammonia--a form of nitrogen that would have
       | been present on the early earth. Then, through trial and error,
       | they discovered a third key ingredient: carbon dioxide. With this
       | mixture, they quickly started seeing amino acids form.
       | 
       | This is all well and good, interesting chemistry even.
       | 
       | However, a-keto acids are not the kinds of things just laying
       | around. These are reactive species and so would interact in a
       | variety of ways with environmental nuclophiles, oxidants, and
       | other stuff.
       | 
       | The article doesn't link to the study in question, which is
       | unfortunate and inexcusable. It does link to a study on a
       | different system earlier this year.
       | 
       | Origins of life research has been plagued with efforts that
       | front-load the problem in various ways. For example, how do we
       | make proteins abiotically? How do we make sugars abiotically?
       | 
       | Load up a flask with all the amino acids you want. Zap it with
       | whatever you want in terms of energy. At the end of it you won't
       | have much but a mess.
       | 
       | There seem to be fundamental principles we're missing that go
       | beyond reaction pathways. Not many people are working on that
       | problem. It's extremely risky for both PIs and students, and
       | almost impossible to fund.
        
       | rlkjlk3 wrote:
        
         | vkazanov wrote:
         | I am not sure Discovery Institute is a reliable source.
         | Wikipedia says that it's a non-profit created with a specific
         | goal of promoting certain non-scientific ideas:
         | https://en.m.wikipedia.org/wiki/Discovery_Institute
        
           | trasz wrote:
           | We can call it by name: a fringe theory spread by Christian
           | extremists, a particular kind that's deranged even by most
           | Christian extremist standards. Same disgusting human trash
           | like the ones behind abortion ban.
        
             | dang wrote:
             | Religious flamewar is not ok here, so please don't take HN
             | threads further into it.
             | 
             | https://news.ycombinator.com/newsguidelines.html
             | 
             | Edit: We've had to ask you this kind of thing many times
             | before - here's a small sample:
             | 
             | https://news.ycombinator.com/item?id=29916978 (Jan 2022)
             | 
             | https://news.ycombinator.com/item?id=29687837 (Dec 2021)
             | 
             | https://news.ycombinator.com/item?id=23578435 (June 2020)
             | 
             | https://news.ycombinator.com/item?id=23578417 (June 2020)
             | 
             | Edit 2: It looks like you've been using HN primarily for
             | political and ideological (and religious) battle. We ban
             | accounts that do this. It's not what this site is for, and
             | it destroys what it is for.
             | 
             | If you keep this up, we're going to have to ban you, so
             | please review
             | https://news.ycombinator.com/newsguidelines.html and use HN
             | as intended. That means for _curious_ conversation on
             | topics of intellectual interest.
        
               | trasz wrote:
               | It's not a flamewar: I can easily provide sources that
               | support all my claims, and I'm following your advice
               | about "two comments at most, three is too much". It also
               | doesn't have much to do with religion as such, as even
               | Catholic Church is officially against the "intelligent
               | design" idea.
               | 
               | Now, what the above is, it is pointing out an organized
               | disinformation campaign, which uses religious beliefs for
               | its purposes. I'm pretty sure that fighting propaganda
               | used to be part of the hacker ethos. And we're not going
               | to solve this problem by pretending this particular
               | propaganda somehow deserves anyone's respect or that it
               | is any different from others. Would you be opposed to
               | comments against antivax theories? If not - can you
               | explain where do you see the difference?
               | 
               | Also, I can't help but notice that while comments that
               | are openly racist are widely tolerated here, pointing it
               | out is an "ideological battle" - as evidenced by your own
               | examples above. Don't you find it a bit... curious? I'm
               | pretty sure I'm not the only person frustrated with it.
        
               | dang wrote:
               | Flamewar has nothing to do with providing sources or not.
               | Nor does it have to do with being right or not. It's easy
               | to be both right and replete with sources and still be
               | doing the name-calling, snark, aggression, and other
               | things that the HN guidelines ask commenters to avoid.
               | 
               | It has to do with inflaming discussion to the point where
               | people angrily hurl talking points and attacks at each
               | other. That's far removed from the curious conversation,
               | respectful across differences, that we want here.
               | 
               | This is not a difficult concept for anyone familiar with
               | internet threads. Moreover, the ways that you've been
               | breaking the site guidelines are not borderline cases.
               | Please just fix this.
               | 
               | Pointing fingers at the bad behavior of others doesn't
               | seem relevant to this point. You've been breaking HN's
               | rules badly for a long time now, and we've asked you to
               | stop a lot. If you first fix this, and then have
               | something to say about other people's bad behavior, or
               | about moderation failures, I'd be happy to address it.
               | 
               | By the way, you've also posted lots of good comments that
               | are perfectly within the site guidelines. I appreciate
               | that, and I definitely don't want to ban you.
               | Unfortunately, bad comments do more damage than good
               | comments add value; plus they add to existential risk
               | (since the default fate of most internet forums is self-
               | destruction, sooner or later). So we need to do something
               | about the bad comments.
               | 
               | https://news.ycombinator.com/newsguidelines.html
        
