The granites.—The term granite was originally used to designate a granular, i.e., a distinctly crystalline, rock, and it is still popularly and properly so used. In scientific treatises it has usually been confined to a special aggregate of crystals of quartz, feldspar, and mica. It has recently been proposed to give it again a more general application, though not quite its original one, by including under it all holocrystalline rocks composed of dominant quartz and feldspar of any kind, with mica, hornblende, or other minerals in subordinate amount. In scientific literature as it now stands, granite consists of quartz, feldspar, and mica, the feldspar being of the alkali-potash or soda variety (orthoclase, microcline, or albite), and the mica, either muscovite or biotite. In the type form the crystals are distinct and sometimes large (Fig. 344). They are intimately mingled with one another, and in growing, interfered more or less with each other and so became interlocked. The granites are among the most common and easily recognized of the holocrystalline rocks. Their color is mainly dependent upon the feldspar, the red and pink varieties of the mineral giving rise to red granite, and the white varieties to gray granite.
Very few granites conform strictly to the type. They vary by the addition and substitution of other minerals, and these sometimes become as prominent as the type minerals. The soda-lime feldspars sometimes take the place of the orthoclase, or accompany it; hornblende and other minerals take the place of the biotite, or occur with it; and so on. Whenever one of these replacing or accessory minerals is notable in quantity, its name is often prefixed, as hornblende-granite, oligoclase-granite, zircon-granite, etc. In this way the rock grades almost insensibly into the syenites, diorites, etc. Variations also arise from the absence of one of the three leading minerals. If mica is absent, the rock is termed an aplite (quartz and feldspar). If the feldspar is absent, it is called a greisen (quartz and mica). If quartz is absent, it is termed a minette (feldspar and mica). These varietal terms are neither universally nor always consistently used, and it is to be hoped they will be replaced by the systematic nomenclature recently proposed and outlined later (p. 451).
The granites were formed from a magma rich in silica, alumina, potash, and soda, but generally poor in lime, iron, and magnesia. Incidentally other substances were present. The alumina, potash, and other bases united with so much of the silica as was required to form the feldspars and micas, and the remaining silica crystallized into quartz.
Granite is normally a massive rock without foliation or banding. If it takes on these characters, it becomes a gneiss, and passes into the foliated or schistose class of rocks, to be discussed later. The texture of graphic granite (see pegmatite) is notably peculiar, due to the simultaneous crystallization of the quartz and feldspar (Fig. 345).
The syenites.—When the mica of a granite is replaced by hornblende, the rock is now commonly known as a hornblende-granite, but it was formerly called syenite, because found at Syene on the Nile. The term syenite is now applied to a rock consisting essentially of feldspar and hornblende or mica, but there is a complete gradation from the granites to the syenites. The magma of the syenites was richer in iron and magnesium than the typical granitic magma. The syenites also grade into other classes, as do the granites, and are named by similar prefixes, as augite-syenite, etc., and some of these varieties have special names. The syenites are red or gray, according to the color of the feldspar, and are usually darker than the granites. The texture of syenite is like that of granite. In the scheme of field names recently proposed, syenite is made to include all holocrystalline rocks composed mainly of feldspar of any kind, with subordinate amounts of mica, hornblende, pyroxene, and other minerals, but without a noticeable amount of quartz.
The diorites.—These embrace rocks which were crystallized from a magma still poorer in silica and the alkalies, and richer in the earthy bases. In composition they closely approach the ideal average rock, but usually fall a little below it in silica and the alkalies, and rise a little above it in the earthy bases. In current usage, diorite is defined as an intimate mixture of crystals of hornblende and a plagioclase feldspar. It differs from the syenite in having plagioclase feldspar instead of orthoclase. By substitutions and the addition of accessory minerals, the diorites graduate toward the granites and syenites on the one hand, as already noted, and into gabbros on the other.
In the scheme recently proposed, all holocrystalline rocks in which hornblende is dominant and feldspar subordinate are classed as diorites.
