[HN Gopher] Unexpected 'Black Swan' defect discovered in soft ma...
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       Unexpected 'Black Swan' defect discovered in soft matter for first
       time
        
       Author : dnetesn
       Score  : 121 points
       Date   : 2021-05-20 10:55 UTC (12 hours ago)
        
 (HTM) web link (phys.org)
 (TXT) w3m dump (phys.org)
        
       | pjungwir wrote:
       | It reminds me of PNP & NPN transistors. Could these liquid
       | "defects" have applications too?
       | 
       | Ever since childhood I've wondered why the water behind a rowboat
       | stays flat for so long. You'd think the surrounding water would
       | flow in and make it as wavy as everything else. Then a few years
       | ago I was on Thera and saw the same thing with the cruise ships
       | coming in. Their flat glassy trails would last for hours. Why
       | does it take so long for them to vanish? It is a liquid
       | transition that is weirdly persistent. Does anyone have an
       | answer? If not, maybe this can be someone's wobbling plate.
        
         | hyperpallium2 wrote:
         | IDK but one factor is most of the water filling the gap would
         | come from underneath (it's at higher pressure), moving up to
         | the surface. Its momentum carries it slightly too high, so it
         | flows outward, then down and inward again, forming a vortex on
         | either side. The surface looks smooth and the twin vortices
         | woukd tend to persist.
        
         | hinkley wrote:
         | WAG: does it have anything to do with dissolved gases slightly
         | changing the physics of the water, making it a case of the
         | waves seeing it as a transition between materials.
        
         | Enginerrrd wrote:
         | If I recall correctly, I think this is usually explained as a
         | thermocline effect where as deeper water gets churned up and
         | mixed in the wake, it is a different temperature than the
         | surrounding water outside the wake. This water has ever-so-
         | slightly different fluid characteristics and so it presents a
         | bit of a barrier to the usual diffusion and mixing you might
         | expect.
         | 
         | There's also the potential for a very thin layer of some type
         | of hydrophobic substance (like an oil) to be left behind that
         | can dramatically reduce waves in that area. There's youtube
         | videos around for that effect.
        
           | hinkley wrote:
           | Probably a different amount of dissolved gasses as well.
        
       | [deleted]
        
       | cinquemb wrote:
       | > While the researchers were not actively looking for any
       | particular defect in the material, the advanced imaging technique
       | uncovered a surface defect, called a twin boundary. At either
       | side of the twin juncture, the molecular networks abruptly
       | transformed their handedness.
       | 
       | Reminds me of Q1D models that simulated glassy dynamics[0]:
       | 
       | "We describe numerical simulations and analyses of a quasi-one-
       | dimensional (Q1D) model of glassy dynamics. In this model, hard
       | rods undergo Brownian dynamics through a series of narrow
       | channels connected by $J$ intersections. We do not allow the rods
       | to turn at the intersections, and thus there is a single,
       | continuous route through the system. This Q1D model displays
       | caging behavior, collective particle rearrangements, and rapid
       | growth of the structural relaxation time, which are also found in
       | supercooled liquids and glasses. "
       | 
       | [0]: https://arxiv.org/abs/1401.0960
        
         | phonethrowaway wrote:
         | > At either side of the twin juncture, the molecular networks
         | abruptly transformed their handedness.
         | 
         | this seems rather intuitive to me, and unsurprising.
         | 
         | for every action there is an opposite and equal reaction.
         | 
         | a spinning cue ball changes directions when it bounces off a
         | rail.
         | 
         | it's the same reason circular polarizers let you see through
         | reflections in glass.
        
       | [deleted]
        
       | Chris2048 wrote:
       | > In biology, we know that even a single defect in DNA, a
       | mutation, can cause a disease or some other observable change in
       | an organism
       | 
       | And this would relate to material science?
        
         | sandworm101 wrote:
         | A single defect can impact the entire field. One unambiguous
         | result could throw the entire standard model out the window. It
         | has happened in astronomy, the father of physics, multiple
         | times.
        
           | optimalsolver wrote:
           | >A single defect can impact the entire field
           | 
           | Just ask Boeing.
        
         | thisismyswamp wrote:
         | In the way that molecules are so fast that they go past each
         | other frequently, making global effects possible to arise from
         | small perturbations.
        
           | acjohnson55 wrote:
           | One thing that comes to mind is prions, which cause diseases
           | like mad cow and CJD.
           | 
           | "Prions are misfolded proteins with the ability to transmit
           | their misfolded shape onto normal variants of the same
           | protein."
           | 
           | https://en.m.wikipedia.org/wiki/Prion
        
             | icoder wrote:
             | I think you and parent came up with a possibly better
             | example than the one in the article quoted by the
             | grandparent comment, more so than it being a clarification
             | of how single DNA mutations ripple out to be big problems.
        
           | gus_massa wrote:
           | That's incorrect. Molecules collide when they are close
           | enough. (There is a small probability of tunneling, but it's
           | really small.)
           | 
           | Small perturbations in a crystal are call "defects"
           | https://en.wikipedia.org/wiki/Crystallographic_defect and
           | they are quite stable, and don't move too much. The effect is
           | very local.
           | 
           | The defects in DNA can have a huge effect if they are in an
           | (un)lucky spot, and they are completely unrelated to material
           | science.
        