         | beefok wrote:
         | The Discovery Institute's only purpose[1] is to push
         | creationism into public education under the guise of
         | 'Intelligent Design'. Of course they never specify 'what' or
         | 'who' the 'designer' is, but we all know what they are pushing.
         | 
         | Their only way of providing 'evidence' for an Intelligent
         | Designer is fallacious at best [2]. Like all creationists, they
         | can only provide bad faith arguments of ignorance and the god
         | of the gaps. They can't even differentiate between what is
         | 'designed' and what is 'natural', what's worse, they think
         | everything is designed in the first place.
         | 
         | Let's say the modern synthesis of the theory of evolution is
         | wrong, and the evidence put forth is wrong (160+ years of
         | evidence.) If this were the case, neither creationism nor
         | intelligent design is suddenly the alternative.
         | 
         | Intelligent design does not have any scientific merit. It does
         | not explain _anything_ about the abundance of evidence we
         | actually have. It cannot make predictions, nor can it be
         | falsified. It 's a worthless unscientific mess that should have
         | been put to rest many times over by now.
         | 
         | If there was ever evidence of 'design', that's evidence of
         | 'design', not evidence of a designer. Before anything, you
         | would first have to meet the burden of proof on the _designer_.
         | 
         | [1] https://en.wikipedia.org/wiki/Wedge_strategy
         | 
         | [2] https://www.americanprogress.org/article/the-flaws-in-
         | intell...
        
       | Calavar wrote:
       | I have always felt that applying the label "origins of life"
       | research on amino acid/nucleic acid synthesis is extremely
       | misleading.
       | 
       | An analogy would be writing an article about the natural
       | abundance of silicon on beaches and calling it "how computers are
       | made."
       | 
       | We have a decent idea of how the first nucleic acids may have
       | been synthesized, and we have a decent framework for how life
       | evolved from protobiont to prokaryote to eukaryote to
       | multicellular organisms. But there is an absolutely staggering
       | gap between the synthesis of individual nucleotides and the
       | synthesis of the first RNA replicase that we know nearly nothing
       | about.
        
         | TrapLord_Rhodo wrote:
         | The whole point of the article was discussing how RNA isn't the
         | orgin of life and we need to push our ideas back further.
         | 
         | RNA-Peptide coevolution is the spontaneous immergence of
         | 'replicating' matter. No one molecule in the system has all the
         | requisites for life, but as a whole they do. (I.E.amino acids
         | and nucleobases can transmit information, replicate, move and
         | 'sense' about the world). Pushing this idea of self-replicating
         | orgiins of life back may illuminate the issue. RNA generation
         | doesn't have to be random, it can be selected for like any
         | other evolutionary proceses.
         | 
         | Finally, Listen to what you are saying... The rhetoric was much
         | different 10 years ago.
         | 
         | We have scientifically narrowed the limit of what we can't
         | explain, and this very small gap in our knowledge is what's
         | left. We are making progress in understandng the origins of
         | life.
        
         | Thorentis wrote:
         | There is also a staggering gap between nucleic acids existing,
         | and just random atoms existing. And then an even more
         | staggering gap between atoms existing, and nothing existing.
        
         | photochemsyn wrote:
         | It's unlikely that RNA replicases ever existed in the absence
         | of short amino acid polymers. The primordial ribosome might be
         | the concept your looking for - an association between short RNA
         | sequences and short amino acid sequences capable of self-
         | replication via various RNA reactions and amino-catalyzed
         | reactions.
         | 
         | This may be the original article discussing this hypothesis:
         | 
         | "The ribosome as a missing link in the evolution of life"
         | (2015) Root-Bernstein & Root-Bernstein, J. Theoretical Biology
         | 
         | https://sci-hub.se/10.1016/j.jtbi.2014.11.025
         | 
         | > "Evolvable entities existing between self-replicating
         | polymers and fully functional cells would presumably have many,
         | though not all, of the functions of a cell, yet be
         | significantly simpler in composition and organization. These
         | entities would be able to self-organize and replicate
         | themselves; store information and replicate that information;
         | translate the information into the components necessary to
         | produce their functional structures; capture metabolic
         | components and energy; and transform these into useful
         | biochemical networks. Norris and his colleagues have called
         | functional forms of organization midway between macromolecules
         | and cells "hyperstructures" (Norris et al., 2007). Such
         | hyperstructures had to be instantiated as evolvable entities,
         | meaning that their components would be subject to variation,
         | replication and natural selection."
        
