[HN Gopher] Gallium helps convert CO2 into Carbon and Oxygen
       ___________________________________________________________________
        
       Gallium helps convert CO2 into Carbon and Oxygen
        
       Author : baptou12
       Score  : 234 points
       Date   : 2021-10-23 11:09 UTC (11 hours ago)
        
 (HTM) web link (www.mining.com)
 (TXT) w3m dump (www.mining.com)
        
       | ohiovr wrote:
       | Would this method be able to grow single crystal grahite crystals
       | if it were controlled tightly? A single of crystal graphite would
       | have a lot of useful properties much like silicon. Because of its
       | anisotropic strength it can be much stronger and more flexible
       | than composites. Things like turbine blades could be carved from
       | single crystal graphite.
        
       | anyfactor wrote:
       | A tangential thought.
       | 
       | Since the last crash of oil prices there was a radical move
       | toward rare earth material mining. Every minining and exploration
       | company tried look into ways to mine and find better uses of rare
       | earth minerals that would generate the same pre-crash oli and gas
       | profits.
       | 
       | But reviewing half a decades stock research or DD of these newly
       | pivoted mining companies I find nothing to be radical and it is
       | often the same repackaged environmental well being rhetoric from
       | the industry.
       | 
       | There is no pioneering business, leader or technology in rare
       | earth mining. And I am often very skeptical of mining industry
       | talking about positive environmental consequences of mining.
       | 
       | Even though we are divided on Musk's contribution in revolution
       | in EV industry but he didn't push an environmental agenda IMO but
       | he pushed for providing better consumer utility while minimzing
       | negative environmental consequences. If rare earth industry as a
       | whole quite non-inuitivetly provide or promise of enhanced
       | utility (in the economic sense) without mentioning positive
       | environmental consequences as a headline then I will believe.
        
       | amts wrote:
       | Can I get funded if I'd compile an R&D program aiming to achieve
       | ~60% or more efficiency, but without gallium or silver?
        
       | Waterluvian wrote:
       | I'm not sure: is the Gallium a catalyst?
        
         | Lev1a wrote:
         | And if so, could it be replaced by orgnano-catalysts which were
         | in the news recently? I only had chemistry in school but maybe
         | it's even as simple as using parts from the chemistry involved
         | in photosynthesis?
        
           | valw wrote:
           | Folks, just to clarify: "catalyst" is a very broad chemistry
           | term for "something that helps a chemical reaction take place
           | without being a reagent nor product of said reaction." So
           | don't get the wrong idea: catalysts have quite specific uses,
           | and you cannot substitute any one catalyst for any other.
        
             | Waterluvian wrote:
             | Yes. Thanks for that clarification. What I meant in my
             | original question is if we consume huge amounts of gallium
             | to do this. Ie. can it scale?
        
               | adrian_b wrote:
               | It depends a lot on which will be the lifetime of the
               | catalyst at industrial scales.
               | 
               | Gallium is one of the most expensive metals, not because
               | it is very rare, but because it is very diluted. There
               | are no minerals with a high concentration of gallium,
               | enough to make their commercial exploitation worthwhile.
               | 
               | There are no mines of gallium. Gallium is always
               | extracted as a secondary product in mining operations
               | where either aluminum or zinc is the main product.
               | 
               | Because of that, the available quantity of gallium
               | depends on the volume of the productions of aluminum and
               | of zinc, and it follows their yearly oscillations.
        
         | adrian_b wrote:
         | The process described in the paper uses both gallium and silver
         | as catalysts.
         | 
         | The advantage of using gallium is that it is in liquid form.
         | When the gallium is regenerated after catalyzing one cycle of
         | the reaction, it mixes again with the liquid gallium.
         | 
         | Being liquid ensures a long life for the catalyst. Solid
         | catalysts are never recovered perfectly after taking part in
         | the reaction and then being again deposited on their support,
         | so they degrade much faster.
         | 
         | The mechanism of solid catalyst degradation is similar to that
         | which limits the life of a rechargeable battery with solid
         | electrodes.
        
       | javier_cardona wrote:
       | A preprint of the paper mentioned in the post is available here:
       | https://www.researchgate.net/publication/347609399_Mechanica...
        
         | GistNoesis wrote:
         | The following link has the additional supplementary images
         | missing from your link
         | https://www.researchsquare.com/article/rs-112257/v1
         | 
         | I quickly skimmed it but the protocol on page 13 seems simple,
         | the chemicals involved are relatively low risk (verify the
         | MSDS).
         | 
         | Mix some gallium metal with a powder of a Silver salt in a
         | mortar and pestle, put it in a solvent, stir it with a magnetic
         | stirrer, while bubbling CO2, in a N2 atmosphere, and carbon
         | snowflakes should float to the top in a few hours.
         | 
         | Maybe some chemist can help make it into a safe for all kid
         | science-fair project.
        
       | mrfusion wrote:
       | I'm actually interested in using this for terraforming Venus.
       | We've got plenty of energy from sunlight and very concentrated
       | co2. To keep them at the right temperature We could build
       | floating blimps with these machines on board.
        
         | lend000 wrote:
         | I wish there was more data on the reaction mechanism. It's
         | unclear which way the equilibrium would shift at the high
         | temperatures present on Venus, or if the solvent is an
         | important part of the reaction/would be in liquid form on Venus
         | (most solvents would not). But I agree that would be an awesome
         | application.
        
           | mrfusion wrote:
           | There are certain altitudes on Venus where the temperature is
           | earth like.
        
         | taf2 wrote:
         | This would be amazing. Venus having nearly the same gravity as
         | earth gives it a big plus in terms of future colonies. The
         | other issue I believe is it's spin - meaning a normal day on
         | Venus is something like 5k hours compared to earths 24... that
         | means you cook for a lot longer on one side instead of a nice
         | even toasting like we have here on earth... still I like your
         | idea because gravity is probably one of the bigger factors of
         | creating a future nice home...
        
           | mrfusion wrote:
           | The long days are a tough cookie for sure. I wonder if we
           | could make a planet scale Hvac system to pump the heat to the
           | cold side.
        
       | gonational wrote:
       | A noble discovery...
       | 
       | However, even if this was an economically viable solution to the
       | perceived problem of CO2 in the atmosphere, this doesn't help
       | with the goal of setting up a global government and global tax,
       | so it would be ignored.
       | 
       | Anthropogenic global warming, as a studied issue, is not about
       | solving the world's problems; it's about setting up a global
       | government with a global tax. It always has been; it hasn't even
       | pretended to be anything else. The motivations have always been
       | ostensibly about solving global warming, but the plans have
       | always been very public; set up a global tax and a global
       | government to implement this tax. That could not be more clear.
       | 
       | Ask yourself, if you were planning on taxing the entire planet,
       | even if it was only .1% of their GDP (~80 billion), would you
       | rather have that money or have some random scientist discover the
       | solution to the problem that leads to you getting 80 billion
       | dollars?
        
       | aychedee wrote:
       | So, for $4.3 trillion dollars / year we can turn the 43 billion
       | tonnes of CO2 we emit per year into oxygen and carbon crust.
       | Which is twice the annual revenue for the global oil industry.
        