The gabbros.—The name gabbro was formerly applied to a coarse-grained basic rock consisting of labradorite and diallage, but the name has been gradually extended until it embraces a large group of rocks that have essentially the same composition as the dolerites mentioned below, but are coarser in crystallization, and the crystals do not embrace one another (i.e., are not ophitic). The principal minerals are plagioclase (normally labradorite) and pyroxene (normally diallage) with magnetite or ilmenite. They are usually dark, heavy rocks. The pearly luster of the cleavage faces of the diallage, when present, gives a peculiar sheen to a fresh surface of the rock. In the recently proposed field names, gabbro is made to include all phanerocrystalline rocks in which pyroxene predominates, attended by feldspar of any kind in subordinate quantity, with or without hornblende or mica.
The peridotites.—These stand at the basic end of the series, having been formed from a magma in which the silica was low (39–45 per cent.), as were also the alumina, lime, and alkalies, but in which the magnesia was relatively very high, ranging from 35 to 48 per cent. The rock consists very largely of olivine associated with pyroxene, magnetite, and other very basic minerals. Little or no feldspar is present. The peridotites are much less abundant than the preceding classes and represent a very distinctive phase of the magma in which the magnesia was greatly concentrated.
Closely allied to the peridotites are rocks which are made up largely of a single basic mineral, as augitite, pyroxenite, hornblendite, rocks essentially formed of the minerals augite, pyroxene, and hornblende respectively. It will be noted that in these rocks the magma became quite simple in nature, just as at the acid end of the series certain rocks become comparatively simple from the concentration of the acid element, as in certain acidic granites, felsites, etc. (See pp. 523–524.)
The basalts.—The term basalt is used in a somewhat comprehensive way to embrace dark, compact, igneous rocks that appear to be nearly homogeneous, owing to the minuteness of the crystals, which are usually so small as to be identifiable only under the microscope. In some cases the crystals are scattered throughout a ground-mass after the porphyritic fashion. In some of these cases there is a true glassy base, and in such cases the rock does not strictly belong in the holocrystalline group. In the more typical cases the constituent minerals are very minutely crystallized and intimately intermixed. The leading minerals are plagioclase (usually labradorite or anorthite) and pyroxene (usually augite), with olivine and magnetite or ilmenite usually present. There is a considerable range in chemical nature, but the basalts are relatively poor in silica, usually also low in potash and soda, but rich in lime, magnesia, and the iron oxides. They are classed as basic and are sometimes highly so. The magmas of the basalts are especially fluid, and when poured forth upon the surface easily spread out in thin sheets. In cooling they are prone to take on a columnar or basaltic structure, the columns standing at right angles to the surfaces exposed to cooling. The columns are sometimes curved, owing to the peculiar attitude of the cooling surface. The columns of Giant’s Causeway and Fingal’s Cave are familiar examples.
The dolerites.—The basalts graduate insensibly into the dolerites; indeed the dolerites may be regarded simply as basalts of coarser crystallization. The minerals are evident to the eye and range up to medium size. The more abundant minerals are plagioclase feldspar (labradorite or anorthite), with one or more of the ferromagnesian minerals (augite, olivine, or biotite), and magnetite or ilmenite. In the growth of the minerals one crystal frequently embraces others, giving an ophitic structure. The dolerites have many varieties, due either to accessory minerals or to the development of some of the constituents more amply than the rest. The type may be said to consist of plagioclase and augite, the other minerals being regarded as accessories. Magnetite or ilmenite is almost universally present. The varieties are usually designated by prefixes, as olivine-dolerite, enstatite-dolerite, etc., but special names are also used for some of these.
The ancient dolerites have usually undergone internal changes and such rocks are often called diabases. While the use of the term has not been uniform, it accords with the better practice to regard the diabases simply as partially altered dolerites and basalts. In general, therefore, the diabases are but ancient dolerites.
The difficulty of distinguishing many of the foregoing rocks from each other by any means available in the field, owing to the minuteness of the crystals, and to the gradation of one type of rock into another, makes it desirable to employ certain general names which will correctly express the leading character of the rock without implying a knowledge of the precise mineral composition. A convenient term of this kind is greenstone, which merely indicates that the ferromagnesian minerals are prominent and usually give a greenish or dark cast to the rock. The greenstones embrace the diorites, dolerites, some of the gabbros and the basalts, and may even extend to the peridotites and some of the more hornblendic of the granitoid rocks. Another convenient name is trap, which may be used for any dark, heavy igneous rock. The name (from trappe, stairs) refers to the step-like arrangement which the edges of the superimposed sheets of lava often take, especially when the lava is of the free-flowing, basaltic kind.