         | gliptic wrote:
         | If we truly didn't know how computers came about, it's
         | certainly progress to figure out the silicon can come from
         | sand.
         | 
         | How is it not origins of life research to attack every step in
         | the process?
        
           | dieselgate wrote:
           | Just a clarifying question but when you use "attack" do you
           | mean from a "critically minded research focused lens" or a
           | "skeptical" one?
        
             | trasz wrote:
        
           | Calavar wrote:
           | It's progress, but the degree of progress is vastly oversold
           | by the media, and sometimes even by academics. Kind of
           | similar to those "amazing new semiconductor" articles that
           | come out every 6 months.
        
             | soco wrote:
             | Maybe you mean the regular amazing new battery
             | breakthrough?
        
             | Calavar wrote:
             | Adding to my previous comment:
             | 
             | If a student asked "how did life originate?" a response
             | about about nucleic acid synthesis would be a bit
             | disingenuous, because that covers only very, very tiny
             | fraction of the surface area of the problem. The more
             | honest answer would be that there are so many large gaps in
             | our knowledge that we truly don't know.
             | 
             | To be clear, I'm not trying to cast skepticism on the whole
             | of biology. There are other questions that we have much
             | better answers to, like the evolutionary pathway from
             | single cellular life to multicellular life. Or the
             | evolutionary link between humans and great apes. But
             | abiogenesis is not one of those questions.
        
               | mannykannot wrote:
               | > If a student asked "how did life originate?" a response
               | about about nucleic acid synthesis would be a bit
               | disingenuous...
               | 
               | As the article title does not say or imply that the
               | answer to this question has been found, let alone that it
               | will be revealed in the article, this is at least beside
               | the point.
               | 
               | In attempting to brush aside gliptic's pertinent
               | question, you have switched to a general (and somewhat
               | subjective) claim that does not seem to hold up in this
               | specific case.
        
               | RosanaAnaDana wrote:
               | Also, and imo fundamentally, it doesn't define a natural
               | process of system where this reaction is
               | thermodynamiccally favorable.
               | 
               | That, imo, is far more important.
        
               | marcosdumay wrote:
               | > The more honest answer would be that there are so many
               | large gaps in our knowledge that we truly don't know.
               | 
               | Are the gaps really that large? We know that some
               | configurations of nucleotids are enough to create a full
               | metabolism, we know that they arrange at random, and we
               | know how most of them appeared.
               | 
               | Except for the few nucleotides that we don't know how
               | they existed, we do know that if you have enough of them
               | on enough places, some kind of life will appear. So looks
               | like the open question here is how those molecules
               | appeared.
        
               | dathanb82 wrote:
               | But RNA / DNA isn't sufficient for life, right? How are
               | proteins synthesized from that string of nucleotides
               | without ribosomes? And nucelotides randomly reshuffling
               | certainly doesn't explain how ribosomes would be created.
               | 
               | It's theorized that under the right conditions amino
               | acids will bond to become proteins without needing the
               | mediation of a ribosome. So it's certainly possible that
               | with enough primordial soup you could get proteins. But
               | that doesn't explain how the nucleotide string ends up
               | getting treated as a reusable blueprint for proteins.
               | 
               | That seems like a pretty big gap.
        
               | marcosdumay wrote:
               | Ribosomes are mostly RNA, and there is good evidence that
               | they evolved from something that was purely RNA. The
               | aminoacid transport and encoding mechanism is also
               | basically composed of RNA, with some evidence that
               | something like them would work without any of the protein
               | parts.
               | 
               | Also, people have created RNA-only self replicating
               | mechanisms that could quite well appear at random, with
               | extremely low odds. Life probably comes from some
               | structure with higher odds that we don't know about, but
               | that's not a huge gap.
        
               | bobthechef wrote:
        
               | sterlind wrote:
               | I wish I recalled better, but I saw a hypothesis that
               | centered around tRNA rather than the ribosome as the
               | origin of replication. after all, the ribosome simply
               | catalyzes the binding of tRNA to mRNA, and amino acid
               | linkage.
               | 
               | iirc the idea centered around the tRNA "code" having a
               | pattern to it - one shaped by its binding affinity to
               | part of the sequence that codes for the tRNA-
               | aminoacyltransferase enzyme itself. I wish I remembered
               | enough to find the reference.
               | 
               | edit: ah! think I remembered. the hypothesis was that the
               | codon sequence had some sort of binding affinity to the
               | amino acid it codes for. that there's a relationship
               | between them, suggesting a world where codons attracted
               | amino acids to bind to them without an enzyme linking
               | them.
               | 
               | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7924937/
        