         | maxerickson wrote:
         | That would make it pretty feasible. A 25% reduction in
         | consumption (if the activity were purely subtractive from the
         | economy, which it probably wouldn't be) is manageable.
        
         | ClumsyPilot wrote:
         | "Which is twice the annual revenue for the global oil
         | industry."
         | 
         | That means that for every $1 the oil industry makes, it is
         | creating $2 of debt for future generations.
         | 
         | This is vandalism, pure and simple
        
         | zz865 wrote:
         | Yeah we could turn CO2 into coal or we could just stop burning
         | coal in the first place.
        
         | franky47 wrote:
         | That is assuming it takes less than a year to convert all that
         | amount. At the given rate of .1 liter/minute, you'd need a lot
         | of those installations or quite the scale-up.
        
         | ericd wrote:
         | Well, don't forget the cost to concentrate CO2 from 440 ppm in
         | the atmosphere to 10^6 ppm. The current cost of direct air
         | capture that I've seen is about $600-$1000/ton (via
         | Climeworks).
         | 
         | Capturing CO2 from flue gas at power plants should be a good
         | bit cheaper, but I think it's still significant.
        
         | xwdv wrote:
         | Any financing options?
        
         | pjc50 wrote:
         | That sounds about right, that it costs more to ameliorate the
         | problem than can be earned by causing it.
        
       | jarenmf wrote:
       | > 92% efficiency in converting a tonne of CO2, using just 230kWh
       | of energy. They estimate this equates to a cost of around $100
       | per tonne of CO2.
       | 
       | Not sure if this is really competitive enough. Just read
       | recently[1][2] that EEMPA based solution can capture at a cost of
       | $47
       | 
       | [1]
       | http://netl.doe.gov/projects/files/CostAndPerformanceBaselin...
       | [2] https://scitechdaily.com/cheaper-carbon-capture-is-on-the-
       | wa...
        
         | harg wrote:
         | But if you get a load of solid carbon as a byproduct that could
         | offset a lot of the energy cost, assuming the solid carbon is
         | in a useful form.
        
         | WithinReason wrote:
         | Assuming 16 tons per person per year emissions [0], you can
         | offset 1 person's carbon footprint for $1600 per year.
         | 
         | [0]: https://astralcodexten.substack.com/p/carbon-costs-
         | quantifie...
        
           | flexie wrote:
           | Every American uses around 400 gallons of gasoline and 12,000
           | kwh electricity per year. So if you put a tax of $2 on each
           | gallon of gasoline and 7 cent on every kwh electricity, you
           | would finance that.
           | 
           | And once it scales, it will be cheaper and cheaper, jut like
           | most other products. With a 10 percent price reduction per
           | year, it would be $620 per person in 10 years, roughly the
           | same as an internet bill.
           | 
           | In the rest of the world it's even cheaper. The average
           | person in the world could be offset for $400 now.
        
         | marcosdumay wrote:
         | Hum... You are comparing a process that separates CO2 from a
         | gas with a process that chemically breaks CO2. Those things do
         | not compare.
        
           | WJW wrote:
           | That depends on what you are trying to achieve? Sure, the
           | captured CO2 is still CO2, but you can put it in an empty gas
           | field somewhere and the net effect on atmospheric CO2 (which
           | is what we are concerned about with regards to climate
           | change) is the same as if you had split apart the molecules.
        
             | adrian_b wrote:
             | The process described in the paper can be used only after
             | CO2 is separated from the air, not instead of it.
             | 
             | Nevertheless converting CO2 into a solid reduces the volume
             | one thousand times and makes its storage very simple.
             | 
             | I doubt that there could be found enough subterranean
             | spaces that can be sealed well enough, in which to pump as
             | much CO2 as it would be needed to reduce the concentration
             | in the air.
        
             | marcosdumay wrote:
             | Yes, and as long as you can store it somewhere, all the
             | power to you. Just ignore the chemical option and do that.
             | 
             | But anybody wanting to use the carbon or store it on any
             | way that is not the limited amount of underground space
             | will use both.
        
       | [deleted]
        
       | garyclarke27 wrote:
       | Buy Silver
        
       | s_Hogg wrote:
       | How much of the cost is the energy? Would hooking it up to a wind
       | turbine help?
        
         | wcoenen wrote:
         | The article says 230 kWh per ton of CO2, so you can just
         | multiply that by a cost per kWh, e.g. 0.07 $/kWh for industry
         | in the US.
         | 
         | 230 * 0.07 = 16.1 dollars.
         | 
         | So that suggests that most of the cost is not energy.
        
       | neom wrote:
       | I would be remiss not to post the amazing LockPickingLawyer
       | videos using Gallium to pwn locks:
       | 
       | https://www.youtube.com/c/lockpickinglawyer/search?query=Gal...
        
       | cletus wrote:
       | So let's do some math. Let's consider natural gas. According to
       | the US government [1], natural gas produced 1.358x10^12 kWh of
       | power and 5.6x10^8 metric tons of CO2 so 1 metric ton of CO2
       | equates to ~2400 kWh of produced power.
       | 
       | This post suggests the energy cost is ~230kWh/ton.
       | 
       | This is an important sanity check because it means that (capital
       | costs aside) and if it scales you could technically remain carbon
       | neutral for a net output of energy.
       | 
       | While this is of course only in a lab and they mention "battery"
       | one should remain skeptical (since pretty much every battery
       | "breakthrough" is nothing more than marketing for research
       | funding).
       | 
       | This may be in the paper but in this summary I didn't see
       | anything about how the CO2 needs to be delivered. Does it need to
       | be in a relatively pure form? What sort of preprocessing is
       | required?
       | 
       | As for the capital costs, it's hard to say anything concrete here
       | other than if silver and Gallium are catalysts, they're both
       | relatively cheap at that scale (Gallium seems to be <$250/kg
       | according to some quick Googling). Catalysts tend to have a
       | lifespan so those aren't one-time costs generally but still.
       | 
       | It's also not clear how much of each material is required.
       | 
       | Not to be a broken record on HN, but I've often said--and I'll
       | repeat here--that I don't believe altruism will solve greenhouse
       | gas emissions and global warming: it'll only be solved when it
       | becomes economic to do so.
       | 
       | Another way of putting that is when the cost of carbon capture
       | and/or non-greenhouse gas emitting energy sources is profitable,
       | that's when you'll see change.
       | 
       | [1]: https://www.eia.gov/tools/faqs/faq.php?id=74&t=11
        
         | adrian_b wrote:
         | "how the CO2 needs to be delivered":
         | 
         | The experiments described in the paper have used pure CO2. The
         | conversion process is unlikely to work directly with air,
         | because it decomposes CO2 into solid carbon partially oxidated
         | and dioxygen.
         | 
         | If one of the products of the catalyzed reaction, i.e. oxygen
         | from the air, would be present in a much larger concentration
         | than the input substance (CO2), like in the air, the conversion
         | reaction will either stop completely or it will be at least
         | slowed down a lot.
         | 
         | So besides the costs for the energy and for renewing the silver
         | and gallium from time to time and also for the organic solvents
         | that might also need to be replaced from time to time, the cost
         | of separating CO2 from the air must be added.
         | 
         | Nevertheless, it might still eventually be cheaper than
         | alternative methods, as most of them also need to first
         | separate the CO2 from the air.
         | 
         | In any case, much more research is needed to scale this from
         | experiments in minute quantities to industrial dimensions.
        
