[HN Gopher] Depleted carbon isotope compositions observed at Gal...
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       Depleted carbon isotope compositions observed at Gale crater, Mars
        
       Author : areoform
       Score  : 46 points
       Date   : 2022-01-21 14:28 UTC (8 hours ago)
        
 (HTM) web link (www.pnas.org)
 (TXT) w3m dump (www.pnas.org)
        
       | tectonic wrote:
       | TL/DR: A paper reports (appropriately conservatively) on
       | tantalizing evidence from Gale crater. Curiosity's SAM lab heated
       | 24 powdered rock samples to 850 degC, releasing their solid
       | carbon as methane gas. The onboard Tunable Laser Spectrometer
       | then measured the carbon isotopes in that gas and found more 12C
       | than would be expected based on the 12C to 13C ratio in the
       | modern Martian atmosphere. On Earth, life preferentially uses 12C
       | over the heavier 13C, bioaccumulating it, so we observe
       | significantly more 12C than 13C in ancient rocks where life grew.
       | Did ancient Martian microbial methanogenesis concentrate this
       | isotope at Gale crater as it built up complex organic molecules?
       | Maybe. Two other hypotheses offer abiotic explanations: one
       | suggests that UV light could have caused CO2 in the Martian
       | atmosphere to form isotopically enriched carbon monoxide
       | molecules that settled to the surface, the other wonders if the
       | isotopes arrived from space when our solar system drifted through
       | a 13C-depleted giant molecular cloud hundreds of millions of
       | years ago. "On Earth, processes that would produce the carbon
       | signal we're detecting on Mars are biological,"[1] but we don't
       | understand the Martian carbon cycle well enough yet to have any
       | real confidence. As with all tantalizing results about microbial
       | extraterrestrial life so far, this will probably turn out to be
       | due to a physicochemical process we don't yet understand. Or
       | maybe not.
       | 
       | I'll be covering this more in the next issue of Orbital Index
       | (https://orbitalindex.com/).
       | 
       | [1] https://www.nasa.gov/feature/goddard/2022/nasa-s-
       | curiosity-r...
        
         | thatcherc wrote:
         | > On Earth, life preferentially uses 12C over the heavier 13C,
         | bioaccumulating it, so we observe significantly more 12C than
         | 13C in ancient rocks where life grew.
         | 
         | If (like me) you're wondering why life prefers to use carbon-12
         | over carbon-13, it appears to be because carbon-12 is simple
         | lighter and thus more likely to diffuse into an organism:
         | 
         | From [1]: _Due to differential uptake in plants as well as
         | marine carbonates of 13C, it is possible to use these isotopic
         | signatures in earth science. Biological processes
         | preferentially take up the lower mass isotope through kinetic
         | fractionation._
         | 
         | NOAA has a bit more detail on the diffusion of carbon isotopes
         | into organism [2].
         | 
         | [1] - https://en.wikipedia.org/wiki/Carbon-13#Uses_in_science
         | 
         | [2] - https://gml.noaa.gov/outreach/isotopes/stable.html
        
           | nousermane wrote:
           | From [1] above:
           | 
           | > atmospheric, [marine] carbonate, and plant derived d13C
           | values all differ.
           | 
           | So, there is a mineral process that can explain change in
           | isotope ratio, which requires water. And also a biological
           | process with the same outcome, also requiring water.
           | 
           | In other words, this looks like a solid new piece of evidence
           | in support of presence of liquid water on Mars in the past.
           | Evidence of life though? That is less certain.
        
         | mrfusion wrote:
         | Is heating rocks a method of producing methane on Mars?
         | 
         | How does that work?
        
         | petschge wrote:
         | Note that the atmosphere is more likely to loose 12C over time
         | than 13C. (It's the lighter molecule and will have larger
         | speeds at equal temperatures, making Jeans escape more likely).
         | The paper itself says "the d13C composition of the atmosphere
         | may have been less 13C enriched when Gale crater sediments were
         | deposited" (compared to now). I am not sure how they exclude
         | that as an explanation why deposits are more 12C rich then the
         | atmosphere is now.
        
           | tectonic wrote:
           | That's a really interesting point. I'd like to know the
           | answer.
        
         | julienchastang wrote:
         | > but we don't understand the Martian carbon cycle well enough
         | yet to have any real confidence. As with all tantalizing
         | results about microbial extraterrestrial life so far, this will
         | probably turn out to be due to a physicochemical process we
         | don't yet understand. Or maybe not.
         | 
         | That's right. I think NASA has learned its lessons from the
         | original Viking missions that initially offered tantalizing
         | evidence of biological chemistry only to turn out that there
         | are non-biological explanations for the data. The lesson there
         | is you have to understand the inorganic chemistry of Martian
         | geology before going further in the search for biosignatures.
        