           | RosanaAnaDana wrote:
           | In the context of building computers and defining
           | computation, silicon can be considered an afterthought.
           | 
           | We already had adding machines and the philosophy necessary
           | for digital logic.
           | 
           | It may well be the case with the original system that
           | initiated the process we call life. RNA (and by extension
           | DNA) may have been a complete afterthought.
           | 
           | I'm always disappointed when I see this research outside of a
           | systems context. Like, sure we can show these things happen,
           | but show me a thermodynamic systems, in place,where this can
           | happen.
           | 
           | In you metaphor about sand and beaches, this may be like
           | taking some one to a dune field and saying 'see all this
           | sand. That's where computers come from'.
        
         | oneoff786 wrote:
         | Is that really a staggering gap? The nucleotides jumble
         | together until they randomly hit a config that leads to a
         | pattern that leads to more of that config. We don't know what
         | that path is exactly but we can be pretty sure it's the result
         | of random mumbling through a series of random searches in an
         | organic chemistry space.
         | 
         | Computers don't arise randomly (without annoying semantic
         | arguments).
        
           | NateEag wrote:
           | > Computers don't arise randomly (without annoying semantic
           | arguments).
           | 
           | If you believe the human brain's processes are computable,
           | and you believe evolution is a random process, then you
           | believe that computers arise randomly.
           | 
           | Is that what you mean by "annoying semantic arguments"?
        
             | oneoff786 wrote:
             | Yes. That is an annoying semantic argument. The intended
             | discussion is pretty clearly a purposefully manufactured
             | device made of silicon and how understanding how that
             | instantiates by watching silicon is not at all like
             | watching how nucleotides arrange into rna.
             | 
             | Discussions of what constitutes a computer in this context
             | or whether an nth order effect of a "random" process are
             | just distracting.
        
               | jdthedisciple wrote:
               | Are you saying you are certain that human DNA was not
               | purposefully manufactured?
        
               | oneoff786 wrote:
               | Human DNA is a lonnnng way down below the timelines and
               | processes we're talking about buddy.
        
           | tengbretson wrote:
           | > Computers don't arise randomly
           | 
           | You are right. They don't.
        
           | rmbyrro wrote:
           | > we can be pretty sure it's the result of random mumbling
           | 
           | If you throw construction materials up 1 quadrillion times,
           | how many times can they randomly fall in the form of a house?
           | 
           | My response is zero. Building a house is not a product of
           | randomness, it's a product of intelligence and will.
           | 
           | Life also can't be a product of randomness. There's some
           | intelligence and will going on in nature's laws to make life
           | happen.
        
             | bglazer wrote:
             | Are you arguing that there was some direct intervention
             | during the origins of life? Like, an intelligent being
             | stuck a probe into a chemical mixture and tipped it towards
             | generating cells?
             | 
             | Or, perhaps you're arguing that the rules of the universe
             | were designed in a way that guaranteed that life would
             | arise?
             | 
             | Something else?
        
               | rmbyrro wrote:
               | More on line of the second thought, yes.
               | 
               | To me, Universal laws aren't random. If they were, I'd
               | expect them to change from time to time.
               | 
               | These laws are immutable and inexorable. They respect,
               | interact and cooperate perfectly with each other.
               | 
               | How did they come to exist and be that way if not by
               | intelligence and will?
               | 
               | I have no idea how this works or came to exist, but it
               | definitely doesn't look random to me.
        
               | giva wrote:
               | https://en.wikipedia.org/wiki/Anthropic_principle
        
               | 323 wrote:
               | There is a physical theory which postulates that life is
               | inevitable and a consequence of the laws of physics:
               | 
               | > _The thermodynamic dissipation theory thus assgins an
               | explicit thermodynamic function to life; the dissipative
               | structuring, proliferation, and evolution of molecular
               | pigments and their complexes from common precursor carbon
               | based molecules under the impressed short wavelength
               | solar photon potential to perform the explicit
               | thermodynamic function of dissipating this light into
               | long wavelength infrared light (heat). In a general
               | sense, the origin of life is no different than the origin
               | of other dissipative structuring processes like
               | hurricanes and the water cycle, except that these latter
               | processes deal with structuring involving hydrogen
               | bonding while life deals with structuring involving
               | covalent bonding. The external photon potential supplied
               | continuously by the environment (our Sun), and its
               | dissipation into heat by the assembly of dissipative
               | structures, are, therefore, both integral components
               | necessary for understanding life._
               | 
               | https://encyclopedia.pub/entry/6923
               | 
               | > _The formula, based on established physics, indicates
               | that when a group of atoms is driven by an external
               | source of energy (like the sun or chemical fuel) and
               | surrounded by a heat bath (like the ocean or atmosphere),
               | it will often gradually restructure itself in order to
               | dissipate increasingly more energy. This could mean that
               | under certain conditions, matter inexorably acquires the
               | key physical attribute associated with life._
               | 
               | https://www.quantamagazine.org/a-new-thermodynamics-
               | theory-o...
        