           | cletus wrote:
           | A big issue with renewable energy, particularly solar and
           | wind, is that the power output is variable and an electric
           | grid needs a base load to operate.
           | 
           | Now I firmly believe the future here is ultimately space-
           | based solar power collectors. I've seen estimates that a
           | panel in space around Earth can generate ~7 times the power
           | it can on Earth. This is a deep topic but generating power in
           | space for use on Earth isn't as crazy as it may sound.
           | 
           | Anyway, another potential application is to use variable
           | power output for useful purposes on-site. For example, you
           | can extract CO2 directly from the atmosphere and with simply
           | chemistry you can make gasoline from that. This is currently
           | cost-prohibitive so no one does it.
           | 
           | At some point this may become economic, in which case the
           | variable power output won't be an issue. You're now only
           | interested in the total output. You also don't lose power
           | from transmission or require the capital cost of transmission
           | lines.
           | 
           | Perhaps CO2 capture is another potential such application.
           | Either the CO2 could be processed on site with a process like
           | this and the byproducts (pure carbon and oxygen) can be sold.
        
             | laserbeam wrote:
             | > space-based solar power
             | 
             | Cute, but very much off topic. Lets have that discussion on
             | an article about energy generation, not about carbon
             | capture.
        
             | GordonS wrote:
             | > I've seen estimates that a panel in space around Earth
             | can generate ~7 times the power it can on Earth
             | 
             | How do you get that power back down to Earth where it can
             | be used?
        
               | chrisweekly wrote:
               | Presumably, laser beams to heat terrestrial mountains of
               | salt. What could possibly go wrong?
               | 
               | /jk
               | 
               | Seriously, I'm curious about this too.
               | 
               | Edit: a quick search shows I was close:
               | https://earthsky.org/earth/space-based-solar-energy-
               | power-ge...
        
               | ClumsyPilot wrote:
               | If you want to place solar panels in a hostile and
               | distant environment to triple their efficiency, we have
               | the Sahara Desert for that.
               | 
               | That article does not mention inefficiency of space that
               | microwave transmission, it is going to wreck that 7x
               | advantage.
               | 
               | Also lifting a solar panel from Earth will cost more
               | energy than it will ever generate You have to have cities
               | and factories in space before any solar collector could
               | even be considered.
        
             | ClumsyPilot wrote:
             | "I've seen estimates that a panel in space around Earth can
             | generate ~7 times the power it can on Earth"
             | 
             | Contrast it with the fact that that panel is 1,000x more
             | expensive, and thats a net loss. We are constrained by
             | capital cost, not lack of sunlight or anything else.
             | 
             | Also consider transmission losses, orbital solar collectors
             | must convert that power into microwaves, which are made of
             | photons, then they must be converted back into electrons on
             | earth. That inefficiency is compounded by atmospheric water
             | absorbing microwaves. (you are heating clouds) You have
             | destroyed that 7x advantage.
             | 
             | If you can place a panel in orbit and deliver power to
             | Earth, then you can put a million panels in Sahara Desert
             | and relay that power anywhere on Earth. Solar panels are
             | made of sand, we are not short on sand. If we covered 1% of
             | uninhabitable deserts in panels, thay would produce more
             | power than we could use, and it would be reliable.
        
           | kortex wrote:
           | It's possible this might work with de-oxygenated air. As long
           | as the nitrogen does not react with the generated oxygen and
           | release NOx, this could be done with an adsorption process,
           | which is a lot cheaper and less energy than full air
           | separation.
           | 
           | Even then, NOx can be mitigated. This process is fascinating
           | in that unlike most "breakthroughs" this has a semblance of a
           | chance of scaling.
        
           | photochemsyn wrote:
           | Preconcentration of CO2 from air makes a lot of sense as you
           | can then do various types of industrial chemistry on a pure
           | CO2 stream at greater efficiency. From here you can go
           | towards either methane and long-chain fuel hydrocarbons
           | (Sabatier, modified Fischer-Tropsch, etc) or, as in this
           | paper, towards solid carbon forms.
           | 
           | Making something like graphite from pure CO2 has certain
           | advantages as well (easier to get purity) and graphite
           | electrodes are used in scrap steel recycling and other
           | industries.
           | 
           | For comparison, see the ISS use of Sabatier reaction and some
           | issues they had with catalyst poisoning:
           | 
           | https://ntrs.nasa.gov/search.jsp?R=20140002591
           | 
           | This indicates that power plant emissions, typically
           | contaminated with sulfur / arsenic / mercury / nitrogen etc.
           | , at about 10% CO2 as I recall, would be a very poor option
           | relative to direct air capture.
           | 
           | As far as scaling, even existing systems (see ISS) could be
           | scaled fairly rapidly and would be able to produce enough
           | fuel for specialized uses, i.e. plausibly supplying SpaceX /
           | ULA/ etc. rocket launches as a first step, then moving to
           | supply airports with jet fuel for long-distance travel at a
           | much larger scale.
        
         | credit_guy wrote:
         | > This is an important sanity check
         | 
         | You have a bug somewhere, I'm not sure where.
         | 
         | Roughly speaking the heat of combustion is proportional to the
         | number of atoms of oxygen in the molecules coming out of the
         | reaction.
         | 
         | So CH4 + 2 O2 = CO2 + 2 H20
         | 
         | If you hypothetically split CH4 first, you get
         | 
         | CH4 + 2 O2 = (C + 2 H2) + 2 O2 = (C + O2) + (2 H2 + O2) = CO2 +
         | 2H20
         | 
         | The first reaction is endothermic, but it absorbs much less
         | heat than the heat produced by the second part of the reaction.
         | 
         | So, you can roughly say that the energy coming from burning CH4
         | comes half from burning the Carbon and half from burning the
         | Hydrogen.
         | 
         | Now, if you can make the reverse reaction CO2 -> C + O2 with
         | 100% efficiency, then sure, you get to economically burn CH4
         | with zero emissions. But if that reaction has only 50%
         | efficiency, then all your (energetic) profit has been wiped
         | out.
         | 
         | The article doesn't say what efficiency this envisioned
         | reaction has, but I'd be mightily surprised if it were 50%.
         | 
         | Much better to not burn the Carbon to begin with. That is what
         | methane pyrolysis [1] tries to do.
         | 
         | [1]
         | https://en.wikipedia.org/wiki/Pyrolysis#Methane_pyrolysis_fo...
        
           | nkingsy wrote:
           | The article clearly states a claimed 92% efficiency.
        
             | credit_guy wrote:
             | Good point. But there are two problems with that claim.
             | 
             | One is about an order a magnitude, the other about a sign.
             | 
             | The first one: if you burn 1kg of pure Carbon, you get 3.67
             | kg of CO2 and 32.8 MegaJoules [1], which is the same as
             | 32800 kJ or, 32800/3600 kWh. That's 9.11 kWh for each 3.67
             | kg of CO2, or 2.4848 kWh/kg. That's quite close to 2500
             | kWh/ton.
             | 
             | They are claiming it takes them 230 kWh/ton to reverse this
             | reaction. You can see this is an order of magnitude wrong.
             | Let's say they meant to say 2300 kWh/ton. If you divide
             | that by 2500 kWh/ton you get exactly 92% that they claim.
             | 
             | But here's the second mistake: you need to put more, not
             | less energy to split CO2, otherwise you'd get energy for
             | free. 2300 kWh/ton is simply impossible. You need to use
             | more than that, and actually more than 2500 kWh/ton if you
             | don't want to violate the first principle of
             | thermodynamics.
             | 
             | [1] https://en.wikipedia.org/wiki/Heat_of_combustion#Heat_o
             | f_com...
        