             | trutannus wrote:
             | Basically, insofar as the perturbation does not impact more
             | than the local lattice structure (sometimes just a few NM
             | across), the overall lattice (therefore properties) will be
             | rather unaffected. I know pure crystals will often have
             | embedded impurities (ie: precursor residues in the
             | product). The impact for the DNA change is that DNA is used
             | to create downstream materials, whereas materials are
             | generally used because of their properties directly. As
             | long as a defect does not impact to a great extent the
             | general properties of the material, it is irrelevant.
             | 
             | In terms of movement inside a lattice structure, the only
             | real movement is vibrational and rotational movement, so
             | global effects because of particles moving about has far
             | lower influence.
        
             | DrJokepu wrote:
             | Depends on the type of defect. Dislocations can move around
             | quite a bit and they do affect the structural integrity of
             | the material.
             | 
             | This is why if you bend a fork, you will never be able to
             | fully unbend it (without heat treatment), there will always
             | be a S-shaped bend it it.
        
             | kragen wrote:
             | an iron whisker with a single crystal defect in it has
             | dramatically different macroscopic properties, especially
             | tensile strength, from an iron whisker without a single
             | crystal defect.
        
       | [deleted]
        
       | thisismyswamp wrote:
       | A Black Swan is an "unknown unknown", something you don't just
       | lack understanding of, but don't expect or predict. The
       | statistical interpretation of the term was popularized by Nassim
       | Taleb in the book of the same name:
       | https://www.goodreads.com/book/show/242472.The_Black_Swan
        
         | [deleted]
        
         | yosito wrote:
         | And what is "soft matter"?
        
           | Cd00d wrote:
           | Matter is stuff.
           | 
           | Condensed matter is stuff that is not gas.
           | 
           | Soft matter is shorthand for soft condensed matter, which is
           | stuff that is not gas nor solid.
           | 
           | Fluidics, liquid crystals, polymers are examples of soft
           | matter.
           | 
           | Source: I am a soft matter physics PhD that focused on liquid
           | crystal phase characterization.
        
             | dmingod666 wrote:
             | The article seems is too shallow in details of their
             | seemingly very important discovery. Atleast nothing I could
             | decipher. What do you think is relevant in their finding?
        
           | abledon wrote:
           | from article....
           | 
           | "Materials can be broadly classified as hard or soft matter.
           | Hard materials, like metal alloys and ceramics, generally
           | have a very regular and symmetric arrangement of atoms.
           | Further, in hard matter, ordered groups of atoms arrange
           | themselves into nanoscopic building blocks, called unit
           | cells. Typically, these unit cells are comprised of only a
           | few atoms and stack together to form the periodic crystal.
           | Soft matter can also form crystals consisting of unit cells,
           | but now the periodic pattern is not at the atomic level; it
           | occurs at a much larger scale from assemblies of large
           | molecules."
        
           | jtbayly wrote:
           | Apparently swans are. I'd guess most birds, especially geese,
           | since their feathers make nice pillows.
        
             | wernercd wrote:
             | This has nothing to do with black swans, the birds... this
             | has to do with unexpected results that are easy to explain
             | in hindsight after the truth is known.
             | 
             | https://en.wikipedia.org/wiki/Black_swan_theory
             | 
             | "Taleb's "black swan theory" refers only to unexpected
             | events of large magnitude and consequence and their
             | dominant role in history. Such events, considered extreme
             | outliers, collectively play vastly larger roles than
             | regular occurrences.[2]:xxi"
             | 
             | This discovery (unexpected behavior of matter) seems like
             | it'll have a surprising and large magnitude.
        
               | meepmorp wrote:
               | The way they use the phrase here has nothing to do with
               | Black swan theory or Taleb's book.
               | 
               | It just means something very rare, and that's been the
               | common meaning of the phrase in English for hundreds of
               | years. It comes from Latin.
        
               | jtbayly wrote:
               | But no correction of my improper interpretation of "soft
               | matter"? ;-)
        
               | wernercd wrote:
               | its early and the caffeine hasn't set in (still hasn't).
               | I guess this is a better comment if I read it with a
               | sarcastic twist?
        
         | teachingassist wrote:
         | I'm not sure I agree with anything you have said here.
         | 
         | "Black Swan" was in use before Taleb's book, at a similar
         | frequency as it is today (Google Trends scores 2 vs 3, where
         | 100 is when the book was released).
         | 
         | "Black swan" as a phrase dates at least to Roman times, often
         | referring to the philosophical idea that the observation of a
         | single black swan would prove their existence. (I've heard
         | 'black sheep' used for this as well, although that has other
         | more popular meanings).
         | 
         | The interesting part is that this did come to pass, for black
         | swans: which are only native to Australia.
         | 
         | So, in my mind, it refers to something which is conceivable,
         | but not believed to exist and not (yet) observed.
        