The term basalt is sometimes used to embrace any of the very fine-grained dark igneous rocks. In such cases, it covers the very fine-grained dolerites, diorites, peridotites, etc. The term granite was used originally for any coarse-grained crystalline rock, and there is a tendency to revive this early use. In general descriptions, some of our best petrographers call any coarsely crystalline rock (e.g., coarse-grained syenites, diorites, gabbros, etc.) granite. The term granitoids may be used with strict propriety to cover all rocks of this class.
Rocks, though commonly made the symbol of the abiding, are subject to constant slow changes. Through these changes newer rocks have been derived from older ones, and still others in turn from these derivatives, and so on in an endless chain. All derived rocks are conveniently termed secondary, though they may be several generations removed from the primitive rocks, and even the primitive rocks, as we now understand them, may be themselves derived. The ordinary changes of rock are most active at or near the surface, and the processes of such change have already been discussed in part under the titles “Weathering” (pp. 54 and 110), “Erosion” (pp. 119–123 and 342–349), “Transportation” (pp. 115–119 and 354–355), and “Deposition” (pp. 177–204 and 355–363).
Regolith.—The first great product of the surface changes is mantle-rock (regolith), which comprehends all the loose matter that springs from rock decay, wear, fracture, and other forms of disintegration. It lies in an unconsolidated sheet on the face of the land, whether as soil, sand, clay, earth, gravel, or loose rock.
Disrupted products: arkose and wacke.—In dry regions, in cold regions, on mountain heights and precipitous slopes, and under other conditions where sudden changes of temperature and frost action work efficiently, rocks are broken down into fine fragments without much chemical decomposition. Such disaggregated rather than decomposed matter, if derived from granitic and similar crystalline rocks, is termed arkose, or arkose sand, and consists of fragments of quartz, feldspar, mica, etc. Common sand consists essentially of quartz grains. If the fine fragments are derived from the darker igneous rocks, and consist mainly of grains of plagioclase feldspar, and ferromagnesian minerals, it is sometimes called wacke. This term is not widely used in just this sense, but there seems to be an important place for it, and it will be so employed in this work. These disaggregated sands are but special phases of the mantle-rock.
Disintegrated products.—When the surface-rock is chemically decomposed, the residual material is confined mainly to the insoluble portions, i.e., the silicious and clayey parts; while the lime, magnesia, soda, potash, and similar substances are largely dissolved and borne to the ocean. The potash is somewhat more disposed to remain with the clays than the soda, lime, or magnesia; but residues of all are usually present.
Shales, sandstones, and conglomerates.—As already shown in the discussion of the atmosphere and surface-waters, the mantle-rock is constantly being borne away and redeposited in lodgment spots on the land or in the basins of the sea, while it is constantly being renewed below. It is an evanescent but ever-renewed derivative mantle. In this process of renewal, removal, and redeposition, the mantle material is usually assorted into mud, sand, and gravel; and these several classes of material are laid down more or less separately, and usually take the stratified form, because their deposition depends on different degrees of motion of the transporting waters or wind. When these several classes of material become cemented or otherwise hardened, they give rise to shales (cemented muds), sandstones (cemented sands), and conglomerates (or pudding-stones, cemented gravel, Fig. 346). If the coarse material remains angular, they form breccia instead of conglomerates (Figs. 347 and 348). For the most part, the deposits of mud, sand, and gravel are made under the sea or in lakes and estuaries, but they are also formed on the land in lodgment basins, in low-gradient valleys, and on base-plains. The deposits of sediment on land have received less recognition than they deserve. When formed under the sea or in other life-sustaining waters, shells and other organic material are liable to be entrapped and to form a part of the rock. These organic remains, or fossils, greatly aid in interpreting the deposits in which they occur. Fossils are less liable to be preserved in sedimentary deposits formed on land. There is, therefore, some ground to suspect that great series of sandstones and shales which do not contain marine or fresh-water fossils were formed in lodgment basins on land, though the absence of fossils cannot be regarded as proof of such origin.
Fig. 351.—Globigerina ooze. Magnified 20 times. (Murray and Renard.)