               | sacred_numbers wrote:
               | Maybe the researchers meant 230 Kwh above the reaction
               | energy of pure carbon and oxygen. That makes the math
               | check out, since 2,485/(2485+230)=91.5%, which could be
               | rounded up to 92%. It would also square up with the
               | estimated costs of $100/ton, since industrial electricity
               | prices can go as low as 0.03 to 0.04 USD.
               | 
               | I wish I could read the source to verify, but
               | unfortunately it's behind an academic publisher paywall.
        
               | alkonaut wrote:
               | > They are claiming it takes them 230 kWh/ton to reverse
               | this reaction.
               | 
               | I don't think that's a claim in the article. If the
               | carbon product was pure in the sense it could be burned
               | again then it wouldn't work out. But that's not claimed.
               | It's not reduced to carbon!
        
           | photochemsyn wrote:
           | These carbon capture and conversion technologies are far more
           | promising as a means of feeding atmospheric carbon dioxide
           | into industrial 'aerochemicals' (to replace petrochemicals)
           | and materials, than as a means of mitigating fossil fuel
           | combustion CO2 emissions.
           | 
           | Obtaining a pure stream of CO2 concentrated from 400 ppm
           | atmospheric sources is the optional approach for industrial
           | chemistry processes (and requires significant upfront energy
           | investment), but from here one can go almost anywhere, to
           | methane or jet fuel or graphite electrodes or carbon fiber
           | building materials or synthetic dyes.
           | 
           | However, it's unlikely these technologies will have much
           | effect on reducing atmospheric CO2 levels. They simply
           | eliminate the need for natural gas / petroleum / coal as raw
           | materials for synthesis of necessary products.
        
         | dr_dshiv wrote:
         | >I'll repeat here--that I don't believe altruism will solve
         | greenhouse gas emissions and global warming: it'll only be
         | solved when it becomes economic to do so.
         | 
         | Completely agree. We need governments to ensure externalities
         | (both positive and negative) are reflected in market pricing so
         | that economic forces can operate efficiently.
         | 
         | Implication: there must be a debt to pay for past and present
         | GHG output. It should not be punitive. But it should be clear
         | and predictable.
        
           | coryrc wrote:
           | > there must be a debt to pay for past ... GHG output
           | 
           | A debt which should be paid by past users, not current users
           | who merely share the same country.
        
             | adrianN wrote:
             | If step 1 in your climate plan is "resurrect the dead since
             | the industrial revolution started", I doubt it will be very
             | successful. Or am I misunderstanding you?
        
           | mcdonje wrote:
           | So, a robust carbon tax.
        
             | BurningFrog wrote:
             | That is the way.
             | 
             | It is however politically impossible in most places.
        
             | joe_the_user wrote:
             | A carbon tax is essentially going to hit the average person
             | hard. Moreover, the average person has a lot of driving
             | they have to do, tax or not. And plenty of rich people
             | could ignore the tax and keep driving.
             | 
             | And the political impact would be angry people ready to
             | listen climate deniers.
             | 
             | What's needed is a plan to eventually give everyone an
             | electric car or some choice, any choice, that lets them do
             | their daily business with much lower carbon consumption.
             | Maybe taxes can change the behavior of industrial users but
             | for consumers, this is totally daft solution.
        
               | imtringued wrote:
               | The average person is also getting hit hard by high
               | energy prices for fossil fuels regardless of tax rate.
        
               | joe_the_user wrote:
               | Yes, average person gets hit by rising energy prices.
               | Some portion of average people (especially small business
               | owners) support demagogue who artificially lowers these
               | at heavy costs. Rinse and repeat.
        
               | Maarten88 wrote:
               | > A carbon tax is essentially going to hit the average
               | person hard.
               | 
               | I think that is just an excuse to not make changes that
               | are necessary. Saying that something will hit the
               | poor/average person/working family is an argument about
               | wealth/cost distribution, which is separate from the
               | actual problem.
               | 
               | When we, as humanity, have the natural resources, the
               | technology and the labor required to do something that is
               | objectively necessary, the only thing that can stand in
               | the way is cost/wealth distribution: who gets to pay the
               | bill.
               | 
               | So when objectively necessary changes do not happen, the
               | only possible reason for that is that maintaining
               | wealth/power are more important than suffering the
               | consequences of not implementing the change.
        
               | dcow wrote:
               | Furthermore, it's not one dimensional. Society would
               | respond to a carbon tax. Maybe if your manager or
               | director really really needs a team/department on site,
               | the company would foot the bill to have you as a carbon
               | consuming commuter. We would all adjust behavior in
               | response to the tax. Things that obviously are bad for
               | the environment are now obviously bad for your wallet and
               | need to be justified. At least there aren't that many
               | wealthy people so if they want to pay the tax and fly
               | around in jets, so be it.
        
               | joe_the_user wrote:
               | _I think that is just an excuse to not make changes that
               | are necessary._
               | 
               | It's not excuse, it's a reason. It's not even the poor
               | that will push back here on gas taxes but the somewhat
               | well-off but not wealthy. These are the kind of people I
               | don't have cultural sympathy with but if you just say
               | tell them "oh, you're going to be paying a whole bunch
               | for that pickup", you may find you don't get to say that
               | after next election.
               | 
               |  _When we, as humanity, have the natural resources, the
               | technology and the labor required to do something that is
               | objectively necessary, the only thing that can stand in
               | the way is cost /wealth distribution: who gets to pay the
               | bill._
               | 
               | The US has a massively unequal distribution of wealth
               | currently. A plan to get the poor to for this problem
               | will fail 'cause they don't actually have money.
        
             | IncRnd wrote:
             | That is economic today for people who rent out the credits
             | that arise by purchasing land then not harvesting the
             | trees. That is economic today for people who claim carbon
             | credits for purchasing new equipment, where the old was at
             | EOL anyway. And so on. The existence of brokers for carbon
             | credit sales should tell you something. For real economic
             | viability that isn't scam-based, something based in reality
             | is needed.
        
               | ryukafalz wrote:
               | You're talking about carbon credits, not a carbon tax.
        
               | IncRnd wrote:
               | I read that wrong. Thanks!
        
               | anonporridge wrote:
               | I've noticed a trend of people trying to suggest we
               | already have a carbon tax via carbon credits.
               | 
               | I'm not sure if they're just confused, or trying to sow
               | misinformation.
        
               | IncRnd wrote:
               | You're inventing things out of whole cloth. I simply
               | misread.
        
