[HN Gopher] Oxidation makes tea black
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       Oxidation makes tea black
        
       Author : cmogni1
       Score  : 82 points
       Date   : 2022-03-15 15:52 UTC (7 hours ago)
        
 (HTM) web link (www.sophiescuppatea.com)
 (TXT) w3m dump (www.sophiescuppatea.com)
        
       | hbarka wrote:
       | The other dark tea, the fermented tea they mention in this
       | article aka _hei cha_ or commonly referred to as pu'er, scares me
       | because there are bad quality versions of it containing mold due
       | to their fermentation process. Hard to detect since it's also a
       | kind of black tea.
        
         | feanaro wrote:
         | It's not a black tea, at least in the western sense. Our black
         | tea is actually called _hong cha_ in Chinese, which means red
         | tea. They 're simply different types of tea.
         | 
         | There are also two different style pf pu'ers which have little
         | to do with each other. The style you're talking about is _shu
         | pu 'er_, which is deliberately piled and made wet in order to
         | trigger a sped up fermentation process. This is opposed to
         | _sheng pu 'er_, which is processed into bricks from very young,
         | raw leaves called maocha, and is then aged for a number of
         | years before it is drank. This results in a much slower and
         | subtler fermentation process. The taste of shu and sheng are
         | quite different.
         | 
         | I've never personally had an encounter with a bad batch of
         | either shu or sheng pu'er, but the shu variant is more prone to
         | this due to the process.
         | 
         | It's notable that pu'er is steeped at a (close to) 100 degrees
         | celsius and the first one or two short steepings are discarded.
         | This is to kill and wash off any microorganisms or dirt that
         | may be present.
        
           | hbarka wrote:
           | Thank you, that's informative.
        
       | chasil wrote:
       | I had always understood that white tea had minimal processing, so
       | I don't understand this assertion:
       | 
       | "Without oxidation, tea would taste unbearably bitter."
       | 
       | Perhaps white tea has not reached an adult phase with the
       | associated bitterness.
       | 
       | Contast to:
       | 
       | "White tea may refer to... minimally processed leaves of the
       | Camellia sinensis plant."
       | 
       | https://en.wikipedia.org/wiki/White_tea
        
         | cmogni1 wrote:
         | White tea is oxidized naturally for a while. The article is
         | referring to freshly picked leaves.
        
           | foo_barrio wrote:
           | That would be green tea no? You pick the green tea, cook it
           | to denature the enzymes to arrest the oxidization (called the
           | "killgreen" step in Chinese) and voila, green tea! Lots of
           | green teas can be quite smooth and even more so with more
           | careful brewing.
        
             | yvdriess wrote:
             | Yes, green tea needs lower temperature and controlled
             | infusion time, but rewards that. The author definitely does
             | not seem to be a fan and is not doing it justice.
        
             | cmogni1 wrote:
             | Yeah! Green tea gets fried or steamed right away to halt
             | oxidation. That kills off some of the undesirable
             | bitterness that masks some flavors that are even present in
             | fresh leaves. It is not that Green doesn't have any taste;
             | it is that there are more guardrails over what flavors can
             | appear and how distinct they can be.
        
             | hinkley wrote:
             | The Brit I mentioned elsewhere seemed to think it was the
             | drying that arrested the chemical processes in the tea.
             | 
             | He was also adamant about storing it in well sealed
             | containers out of direct sunlight. I ended up throwing away
             | a couple of containers because of this (although I've kept
             | a couple that are just too beautiful to part with - I store
             | my daily drinker in there since it doesn't need to keep as
             | long). Also explains why my dealer uses mylar vacuum packs
             | for anything over an ounce. No oxygen, no light.
        
               | foo_barrio wrote:
               | White tea does not undergo the "killgreen" step that
               | green teas and oolongs teas do IIRC. The drying slows the
               | oxidation but does not arrest it. "Aged" white tea is a
               | thing. If you let it sit around long enough it turns deep
               | red. Green tea just turns into stale tea. They even
               | compress white teas into something similar to those
               | "Pu'er Cakes".
        
           | chasil wrote:
           | The odd thing is that the range (and top end) of antioxidants
           | in white tea is larger than in green.
           | 
           | "Total catechin content (TCC) for white teas ranged widely
           | from 14.40 to 369.60 mg/g of dry plant material for water
           | extracts and 47.16 to 163.94 mg/g for methanol extracts. TCC
           | for green teas also ranged more than 10-fold, from 21.38 to
           | 228.20 mg/g of dry plant material for water extracts and
           | 32.23 to 141.24 mg/g for methanol extracts."
           | 
           | https://pubmed.ncbi.nlm.nih.gov/20722909/
        
             | hinkley wrote:
             | Is it odd or is it thermal breakdown of chemicals?
        
