[HN Gopher] Turning desalination waste into a useful resource
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       Turning desalination waste into a useful resource
        
       Author : thereare5lights
       Score  : 36 points
       Date   : 2021-01-24 12:17 UTC (10 hours ago)
        
 (HTM) web link (news.mit.edu)
 (TXT) w3m dump (news.mit.edu)
        
       | dj_mc_merlin wrote:
       | > The researchers have discussed the concept with companies that
       | may be interested in the next step of building a prototype plant
       | to help work out the real-world economics of the process. "One
       | big challenge is cost -- both electricity cost and equipment
       | cost," at this stage, Kumar says.
       | 
       | Huh, I thought their big breakthrough would be figuring out how
       | to make this economically viable. It's not a big surprise you can
       | make useful chemicals out of brine, right?
        
       | detritus wrote:
       | Use it to maintain salinity levels in deep ocean currents, to
       | sustain current circulation patterns and reduce the impact of
       | arctic runoff, impacting weather systems. Or something.
       | 
       | https://www.nature.com/articles/s41467-020-14474-y
        
       | heimatau wrote:
       | HN community seems to really like desalination. Various
       | innovations seem to hit the FP occasionally.
       | 
       | I'll say this to the general sentiment. My 9th grade chemistry
       | teacher say 'your generation will face two major problems: xxxxxx
       | and water'[1]. He's been a sage in my life, retired for about 1.5
       | decades.
       | 
       | I say all this to attempt to say that 'this is refreshing' that
       | this community understands that we are in an impending crisis of
       | water. Onward! :)
       | 
       | [1] - I'm a millennium and I won't reveal 'xxxx' because I'm not
       | trying to incite anger but he was correct about 'xxx'.
        
         | billfruit wrote:
         | Also another thing I hear a lot of hype about is Atmospheric
         | Water Extraction, but as of now remains longway from being
         | practical at scale.
        
         | enkid wrote:
         | Why do the x's keep getting fewer? Is the crisis a lack of x's?
        
           | heimatau wrote:
           | > Why do the x's keep getting fewer? Is the crisis a lack of
           | x's?
           | 
           | Yeah. I ran out of ink.
        
         | inglor_cz wrote:
         | xxx = Mass migration?
         | 
         | Depends on where you live, it is already happening. And it is
         | sometimes caused by long droughts, actually.
        
         | umvi wrote:
         | xxx = misinformation
        
         | klyrs wrote:
         | I've got karma to burn, so I'll come out and address the
         | controversy straight on. xxxx is the rarity of Charizard in
         | Pokemon Go.
        
         | simonebrunozzi wrote:
         | xxx = pollution? energy?
         | 
         | edit: or a certain political guy?
        
         | andromeduck wrote:
         | My thesis in grade school thesis from ~17 years ago was that
         | the two most important problems to by solved in my lifetime
         | were going to be low cost, low emission and low land use energy
         | production and efficient information processing and
         | communication.
         | 
         | I think desal is much less of a problem if we had a cheap,
         | clean, and reliable source of energy to power it such as
         | nuclear.
         | 
         | Quality of life is strongly correlated with energy intensity.
        
           | heimatau wrote:
           | I'm not entirely sure how but in the past two years, I've
           | become a believer in the capitalism structure for the markets
           | and that it's _able_ to solve any given problem (including
           | what you 're saying). Capitalism just needs to get nudged
           | into a direction and the solutions will be a product of
           | markets.
           | 
           | To elaborate my point, through government subsidies: -
           | American has seen massive production of food (so much that we
           | waste an insane amount every year) - Massive creation with
           | minimal resources (via petrol innovation; even if y'all don't
           | like it, it was an easy win for society and we're living with
           | the second order effects) - Vehicle fuel efficient rise -
           | Green revolution is almost profitable without government
           | subsidies.
           | 
           | I'm not an economist but the game theory does seem to playout
           | in such a way, for the past century, to confirm 'we'll find a
           | way, given a nudge in the right direction'.
        
             | andromeduck wrote:
             | You should check out the Decouple podcast :)
             | 
             | https://podcasts.apple.com/us/podcast/decouple/id1516526694
        
             | toiletfuneral wrote:
             | Capital has shown it will not fix climate change but only
             | try and profit on the destruction. If free markets could
             | solve healthcare or the island of plastic in the pacific,
             | it would've happened.
             | 
             | Literally nothing is getting better while corporate
             | earnings increase, so wake me up when the market figures
             | out how to respond to actual problems, not just automate
             | away labor.
        