           | throwaway894345 wrote:
           | It's remarkable how effectively the fossil fuel industry has
           | gotten progressive environmentalists to believe that we can
           | solve this problem without carbon tax.
           | 
           | The moment you mention how a carbon tax works (that it's a
           | _market_ mechanism) progressives recoil. When evangelizing to
           | progressives, I try to focus on "making polluters pay for the
           | damage they are doing" (as opposed to making taxpayers bail
           | us out) since they are more likely to be persuaded by appeals
           | to fairness rather than efficacy.
           | 
           | Similarly, conservatives recoil at "tax" nomenclature, so
           | when evangelizing to the , I refer to it as "carbon pricing"
           | and emphasize the economic efficiency argument.
           | 
           | In either case, we have a long way to go, politically.
        
             | throwawayboise wrote:
             | The "polluters" are you and I. We buy the cars, we buy the
             | other things, we use electricity and gas and oil in our
             | homes and cars.
             | 
             | We, the consumers, will ultimately pay any carbon taxes.
             | Which may be appropriate, but let's not be unrealistic
             | about who will be paying.
        
               | Swenrekcah wrote:
               | Not all of it. Some of the tax will have to be eaten by
               | the producers since the market will not tolerate just any
               | price. Then also the tax will make less polluting
               | alternatives more viable and thus likely reducing their
               | price in the long run.
               | 
               | And of course, we the public consumers will also benefit
               | the most from making our industries greener and cleaner.
        
               | malermeister wrote:
               | > We buy the cars
               | 
               | Speak for yourself. I haven't owned a car in my life and
               | don't plan to change that.
        
               | bagels wrote:
               | I'd be willing to bet many of your daily activities
               | (eating, using the internet, etc.) involve burning
               | hydrocarbons. It's pervasive.
        
               | mechanical_bear wrote:
               | Ok, but you certainly pollute in other ways.
        
               | eecc wrote:
               | Sure, just not that way anyway.
               | 
               | Try again.
        
               | heavyset_go wrote:
               | Prices aren't determined by costs.
        
               | [deleted]
        
           | hcurtiss wrote:
           | Who would pay that debt for past emissions, and what price
           | should they pay?
        
             | c1sc0 wrote:
             | Boomers. Everything they own.
        
               | [deleted]
        
             | coldtea wrote:
             | Let's tax at 50% every private property of a few million.
             | That would do it.
        
             | jtms wrote:
             | Nothing, forward is the only direction to move if we want
             | to have any hope of survival. If we mire ourselves in
             | economic finger pointing we will end up doing nothing about
             | the actual problem
        
             | smitty1e wrote:
             | I'm not sure, but there is little more terrifying short of
             | a nuclear accident than the idea of faceless people in an
             | office somewhere deciding who gets a pass and who gets
             | crushed for sins uncommitted by them.
             | 
             | In short: you hint at tryanny.
        
             | rtpg wrote:
             | Perhaps society as a whole should just try to solve these
             | problems.
             | 
             | This is the tarpit of market-based solutions: debating
             | endlessly about who bears costs, instead of just doing
             | collective things collectively. And if you do have markets,
             | every middleman and their dog will demand their slice of
             | the pie.
        
               | voakbasda wrote:
               | The only way to get everyone to participate in a solution
               | will be regulation. The last thing that I want is the
               | government regulating this market. We will end up with
               | another cartel like the oil industry.
        
               | malermeister wrote:
               | So what do you suggest then? We do nothing and slowly
               | walk towards our demise?
        
               | throwawayboise wrote:
               | Probably this, yet. When the problem is real, people will
               | find real solutions. Or not, but it's not happening now
               | anyway. Are you driving less? Have you stopped eating
               | beef?
        
               | malermeister wrote:
               | When the problem is "real", it will be too late for
               | solutions. We need to do something right now. Besides,
               | I'd argue the problem is starting to be "real" right now.
               | California, Australia, Siberia and Greece were on fire
               | this year, Germany had historic floods and the East Coast
               | keeps getting devastated by hurricanes.
               | 
               | I also disagree with the tactic of shifting
               | responsibility to the individual to avoid doing anything
               | where it actually matters. My individual contributions to
               | climate change are negligible, this is a collective
               | issue. We need to get industry and corporations in check
               | and the only way we can do that is with heavy regulation.
        
               | mechanical_bear wrote:
               | We are on fire every year. Gross mismanagement has made
               | it worse.
        
               | throwawayboise wrote:
               | You're not wrong, but I'm being realistic about human
               | nature. People are not going support heavy regulations
               | that make their lives more difficult and expensive, if
               | they are working 5 or 6 days a week to pay bills and
               | support a family. Some theoretical problem 20 years from
               | now is not high on their list of concerns.
        
               | dcow wrote:
               | Are wildfires a result of climate change? I though they
               | just happened naturally and since we stopped doing
               | controlled burns have gotten worse. I'm not disagreeing
               | with your general point, there are plenty of signs we
               | should be acting now. I'm just always surprised when
               | wildfires get linked to climate change.
        
               | Swenrekcah wrote:
               | I think the point is the regions that already had them
               | get them worse, and some regions that didn't have them
               | now get them.
               | 
               | What global warming does is destabilise the equilibrium
               | we had in the global climate system, and one of the
               | outcomes of that is more extreme weather. That means for
               | example longer and drier droughts which obviously
               | contributes to wildfire risk.
        
         | johnchristopher wrote:
         | Do we need something like... Business, corporations can't do
         | one thing: not making money. If they don't and can't pay taxes
         | they go bankrupt and can't operate anymore.
         | 
         | Can we have a carbon bankrupt ? If a company can't prove they
         | are not emitting CO2 or getting CO2 out of the atmosphere then
         | they are not allowed to operate anymore ?
         | 
         | I know it's nickelodeonsimplistic but can't carbon emissions be
         | considered more important than money when deciding to allow
         | companies to operate ?
        
         | hexane360 wrote:
         | The news reporting on this article has been a little
         | misleading. First, the main goal of this is _not_ to reduce CO2
         | into carbon, but simply to sequester CO2. The  "carbonaceous
         | sheets" that are produced are "graphene oxide", which is less
         | oxidized than CO2 but still highly oxygenated. So the energy
         | required is much less than what would be needed to reduce CO2
         | completely. But yeah, you won't be able to burn the end
         | product.
        
           | mah4k4l wrote:
           | Ok makes a hell of a lot more sense now. Thanks for pointing
           | that out.
        
         | amelius wrote:
         | How much energy does it cost to simply heat CO2 to the point
         | where it breaks into its constituents?
        
         | theropost wrote:
         | Also keep in mind the limited supply/uses of Gallium at the
         | moment, it tends to be a biproduct from other mining
         | activities. If suddenly there were a large and scaled demand
         | for this material, then I am quite sure we would see a huge
         | spike in price in the near/medium term, and future price would
         | depend on the new demand, and capabilities to get sufficient
         | supply. $250/kg is pretty cheap at the moment;
        
         | 5faulker wrote:
         | It's the same story of business and innovation as usual. And
         | what about the pollution raw materials can cause....
        
         | lisper wrote:
         | > it'll only be solved when it becomes economic to do so.
         | 
         | That's true, but the economics are being badly skewed by not
         | properly accounting for the externalities of emissions. If this
         | were done (e.g. a global carbon tax) the situation would change
         | dramatically.
         | 
         | If you are a young person reading this I would seriously
         | consider making this a litmus test for any politician you are
         | considering voting for, and urging your peers to do the same.
         | Otherwise your generation is in for a (literally!) a world of
         | hurt.
        