         | hinkley wrote:
         | Traditionally white tea was created from tea buds. If you've
         | ever gardened, you know how dicey those first few days are
         | because the plants that have defenses against caterpillars and
         | slugs are vulnerable until the leaves are fully formed.
         | Caffeine is a pesticide, and the young shoots don't contain
         | much of it. Last I remembered looking, white tea has about the
         | same caffeine as decaffeinated coffee (which I use both as a
         | sales pitch for getting people to try white tea and a warning
         | against people complaining about having trouble sleeping -
         | there's still caffeine in your decaf, buddy).
         | 
         | Since you pick the leaves before they are grown, you're pruning
         | the tree and potentially reducing your crop. Which is why it
         | was a drink of the nobility. Basically you're so rich you can
         | afford to reduce your crop by (conjecture) 10% for a taste
         | sensation, or pay someone else for the privilege.
         | 
         | I suspect we have so much of it now because 1) Republic of Tea
         | basically went through every tea fad in the history of tea in a
         | 15 year period, presumably to keep sales numbers up with
         | novelty, and 2) it's likely that there is oversupply in the tea
         | market, so white tea gives you another shot at a sale.
         | 
         | Unlike coffee, which gets one harvest per year (although some
         | people are trying to bring coffee leaf tea into the group
         | consciousness), it's typical to get at least 2 harvests of tea
         | per year, 3 or more in a great year. Which I discovered when I
         | noticed my dealer putting numbers and/or seasons on her tea. If
         | they are regrowing that fast then white tea might not be that
         | big of a burden.
        
         | [deleted]
        
       | amelius wrote:
       | Tangential. Has anyone tried Tulsi tea? I recently did and got a
       | bad experience from it. I think it has some psychoactive
       | substance in it.
        
         | throwaway1777 wrote:
         | Tulsi, aka holy basil, has a lot of effects, but not really
         | psychoactive ones. It's generally thought to have a wide range
         | of beneficial properties on stress, the immune system, etc but
         | it does disagree with some people too.
        
           | amelius wrote:
           | Maybe I should try a less strong cup.
        
           | mbg721 wrote:
           | It's basically basil-like in flavor, right?
        
       | hinkley wrote:
       | I stumbled into a presentation on tea at a tea festival a number
       | of years ago. I keep meaning to figure out which notebook my
       | notes are in and make copies because it was so good. The
       | presenter was this elderly British gent with a background in
       | operations who got sent out to figure out how to boost tea
       | output.
       | 
       | There were a bunch of charts about time and temperature and
       | humidity for various types of tea but the biggest fact was
       | slightly buried. 'fermentation' with respect to tea is a bit of a
       | euphemism. It's actually autolysis. The big epiphany moment for
       | me was connecting the dots and seeing why that was the case.
       | Caffeine is an insecticide. It's stored in little crystals in the
       | tissue. With oxalic acid, the crystals are the point. They're
       | sharp and they damage the attacker.
       | 
       | With caffeine it's metabolic disruption. Within other organelles
       | in the tea leaf are enzymes that can decompose the caffeine
       | crystals into a solluble form. These chemicals only mix when the
       | leaf is bruised, or masticated. They are booby trapped.
       | 
       | When you process _camellia sinensis_ into tea, the oldest process
       | is matcha, which started in China and is now mostly preserved in
       | Japan, is drying the leaves and then powdering them, which I
       | presume frees up some of the caffeine simply by mechanical
       | decomposition. For the others the leaves are processed by
       | bruising, heating and drying the leaves, and the order and
       | duration dictates which kind of tea you get, and how much of the
       | caffeine has been converted to a form that is water soluble.
       | Black tea is aged longer, and has more available caffeine.
       | 
       | Almost none of them are actually fermented as in beer (puehr is
       | the most notable, and the common reaction upon smelling it is,
       | "This reminds me of my grandmother's garden." It is an acquired
       | taste.) Edit: and kombucha, which is fermented after being
       | steeped, rather than before. Also by many accounts an acquired
       | taste.
        