               | tcmart14 wrote:
               | Wouldn't this also have to assume a single universe. If
               | our universe is just one of many, then randomness can
               | still play an affect. We just happen to live in the
               | universe with these laws. But the universe next door
               | might have gotten a significantly different dice roll.
               | Does that mean life isn't present there? No exactly, but
               | I imagine it would look much different than us.
        
               | throwoutway wrote:
               | Our universe is single. The many concept is/was an
               | attempt to make a square fit in a round hole when looking
               | at some perplexing results. To me, Occam's Razor points
               | to intelligence arguments as simpler rather than the
               | "multi universe" arguments
        
               | sterlind wrote:
               | how do neural networks learn? is it by intelligence and
               | will?
               | 
               | no, it's by backpropagation. error is propagated and
               | minimized. simple equations lead to emergent complexity.
               | 
               | canyons form as water follows paths of least resistance,
               | and incrementally erode rock. the water doesn't use its
               | intelligence and will to construct a canal, even though
               | the resulting river system looks like a max flow
               | solution.
               | 
               | the intelligence and will emerges from the math. simple
               | systems with enough feedback can become very
               | sophisticated.
        
               | oneoff786 wrote:
               | Whether universal laws are self evident, random or
               | intelligently designed is irrelevant to the discussion at
               | hand though. The laws are there. It is through these laws
               | that life arose. We have a procedural generation
               | algorithm and a seed.
               | 
               | Even if you claim there is a single god that created both
               | of these things, backwards deriving the seed necessary to
               | generate the current state, it still routes through this
               | physical process which is describable with physics and
               | could be extrapolated to other starting conditions or
               | future scenarios that humans can utilize.
               | 
               | It makes no difference.
        
               | trasz wrote:
               | They don't cooperate perfectly; they cooperate somehow.
               | They could be entirely different, and the life would look
               | different - but there's no reason to think it wouldn't
               | work.
        
             | oneoff786 wrote:
             | That's my point. Organic chemistry is not like your
             | construction materials (or silicon computers). The organic
             | chem functionality for nucleotides to begin organizing into
             | repeating patterns exists. We know it does. And while we
             | might not know the exact reactions that it took, they are
             | highly likely to exist, and were arrived upon randomly.
             | 
             | If you arrange your biological soup a large number of times
             | randomly, you will eventually land on a pattern that causes
             | other nucleotides to arrange in a similar or improved
             | pattern around it.
             | 
             | Not too dissimilar from thinking about the creation of
             | specific atoms through various astronomical processes.
             | 
             | Even if you need to believe in god for some reason, it's
             | not incompatible with god defining the organic chemical
             | reactions that enabled life to form via random interactions
             | of nucleotides until they happened to land on god's lucky
             | number
        
               | rmbyrro wrote:
               | And why is it that they can combine?
        
               | oneoff786 wrote:
               | Because that's how organic chemistry works.
        
             | chris_overseas wrote:
             | > There's some intelligence and will going on in nature's
             | laws to make life happen.
             | 
             | And how do you suppose the intelligence you refer to
             | originated? You're not offering a solution, you're merely
             | adding another layer of complexity that still needs an
             | explanation along the same lines.
        
               | rmbyrro wrote:
               | I'm not trying to explain, just expressing that, to me,
               | randomness also doesn't explain. The fact that I see
               | intelligent processes going on is what makes me conclude
               | that.
        
             | dalmo3 wrote:
             | > If you throw construction materials up 1 quadrillion
             | times, how many times can they randomly fall in the form of
             | a house?
             | 
             | It depends on what you call a house.
             | 
             | It will probably never fall in any given expected shape.
             | 
             | It may very well fall into multiple configurations that
             | someone arriving at the scene after the fact, and without
             | prior knowledge of what you expected when you run the
             | experiment, would call a "house".
        
               | rmbyrro wrote:
               | Would electricity from the grid run through wires into a
               | power outlet?
        
               | dalmo3 wrote:
               | Is photosynthesis a requirement for life?
        
             | wussboy wrote:
             | It will never form a house. But it doesn't need to, and
             | expecting it to is a misunderstanding of evolutionary
             | processes.
             | 
             | What it needs to form is any kind of a shelter that is
             | better than not a shelter. A 4x8 sheet of plywood that
             | happens to lean against a brick forming a roof is all that
             | is required for a first house.
             | 
             | Life is a product of randomness. There is no intelligence
             | or will going on in nature's laws. Neither of those things
             | are required.
        