         | rbanffy wrote:
         | We don't have a water crisis. We have a clean energy one. With
         | abundant energy we could simply boil sea water to get drinkable
         | water. The biggest problem of the various desalination methods
         | are their energy cost, and this method to reprocess the brine
         | is meant to offset it by extracting commercial value from the
         | desalination residue. While it's great to make desalination
         | commercially viable, we also need to remember our energy needs
         | will not drop.
         | 
         | I have the nagging feeling that the "commercial" part is what
         | we'll need to solve if our species is to survive long term. In
         | some matters, whether its commercially viable should not be a
         | concern.
        
           | mschuster91 wrote:
           | > With abundant energy we could simply boil sea water to get
           | drinkable water.
           | 
           | That still leaves you with either solid salt that needs to be
           | disposed of (preferably, somewhere where it can't eventually
           | leach out into groundwater) or highly concentrated brine
           | which will kill anything near it.
        
             | hutzlibu wrote:
             | "highly concentrated brine which will kill anything near
             | it."
             | 
             | That sounds a bit dramatic, for salt in water, don't you
             | think?
             | 
             | Sure, it is not a enviroment, live can prosper and it kills
             | most living things, that would have to live in it, but it
             | is also not deadly toxic, "killing anything near it" like
             | your comment implies.
        
             | philwelch wrote:
             | How much waste salt would we have compared to the amount of
             | salt that we are going out of our way to extract or mine
             | already? I mean, I literally pay money for sea salt at the
             | grocery store.
        
               | enkid wrote:
               | How much salt do you use in a month? How much water do
               | you drink?
        
               | hansvm wrote:
               | That's not really a fair comparison. There's easily 25x
               | as much water vs salt in the ocean, and a 10x higher
               | fraction of water usage is residential than salt usage.
               | The break-even point you're pointing to is closer to
               | 250:1, not 1:1.
        
               | enkid wrote:
               | That's fair enough, but I still doubt you use 1/250 of
               | water in salt, even when you're cooking. If you add
               | things like showering, washing clothes, and lawn care,
               | it's not even close
        
               | hansvm wrote:
               | The numbers I gave did include factors like showering.
               | 
               | Edit: I do think that you use more than 1/250 salt vs
               | water in cooking though (whether by mass or volume). By
               | mass that's around 1tsp of salt per 6.3 cups of water,
               | and soup recipes for example will often call for that
               | much extra salt on top of whatever is already in the
               | other ingredients you're using.
               | 
               | Edit: Individual recipes are probably the wrong way to
               | look at that. It's recommended to eat under 1tsp of salt
               | (actual usage is higher in the USA) and drink over 10
               | cups of water each day, so whatever combination of
               | food/beverages you're taking in you still wouldn't quite
               | hit that crude 1/250 threshold.
        
               | philwelch wrote:
               | Salt is also useful for things other than eating it, and
               | more of those uses may be cost-effective if salt were
               | more plentiful.
        
               | throwawayboise wrote:
               | Sea salt contains microplastics. You should seek out
               | mined salt.
        
               | rbanffy wrote:
               | Or we could find a way to remove them from, say, the
               | brine.
        
             | andromeduck wrote:
             | Just put it back from whence it came. The extracted water
             | doesn't exactly leave the environment, it will find its way
             | back into the oceans anyway.
             | 
             | If the excess brine is diffused over a wide enough area or
             | as is often the case, the outlet of an estuary, local
             | disruption is minimal and global disruption is exactly
             | zero.
        
       | doodlebugging wrote:
       | I would also point out that there is an endless stream of oil-
       | field brines and related contaminated waters available for
       | processing should anyone want to have a continuous source of raw
       | material.
       | 
       | The industry, in its never-ending quest to monetize waste
       | products or to place the cleanup burdens on someone else (the
       | public usually) is currently trying to get Texas to agree to
       | allow pumping of these highly contaminated wastes into aquifers.
       | 
       | Any time you produce oil or gas you always produce some waste
       | water with it. Volumes will vary from well to well depending on a
       | lot of variables unique to a field or a well. This water, or most
       | of it, is not all water from production if I read the article
       | correctly, a lot of it is flow-back water from the fracking
       | process. That means it is not water that would normally be
       | reinjected to help maintain formation pressures to allow
       | continued production. It is water pulled from public and private
       | potable water supplies including, lakes, aquifers, etc. This
       | water should have been reserved for human consumption or for use
       | in farm or ranch maintenance.
       | 
       | T Boone Pickens set in motion the whole idea of gathering rights
       | to large volumes of water and selling it to users far from the
       | source. This really set the stage for the massive over-use of
       | public water in fraacking in the Permian Basin and other related
       | areas that saw a large fracking boom.
       | 
       | The potable water is gone now, polluted by the O&G industry, and
       | now they want to be able to just put it back where they found it
       | and let God sort out the contaminants. Disgusting really.
       | 
       | But, it sounds like a great opportunity for someone operating in
       | the water treatment space to test and validate options for
       | wastewater treatment and for recovering chemical and mineral
       | contaminants from non-potable water.
        