         | almog wrote:
         | That's a very good description of the enzymatic process in tea.
         | 
         | Regarding "oldest process" though, I'm not sure which is the
         | earliest processing method for tea but compressed tea / tea
         | bricks as Pu-erh (although compressed tea [?] Pu-erh) is
         | attributed to Tang dynasty (AD 618-907) and it precedes Matcha
         | which is attributed to the Song dynasty period (960-1279).
        
           | WillPostForFood wrote:
           | The way they drank tea in the Han dynasty is interesting;
           | centuries before before a real processing method came about.
           | 
           |  _Guo Pu noted in the book Er Ya (Chinese: Er Ya ), the
           | earliest Chinese dictionary, tea can be boiled to consume
           | like thick soup. More precisely, to make a cup of tea at that
           | time you need to mix millet and other condiments with tea
           | leaves first them boil them together till mushy state_
           | 
           | https://www.teavivre.com/info/ways-of-drinking-tea-in-
           | ancien...
        
           | hinkley wrote:
           | The problem with summarizing complex things for people is
           | that you leave out the bits that you don't think will stick,
           | and even what is left over becomes a game of telephone.
           | 
           | At the time, puehr was about to have a little resurgence but
           | was pretty obscure in the west. I'm not sure which of us
           | redacted that from the brief timeline.
           | 
           | I like a little puehr once in a while. It tastes like leaf
           | mould smells, which is probably not far off from reality.
           | 
           | Edit: some imported tea is still delivered in compressed
           | bricks, green, black and oolong. Among those are teas that
           | are treated like scotch. and I have seen but not tasted a 25
           | year old tea brick (which I think she kept in part for
           | bragging rights. IIRC it was not for sale.) I already have a
           | Scotch habit, I don't need to be buying 18 year old tea on
           | top of it, so as curious as I was I made no attempts to get
           | involved in any private tea tastings.
        
             | almog wrote:
             | Agreed. AFAIK it was created as a method to transport tea
             | efficiently all across the Tang empire (and as a mean to
             | keep the peace within it) while not crushing the leaves. I
             | have no idea about what kind of tea made it to the west
             | back then. Even today most western people aren't aware of
             | the variety of teas there are out there or how wildly
             | different the final product is depending on the processing
             | methods, let alone bush cultivar, age, flush stage,
             | altitude etc.
             | 
             | Pu-erh really can be weird, Hei-Cha even weirder I think.
             | It took my quite a while to like pu-erh and if it wasn't
             | for its aesthetics I'm not sure I'd have bothered to try
             | that much. For my palate, Shou pu-erh teas were an easier
             | taste to acquire. It took me a lot of trial and error to
             | get my palate around Shengs but now I like it well enough
             | to get the same kind of craving I get for a good coffee.
        
               | SamoyedFurFluff wrote:
               | I actually find Sheng more palatable than shou. Shou is
               | too smooth for me. I need a tea with fragrance and
               | brightness.
        
         | mips_avatar wrote:
         | The term black tea is ambiguous because it refers to different
         | things depending on where you are/who you are talking to. In
         | the west, black tea generally refers to a fully oxidized
         | (autolysis) red tea that has not been fermented. However, in
         | other parts of the world black tea refers to fermented puerh.
         | How the puerh is fermented depends on whether it is wet or dry
         | processed (shu vs sheng) but fermentation is an important part
         | of both processes.
        
           | LAC-Tech wrote:
           | I remember in Taiwan I was confused the tea I called "black"
           | they called "red" (Hong Cha )
           | 
           | But then I google that and there are some seriously red
           | looking teas out there.
        
         | R0b0t1 wrote:
         | You sure on the oxalic acid aspect? I could see it maybe for
         | bugs, but I figured the crystals would be too tiny. Oxalic acid
         | causes kidney problems in larger organisms because it is hard
         | to process. I suppose its crystal formation and poor solubility
         | are linked here.
        
       | blacksmith_tb wrote:
       | This is a pretty thorough intro to (mostly) Chinese tea, which
       | seems fair to me since tea originated in China. Though I can see
       | a few details to quibble over (e.g., some Taiwanese oolongs are
       | barely oxidized, ~5% for Baozhongs sometimes[1]). Personally as
       | much as I like white, green, and black teas, I think oolongs have
       | the most variation, since they can have a mix of the
       | characteristics of the other types. But I drink plenty of them
       | all.
       | 
       | 1: https://teadb.org/baozhong/
        
       | timonoko wrote:
       | I was sort of suffering from colored tooths (teeth?) problem.
       | Meaning every time I took selfie I suffered about 5 seconds. The
       | bloody dentist suggested monthly visits to the bloody dental
       | hygienists.
       | 
       | Strange thing happened: I was flying my kite for kite aerial
       | photography and a chinese ((or taiwanese) or japanese) tourist
       | noted my blackened teeth an told that green tea does not color.
       | And it worked ok. Even the cheapest Lidl tea works ok. I bit of
       | acquired taste, but you will learn to love it.
        