         | areoform wrote:
         | To add to Tectonic's amazing comment. There's another reason
         | why this is an extremely important find. The 12C concentration
         | exists in a gradient.
         | 
         | I can't say who this person is, but they're a senior scientist
         | involved with the project. They pointed out something profound
         | based on the history of the crater. water came over the rim of
         | the crater and it slowly evaporated, down to the bottom, until
         | it evaporated completely.
         | 
         | If there was life there, then it followed this water all the
         | way down, before its eventual death (?) due to dehydration. And
         | the signatures match that hypothesis! The most anomalous
         | signatures are the ones from the samples taken at the bottom of
         | the crater.
         | 
         | What's even more exciting is that the other two phenomena that
         | are used as examples would have left a wider distribution. The
         | specific pattern in which the signatures were found are even
         | more suggestive of life, but all other hypotheses need to be
         | eliminated first.
         | 
         | -
         | 
         | If it is indeed life, this changes everything. I have been in
         | favor of orbitals for space settlement for a long time, and
         | this reinforces my beliefs. We might have to declare Mars to be
         | the solar system's largest natural preserve and outlaw human
         | settlement (other than Mars bases for research into this life).
         | 
         | We will carry our microbiome to Mars, and any large scale
         | settlement will have inevitable leakage of our microbiome to
         | the subsurface layers of Mars, causing the microbes we have to
         | out-compete (and perhaps mingle?) the life that exists on Mars.
         | (if it exists)
         | 
         | At the very least, making a settlement on Mars should be put on
         | hold until we have had a definitive detection and have found
         | the native Martians.
         | 
         | This is one of the most important scientific finds in human
         | history.
        
           | d883kd8 wrote:
           | Why do you assume Earth microbes would outcompete martian
           | microbes in their native environment?
        
             | areoform wrote:
             | Because Mars isn't carpeted with life. It is generally
             | thought that if life does indeed exist on Mars, it's likely
             | to be at the poles, in the ice, and/or under the surface
             | where most of the water is.
             | 
             | Life on Earth, on the other hand, carpets the Earth and is
             | almost impossible to completely kill. For example, most
             | space probes are sterilized for forward planetary
             | protection, but they can't be completely sterilized, so
             | they're instead sterilized to different standards. Here's
             | the standard under COSPAR for Mars,
             | 
             | > then the entire landed system shall be sterilized to the
             | following levels: a surface biological burden level of 30
             | spores (see 5.3.2.4) and a total (surface, mated, and
             | encapsulated) bioburden level of 1.5x10^-4 spores (see
             | 5.3.2.4).
             | 
             | 5.3.2.4 states,
             | 
             | > 5.3.2.4 The 30 spore figure takes into account the
             | occurrence of hardy organisms with respect to the
             | sterilization modality. This specification assumes
             | attainment of PP Category IVa surface cleanliness, followed
             | by at least a four order-of-magnitude reduction in viable
             | organisms. Verification of bioburden level is based on
             | presterilization bioburden assessment and knowledge of
             | reduction factor for the sterilization modality.
             | 
             | Life on Earth has survived, amongst other things,
             | - On the outside of spacecraft, for several years.
             | - Beyond the photosphere in places like geothermal vents or
             | the movile cave, https://en.wikipedia.org/wiki/Movile_Cave
             | - Hyperacidic and hypersaline lakes         - In volcanoes
             | - Anoxic lakes
             | 
             | Given that there are - almost certainly - more varieties of
             | life in more niches on Earth, and that these species often
             | co-exist with humans. If any large-scale settlement of Mars
             | occur, then human by-products like sewage, and other by-
             | products produced through agriculture, are likely to cause
             | sub-surface contamination. All it takes is one place for
             | the microbe laden water to seep through into the subsurface
             | water of Mars, and we may end up killing off life on Mars.
             | 
             | More specifically, the worry isn't that they interact with
             | each other, but that our life will out compete the martians
             | for the same resources.
             | 
             | Backwards contamination is less of a concern, at least
             | right now, as we may not be that biocompatible and it is
             | extremely unlikely that the Martians will have the right
             | proteins etc to get past our cell membranes and make us
             | sick. The most plausible disease scenario is the one
             | discussed in the Expanse, where an alien organism finds its
             | way into the vitreous humor of the eyes and starts growing
             | there, causing blindness.
        
