[HN Gopher] A new air-conditioning system manages without nasty ...
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       A new air-conditioning system manages without nasty gases
        
       Author : prostoalex
       Score  : 58 points
       Date   : 2021-07-23 20:18 UTC (2 days ago)
        
 (HTM) web link (www.economist.com)
 (TXT) w3m dump (www.economist.com)
        
       | matmatmatmat wrote:
       | Wish they had mentioned the efficiency and how it compares to
       | existing options. Anyone know?
        
         | Animats wrote:
         | No idea. Nitinol heat engines are available in toy-size.[1]
         | There used to be interest in shape-memory alloys as robot
         | actuators, but they're slow and need too much power. It takes
         | too much heat to generate mechanical motion.
         | 
         | Does that mean it has high heat pumping capability, since
         | refrigeration is the inverse of a heat engine? I don't know.
         | 
         | [1] https://www.imagesco.com/articles/nitinol/09.html
        
         | laurencerowe wrote:
         | > Tony Ennis, Exergyn's chairman, reckons this method of
         | cooling is not only more environmentally friendly than an HFC
         | set-up, but will also be less expensive to buy and 30-40%
         | cheaper to run.
         | 
         | Not absolutely clear, but the cheaper running cost implies it
         | uses less electricity than existing options.
        
       | mlwiese wrote:
       | You can use CO2 as a refrigerant. Non flammable and enables heat
       | pumps to be practical at lower temperatures. Lots of products on
       | the market. See https://r744.com
        
         | tgsovlerkhgsel wrote:
         | I assume using it results in a less efficient system though,
         | right?
        
           | GuB-42 wrote:
           | I don't know about efficiency but the pressure is much
           | higher, making the system much more expensive.
        
           | namibj wrote:
           | Runs at high pressure, can be quite efficient though, iirc.
        
       | kensai wrote:
       | A similar amazing technology has been recently shown at a
       | Fraunhofer Institute in Germany. And the magnetocaloric approach
       | sounds even more promising!
       | 
       | https://www.ipm.fraunhofer.de/en/press-publications/press-re...
       | 
       | https://www.youtube.com/watch?v=6tKtc0cHrUg
        
       | nanomonkey wrote:
       | Stirling engines can be run in reverse to act as a heat pump.
       | 
       | In fact, I have a two 25 liter coolers that utilize Stirling
       | engines, they run silently and cycle between using 5 and 33
       | watts, averaging about 11 watts once the components the contents
       | have settled on the 4 C set point.
       | 
       | Curious if anyone has looked into utilizing larger ones for
       | cooling buildings.
        
         | tgsovlerkhgsel wrote:
         | Wikipedia: "At typical refrigeration temperatures, Stirling
         | coolers are generally not economically competitive with the
         | less expensive mainstream Rankine cooling systems, because they
         | are less energy-efficient."
        
       | haspoken wrote:
       | https://archive.is/y4OwA
        
       | Waterluvian wrote:
       | Say there's a hypothetical AC that works very well and requires
       | no environmentally problematic materials and lasts forever,
       | 
       | Does the simple act of moving heat from inside to outside do any
       | measurable, meaningful harm to nature?
        
         | stickfigure wrote:
         | By doing work you're contributing, in a minute but measureable
         | amount, to the heat death of the universe in about 10^100
         | years.
        
         | throw0101a wrote:
         | > _Does the simple act of moving heat from inside to outside do
         | any measurable, meaningful harm to nature?_
         | 
         | It would still take energy to run. How is/would that energy
         | produced?
        
         | Cthulhu_ wrote:
         | > Does the simple act of moving heat from inside to outside do
         | any measurable, meaningful harm to nature?
         | 
         | No, the heat moved is trivial compared to the heat coming in
         | from the sun. That said, urban design (concrete, asphalt, etc)
         | that absorbs a lot of extra heat will have a noticeable effect,
         | definitely on a local level. Cities with a lot of green are a
         | few degrees cooler as well, in part because of shade (the heat
         | is captured higher up), in part because of evaporation.
        
         | BayAreaEscapee wrote:
         | No air conditioner is going to be 100% efficient. You're still
         | going to consume a fraction of the heat energy being
         | transferred from indoors to outdoors. Unless your home is
         | powered by 100% green energy, you're still indirectly adding
         | carbon to the atmosphere.
        
           | Scipio_Afri wrote:
           | Even if its 100% green energy - which don't get me wrong is
           | orders of magnitude better for warming of the planet - it
           | still contributes to warming of the earth. You're taking some
           | wavelengths of light that would normally be absorbed by say
           | plant matter (thus using that energy to pull CO2 out of the
           | atmosphere) over an area and/or some wavelengths simply
           | reflected out to space without being absorbed by the solar
           | panels (which definitely are designed to absorb as many
           | wavelengths as possible). Then energy conversion from DC to
           | AC and to transmissions lines to where its used all have
           | losses which is energy dissipated in heat form. So the
           | conversion process there can cause heating as well.
           | 
           | Certainly better than combustion which creates heat AND
           | creates gasses which trap that and other radiation as heat.
        