       | stareatgoats wrote:
       | > The team also continues to look at the possibility of
       | extracting other, lower-concentration materials from the brine
       | stream, he says, including various metals and other chemicals
       | 
       | Lithium from desalination brines seems to be one potential (and
       | promising) such [0], environmentally better in more than one way
       | than the current methods of lithium mining [1].
       | 
       | [0]
       | https://www.researchgate.net/publication/313372304_Towards_l...
       | 
       | [1] https://www.wired.co.uk/article/lithium-batteries-
       | environmen...
        
         | philwelch wrote:
         | You can also extract uranium from seawater, and use it to fuel
         | nuclear reactors, and use the nuclear reactors to power your
         | desalination.
        
           | enkid wrote:
           | Do you get enough volume for this to work? My intuition would
           | be the levels of Uranium would be low enough that it would
           | not be energy positive. Do you have more information about
           | this process?
        
             | vilhelm_s wrote:
             | Googling a bit: it takes about 13 MJ to desalinate 1 m^3 of
             | water by reverse osmosis. Seawater contains 3mg uranium per
             | m^3, which gives 2 MJ, So it's not energy positive.
        
             | 08-15 wrote:
             | Energy consumption of reverse osmosis is about 4kWh/t. The
             | byproduct is a ton of brine. Sea water contains about 3ppb
             | Uranium, so our brine contains 6mg of U per ton of fresh
             | water produced.
             | 
             | A 1GW nuclear power station consumes about 1t of U per year
             | and produces about 8000GWh of electricity in that time. So
             | we need about 1mg/8kWh. We got 12 times that much.
             | 
             | So, it sort of works out. Of course, this assumes a breeder
             | reactor and I pretended that brine is purified uranium. If
             | breeders are commercialized, it might be worth looking into
             | this. Right now, it isn't.
        
               | enkid wrote:
               | Awesome, thanks!
        
               | wolfhumble wrote:
               | So 4kWh/t is used to desalinate 2 tons of seawater that
               | turn into 1 ton of freshwater and 1 ton of brine?
        
               | credit_guy wrote:
               | Nice analysis. But the premise of the discussion here is
               | that people do the desalination for its own sake, not in
               | order to harvest Uranium.
               | 
               | This [1] article from 2012. It presents a Uranium
               | extraction method from seawater that would put the
               | extraction cost at $300/kg. Nowadays the market price is
               | about $70/kg. However, if method were to be applied to
               | brine instead of regular seawater, maybe the cost would
               | go down. Hard to see it going down by a factor of 5
               | though.
               | 
               | [1]
               | http://large.stanford.edu/courses/2012/ph241/ferguson2/
        
               | vilhelm_s wrote:
               | I think you overestimate the energy in uranium. 8000GWh
               | per tonne and year would be 28.8 TJ/kg, while the numbers
               | I have seen is more like 0.7 TJ/kg
               | (http://www.plux.co.uk/energy-density-of-uranium/).
        
               | 08-15 wrote:
               | What part of "this assumes a breeder reactor" did you not
               | understand?
        
             | jbay808 wrote:
             | I remember some projects going on at MIT on this topic.
             | 
             | https://dspace.mit.edu/handle/1721.1/111821
        
         | HarryHirsch wrote:
         | For a long time, bromine was an important product made from
         | brine. But that market has fallen away, since the lions share
         | used to be made into lead scavengers for leaded petrol. The
         | bromine works at Amlwch on Anglesey closed in 2004:
         | https://www.octelamlwch.co.uk/
         | 
         | The other obvious product would be magnesium, but they didn't
         | isolate magnesium chloride at the bromine plant. The Wylfa
         | nuclear power station was nearby, and Rio Tinto had an
         | aluminium smelter nearby to provide a base load. Since
         | magnesium is oftentimes produced through electrolysis a
         | magnesium plant would have made sense, but somehow they didn't
         | build one, likely for economic reasons.
        
       | dzhiurgis wrote:
       | There was some research into using it in concrete.
       | 
       | I thought perhaps it can be shipped to northern territories that
       | spray brine onto streets in winter to melt snow.
        
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