         | fredgrott wrote:
         | They stated it operates at room temp so I am assuming that one
         | could in fact pipe in CO2 from factory stacks once some
         | processing of cooling the CO2 from the factory stacks has been
         | implemented.
         | 
         | Give you an idea. Gen plant burning natural gas produces CO2,
         | use some of gen electric to cool the emitted CO2 down then mine
         | the result battery artifacts
        
         | api wrote:
         | To those who think it sounds impossible, remember that methane
         | is CH4 and a good amount of the energy released is attributable
         | to those hydrogens getting together with oxygen. So you are
         | basically subtracting the yield from carbon.
         | 
         | Wouldn't it be a lot better though to somehow turn CH4 into
         | hydrogen and carbon, bury the carbon or use it for uses that
         | don't end up in the atmosphere, and burn the hydrogen alone or
         | use it in fuel cells? Fuel cells might get you to pretty good
         | energy yields.
        
         | joe_the_user wrote:
         | _Not to be a broken record on HN, but I 've often said--and
         | I'll repeat here--that I don't believe altruism will solve
         | greenhouse gas emissions and global warming: it'll only be
         | solved when it becomes economic to do so._
         | 
         | The term "economic" can mean a lot of things. Solar and Wind
         | can be cost-effect replacements for many uses of fossil fuel.
         | With some regulations and transformation of daily surplus
         | energy to other forms, you could get an economy with energy
         | costs similar to the present and low carbon usage. So if
         | "economic" just means, idk, works in an economy, then it's
         | essentially not an important barrier (except the state should
         | finance it's efforts with a graduated income tax and not a
         | visibly-punishing measures like carbon or at-the-pump taxes,
         | instead just making some things eventually prohibited but
         | cushioning the blow for those poor or industries want to
         | preserve).
         | 
         | But if by "economic", you mean the economy has to just do what
         | it "wants" with no intervention at all, well we'll not only
         | suffer the disasters of global warming but also unbridled
         | pollution.
        
         | jandrewrogers wrote:
         | Gallium cannot be produced at scale because it does not form
         | concentrated ores in nature. It cannot be usefully mined
         | directly. The only reason it is relatively inexpensive is that
         | there is limited demand for the minuscule quantities that are
         | currently produced.
         | 
         | Gallium is currently supplied by reprocessing the waste from
         | other convenient metal ores to extract the traces of gallium.
         | Even if we maximized gallium extraction from these waste
         | streams, we are talking about a few thousand tons of gallium
         | per year. We produce more _gold_ every year than there is
         | practically available gallium.
         | 
         | Unfortunately this is the story with many proposed solutions to
         | carbon capture. Many things are possible as a prototype which
         | are completely infeasible at the industrial scales required to
         | make a dent in atmospheric carbon because the resources don't
         | exist to run chemistry at that scale.
        
           | evgen wrote:
           | > The only reason [Gallium] is relatively inexpensive is that
           | there is limited demand for the minuscule quantities that are
           | currently produced.
           | 
           | It is possible that we might be able to find more if we
           | actively start looking for it? This would not be the first
           | time that what was once a waste product becomes valuable once
           | we know how to use it. Regarding gallium itself, its presence
           | as basically waste product in bauxite ore suggests we can
           | increase production (https://www.sciencedirect.com/science/ar
           | ticle/abs/pii/S03014...) and there may be other sources if we
           | start searching.
        
             | jandrewrogers wrote:
             | Gallium is found everywhere, it doesn't make sense to
             | actively search for it because it doesn't concentrate
             | anywhere. _That 's the whole problem._ There is little that
             | distinguishes bauxite ore from my backyard in terms of the
             | amount of gallium that can be extracted.
             | 
             | The advantage of extracting it from certain ore waste
             | streams is two-fold even though they don't contain much
             | gallium. First, the chemical processing cost varies with
             | the chemistry of the rocks you extract the gallium from,
             | and certain types of ore waste such as bauxite, zinc, etc
             | are cheaper to deal with. Second, these rocks have already
             | been dug out of the ground as part of a mining operation,
             | which is much cheaper than strip mining an arbitrary place
             | to extract the same trace quantities of gallium -- you get
             | to free-ride on the extraction costs of the primary mineral
             | someone already paid for. If it doesn't matter where you
             | dig, then all you can really optimize for is the processing
             | cost of where someone _already_ dug.
             | 
             | It would make no sense to increase bauxite production for
             | the purpose of gallium production. Extracting gallium from
             | bauxite is only economical to the extent that there is
             | healthy demand for the aluminum produced from that bauxite.
             | This is common in mining operations -- a secondary mineral
             | that cannot be economically mined by itself becomes
             | profitably extractable from the same ore if and only if the
             | primary mineral is sufficiently profitable. Many less
             | common metals are produced solely via secondary extraction
             | because they cannot be profitably mined directly even when
             | they concentrate.
        
           | bitwize wrote:
           | Yeah, basically there's only one solution to the CO2 problem
           | that's also the solution with the least political will to
           | push it through: deindustrialization.
           | 
           | Everything else relies on miracles and/or unobtainium.
        
             | exporectomy wrote:
             | The implication of that is that we should accept climate
             | change, is that what you're saying? Deindustrialization
             | would probably be worse than climate change so it's likely
             | not an option. In case you want deindustrialization, can
             | you estimate it consequences in terms of deaths caused or
             | some other important metric so we can compare it to climate
             | change?
        
               | andy_ppp wrote:
               | I think we could do the following; local seasonal food
               | farmed as naturally as possible. It's likely to still use
               | some carbon, but doing this would massively reduce what's
               | used today.
               | 
               | Tax meat production heavily.
               | 
               | Tax air travel heavily and these taxes should increase
               | exponentially per journey per person.
               | 
               | Stop shipping goods half way around the world... make the
               | things you need locally.
               | 
               | Improve the grid and invest in plans for heating using
               | electricity.
               | 
               | Build hundreds of small nuclear plants.
               | 
               | I think that's net zero roughly but it's not possible
               | politically even though it's a feasible solution to the
               | problem.
        
             | lovecg wrote:
             | Surely that's what they were saying about world hunger and
             | how depopulation is the only solution before the invention
             | of the Haber process?
        
         | pxi wrote:
         | The market based approach has a limited shelf life. Once we get
         | cooking in the CO2 500ppm+ range, things will become
         | increasingly desperate. Then a military based approach will
         | start to look attractive. I can't see mankind undertaking
         | various geo-engineering activities before first putting out
         | fires with firepower.
        