               | rmbyrro wrote:
               | With that line of reasoning, would we conclude that
               | having H2O formed in the planet 4 billion years ago was a
               | form of life better than not a life?
               | 
               | Would we conclude that everything in the Universe is
               | alive?
               | 
               | I think that's a pretty interesting way of seeing things.
               | And (to me, personally) it strengthens my view that there
               | are intelligent processes going on in the Universe.
        
               | ako wrote:
               | There is intelligence: solutions can replicate itself,
               | with small variations, and the best variations will be
               | more successful going forward. It's not complete
               | randomness, it's an optimizing algorithm.
        
               | wussboy wrote:
               | I was going to disagree with your definition of
               | intelligence. But Wikipedia says "to retain it as
               | knowledge to be applied towards adaptive behaviors within
               | an environment or context", and certainly, in a way,
               | evolutionary processes do indeed retain specific ways to
               | do things that can be applied towards adaptive behaviors.
               | So, yeah! :)
        
               | shockeychap wrote:
               | Throwing up materials that randomly fall into the shape
               | of a crude shelter can certainly happen. But without a
               | LOT of evolutionary mechanisms already in place, that
               | crude shelter will just fall apart, and it certainly
               | won't turn itself into something more sophisticated.
               | 
               | What is necessary for life to arise from a random stew of
               | disorganized chemicals is far more than just a good
               | arrangement of a few molecules that exhibit some
               | characteristics of life. Since all life dies as part of
               | the never-ending march toward entropy, you also need to
               | be capable of some form of reproduction and able to carry
               | out reproduction at a faster rate than death. What is the
               | minimum complexity involved in such a thing? I'd argue
               | that it's probably more complicated than any house in
               | existence.
        
               | achenatx wrote:
               | not really, any structure that can absorb energy and
               | replicate could initiate life.
               | 
               | nucleotides spontaneously form, then start to bind to
               | each other in chains. Those chains spontaneously fall
               | apart and reform.
               | 
               | amino acids start to bind to the nucleotide chains and
               | cause them to be more stable. Nucleotide chains bound to
               | the amino acids have a longer life expectancy than those
               | not bound to amino acids. The amino acids start to bind
               | to each other (they naturally do). The RNA binding makes
               | them slightly more energy efficient essentially
               | catalyzing the reaction.
               | 
               | over millions or billions of years, random chaining of
               | nucleotides leads to random chaining of proteins that are
               | slightly more energy efficient. Those forms "outcompete"
               | alternate forms.
               | 
               | Once a particular type of amino acid chain exists, it can
               | influence other amino acid chains to follow the same
               | structure. For example prions are extremely short but
               | binding to normally folded versions of the protein causes
               | the normal version to change patterns.
        
               | joshuahedlund wrote:
               | > over millions or billions of years
               | 
               | one of the interesting constraints is you don't have
               | billions of years. Life appeared on Earth within 100
               | million years of the planet cooling down enough to have
               | standing water, possibly even less, depending on your
               | reading of the evidence that gets more disputed the
               | farther back you go.
               | 
               | It took 2 billion years for prokaryotes to turn into
               | eukaryotes, and it took another billion for eukaryotes to
               | go multi-cellular, but somehow the initial development of
               | a self-replicating cell with a code took less than a
               | tenth of that.
        
             | gls2ro wrote:
             | Evolution is not randomness. It is running smaller
             | incremental multiple randomlike experiments and only few
             | pass to the next increment where again a lot of variations
             | will be generated and again selected only some few for the
             | next stage ...
             | 
             | So in your example with the house here is how it might be:
             | 
             | Throwing 1 quadrillion times materials will they arrange in
             | a fundation? Of course. Then throw again and will there be
             | some kind of wall or pillar?
             | 
             | Then you now have foundation and pillars. Throw again a
             | huge number of times, will there be materials that might
             | form a wall?
             | 
             | Please also take into consideration that evolution is not
             | only in a vertical progression (from materials to house)
             | but also running horizontally (like creating multiple types
             | of walls of all shapes before going for a roof).
             | 
             | But more importantly evolution will not create a house as
             | long as there is not need for one.
             | 
             | On the other hand, as we are poaching the limits of
             | science: how do you know that given a close to infinite
             | number of arrangements those materials will not arrange
             | into a house?
        