             | AnimalMuppet wrote:
             | Yeah. More, why do you assume that martian microbes would
             | not kill _us_?
             | 
             | We don't just need quarantine to protect life on Mars. We
             | need quarantine to protect life on Earth.
             | 
             | (Presuming that this actually _is_ life, which, despite the
             | tantalizing hints, is still a presumption...)
        
               | echelon wrote:
               | >> Why do you assume Earth microbes would outcompete
               | martian microbes in their native environment?
               | 
               | > Yeah. More, why do you assume that martian microbes
               | would not kill us?
               | 
               | While we can't conclusively argue one way or the other, I
               | wager that life on Earth has probably been subjected to a
               | wider range of states than life on Mars. Our life has
               | explored evolutionary state space from geothermal,
               | oceanic, and hundreds of terrestrial environments. Our
               | microorganisms fiercely compete, and if one of them finds
               | a new optima, the ecosystem adjusts.
               | 
               | While there could be some higher metabolomic maxima that
               | life on Mars discovered, I'd wager it is statistically
               | less likely.
               | 
               | An interesting way this thesis might be compromised
               | however is if alien life uses an altogether different and
               | (probably simpler) biochemistry. All life on Earth sits
               | atop a remarkably uniform platform. Maybe alien life
               | won't pay the same expenses for maintenance of cells and
               | information, and they could compete metabolically in that
               | sense.
        
               | AnimalMuppet wrote:
               | > I'd wager it is statistically less likely.
               | 
               | Yeah... let's _not_ wager _the entire human race_ on
               | "statistically less likely, OK?
        
               | echelon wrote:
               | We've done it several times in the past.
               | 
               | https://en.wikipedia.org/wiki/Safety_of_high-
               | energy_particle...
               | 
               | https://www.insidescience.org/manhattan-project-
               | legacy/atmos...
        
       | ms512 wrote:
       | Recent HN post of a science.org article on this topic:
       | https://news.ycombinator.com/item?id=29972342
        
       | plutonorm wrote:
       | The evidence for extant microbial life on mars is getting pretty
       | solid at this point.
       | 
       | Seasonal methane. Seasonal oxygen. Viking label release
       | experiments. Now accumulation of C12.
       | 
       | At some point someone has to call it.
       | 
       | I'll take my down votes, but I'll wager I've thought about this
       | longer and more carefully than most. I urge you to think
       | critically about this.
        
         | q1w2 wrote:
         | I think the "point someone calls it" will be when we see images
         | of them under a microscope.
         | 
         | Is the theory that they are too deep under ground for a rover
         | to dig up and look at?
        
           | kadoban wrote:
           | Images under a microscope may not do it. They could be
           | contamination from Earth either at time of test or before
           | that.
        
             | hyperbovine wrote:
             | Genetic analysis to the rescue. It will be glaringly
             | obvious whether billions of years of divergent evolution
             | have occurred or not.
        
         | AnIdiotOnTheNet wrote:
         | Given the milestone that the discovery of extraterrestrial life
         | represents, I would expect nothing short of actually seeing a
         | martian microbe that is provably not a hitchhiker from earth
         | before anyone credible "calls it".
        
           | plutonorm wrote:
           | You may be correct, but there is also a huge taboo here and
           | it's damaging to the pursuit of truth.
        
             | biorach wrote:
             | There is not a taboo. There is a very very high standard of
             | proof required, rightly so because of the sensational
             | nature of the subject.
        
             | AnimalMuppet wrote:
             | How damaging is it to not call it until there's _proof_?
             | 
             | How damaging would it be to call it and later have to
             | retract it?
             | 
             | Seems to me it's better to wait for definitive proof than
             | to go without it.
        
             | s1artibartfast wrote:
             | What is wrong with saying that it is increasingly likely
             | that there is life on mars and waiting to call it until we
             | see it.
             | 
             | Whats the rush and who is it hurting?
        
         | yupper32 wrote:
         | Meh. It's not like there are immediate action items if they
         | just call it and say "there was life on Mars". Might as well
         | take their time and be as sure as they can.
        
           | kadoban wrote:
           | It may change research priorities if we knew/admitted that
           | life used to exist. If there _was_ life, we should search
           | harder and see if it still exists and if we can find it. We
           | could learn a lot of really exciting things from a
           | potentially alien set of living things.
           | 
           | As I understand it, we're really not looking that closely for
           | life at the moment.
        