       | KaiserPro wrote:
       | You can use propane for the refrigerant. The halflife in the
       | atmosphere is pretty short. Its cheap, non toxic and fairly well
       | understood.
       | 
       | In the EU/UK it also has the advantage of not needing a license
       | to install yourself.
       | 
       | Obviously this new technology is important, but its not here now.
        
         | kube-system wrote:
         | r1234yf is already in wide use. It a little bit expensive, but
         | it does not pose the global warming concerns of HFCs, doesn't
         | deplete ozone like CFCs, and isn't as flammable as
         | hydrocarbons.
         | 
         | https://en.wikipedia.org/wiki/2%2C3%2C3%2C3-Tetrafluoroprope...
        
           | marcus0x62 wrote:
           | R1234YF is _ridiculously expensive_ compared to R134A, like
           | 10 times the price. (For reference - I can buy a 10 pound
           | cylinder of R1234-YF on eBay for $500. A 30 lb cylinder of
           | R134A is $150 - $200.)
           | 
           | It is also takes more expensive equipment and a significantly
           | longer amount of time to charge a R1234-YF system. All
           | around, it is a terrible refrigerant for an end-user.
        
             | userbinator wrote:
             | 152a is another cheap alternative, and can even be bought
             | without any license, at least in the US - it's the gas in
             | "gas dusters".
             | 
             | While 134a operates at a higher pressure than 12, 152a is a
             | close match and works well as a replacement for old R12
             | systems.
        
         | throwaway0a5e wrote:
         | Rational people turn into tantrum throwing toddlers and
         | absolutely go crazy if you suggest using a flammable
         | hydrocarbon as a refrigerant (never-mind that many refrigerants
         | are already flammable hydrocarbons or nasty in indoor spaces to
         | the point where propane isn't worse).
        
           | KaiserPro wrote:
           | to be fair I was a bit sceptical about it when I first put it
           | in. Its pure, rather than having the tell-tale smell. So I
           | was a bit worried about silent leaks.
           | 
           | However as you point out, some other refrigerants are pretty
           | flammable, or otherwise generally a bit shit for your health.
           | 
           | Also, in my unit, there is something like 66grams, although I
           | suspect 10 grams of that was bled off to purge the lines of
           | air. So if there was a slow leak, its unlikely to persist for
           | long, or cause an explosion.
        
             | Gibbon1 wrote:
             | Evaporated I think 66grams of propane is about 1cuft of
             | gas. which doesn't seem to me to be that scary. A perfect
             | air to fuel ratio would require mixing 16 cuft of air. And
             | flammable range is narrow. Comparison, your kitchen is
             | probably 1000 cuft.
             | 
             | So I think you are right, slow leak isn't much of a hazard.
        
             | tgsovlerkhgsel wrote:
             | 66 grams of propane are 35.1 liters. The lower explosive
             | limit is 2.1%. So if the content leaks out slowly enough to
             | mix with at least 2 cubic meters of air, it's going to be
             | fine. However, if it leaks a bit more quickly, I can
             | totally see it creating an explosive mixture in the space
             | behind your fridge (or inside), to be ignited when the
             | compressor/light switch trigger next.
             | 
             | I can see why people aren't super happy with the prospect.
             | A stoichiometric mixture forming inside your fridge and
             | blowing up when you open it would definitely ruin your day.
        
             | ashtonkem wrote:
             | A typical natural gas range probably releases more than 66g
             | of unburnt hydrocarbons into your home.
        
               | userbinator wrote:
               | Natural gas is basically methane, which is around
               | 16g/mol. 1mol of gas at STP is 22.4L, so 66g of methane
               | is around 90L.
               | 
               | A typical gas range has a flow rate of a few cubic meters
               | per hour, or a few liters per minute. So just to get 66g
               | of unburnt gas released, you'd need to leave a burner un-
               | ignited for most of an hour, or considerably longer if it
               | was burning.
        
           | Animats wrote:
           | Before freons, ammonia was used. Getting rid of ammonia
           | refrigerants was considered a big step forward.
        
             | cartoonworld wrote:
             | In large commercial applications ammonia is still commonly
             | used.
             | 
             | Getting this crazy crap out of our homes and stuff is
             | indeed a big step forward, though
        
           | mannykannot wrote:
           | Not to mention that gaseous hydrocarbons are widely used
           | within homes, and not in hermetically-sealed devices either,
           | as would be the case when used in a heat pump.
        
