[HN Gopher] Nanokelvin-resolution thermometry at room temperature
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       Nanokelvin-resolution thermometry at room temperature
        
       Author : pcrh
       Score  : 44 points
       Date   : 2022-06-17 16:11 UTC (6 hours ago)
        
 (HTM) web link (www.nature.com)
 (TXT) w3m dump (www.nature.com)
        
       | AdamH12113 wrote:
       | > Specifically, using a suspended asymmetric Fabry-Perot
       | resonator and a wavelength-stabilized probe laser we demonstrate
       | a thermoreflectance coefficient of >30/K, enabling measurements
       | with a thermometry noise floor of ~60 [nK/root Hz] and a
       | temperature resolution of <100 nK in a bandwidth of 0.1 Hz.
       | 
       | Is a bandwidth of 0.1 Hz good in this context? Does it imply that
       | the temperatures they're measuring are very stable on a time
       | scale of a second or so? Or are higher-frequency variations
       | ignored?
        
         | ISL wrote:
         | It is a reasonable bet that the thermalization time of their
         | sensor is in the neighborhood of 100ms or so (which is very
         | fast).
         | 
         | The thing that is really good/interesting is the 60 nK/rtHz
         | sensitivity at those frequencies. Off the top of my head, I
         | believe that the best thermistor-based systems I've built have
         | been in the 10-100 uK/rtHz realm.
         | 
         | It is interesting to ponder whether such extreme sensitivity
         | for a small object might open up some new avenues in
         | fundamental physics. Things related to temperature are
         | generally hard, but every time a new technique emerges, it is
         | worth looking around to see if any new doors have opened.
        
       | twawaaay wrote:
       | I have built a thermometer for an automation project with the
       | requirement to be able to measure rate of temperature change 50
       | times a second with resolution of 0.001K/s (between 50 and 140C).
       | 
       | I can tell you, I spent probably a month just learning how
       | difficult it is to measure temperature and what are all different
       | ways you can screw up the measurement. You can't just stick a
       | thermocouple anywhere you want. Everything has thermal mass,
       | everything is thermal impedance, everywhere there is a thermal
       | gradient. If you have ANY rate of change of temperature, your
       | measurement method will always greatly impact the result
       | regardless of how precise thermocouple and electronics you use.
       | 
       | If they really can get nanokelvin resolution I would be more
       | interested in understanding their measurement method, because
       | resolution is pretty much worthless if you stick it in the wrong
       | place.
        
         | semi-extrinsic wrote:
         | Wow, 0.001K is impressive for something you've built yourself.
         | Care to share what approach you used?
        
           | twawaaay wrote:
           | It wasn't anything special. I am an amateur EE and not
           | especially talented. I did some cursory search on the
           | Internet, found a circuit that was looking promising and
           | brute forced it by using best components I could find and
           | then ovenized it for great stability and removed any sources
           | of noise I could imagine (for example using linear power
           | supply, etc.) I think just the measurement circuit with the
           | oven was about $500 which is just saying I did poor at
           | optimising for the cost.
           | 
           | But for this project the price was not an issue and the real
           | challenge and bulk of work was in building a model and
           | control algorithm.
           | 
           | There is couple of gotchas. For example if you use very low
           | current through the RTD (PT100 in my case) you get a lot of
           | noise so you need to use relatively high current. But this
           | causes it to heat up. Rather than try to eliminate this
           | effect I decided to make sure this heating up is as constant
           | as possible. This is one of the reasons it had poor absolute
           | precision but was good for measuring changes over time.
        
         | anfractuosity wrote:
         | Out of interest what pt100 probe did you use?
         | 
         | Would this be a 4 wire pt100?
         | 
         | Also did you use a specialised chip for converting to digital
         | readings?
         | 
         | I vaguely recall looking at some fancy reference RTD
         | thermometers with glass housings (just found them, they seem to
         | be called SPRTs - https://isotech.co.uk/products/isotech-
         | model-670/)
        
           | twawaaay wrote:
           | I don't remember the exact PT100 I used but it wasn't very
           | expensive (still probably one of the more expensive things I
           | ever bought per unit of mass -- they are probably more
           | expensive that diamonds).
           | 
           | It was definitely 4 wire (you don't want to measure wire
           | resistance change and 4 wire is only way to get rid of it).
           | 
           | As to housing and type of RTD, a lot of the cost here is
           | spent on making sure the measurements are stable over long
           | time (so for example to prevent humidity and other gasses
           | from putting it out of calibration).
           | 
           | In my case I did not care a lot about it because I wasn't
           | after absolute precision, for me the important part was rate
           | of change. If you are after absolute precision you might want
           | one of the fancy RTDs.
           | 
           | But I cared that it is small and that it has very low thermal
           | impedance interface with the measured object. Smaller means
           | less thermal mass means faster response.
           | 
           | For the chip I used a general purpose ADC. You also need a
           | very good voltage reference, otherwise even best ADC isn't
           | worth much.
        
             | ISL wrote:
             | If you're primarily chasing sensitivity, one can generally
             | be much more sensitive with a non-platinum thermistor.
             | They're less stable but exhibit a _much_ greater change in
             | resistance with temperature.
             | 
             | A good voltage reference (or current source) is important,
             | but even more important is building up a reliable bridge
             | topology.
        
               | [deleted]
        
       | [deleted]
        
       | narush wrote:
       | Sounds like a bunch of very cool gobbledy-gook to me. My
       | (extremely) layman's understanding is that this this is
       | effectively better thermometers that could be useful for (among
       | other things) bio-calorimetry.
       | 
       | My previous understanding of the word calorimetry was "indirect
       | vs. direct calorimetry" - which (I think) are two techniques for
       | measuring the energy used by some person either at rest or
       | during. It's useful to understand how much energy someone is
       | burning for obvious reasons related to health, nutrition, energy
       | balance, etc. It seems like calorimetry has a much more general
       | usage though, and it's pretty much the science of measuring heat
       | transfers. Cool :}
       | 
       | There is so-much extremely-high-context science out there, and it
       | would would be so fun and thought-provoking to keep up with some
       | it it. It feels like my only options are a) spending a ton of
       | time trying to parse extremely high-context articles (and
       | probably misinterpreting them, like I do above), or relying on
       | pop-science communication. The latter, to me, seems to miss most
       | of the time - it usually simplifies things to just conclusions
       | like "new X does Y," which feels like it misses most of the
       | scientific processes while also misunderstanding the scientific
       | spirit of this sort of knowledge...
        
         | pcrh wrote:
         | Bio-calorimetry can be used to detect interactions between
         | biological molecules, such as between proteins, drugs binding
         | to proteins, etc,
         | 
         | A quick search lead me to this conference, where you can see a
         | wider range of uses of calorimetry in biological sciences.
         | 
         | https://www.biocalorimetry.org/program/
        
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