         | ineedasername wrote:
         | _don 't believe altruism will solve greenhouse gas emissions
         | and global warming: it'll only be solved when it becomes
         | economic to do so._
         | 
         | You've listed altruism and economics, but may have discounted
         | self-interest-- not financial, but survival. Young adults
         | especially are both at an age where they can expect to feel
         | some especially nasty impacts of climate change, and at a point
         | in their career where they can begin making decisions
         | accordingly.
         | 
         | The generations above that have family, children, etc, and that
         | too is at least a mix of self interest and , I supposed, a form
         | of altruism directed towards your family.
         | 
         | It's not easy for us to think in such timelines and abstract
         | outcomes, but we're making progress in that direction.
         | 
         | I'm not saying self-interest in terms of self preservation will
         | be _the_ key factor here either, just that it not just about a
         | sort of mechanical economic optimization point. At some tipping
         | point, economic w / technological advances will converge with
         | self preservation. I guess the question is whether or not that
         | will happen soon enough to really matter. Economics may be the
         | dominant factor now, but the worse things get, the less that
         | economics will matter in making decisions, the more that self
         | preservation will become dominant.
        
           | BurningFrog wrote:
           | Global climate change is not something one person or family
           | can affect, so I don't understand what form of self-interest
           | driven action could impact it.
           | 
           | BTW, the "economic" solution consists of making it in
           | everyone's self interest to work against CO2 emissions.
        
           | jvanderbot wrote:
           | I think environmental issues are the classic tragedy of the
           | commons. The first to put aside environmental issues in favor
           | of riches will have a disproportionate advantage with a
           | proportionate impact. One country burning gas gets cheap fuel
           | to expand their industries but only has a marginal increase
           | in future global warming and (the worst part) almost no
           | impact on today's temperature.
           | 
           | We need more than altruism, which is local sacrifice. We need
           | global enforcement and agreement and, I agree with GP,
           | incentive.
        
         | xyzzy21 wrote:
         | This also assumes pure CO2 input. That's perhaps possible if
         | you are collecting CO2 fresh off an engine or similar process.
         | 
         | However if you are talking about CO2 already in the air, you
         | have a MASSIVE amount of energy required to
         | separate/concentrate the CO2 FIRST.
        
         | jeffybefffy519 wrote:
         | Preprint of the paper is available in other parts of this post,
         | but it does say this:
         | 
         | > The solid co-contributor of silver-gallium rods ensures a
         | cyclic sustainable process
         | 
         | Unsure if this means the gallium is consumed or not during the
         | process.
        
         | sabujp wrote:
         | does the semiconductor industry not use large quantities of
         | GaAs? Has the industry replaced its use with something else?
         | https://en.wikipedia.org/wiki/Gallium_arsenide
        
         | punnerud wrote:
         | The cost of 230kWh is around EUR30 in Norway (lower during the
         | summer), the CO2 quota price is around EUR60/ton.
         | 
         | Norway is now building pipes to pump CO2 down to the old oil
         | wells.
         | 
         | Seems like it starting to get economically profitable to grab
         | CO2 from the air and sell the quota?
        
           | londons_explore wrote:
           | > Norway is now building pipes to pump CO2 down to the old
           | oil wells.
           | 
           | You should know that injecting old oil wells with CO2 helps
           | them produce more oil. The CO2 becomes carbonic acid under
           | pressure, which then dissolves pores in the rock wider,
           | allowing more oil and gas to escape.
           | 
           | Also, it looks pretty doubtful that CO2 will stay in gas
           | wells for a long time. Eventually it'll find some fissure and
           | due to the acidity any crack will be eroded wider till all
           | the CO2 comes out like a fizzy drink.
           | 
           | But don't worry. Oil and gas companies will happily collect
           | government subsidies for pumping CO2 underground to get more
           | oil out to sell, in the knowledge that when the gas escapes
           | in a few decades they can act all surprised...
        
             | ericd wrote:
             | Yeah, it's been branded "enhanced oil recovery", and iirc
             | it's currently the most economically rewarding use for CO2.
        
             | HPsquared wrote:
             | That's interesting, I'd always thought it was more the CO2
             | acting as a solvent to flush out the oil. Is there any
             | reading material on this?
        
               | punnerud wrote:
               | https://www.equinor.com/en/magazine/carbon-capture-and-
               | stora...
        
           | lrem wrote:
           | Note that EUR30 is obtained with pure CO2 as input. What's
           | the cost of going from air to that? Or even from exhaust to
           | that?
        
           | ClumsyPilot wrote:
           | Most developed nations produce circa 10 tons of CO2 per
           | person. Assume EUR100 to cover capital costs and
           | inefficiency.
           | 
           | At ~EUR1000 per person we could easilly afford to go CO2
           | neutral. It's just a question of will
        
         | andi999 wrote:
         | So reducing petrol demand (let's say by switching to electric
         | cars) might reduce the economic incentives of carbon capture
         | significantly, interesting thought.
        
           | cogman10 wrote:
           | The economics of a natural carbon market will never work out.
           | There is simply too much carbon available for too low of a
           | price.
           | 
           | The carbon capture market NEEDS to have public
           | funding/intervention to make it profitable.
           | 
           | Now, carbon capture will be important if we want to have a
           | chance of undoing atmospheric CO2, but IMO, while now it the
           | time to invest in research it's not the time to deploy. More
           | public/government funds need to be pushed towards limiting
           | CO2 output and eliminating sources of CO2.
           | 
           | The notion of carbon capture is much the same as having urine
           | capture in a swimming pool. There is no way it won't cost
           | more energy to remove than it produced when released.
        
             | seventhtiger wrote:
             | Urine capture would work great if it's attached to every
             | person.
             | 
             | Even with renewable energy and electric transportation, if
             | we could keep using oil but not produce CO2, then we
             | should. Cheap energy is lifting humanity out of poverty.
        
               | adrianN wrote:
               | You're assuming that the carbon capture process is
               | cheaper than the shrinking price advantage of fossil
               | fuels over renewables.
        
               | seventhtiger wrote:
               | I'm not. I'm just leaving room for an equilibrium that
               | includes oil.
               | 
               | I don't believe we'll be able to take cheap sources of
               | power offline without affecting the bottom line for the
               | developing world. Poor countries can't make the choice to
               | regulate themselves into worse conditions.
               | 
               | Centralizing carbon capture at power plants can be cost
               | effective. The tech is almost within reach. It will
               | vastly increase the amount of available energy in the
               | world.
        
           | cletus wrote:
           | Electrifying vehicles at a mass scale actually has a lot of
           | problems, not the least of which is does the grid support the
           | ability to transmit that much power. In many places it does
           | not.
           | 
           | That aside, electrifying vehicles doesn't necessarily reduce
           | emissions significantly. It may simply shift the emissions
           | from individual vehicles to the power plant that produces the
           | power that charges the cars.
           | 
           | Now this is nearly always a net positive: large-scale fossil-
           | fuel burning power generation is pretty much always more
           | efficient (even accounting for transmission power loss) but
           | the point is that emissions don't go to zero.
           | 
           | Another interesting thought: the price of gasoline acts as a
           | barrier to vehicle usage to some degree. As in, knowing you
           | have to spend $50 to fill up the tank affects your behaviour
           | to varying degrees. Well with electric vehicles depending on
           | where you live that marginal cost might be <$5 per tank-
           | equivalent of range.
           | 
           | I wonder if that means that with a fully electrified vehicle
           | fleet, people will end up driving more because of the lower
           | marginal costs.
        