               | dragonwriter wrote:
               | > Evolution is not randomness.
               | 
               | Darwinian evolution in the narrow sense is duplication
               | _of_ life plus random variation plus filtering (that may
               | also be random, but which at a minimum contains some bias
               | which is, if not _consistent_ over time, at least usually
               | changes very slowly compared to the rate of random of
               | variation.)
               | 
               | Darwinian evolution in the broad sense is the same thing,
               | but without the "of life" part.
               | 
               | But abiogenesis is not Darwinian evolution in the narrow
               | sense, and may or may not significantly involve Darwinian
               | evolution in the broad sense, so arguing about what
               | evolution is or is not in the context of the initial
               | creation of life as opposed to the explosion of diversity
               | of life after its initial creation is, at best, skipping
               | steps.
        
             | uoaei wrote:
             | Assembly theory from Sara Walker et al. takes a principled
             | stab at questions like this using a combinatorial
             | "assembly" framework of small constructions that recombine
             | into larger ones. The model requires only Markov conditions
             | so fits into this description of probabilities of observing
             | certain assemblages.
             | 
             | Intelligence fits into this in interesting ways. One way to
             | consider it is as a guide to the assembly process from less
             | complex from more complex.
        
           | pfdietz wrote:
           | Where do the nucleotides come from?
        
           | jdthedisciple wrote:
           | > Computers don't arise randomly
           | 
           | As if, contrary to that, humans do/did.
        
           | Calavar wrote:
           | No, it's not as simple as that. The probability of self-
           | replicating RNA arising by random assembly of bases is very
           | low. There was a good Nature article [1] published a couple
           | years back that digs through some of the numerical issues.
           | (And a good, more layperson oriented summary as well [2].)
           | The gist is that a self-replicating RNA sequence would have
           | to be at least 40 nucleotides (and possibly even as long as
           | 100), but the probability of randomly synthesizing a
           | 40-nucleotide long sequence that happens to be self-
           | replicating anywhere in the visible universe over the span of
           | 13 billion years is effectively zero.
           | 
           | To be fair, the probability gets closer to one if you expand
           | your view to include the entire universe and assume that it
           | is many, many orders of magnitude larger than the visible
           | universe. But my take away, at least, is that we are not
           | dealing with a situation where random assembly of RNA is so
           | likely to generate self-replicating sequences that
           | abiogenesis was effectively an inevitability. That was the
           | narrative I was sold in grade school and undergrad, but it
           | appears to be wrong.
           | 
           | There are a good number of free parameters in the journal
           | article that I linked: The fraction of RNA sequences that are
           | self-replicating, the fraction of planets that are habitable
           | for life, the average decay rate of RNA on a habitable
           | planet, etc.
           | 
           | You take can take issue with the empirical estimates for
           | those parameters, but that points to missing pieces in the
           | framework: Was there a chemical process on early earth that
           | stabilized RNA oligomers that no longer exists? Are self-
           | replicating RNA sequences more common than we believe? If so,
           | why haven't we encountered more of them in nature? And so on.
           | In my opinion, these are the truly interesting questions, not
           | whether nucleotides and amino acids can form spontaneously.
           | 
           | [1] https://www.nature.com/articles/s41598-020-58060-0
           | 
           | [2] https://mathscholar.org/2020/05/the-origin-of-life-in-an-
           | inf...
        
             | trasz wrote:
             | >The probability of self-replicating RNA arising by random
             | assembly of bases is very low.
             | 
             | But it parallelizes extremely well - throughout the entire
             | universe for billions of years.
        
               | JJMcJ wrote:
               | Or here on Earth over say 100 million years with
               | trillions of little globs of organic chemicals, likely
               | with even simpler replication mechanisms that are not
               | understood currently.
        
             | adgjlsfhk1 wrote:
             | What this is missing is that it assumes way too little
             | structure. You don't have to generate a self replicating
             | set of RNA. Many RNA strands (maybe most?) will do
             | something, so all you need is to generate a strand of RNA
             | that will eventually produce a self replicating set of RNA
             | which is likely much easier.
        
             | oneoff786 wrote:
             | Undiscovered mechanisms of self replicating RNA arising by
             | chance seems very likely though. That's my point. I agree
             | there's a lot of good questions to be answered. I think it
             | is likely that we will answer them by staring at nucleotide
             | soup.
        
             | skupig wrote:
             | >the probability [...] is effectively zero
             | 
             | Is that meaningful? No matter how unlikely our existence
             | is, here we are.
        