             | yupper32 wrote:
             | > As I understand it, we're really not looking that closely
             | for life at the moment.
             | 
             | ???
             | 
             | Perseverance:
             | https://mars.nasa.gov/mars2020/mission/overview/
             | 
             | Two out of the four science objectives:
             | 
             | - Looking for habitability: identify past environments that
             | were capable of supporting microbial life.
             | 
             | - Seeking biosignatures: seek signs of possible past
             | microbial life in those habitable environments,
             | particularly in specific rock types known to preserve signs
             | over time.
             | 
             | Curiosity:
             | https://mars.nasa.gov/msl/mission/science/objectives/
             | 
             | Three of the eight science objectives:
             | 
             | - Determine the nature and inventory of organic carbon
             | compounds
             | 
             | - Inventory the chemical building blocks of life (carbon,
             | hydrogen, nitrogen, oxygen, phosphorous, and sulfur)
             | 
             | - Identify features that may represent the effects of
             | biological processes
        
               | kadoban wrote:
               | That's, as I understand it, looking for markers that
               | _may_ mean there was, at any point in the past, life. I
               | think you'd look other places, and use other instruments
               | if you're looking for actual, current, life.
        
               | Scarblac wrote:
               | Like where?
        
               | kadoban wrote:
               | South pole would be my bet.
        
         | nescioquid wrote:
         | As a very casual observer who hasn't thought long and carefully
         | on this topic, it seems we've been looking for life on mars
         | since the 70's with nothing conclusive having been found (not
         | that we've applied exhaustive efforts over the last 50 years).
         | 
         | > At some point someone has to call it.
         | 
         | With humility, why would that point be anywhere prior to
         | actually finding a Martian organism? I recall people seemed
         | willing to "call it" after President Clinton's remarks on rock
         | 84001, and so on.
         | 
         | Genuinely curious if there is some criteria to conclusively
         | show past/present life on Mars in the absence of the discovery
         | of an organism. I'm thinking also of the headline-grabbing
         | announcement of biological processes on Venus owing to
         | phosphine observations.
        
           | plutonorm wrote:
           | If you are genuinely asking - there has not been a concerted
           | effort to find extant life on mars. Missions since the viking
           | era have been strictly geological in nature. As so often
           | happens in science, certain theories become taboo. Martian
           | life was one of these and as a result the targeting of the
           | missions became ultra focused on geology. It is only as the
           | sophistication of instrumentation has improved that these
           | signs have emerged as incidental observations outside of a
           | targeted search for life.
           | 
           | By saying "call it", I am fighting against the prevailing
           | taboo of seriously considering and acknowledging the
           | possibility of life on mars.
           | 
           | As regards phosphine in Venus's atmosphere, the jury is most
           | definitely still out on that one.
        
             | nescioquid wrote:
             | Thanks, I was genuinely asking and I see I misunderstood
             | what you were saying. I hadn't realized that looking for
             | Martian life was scientifically taboo, though I vaguely
             | recall seeing something about funding sources being
             | skittish about it at some point (maybe that's tantamount to
             | the same thing).
             | 
             | At any rate, I agree this shouldn't be closed to inquiry,
             | though I imagine there's close competition for which
             | experiments and observations to run on Mars. If that's
             | true, does that amount to a taboo or does it just indicate
             | that other lines of investigation have a higher expected
             | utility? Or perhaps you are just saying that at this point,
             | you feel there is enough evidence to warrant a more full-
             | bodied investigation?
             | 
             | Again, genuinely interested.
        
             | areoform wrote:
             | Knowing people at NASA, this hasn't been the case in my
             | life-time. Most of the flagship rover missions have been
             | designed _principally_ to find evidence of water and life
             | on Mars. Those  "geological" missions have been dedicated
             | to finding the evidence of water (something that has been
             | done in my lifetime. https://en.wikipedia.org/wiki/Scientif
             | ic_information_from_th...
             | 
             | Once detection was confirmed, the mission brief for
             | Curiosity and Perseverance has evolved to finding life. One
             | of the largest science initiatives at NASA right now
             | revolves around sample return to perform a more exhaustive
             | search for Martian life using Earthen laboratories.
             | https://www.nasa.gov/press-release/nasa-moves-forward-
             | with-c...
             | 
             | I have had the good fortune to get to know some of the
             | senior scientific leadership at NASA. I can confidently
             | say, based on their budget and talking to them, that
             | detection of life in the solar system and other planets is
             | the #1 scientific priority at NASA.
        
           | [deleted]
        
         | Beltiras wrote:
         | I don't think you deserve downvotes, but your appeal to an
         | authority (yourself), is not very convincing on it's own.
        
           | queuebert wrote:
           | What if he's a Martian in disguise?
        
             | djmips wrote:
             | Reddit's calling you.
        
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