             | epistasis wrote:
             | What, you mean this methane spewing stove that causes
             | really bad air quality, and is no more responsive than an
             | induction stove and far less powerful than an induction
             | stove?
             | 
             | "Cooking with gas" is great marketing, but not so great in
             | reality unless it's an outdoor wok.
        
           | userbinator wrote:
           | People remember things like this:
           | https://en.wikipedia.org/wiki/Cocoanut_Grove_fire
           | 
           | edit: please READ the article before you think of downvoting.
        
             | ashtonkem wrote:
             | ... which had absolutely nothing to do with refrigerants.
        
               | userbinator wrote:
               | I know the article is lengthy, but did you even try to
               | search for refrigerant or freon in it?
               | 
               |  _The air-conditioning also used flammable gas, because
               | Freon was in short supply_
        
               | [deleted]
        
               | ashtonkem wrote:
               | Which wasn't determined to be a source or contributor to
               | the fire.
               | 
               | > The Boston Fire Department investigated possible causes
               | of ignition, the rapid spread of the fire and the
               | catastrophic loss of life. Its report reached no
               | conclusion as to the initial cause of ignition, but
               | attributed the rapid, gaseous spread of the fire to a
               | buildup of carbon monoxide gas due to oxygen-deprived
               | combustion in the enclosed space above the false ceiling
               | of the Melody Lounge. The gas exuded from enclosed spaces
               | as its temperature rose and ignited rapidly as it mixed
               | with oxygen above the entryway, up the stairway to the
               | main floor and along ceilings. The fire accelerated as
               | the stairway created a thermal draft, and the high-
               | temperature gas fire ignited pyroxylin (leatherette) wall
               | and ceiling covering in the foyer, which in turn exuded
               | flammable gas.
               | 
               | Yes, they used flammable gas in the AC, no that was not
               | determined to be a source or contributing factor to the
               | fire.
        
               | nzgrover wrote:
               | This one did:
               | https://en.wikipedia.org/wiki/Tamahere_coolstore_fire
        
             | [deleted]
        
           | s0rce wrote:
           | They sell them in appliance stores now, most people wouldn't
           | even know, it's called R290. My fridge used it, sadly it died
           | and was replaced with a conventional refrigerant model.
        
             | blibble wrote:
             | they seem concerned about labeling it as propane
             | 
             | the one I bought had "R290 ECO-FRIENDLY REFRIGERANT" all
             | over the box, with the chemical name nowhere to be found
             | 
             | (of course I immediately wanted to know what R290 was and
             | googled it...)
        
         | tdeck wrote:
         | Here's a guy who recharged an old fridge with propane:
         | 
         | http://www.sparkbangbuzz.com/els/refrig2-el.htm
        
           | s0rce wrote:
           | My old fridge used propane from the manufacturer, sadly it
           | only lasted a few years and repair was more expensive than
           | another one. The new one uses a more conventional
           | refrigerant.
        
         | jeroenhd wrote:
         | Most portable air conditioners I've seen use "R290" (propane)
         | as a coolant, both from expensive brands and budget brands. I'd
         | say propane is very popular in that industry, it's not just an
         | option.
         | 
         | Of course, there are some risks to using propane (which is why
         | these devices come with warnings not to store them in small
         | rooms) but I suspect many people will already be using propane
         | cooling somewhere without even knowing.
        
         | throw0101a wrote:
         | > _You can use propane for the refrigerant._
         | 
         | Used in medical/scientific freezers that go down to -80C:
         | 
         | * https://www.thermofisher.com/ca/en/home/life-science/lab-
         | equ...
         | 
         | A combination of R290 (propane) and R170 (ethane) + R290 mix.
        
           | throwawayboise wrote:
           | A mix of propane and iso-butane can be used (perhaps
           | illegally, depending on where you are) as a replacement for
           | old R12 refrigerant.
        
             | frosted-flakes wrote:
             | Confusingly labelled as R12a and sold under brands such as
             | RedTek. This is the only type of refrigerant available to
             | unlicensed consumers in Canada, and it is widely available
             | in stores everywhere. R134a is not sold in stores here. The
             | US is the opposite--R134a is available to DIYers
             | everywhere, but R12a is banned because it is flammable.
        
       | nippoo wrote:
       | R32 (difluoromethane) or R290 (propane) both have ozone depletion
       | potential (ODP) of 0 and are in common use with new refrigeration
       | units.
       | 
       | This technology looks interesting due to its simplicity and could
       | potentially be cheaper than existing phase-change systems which
       | are prone to leaking and need maintenance. But refrigerants which
       | don't directly harm the ozone layer are already here...
        
       | MrStonedOne wrote:
       | rubber band fridge: https://www.youtube.com/watch?v=lfmrvxB154w
       | 
       | same concept, less refined.
        
       | b0rsuk wrote:
       | The Revenge of the Circulating Fan
       | 
       | https://www.lowtechmagazine.com/2014/09/circulating-fans-air...
        
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