Fig. 352.—Pteropod ooze. Magnified 4 times. (Murray and Renard.)
Limestones and dolomites.—Of the lime, magnesia, soda, and potash leached out of the surface-rocks and carried to the ocean in solution, the lime is largely extracted to form the shells, skeletons, teeth, armor, and other hard parts of sea-animals and sea-plants. These limy parts are at length left on the floor of the ocean and become more or less disintegrated and help to form beds of lime-mud and lime-sand which in time are cemented into limestone (Figs. 349, 350, 351, and 352). A larger proportion of the magnesia remains in solution in the sea-water, but in ways not yet well understood, the magnesia sometimes unites with the lime to form dolomite, a double carbonate of lime and magnesia (Ca,Mg)CO3. This change is sometimes local, and sometimes affects great series of beds, more commonly the ancient ones than the modern. Sometimes the dolomization appears to have taken place long after the original limestone was formed and probably sometimes after it was lifted out of the sea, while in other cases it seems to have taken place while the sediment was accumulating, or at least before the next overlying beds were laid down. The potash in solution is to some large extent taken up by the land- and sea-plants or is retained in the clays, and through them becomes again incorporated in the sediments. The soda largely remains in solution in the sea-water.
Precipitates.—When a portion of the ocean-water is isolated in a region where evaporation from the surface of the water is greater than the rainfall on it, and the inflow from the tributary basin, the lime, magnesia, soda, potash, and other dissolved substances (solutes) are concentrated until the water becomes saturated. The solutes are then precipitated in the order in which they reach the point of saturation. This order, when taken in strict and full detail, gives a very complex series, but the leading deposits are calcium carbonate (limestone), calcium sulphate (gypsum), and sodium chloride (halite or rock salt) (see p. 375). Isolated lakes in arid regions may give rise to similar deposits. It has sometimes been thought that the ancient limestones were produced largely by precipitation from concentrated sea-water. While this is probably the case in some instances and to some degree, it has not been demonstrated that the great limestone formations were made to any large extent in this way. The more accepted view is that the limestones in the main were made from organic remains. The lime in solution in the ocean is chiefly in the form of the sulphate.
Iron Ore-beds.—In a somewhat different way iron ore-deposits are formed by the precipitation of iron oxide or iron carbonate from solutions of ferrous compounds. The ferrous compounds in solution were leached from iron-bearing rocks by percolating waters. The most familiar case is that of iron-bearing springs. On exposure to the air, the iron compounds in solution undergo change, and ferric oxide is thrown down, usually forming limonite (Fe2O3,3H2O), but sometimes hematite (Fe2O3). This change is common in marshes and gives origin to “bog-ore.” Similar deposits take place in certain shallow lakes, and hence are known as “lake ore.” Iron ore sometimes also forms at the bottom of a peaty bed or in muddy soil. In connection with the great coal formations, beds of iron carbonate (siderite) occur. Organic matter seems to play a great part both in the original solution and the later deposition of these ores. From certain soils and clay-beds on which the ancient coal-producing forests grew, the iron has been almost completely removed, either by the action of the roots, or more probably by organic acids arising from their decay and from the decaying vegetation on the surface. On flowing into shallow bodies of water or into marshes, the waters containing such dissolved iron compounds usually throw down their iron content either as a carbonate (siderite), or as a hydrous ferric oxide (limonite). The siderite is formed where decaying vegetation is present to furnish abundant carbon dioxide and to partially protect the iron solution from oxidation, and the limonite where free oxidation takes place. Sand, silt, clay, or calcium carbonate often accumulates with the iron precipitate, and the result is an impure deposit which becomes an ironstone. Such deposits often become segregated into nodules, as will be explained later. It is thought that diatoms sometimes aid in the deposit of iron ore in shallow waters.
Silicious deposits.—In the decomposition of igneous rocks, a certain portion of the silica, as well as of the bases, is dissolved and carried away in solution. Certain organisms extract this from solution for their skeletons, just as others extract calcium carbonate. The accumulation of these silicious skeletons often forms silicious rocks. The diatom, radiolarian, and other oozes (Fig. 353) of the deep sea are the great examples. Sometimes layers of infusorial earth, tripolite, arise from the shells of diatoms and other aquatic organisms secreting silica. The waters in which such earths accumulate are rather shallow, and either fresh or salt. The most familiar examples of indurated rocks formed in this general method are the flints and cherts (impure flints) that occur in limestone and chalk, chiefly as nodules, but sometimes in distinct beds.