             | lisper wrote:
             | > Are self-replicating RNA sequences more common than we
             | believe?
             | 
             | Almost certainly yes.
             | 
             | > If so, why haven't we encountered more of them in nature?
             | 
             | Because they can't compete with modern life. Nearly all of
             | the biomass on earth is in use. A primitive replicator,
             | even if it arose today, would have to compete for resources
             | against all the existing life on earth. It wouldn't stand a
             | chance. This is the reason there is only one universal
             | common ancestor. It's not necessarily that abiogenesis only
             | happened once, it's that only the descendants of one common
             | ancestor survive today. All traces of all other abiogenesis
             | events have been obliterated.
             | 
             | You have to compute the abiogenesis odds for an environment
             | that, by definition, does not yet include life. Here is a
             | rough back-of-the-envelope approximation: the biomass of
             | earth is about 2^52kg. Avogadro's number is 2^76. So there
             | is the potential for the early earth to have 2^120
             | nucleotide bases and amino acid molecules floating around.
             | If the complexity of a simple replicator is around O(100)
             | bits then the odds of finding one by chance when you are
             | rolling that many dice in parallel approaches 1 in just a
             | few million years. After that, evolution takes over.
        
             | pfdietz wrote:
             | Back up from that... how are the nucleotides formed? And
             | don't they need energetic polyphosphate groups on them to
             | drive the polymerization? And how does this work in an
             | impure solution with all sorts of variant nucleotides and
             | other cruft?
        
             | JJMcJ wrote:
             | To my thinking, that means that self replicating systems
             | arose in an even simpler chemical environment and even RNA
             | was a later development.
        
         | rojobuffalo wrote:
         | Dr. Nick Lane is my favorite author on this subject. My reduced
         | summary of a slide he presented titled "what is life" goes:
         | 
         | - free energy powers growth
         | 
         | - growth is thermodynamically favorable
         | 
         | - heredity is growth, doubling by exact copying
         | 
         | - growth combines carbon and energy metabolism
         | 
         | - growth is driven by environmental disequilibria
         | 
         | That doesn't explain away the mystery of the first RNA
         | replicase, but I really like how it explains growth and
         | doubling as a form a growth. That's copy-pasted from a
         | newsletter draft I'm writing. It'll be posted next week on
         | https://0123.substack.com
        
           | kabdib wrote:
           | If you like Nick Lane's writing, I also recommend David
           | Dreamer's _Assembling Life_. It gets a good deal more
           | technical (chemical?), and has more depth about possible ways
           | that membranes were  "invented".
           | 
           | Paul Falkowski's _Life 's Engines_ is also quite good.
        
         | pfdietz wrote:
         | > We have a decent idea of how the first nucleic acids may have
         | been synthesized,
         | 
         | Really? Nucleotides are already too complex to have been
         | produced in any valid OoL experiment at more than vanishingly
         | small concentrations. Experiments that demonstrate some
         | chemical X can be produced, and then lead to another experiment
         | where X is made available in pure form at high concentration
         | (and then rinse and repeat down the synthesis chain), don't
         | tell us anything interesting at all.
        
       | jbj wrote:
       | For those who find this subject fascinating and want more origin
       | of life chemistry, I recommend to find a video of Jack Szostack
       | giving a presentation after he got his Nobel price.
        
         | gnatman wrote:
         | 2nd video down on this page (first is the introduction):
         | 
         | https://www.nobelprize.org/prizes/medicine/2009/szostak/lect...
        
       | nomel wrote:
       | I highly recommend the Lex Fridman podcast with Lee Cronin
       | (#269), about the origins of life and complexity theory [1].
       | 
       | The discussion is really incredible. It really changed my naive
       | perspective of life, and the universe.
       | 
       | 1. https://www.youtube.com/watch?v=ZecQ64l-gKM
        
       | hsnewman wrote:
       | We don't have a clear defination of life, for example, James
       | Lovelock's Gaia theory says the earth is alive. How can one
       | discover something when that something is undefined?
        
         | nomel wrote:
         | It's incorrect to say it's "undefined" which means "without
         | definition". The "problem" is that it has a "fuzzy definition",
         | or you could rightly claim "multiple definitions", depending on
         | the context.
         | 
         | But, a good definition must come _after_ understanding, not
         | before. And, just because something doesn 't have a precise
         | definition or understanding doesn't mean that understanding
         | can't be _improved_ , or even _branched_ , in the form of a
         | _discovery_ , to create some new label that better fits the
         | concept.
         | 
         | Until then, we have to live with something fuzzy, with the
         | understanding that it is somewhat incorrect (which anyone
         | familiar with biology will happily tell you). Lack of
         | definition, which is lack of understanding, doesn't impede
         | discovery. Lack of definition and understanding are necessary
         | _requirements_ for discovery.
        
         | mcphage wrote:
         | > We don't have a clear defination of life
         | 
         | We don't even have a clear definition of tall--is a person 6'
         | 4" tall? How about 6' 3"? Or 6' 2"? Or 6' 1"? And yet a
         | building 6' 4" high would be tiny. What about a rock--is a rock
         | high 6' 4" tall?
        
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