         | mgkimsal wrote:
         | pfft.... what do the Chinese know about tea? ;)
        
           | timonoko wrote:
           | Shudup son. There is a very special connection between China
           | Tea and Finland: https://www.youtube.com/watch?v=hlMYrblsZp4
           | 
           | I have tasted genuine Silver Needles but was not impressed.
        
         | odiroot wrote:
         | > I was flying my kite for kite aerial photography and a
         | chinese ((or taiwanese) or japanese) tourist noted my blackened
         | teeth an told that green tea does not color. And it worked ok.
         | 
         | I think black (red) tea is very much worth it. I just couldn't
         | do without at least a single cup a day. I do brush my teeth
         | afterwards though.
        
           | dgarrett wrote:
           | I've been told by a dentist specifically not to brush your
           | teeth after tea. Instead, swish your mouth with water and
           | brush your teeth later.
           | 
           | The claim is that the acidity of the tea will soften your
           | teeth and lead to damage from the brushing.
        
       | aradox66 wrote:
       | The website is new, but this business also runs one of my
       | favorite brick and mortar tea shops! It's in the Oakland hills.
       | 
       | They pile up the steaming leaves from every cup they brew and the
       | shop fills with the earthy caramel aroma of good tea.
        
         | dijondreams wrote:
         | ditto, one of the best stores i know of
        
         | jeffbee wrote:
         | It's going to be even better with the new plaza on Antioch.
        
         | andjd wrote:
         | May just be the prices on their website, but they strike me as
         | being quite expensive. They also use anglicized names with very
         | little information about the tea, so it's hard to know what
         | you're buying.
        
           | dijondreams wrote:
           | yeah it's definitely expensive but that's mainly because they
           | go to China every year to each farm to find the best teas.
           | they will go into depth on each and every one if you inquire
        
       | [deleted]
        
       | hammock wrote:
       | Most things that are black are oxidized
        
       | lambic wrote:
       | Can anyone explain this sentence: "Because tannins weigh more
       | than catechins, they do not taste bitter."
        
         | cmogni1 wrote:
         | Higher weight polyphenols tend to taste less bitter than lower
         | weight ones. Its more correlation than causation because I
         | don't think we precisely know why this is.
        
           | hinkley wrote:
           | I wonder if they're talking about the blurred lines between
           | taste and smell. Most of what we 'taste' is happening in our
           | nose.
           | 
           | Turns out the French and Italians with all of their fancy
           | wine glasses for different kinds of wine are not insane.
           | Glass shape effects the timing of scent versus taste, and so
           | lighter wines have a narrower glass to shorten the time. The
           | heavier the red the wider the glass.
        
       | prophesi wrote:
       | "Contrary to popular belief, Red teas like Darjeeling actually
       | have less caffeine than White or Green teas because they are so
       | highly processed."
       | 
       | Is this actually true? I've never heard of green tea having more
       | caffeine than red tea, besides maybe gunpowder green tea, which
       | retains more caffeine due to less breakage from being rolled up.
        
         | Bayart wrote:
         | I think lighter teas does have more caffeine per weight, but
         | they're have much shorter infusion times (with the exception of
         | Pu'er, which can go through15 infusions).
        
           | hinkley wrote:
           | I think it's some of both. I emulate my dealer (Taiwanese
           | direct importer), who intimated that she skips the strainer
           | with her green tea and just puts here whole leaf green tea
           | straight into the cup (you can only do this with whole leaf,
           | as your lip becomes the strainer and broken tea ends up in
           | your teeth). She reuses the same cup all day, topping it off
           | when it's half full. When I space and drain it (often in the
           | middle of a coding session), it still tastes and acts like
           | tea for at least the first three cups, after that it gets
           | pretty weak, until I abandon it for a good long while and
           | then discover it's gone from weak to bitter.
        