             | pjc50 wrote:
             | > people will end up driving more because of the lower
             | marginal costs.
             | 
             | I suspect places will have to move to either London-style
             | congestion charges or milage-based road taxes to offset
             | this. With an admittedly big loss of privacy, you could
             | even price at the level of individual roads and put Uber-
             | style surge pricing on the roads themselves.
             | 
             | Another possibility is that the "markets in everything"
             | self-driving companies win and cars become a capital asset
             | that can work itself. No reason to drive your car around
             | uselessly if you can rent it out instead, and _in theory_
             | this could result in fewer cars. However I 'm skeptical.
        
             | dooferlad wrote:
             | Grid stress in the first world isn't a big problem since
             | electric vehicles can charge when the grid is under less
             | pressure. The demand curve over a day has a reasonably
             | predictable shape and EV charging can often be done when
             | wholesale prices are low. Of course we will need to
             | increase capacity, but that can be done over time.
             | 
             | Fossil power to generate electricity that then powers your
             | car is less carbon intensive than just using an internal
             | combustion engine. The overhead of getting oil out of the
             | ground, refining it and transporting it is big. You then
             | lose lots of energy as heat as you run your engine.
        
             | chipsa wrote:
             | Average US driver goes 13.5kmi/year. This is about 36mi/
             | day. Most cars will get 2-4 mi/kWh, so this is about
             | 12kWh/day. Average charging of like 8 hours gives about 1.5
             | kW over night. This isn't nothing, but it's a bunch less
             | than people think about. I was regularly driving off of
             | what a standard 120v socket would supply. (Not right now,
             | because I can no longer charge overnight, due to a recall)
             | 
             | Also grid power can become more green if more green sources
             | come online, but your gas powered car will always be gas
             | powered.
        
             | ZeroGravitas wrote:
             | I remember when EVs where a pointless toy for rich people
             | to flaunt their wealth, now they're causing problems by
             | letting poor people drive more. That's some remarkble
             | progress they've made while still somehow remaining vaguely
             | problematic.
        
       | halaahmed wrote:
       | I get how you could use this to take solar energy and pull CO2
       | out of the air, but the article mentions using it in cars, which
       | makes no sense. You're going to use more energy than you get from
       | burning gas to then capture the carbon?
        
       | mah4k4l wrote:
       | So you can separate it to oxygen and carbon at a 92% efficiency
       | for EUR30 max or something? If you could now burn the newly
       | donned carbon again and maybe enhance the burning with the
       | harvested oxygen then how much is that worth as energy produced
       | monetarily? Maybe not the eternal mover but just saying this
       | might just be how this will play out in real life in the end
       | (once again).
        
       | mikewarot wrote:
       | How can they capture 92% of the CO2 generated by burning coal for
       | less energy created by burning it, creating steam, running the
       | steam through a turbine which then runs a generator, through a
       | switching yard, and out to the world? The Carnot limit is far
       | less than half, and yet this can get most of the Carbon back,
       | with a balance of almost half of the energy? I did the math on
       | this in the thread about this last week, and it seems like over-
       | unity, a big red flag.
       | 
       | The need for the worlds supply of gallium and a lot of silver and
       | other chemicals signals more red flags.
       | 
       | HN Story 8 days ago:
       | https://news.ycombinator.com/item?id=28873458
       | 
       | My response: https://news.ycombinator.com/item?id=28874831
        
         | colechristensen wrote:
         | The carbon output isn't pure carbon, but carbon oxides. Some of
         | the oxygen is stripped from CO2 and the result is carbon-oxygen
         | solids which are apparently industrially useful.
        
           | ashtonkem wrote:
           | The problem is that if you turn around and use those carbon
           | materials in industry, then you really haven't captured the
           | carbon at all. All that would accomplish is playing an
           | emissions shell game, allowing fossil fuel consumers to shift
           | the emissions to someone else.
           | 
           | For carbon capture to be useful from a climate perspective,
           | we have to actually lock away the consumed carbon somewhere
           | where it can't enter the fast carbon cycle.
        
             | colechristensen wrote:
             | Depends on what you do with the thing when you're done with
             | it. Dumping it in a landfill after a decade would indeed by
             | carbon capture.
        
       | anoncow wrote:
       | Will this result in an increase in O2 levels? If yes, what risk
       | does that bring?
        
         | ClumsyPilot wrote:
         | O2 levels are currently decreasing. In a thousand years we will
         | run out
        
           | jjcon wrote:
           | Try >1 billion years from now
        
         | nominatronic wrote:
         | Giant predatory dragonflies the size of seagulls, if the fossil
         | record is anything to go by.
         | 
         | https://www.sciencedaily.com/releases/2010/10/101029132924.h...
        
         | IshKebab wrote:
         | Not an issue. The oxygen release is just oxygen that was
         | already in the atmosphere before it was used to burn oil.
         | 
         | Even if that weren't the case, the atmosphere is 21% oxygen and
         | 0.04% CO2.
        
       | steeve wrote:
       | This is great. That said, to put things into perspective, the CO2
       | surplus we have to offset is 20 _giga_ tonnes of CO2 _every
       | year_.
        
       | beders wrote:
       | If we would charge the fossil fuel industry for the cost of
       | destroying the environment, the millions of lives lost due to
       | pollution, it would become infeasible to pump or mine more stuff
       | out of the ground.
       | 
       | We don't need technological solutions, we need political
       | solutions. Now
        
         | vixen99 wrote:
         | No, you and I kept up the demand on the fossil fuel industry
         | without which it would not exist and all of us went along with
         | it and now you want _them_ to pay for your and my indulgence.
         | How sweetly ironic! It 's never our fault, is it?
        
           | malermeister wrote:
           | This is a classic case of victim blaming. You and I didn't
           | "keep up demand" because we wanted to, we "kept up demand"
           | because it was the only option available to heat our homes.
           | 
           | It's not our fault the industry didn't provide us with
           | alternatives.
        
             | joe_the_user wrote:
             | Whether you blame the fossil fuel industry or not, they
             | don't have the cure to their destruction in their back
             | pocket or something.
             | 
             | Even if you seized all the stocks and bonds of the fossil
             | fuel industry, you wouldn't have the money required to
             | solve this problem and you wouldn't have a plan to solve
             | the problem.
             | 
             |  _It 's not our fault the industry didn't provide us with
             | alternatives._
             | 
             | It's not really the job of a given industry to provide
             | alternatives. That job, in a modern democratic society,
             | devolves to the state. The US state certainly failed there
             | and was corrupted by private industry (auto and petroleum
             | certainly). But the only way out is the state stepping up
             | and moreover, the state stepping up with statist solutions
             | - building things (public transit), requiring things
             | (electric cars), prohibiting things (CO2 generating
             | production processes) and requiring things (Non-CO2
             | generating things and possibly/eventually sequestering).
             | Honestly, I'd see anyone thinking taxes or credits could be
             | the solution as part of the problem.
        
         | pfortuny wrote:
         | Well, well, well...
         | 
         | The political solution were nuclear plants in the 70's. They
         | were damned by the Ecologists (at least in Europe). We are
         | reaping what we sowed.
         | 
         | Where do you want the energy to come from?
        
           | adrianN wrote:
           | Not building more nuclear in the seventies probably was a bad
           | decision. But today it is not at all clear that nuclear is
           | the cheapest solution for carbon-free energy. Neither is it
           | clear whether we can scale nuclear quickly enough.
        
       | [deleted]
        
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