https://phys.org/news/2022-07-physicists-family-robust-superconducting-graphene.html Phys.org Topics * Week's top * Latest news * Unread news * Subscribe [ ] Science X Account [ ] [ ] [*] Remember me Sign In Click here to sign in with or Forget Password? Not a member? Sign up Learn more * Nanotechnology * Physics * Earth * Astronomy & Space * Chemistry * Biology * Other Sciences * Medical Xpress Medicine * Tech Xplore Technology * * share this! * 1.7K * 101 * Share * Email 1. Home 2. Physics 3. Superconductivity * * * --------------------------------------------------------------------- July 8, 2022 Physicists discover a 'family' of robust, superconducting graphene structures by Jennifer Chu, Massachusetts Institute of Technology Physicists discover a 'family' of robust, superconducting graphene structures MIT physicists have established twisted graphene as a new "family" of robust superconductors, each member consisting of alternating graphene layers, stacked at precise angles. Credit: Courtesy of the researchers When it comes to graphene, it appears that superconductivity runs in the family. Graphene is a single-atom-thin material that can be exfoliated from the same graphite that is found in pencil lead. The ultrathin material is made entirely from carbon atoms that are arranged in a simple hexagonal pattern, similar to that of chicken wire. Since its isolation in 2004, graphene has been found to embody numerous remarkable properties in its single-layer form. In 2018, MIT researchers found that if two graphene layers are stacked at a very specific "magic" angle, the twisted bilayer structure could exhibit robust superconductivity, a widely sought material state in which an electrical current can flow through with zero energy loss. Recently, the same group found a similar superconductive state exists in twisted trilayer graphene--a structure made from three graphene layers stacked at a precise, new magic angle. Now the team reports that--you guessed it--four and five graphene layers can be twisted and stacked at new magic angles to elicit robust superconductivity at low temperatures. This latest discovery, published this week in Nature Materials, establishes the various twisted and stacked configurations of graphene as the first known "family" of multilayer magic-angle superconductors. The team also identified similarities and differences between graphene family members. The findings could serve as a blueprint for designing practical, room-temperature superconductors. If the properties among family members could be replicated in other, naturally conductive materials, they could be harnessed, for instance, to deliver electricity without dissipation or build magnetically levitating trains that run without friction. "The magic-angle graphene system is now a legitimate 'family,' beyond a couple of systems," says lead author Jeong Min (Jane) Park, a graduate student in MIT's Department of Physics. "Having this family is particularly meaningful because it provides a way to design robust superconductors." 'No limit' Jarillo-Herrero's group was the first to discover magic-angle graphene, in the form of a bilayer structure of two graphene sheets placed one atop the other and slightly offset at a precise angle of 1.1 degrees. This twisted configuration, known as a moire superlattice, transformed the material into a strong and persistent superconductor at ultralow temperatures. [INS::INS] The researchers also found that the material exhibited a type of electronic structure known as a "flat band," in which the material's electrons have the same energy, regardless of their momentum. In this flat band state, and at ultracold temperatures, the normally frenetic electrons collectively slow down enough to pair up in what are known as Cooper pairs--essential ingredients of superconductivity that can flow through the material without resistance. While the researchers observed that twisted bilayer graphene exhibited both superconductivity and a flat band structure, it wasn't clear whether the former arose from the latter. "There was no proof a flat band structure led to superconductivity," Park says. "Other groups since then have produced other twisted structures from other materials that have some flattish band, but they didn't really have robust superconductivity. So we wondered: Could we produce another flat band superconducting device?" As they considered this question, a group from Harvard University derived calculations that confirmed mathematically that three graphene layers, twisted at 1.6 degrees, would exhibit also flat bands, and suggested they may superconduct. They went on to show there should be no limit to the number of graphene layers that exhibit superconductivity, if stacked and twisted in just the right way, at angles they also predicted. Finally, they proved they could mathematically relate every multilayer structure to a common flat band structure--strong proof that a flat band may lead to robust superconductivity. "They worked out there may be this entire hierarchy of graphene structures, to infinite layers, that might correspond to a similar mathematical expression for a flat band structure," Park says. Shortly after that work, Jarillo-Herrero's group found that, indeed, superconductivity and a flat band emerged in twisted trilayer graphene--three graphene sheets, stacked like a cheese sandwich, the middle cheese layer shifted by 1.6 degrees with respect to the sandwiched outer layers. But the trilayer structure also showed subtle differences compared to its bilayer counterpart. "That made us ask, where do these two structures fit in terms of the whole class of materials, and are they from the same family?" Park says. An unconventional family In the current study, the team looked to level up the number of graphene layers. They fabricated two new structures, made from four and five graphene layers, respectively. Each structure is stacked alternately, similar to the shifted cheese sandwich of twisted trilayer graphene. The team kept the structures in a refrigerator below 1 kelvin (about -273 degrees Celsius), ran electrical current through each structure, and measured the output under various conditions, similar to tests for their bilayer and trilayer systems. Overall, they found that both four- and five-layer twisted graphene also exhibit robust superconductivity and a flat band. The structures also shared other similarities with their three-layer counterpart, such as their response under a magnetic field of varying strength, angle, and orientation. These experiments showed that twisted graphene structures could be considered a new family, or class of common superconducting materials. The experiments also suggested there may be a black sheep in the family: The original twisted bilayer structure, while sharing key properties, also showed subtle differences from its siblings. For instance, the group's previous experiments showed the structure's superconductivity broke down under lower magnetic fields and was more uneven as the field rotated, compared to its multilayer siblings. The team carried out simulations of each structure type, seeking an explanation for the differences between family members. They concluded that the fact that twisted bilayer graphene's superconductivity dies out under certain magnetic conditions is simply because all of its physical layers exist in a "nonmirrored" form within the structure. In other words, there are no two layers in the structure that are mirror opposites of each other, whereas graphene's multilayer siblings exhibit some sort of mirror symmetry. These findings suggest that the mechanism driving electrons to flow in a robust superconductive state is the same across the twisted graphene family. "That's quite important," Park notes. "Without knowing this, people might think bilayer graphene is more conventional compared to multilayer structures. But we show that this entire family may be unconventional, robust superconductors." --------------------------------------------------------------------- Explore further Unusual superconductivity observed in twisted trilayer graphene --------------------------------------------------------------------- More information: Jeong Min Park et al, Robust superconductivity in magic-angle multilayer graphene family, Nature Materials (2022). DOI: 10.1038/s41563-022-01287-1 Journal information: Nature Materials Provided by Massachusetts Institute of Technology Citation: Physicists discover a 'family' of robust, superconducting graphene structures (2022, July 8) retrieved 11 July 2022 from https: //phys.org/news/ 2022-07-physicists-family-robust-superconducting-graphene.html This document is subject to copyright. Apart from any fair dealing for the purpose of private study or research, no part may be reproduced without the written permission. 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