[HN Gopher] Flow Batteries Are Here and They Will Change Everything
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       Flow Batteries Are Here and They Will Change Everything
        
       Author : socialdemocrat
       Score  : 31 points
       Date   : 2022-07-01 15:30 UTC (7 hours ago)
        
 (HTM) web link (medium.com)
 (TXT) w3m dump (medium.com)
        
       | socialdemocrat wrote:
       | Instead of $132 per kWh like Lithium batteries these cost $25 per
       | kWh and with almost endless number of cycle times. Covers pros
       | and cons.
        
         | vardump wrote:
         | I think lithium batteries currently range $50-$100, $132 seems
         | pretty high.
        
           | bioemerl wrote:
           | Might be comparing different metrics. If it's lifetime costs
           | you have to cover replacement timelines for lithium
           | degradation, facilities, and so on.
           | 
           | Lots of electronics involved when you have banks of thousands
           | of batteries
        
         | tyrfing wrote:
         | The problem with those LCOS numbers is, from what I've seen,
         | that it's a projected cost once production is scaled to a
         | certain (high) level. Lithium ships in high volume today and
         | benefits from scale, flow batteries don't. Manufacturers with
         | public info like ESS are careful to qualify the price
         | disclosures like that by saying it assumes future scaling -
         | it's not their cost _today_.
         | 
         | For example, from the ESS ($GWH) 10-K:
         | 
         | > [W]e have not yet produced any iron flow batteries, Energy
         | Warehouses or Energy Centers at volume and our expected cost
         | advantage for the production of these products at scale,
         | compared to conventional lithium-ion cells, will require us to
         | achieve rates of throughput, use of electricity and
         | consumables, yield, and rate of automation demonstrated for
         | mature battery, battery material, and ceramic manufacturing
         | processes, that we have not yet achieved.
         | 
         | If there's info to the contrary, I'd love to see it, but I'm
         | skeptical of any current cost advantage. At the moment they
         | seem to mostly be attractive for longer duration battery
         | installations, like that Fort Carson 10-hour battery mentioned
         | in the article.
        
       | ncmncm wrote:
       | Flow batteries represent an intermediate point between regular
       | batteries and synthetic fuels.
       | 
       | A regular battery costs in capital expenditure per kWh it can
       | store when fully charged. Once full, the only way to store more
       | is to buy more. But efficiency is usually high, and rate of
       | energy in and, particularly, out are high.
       | 
       | Synthetic fuels suffer conversion losses, but more storage is as
       | cheap as tankage. The expensive parts are the synthesis equipment
       | -- electrolyser, catalyzer, compressor, cooler -- and stuff to
       | get the stored energy back out, such as a fuel cell or turbine.
       | Those cost per kW, not per kWh.
       | 
       | Flow battery storage capacity can be extended by adding tankage
       | and electrolyte. The expensive part is the bit the electrolyte
       | flows through. So, kW in and kW out cost, per, but round trip
       | efficiency is higher. And you can't generally sell somebody
       | charged-up electrolyte, or buy it.
        
       | bioemerl wrote:
       | The efficiency downside doesn't even appear to be a downside. We
       | already have solar excess power when we don't need it. If you can
       | store that power and store it cheap, 80 percent efficiency is
       | better than zero.
       | 
       | I hope these pan out. We need something to happen ASAP.
        
       | undoware wrote:
       | This is incredibly exciting news, but I'd like to kick the tires
       | real quick.
       | 
       | Main worry: The magic ingredient this time appears to be vanadium
       | instead of lithium, but there's still a magic ingredient (at
       | least, according to my cursory understanding of the tech,
       | entirely due to the OP's link)
       | 
       | - How abundant is vanadium? Wikipedia says it's 'rarely found in
       | nature' https://en.wikipedia.org/wiki/Vanadium
       | 
       | - What are the geopolitics of vanadium? Under what conditions is
       | it typically mined? Within which nation-states' territories is it
       | typically found?
       | 
       | - What other industrial uses does vanadium have?
       | 
       | - What quantity is needed?
       | 
       | - Can we ramp up exploitation of deposits, or are there hard
       | reasons (scarcity, remoteness, etc) that prevent this?
       | 
       | - EDIT: most importantly, are there other candidate elements that
       | can, in the case of shortage or war, also provide service?
        
         | mhink wrote:
         | I'll grant that I'm not an expert in this kind of thing, but
         | according to the article:
         | 
         | > Furthermore, vanadium is a readily accessible element in many
         | different easy-to-find minerals. The rest of the battery is
         | made up of equally accessible materials, making it easy to
         | assemble and recycle, in comparison to lithium-ion batteries,
         | which need metals like cobalt and manganese to function.
         | 
         | This paragraph links to the following website:
         | https://www.australianvanadium.com.au/what-is-vanadium/
         | 
         | Obviously this doesn't answer all questions, but at the very
         | least it's a place to start.
        
       | exabrial wrote:
       | Flow batteries have been in the news every year but I've yet to
       | see a deployment other than this one. If they're so simple what
       | is holding large scale implementation back?
        
         | ZeroGravitas wrote:
         | They only make sense when you have large amounts of low carbon
         | power that you want to store for long periods of time.
         | 
         | Usually, just turning down some fossil fuel plant is a better
         | option.
         | 
         | Using the electricity via demand response comes after that.
         | 
         | A long wire to somewhere else that can use it and send you back
         | some of their excess is next.
         | 
         | If you really can't use that power for anything lithium
         | batteries are cost efficient as long as you regularly cycle
         | them (e.g. daily solar peaks).
         | 
         | So you need to get into storing power for long periods of time
         | before they have a niche. Which is on its way, but isn't here
         | yet. So building more renewables makes more sense. (Do enough
         | of that and eventually you'll want some more storage options).
        
         | Ajef wrote:
         | The article has a link in it to:
         | https://www.sciencedirect.com/topics/engineering/flow-batter...
         | 
         | If you scroll down there's a table 32.7 about Projects in
         | China. A number of which, according to that table, are
         | completed.
        
       | gardenfelder wrote:
       | Seems worth exploring. few links:
       | 
       | https://en.wikipedia.org/wiki/Flow_battery
       | 
       | https://sumitomoelectric.com/sites/default/files/2020-12/dow...
       | 
       | https://www.powermag.com/flow-batteries-energy-storage-optio...
       | 
       | https://www.sciencedirect.com/topics/engineering/flow-batter...
       | 
       | https://www.science.org/content/article/new-type-flow-batter...
       | 
       | http://www.cei.washington.edu/education/science-of-solar/flo...
        
       | safsgf wrote:
       | Flow batter, Glass batteries, seems like everyday there is a new
       | battery.
       | 
       | The real question: Can these batteries operate at Grid Scale.
       | What happens with Tokyo has a disaster event or any other mega
       | city for that matter (where 70% of the population will live
       | decades from now).
       | 
       | Today 96% of storage is water being pumped up a hill...
        
         | tim333 wrote:
         | Vanadium redox flow batteries aren't that new - the first
         | successful ones were made in the 80s -
         | https://en.wikipedia.org/wiki/Vanadium_redox_battery
         | 
         | I hope they get the economics to work.
         | 
         | Also the longest duration flow battery in the Wikipedia article
         | runs 10 hours. We really need something that can charge for
         | months in the summer and discarge for months in the winter.
         | Maybe rust https://news.ycombinator.com/item?id=27944600 or
         | aluminium https://news.ycombinator.com/item?id=26463249 ?
        
       | nullc wrote:
       | It's kind of weird to talk about the prices of flow batteries
       | when they're not really commercially available.
        
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       (page generated 2022-07-01 23:03 UTC)