Organic rocks.—While most limestones, chalks, flints, cherts, and the silicious and calcareous oozes are formed through the agency of organisms, they are not themselves strictly organic. There is, however, a small but important group of rocks formed directly from organic matter. In favorable situations the woody parts of plants, falling into water, are so far preserved from decay that they accumulate in beds, and by slow changes pass into peat, lignite, bituminous coal, anthracite, and graphite. The first of these is composed essentially of carbohydrates and hydrocarbons much as plants are, while the last two are mainly carbon, and the intermediate members represent stages of passage from the first to the last. They are all derived from the strictly organic part of the plants, and spring essentially from the atmosphere and hydrosphere. They are only indirectly associated with the evolutions of the inorganic series.
Besides the extreme alterations of rocks at the surface of the earth by which they pass into solution and into residual mantle-rock, and at length by transportation and re-sedimentation become stratified rocks, as just described, those rocks which are not at the surface are subject to changes that give rise to several varieties of altered rocks. These changes are taking place constantly under ordinary conditions, though usually very slowly. Under great pressure and heat the changes are relatively rapid and intense, and lead to results not reached under other conditions. These more profound changes are termed metamorphism, and will be considered later. It is, however, important to recognize the great fact that the outer part of the earth, for perhaps 20,000 or 30,000 feet, is more or less fractured and permeated by water containing in solution various substances dissolved from the atmosphere, the soil, and the rocks through which it has already passed, and that this permeating and circulating water is now, and for long ages has been, working changes in the rocks, partly by dissolving matter out of them, partly by depositing matter in them, and partly by furnishing a medium through which new combinations of their constituents may take place. This outer fractured portion of the lithosphere has been called the zone of fracture.[201]
Oxidation and deoxidation.—At and above the surface of the underground water, where the rocks are easily reached by atmospheric waters carrying much free oxygen, and by the air itself, oxidation prevails. Through oxidation the ferrous oxides are changed to ferric oxides, a change which is usually manifested by a transition from a gray, green, or blue color, to buff, brown, yellow, or red. The partial progress of such oxidation is often shown in a fractured block or bowlder whose exterior shows the latter colors, while the interior shows the former. The sulphides, of which common pyrites (FeS2) is the most familiar, are oxidized into sulphates, and then sometimes pass on into the higher oxides and other compounds. Thus copperas (FeSO4) arises from pyrites (FeS2) by direct oxidation of both Fe and S. The sulphuric acid of this compound, uniting with some base stronger than the ferrous oxide, gives rise to further oxidation and results in hematite (Fe2O3) and limonite (Fe2O3,3H2O). In general, the mineral constituents of the rocks in this upper zone take on their maximum states of oxidation. This oxidation affects more or less profoundly the character of the rock as a whole. Deeper in the earth oxidation is less prevalent, and the action is sometimes reversed and deoxidation takes place. So also wherever organic matter is undergoing decomposition deoxidation is likely to occur.
Solution and deposition.—Solution preponderates in the upper part of the zone of fracture, but deposition is prevalent in its deeper parts. The calcium carbonate and silica dissolved near the surface are often deposited below as calcite and quartz. The sulphates and other sulphur compounds that are formed and dissolved near the surface are apt to be changed into sulphides lower down by deoxidation. The soluble oxides and other compounds formed near the surface are often likewise precipitated below. This is particularly true where the descending waters encounter decomposing organic matter, and where they mingle with waters that have followed other routes and have become charged with different solutes. On coming together, reaction between the constituents takes place, resulting sometimes in new solutions and sometimes in precipitation.
If these lower deposits of calcite, quartz, sulphides, etc., are made in the pores of the rock, they change its texture and composition. If they are made in fissures they constitute veins, and if a sufficient percentage of the vein matter consists of valuable metallic compounds, they constitute ores.