           | brobdingnagians wrote:
           | The Roman writer Juvenal is the origin of the phrase [1].
           | Neat to see pictures of them. [2] And humbling to think it
           | took almost two thousand years for them to find out that the
           | proverbial phrase was wrong.
           | 
           | [1] https://www.etymonline.com/word/black%20swan
           | 
           | [2] https://en.wikipedia.org/wiki/Black_swan
        
           | gumby wrote:
           | > "Black Swan" was in use before Taleb's book
           | 
           | In fact he likely used the term for his title because it's a
           | well-known metaphor.
        
         | tmptmp123 wrote:
         | The term black swan as it appears on the book actually comes
         | from a philosopher. I think it is from David Hume. Does anyone
         | here on HN knows? Its basically the concept in science that the
         | connection between cause and effect is an ilusion. I remember
         | reading the thought experiment from a philosopher in that
         | context. Since google stopped working finding these things has
         | proven more difficult.
        
         | meepmorp wrote:
         | A black swan is not "an unknown unknown." It's something very
         | rare, possibly non-existent - the phrase has been part of the
         | English language for centuries (from Latin), and is clearly not
         | being used in reference to Taleb's book:
         | 
         | > "This defect is like a black swan--something special going on
         | that isn't typical," said Dr. Edwin Thomas, professor in the
         | Department of Materials Science and Engineering
        
           | devy wrote:
           | Yep. Even though related but the phrase "black swan" is
           | different from the "Black Swan Theory".
           | 
           | The wikipedia entry[1] has the explanation of both. And the
           | usage by Dr. Thomas certain refers to the phrase not the
           | theory.
           | 
           | [1]: https://en.wikipedia.org/wiki/Black_swan_theory
        
           | peheje wrote:
           | Rather "Outside context problem"?
        
             | SAI_Peregrinus wrote:
             | Related, but that's a subset of "black swan". Not every
             | "black swan" is a problem.
        
           | rozab wrote:
           | The meaning of the phrase changed completely once black swans
           | were actually discovered in Australia.
        
             | waheoo wrote:
             | Did it though?
        
               | RosanaAnaDana wrote:
               | Right..
        
               | blacksmith_tb wrote:
               | Isn't that the point? Before English-speakers had seen
               | one, 'black swan' was a nonsense impossibility, like
               | water flowing uphill. After Brits saw them in Australia,
               | the phrase changed from 'total impossibility' to
               | 'extremely unlikely but what do you know, actually true!'
        
         | amelius wrote:
         | What is the relevance of the term here?
        
           | mohanmcgeek wrote:
           | That it's in the title?
           | 
           | GP is pointing out that it's being used incorrectly
        
             | meepmorp wrote:
             | The term isn't used incorrectly
        
             | gumby wrote:
             | except that, this being the Internet, the observation is
             | not in fact correct.
             | 
             | (I think we've all been "guilty" of this at one point or
             | another)
        
           | dkarl wrote:
           | This subthread is an illustration of the HN tendency to seize
           | on whatever aspect of the article we think we can sound smart
           | about, which, despite seemingly being an isolated comment
           | that the scientist did not clarify or expand on at all, the
           | journalist cleverly elevated to the headline.
        
             | arkitaip wrote:
             | You've just summarized the beauty that is n-gate.
        
           | agilob wrote:
           | Black Swan event is always unexpected, unpredictable, with no
           | prior recorded history of such event, so no one could prepare
           | for such event. It's always catastrophic as a system couldn't
           | be possibly ready for it.
        
         | booleandilemma wrote:
         | Black swan is one of those terms no one can quite seem to agree
         | on and people correct others corrections.
         | 
         | Kind of like np-completeness.
        
           | atq2119 wrote:
           | NP-completeness has a rigorous mathematical definition.
           | People who know the field definitely agree on it, there's
           | nothing fuzzy about it.
        
           | GuB-42 wrote:
           | ... and AI
        
         | harshbutfair wrote:
         | I still think it's a strange phrase. To me a black swan is a
         | normal swan.
        
           | robbiep wrote:
           | But until Europeans had come to Australia, no Europeans had
           | ever seen a black swan
        
             | domano wrote:
             | So if i see a black swan here in germany, this means it is
             | a a descendant of an australian swan?
        
               | robbiep wrote:
               | apparently so
               | 
               | [0] https://en.wikipedia.org/wiki/Black_swan_emblems_and_
               | popular...
        
             | inopinatus wrote:
             | Grey geese though.
        
         | cleansy wrote:
         | However, in this article it's referred to as an actual black
         | swan, not the concept in the book.
        
           | [deleted]
        
           | wernercd wrote:
           | "actual black swan, not the concept"
           | 
           | 2nd paragraph of article, first sentence: "This defect is
           | like a black swan--something special going on that isn't
           | typical,"
           | 
           | So how is this an actual black swan - a bird with wings...
           | and not a "black swan" - an unkown unknown (as described
           | eslewhere)?
        
       | CositaS wrote:
       | The actual article this story is about:
       | https://www.pnas.org/content/118/12/e2018977118
       | 
       | (the link was there but buried at the bottom of the page)
        
       | [deleted]
        
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