           | radicaldreamer wrote:
           | Same thing with coffee, light roasts have more extractable
           | caffeine than dark roasts.
        
           | prophesi wrote:
           | Ah that would make sense. And water temperature likely plays
           | a vital role as well. But for properly brewed green tea, it
           | will still result in less caffeine than red tea as expected.
        
         | x3iv130f wrote:
         | We really shouldn't be judging caffeine content by color.
         | 
         | Certain tea varietals like Assamica have more caffeine than
         | others.
         | 
         | Black teas are seen as high caffeine because they use Assamica
         | varietals more than other types of tea.
         | 
         | Processing tea does remove caffeine. However I wouldn't be
         | surprised if it also removed some of the neurochemicals that
         | modulate caffeines effects.
         | 
         | So your results may vary.
        
           | hinkley wrote:
           | I'm not sure it's so much removing as bioavailability. As I
           | just stated up thread, black and green tea rely on autolysis
           | - enzymes in the leaf decompose insoluble caffeine crystals
           | into a water soluble form.
           | 
           | L theanine I think may be some of both. The heating and
           | drying processes also help define what kind of tea you get,
           | and we know that some vitamins don't survive cooking all that
           | well (famously, sailors and scurvy).
        
         | hackernewds wrote:
         | Red tea from Darjeeling is in a category called CTC tea, which
         | is distinct from what you'd expect from black tea. Easy mixup
         | since they look similar, besides the packaging
        
           | prophesi wrote:
           | You can have loose leaf Darjeeling red tea as well. CTC is
           | typically for bagged tea, which is unfortunately what's most
           | popular in the USA/UK.
        
         | gwern wrote:
         | A while back I looked at a few chemistry papers on measuring
         | caffeine content in a variety of tea leaves, in the hopes of
         | finding some low-caffeine green/oolong I could drink late at
         | night. The impression I got was that there is so much variation
         | batch to batch or year to year (not to mention preparation)
         | that it largely swamps any attempt to say 'Darjeeling has less
         | caffeine than Gunpowder Green'. There may be average
         | differences but it's not too useful to know. Whether Red or
         | Green, that tea could still easily be one that will keep you up
         | if you drink it at 10PM. Ah well. (And decaffeinated teas are
         | uniformly garbage-tasting, so that's no, ahem, solution.)
        
         | WillPostForFood wrote:
         | Generalizations like this are always dicey, especially when the
         | statements are so imprecise. Is he talking about green tea vs
         | black tea leafs, or prepared green vs black tea? When he says
         | green tea, what variety?
        
         | andjd wrote:
         | My suspicion here is that black tea, especially when prepared
         | in the British style, has more caffeine per cup because it's
         | brewed to be much stronger than green teas typically are. So
         | both can be true, black tea typically has more caffeine per
         | cup, but black tea leaves have less caffeine than green tea
         | leaves when compared by weight or volume.
        
       | [deleted]
        
       | noufalibrahim wrote:
       | An interesting colour change I've noticed it when you squeeze
       | lemon into dark (almost black) tea. It lightens up a lot and
       | becomes a pale brown. I'm not sure what but there is some
       | chemical change going on there.
        
         | skibob1027 wrote:
         | "The thearubigins in brewed tea are highly coloured (red-brown)
         | molecules that change according to the acidity of the liquid
         | used.
         | 
         | If the water used for the tea infusion is relatively alkaline
         | (for example, due to limescale found in "hard" water), the
         | colour of the tea will be darker and deeper.
         | 
         | However, once an acid such as a slice of lemon or lemon juice
         | is added, tea changes colour because of an increase in acidity
         | (reduction in pH) of the beverage itself. Lemon juice is quite
         | strong as a food acid - a few drops are enough to alter the
         | theaurbigins, resulting in a dramatic change in colour.
         | Interestingly, theaflavins are not that affected by the change
         | in acidity, and still retain their normal dark red colour."
         | 
         | Source: https://theconversation.com/ive-always-wondered-why-
         | does-lem...
        
       | Teracotage wrote:
       | How about manipulating Oxidation of your tea cup? I add a squeeze
       | of lemon and the tea lightens up in color, and it lasts longer
       | before it tastes stale. In addition to lemon, I would add either
       | cardamom,or cinnamon, or event mint leaves, and the over-
       | oxidation that would make my cup of tea go stale will be delayed.
       | I am that lazy tea drinker who is OD'ing on tea/j.
        
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       (page generated 2022-03-15 23:01 UTC)