As the waters descend they suffer greater and greater pressure and some increase of temperature, and these changes modify their power to hold substances in solution. In general, the waters increase in solvent power, but the effect is different for different mineral substances, and hence as a rule the waters are taking up some substances and laying down others as they proceed. After penetrating to greater or less depths, the waters may come again to the surface, either because they are pushed up by the higher head of the waters behind, or because they become warmer and thus lighter, and are forced up by the heavier cold waters above, or else they pass up by diffusion through the descending waters. In any case, the deep, warm waters, usually rather highly charged with material dissolved in their previous courses, are apt to deposit some of their burden as they ascend to horizons of lower pressures and temperatures. They are particularly liable to make deposits where they commingle with other waters differently charged with solutes. Thus internal changes in the body of the rocks are, and for ages have been, taking place. In the upper part of the depositing zone, calcite is the dominant mineral deposited, while in the lower, quartz is more common; but much depends on local conditions and other influences, and no rigid rule holds good.
Hydration and dehydration.—Water sometimes unites directly with some of the constituents of a rock and produces hydrated minerals, i.e., minerals that have water as an element of their constitution, not simply water absorbed into their pores. A large class of minerals known as zeolites, because they swell up and undergo life-like contortions when their basic water is driven off by heat, are examples of hydrous products. A more familiar example is limonite (Fe2O3,3H2O), of which yellow ocher is a variety, which on heating sufficiently gives off its water and becomes hematite (Fe2O3) or red ocher. The turning of yellow clay to red brick on burning is a familiar example of dehydration. The general tendency in the upper zones penetrated by water is toward hydration. In the lower zones, where the pressure is great, Van Hise holds that there is a tendency toward dehydration, if the rocks have been previously hydrated. This may be the case if rocks have once been near the surface and later deeply buried by the accumulation of sediments on them. If the principle holds, rocks subjected to intense lateral pressure may be dehydrated.
Carbonation and decarbonation.—The igneous rocks are largely silicates. The carbonic acid of the surface-waters and of the air acting upon them, converts them, in part, into carbonates. In this way has arisen most of the original supply of calcium and magnesium carbonates. Original carbonates formed in this way are precipitated and redissolved again and again. The carbonates in river-waters are much more largely solutions of previously solid carbonates than original carbonates formed from the silicates. The potassium and sodium of the silicates also form carbonates, but by preference they unite with the sulphur and chlorine, and hence appear more largely as sulphates and chlorides.
Carbonation is usually accompanied by oxidation and hydration. These several processes break up the complex and relatively unstable silicates into simpler and more stable silicates, carbonates, and oxides. This is illustrated by the following formulas illustrative of the changes undergone by augite and labradorite, two common rock-forming minerals.
The composition of augite may be represented by the formula
| { | CaO.(Mg,Fe)O.2SiO2 |
| (Mg,Fe)O.(Al,Fe)2O3.SiO2. |
Assuming Mg and Fe to be equal in amount in the first half of the above formula, and Mg and Fe to be equal in the first part of the second half, and Al and Fe to be equal in the last part of the second half, doubling the whole and allowing it to be acted on by CO2 and H2O, we have
The hydrous silicate of the last part of the equation is kaolin.
The composition of labradorite is represented by the formula
| { | CaO.Al2O3.2SiO2 |
| Na2O.Al2O3.6SiO2. |
Assuming the two molecules represented by this formula to be equally abundant, and allowing the whole to be acted on by H2O and CO2, we have
When waters charged with carbonates descend into the earth they are likely to precipitate a portion of their burden, forming calcite and other crystalline carbonates, and hence these are among the most common minerals found in veins and rock cavities. Carbonates are also deposited when carbonate-charged waters come to the surface and evaporate or lose a part of their carbon dioxide.
Decarbonation also takes place, but it is, at least at the surface, a much less common process, and its conditions are less well understood. Sufficiently high heat will drive off the carbon dioxide, as in the artificial process of burning lime, but this is rarely observed in nature. Even lava intrusions do not usually reduce limestone to caustic lime at any appreciable distance from the contact. It is believed, however, that in the deeper zones, where high pressure and heat prevail, carbonates are changed into silicates, thus in a way reversing the process that prevails at the surface, and setting free again a portion of the carbon dioxide that had become locked up in the formation of the carbonates. To this action some of the carbon dioxide of deep-seated thermal springs is assigned.
The carbonation of the silicates takes place at the expense of the carbon dioxide of the atmosphere and hydrosphere, and hence in proportion as the igneous rocks are changed into carbonates, the atmosphere and hydrosphere are depleted of carbon dioxide, new supplies being neglected. As plants are dependent on carbon dioxide for their principal food, and as animals are dependent on plants for their food, directly or indirectly, the process of carbonation has a profound bearing on the life-history of the earth, and will often invite attention in the historical chapters. It is sufficient here to note that carbonation is one of the chief processes in the alteration of igneous rocks and furnishes, directly and indirectly, a larger percentage of the mineral substances dissolved in the waters that flow from the land, than any other single process.
Molecular rearrangements.—Besides these and similar changes that involve additions and subtractions through the agency of percolating water, the molecules of some of the rock constituents rearrange themselves, or the elements enter into new chemical relations; thus, pyroxene may pass into hornblende by a change of the crystalline arrangement of the molecules. The change may sometimes be caught in progress, the outer part of the crystal being hornblende (which when thus formed is called uralite), while the heart of the crystal remains pyroxene. So aragonite may pass into calcite.
By changes of the foregoing kinds, many crystalline rocks are much altered. Some become chloritic from the development of the soft, green hydrated mineral, chlorite, derived from the pyroxene, amphibole, biotite, and perhaps other silicates of the original rock. Others become talcose from the development of talc, a very soft, unctuous, hydrous magnesian silicate developed from the magnesian minerals of the original rock. Soapstone or steatite is a rock composed essentially of such secondary material. Serpentine is a rock made up of a similar secondary mineral (serpentine) apparently derived from chrysolite (olivine) and other magnesian minerals. Epidote, a complex lime-iron-alumina silicate, often recognizable by its peculiar pistachio-green color, is derived from other silicates, and is rather common in many varieties of crystalline rocks. Melaphyre is a name applied rather loosely and variously to certain altered basic rocks of the basalt family. Diabase is essentially an altered dolerite. Nearly all the very ancient basaltic rocks show notable degrees of alteration, even though they appear to have escaped unusual dynamic conditions since their original formation, and hence their alteration seems to have resulted chiefly from the operation of unobtrusive agencies, chief among which is the circulation of water.
The foregoing processes by which primitive or igneous rocks are disintegrated and their constituents converted into fragmental material may be said to constitute the descent of rocks in its fuller sense. Viewed chemically, the great features of the process are (1) the breaking down of the complex silicates, and (2) the gathering of the resultant simpler silicates (mainly aluminum silicates) into the silt and clay beds, (3) the assembling of a large part of the free acidic element (the quartz) into the sand and gravel beds, and (4) the concentration of a large part of the earthy basic element (the calcium, magnesium, and iron oxides) into the calcareous, magnesian, and iron deposits, while (5) a large part of the alkaline basic remainder (the sodium, and potassium oxides) is dissolved and held in the sea-water. Physically, the great features are (1) the disaggregation of the antecedent rock, and (2) the separation from one another of products which are physically unlike, that is, the coarser from the finer, and the heavier from the lighter, and (3) the aggregation of these diverse materials in more or less distinct beds. It is to be noted that while the rearrangement of the sediments is made on the basis of their physical characters, it results in chemical differentiation as well, for the products of rock decay, which are physically diverse, are often chemically diverse as well. The physical assortment and the stratification are to be looked upon as a step in the direction of a simpler grouping of the material. On the whole, the process is descensional in character.
Running hand in hand with this descensional process, there has always been a reascensional process by which the coherence, the crystallization, and in some measure the complex composition of the rocks are restored. This is partially due to external mechanical agencies, but chiefly to internal chemical and molecular forces.
Two general phases of this reconstructional work are recognized. The first, simplest and most universal, is that by which the incoherent materials produced by the descensional processes, i.e., the muds, sands, and clastic materials generally, are hardened into firm, coherent shales, sandstones, and limestones, and incidentally more or less changed in composition and molecular arrangement. The second is that by which more profound changes of induration and of composition are wrought, bringing the rock back to a state resembling its original crystalline character. This is known as metamorphism. Often, however, it is but an extension and intensification of the more common processes of the first class. Metamorphism is essentially reconstruction.
Induration under ordinary pressures and temperatures.—All kinds of loose fragmental material, whether soils, earths, clays, sands, gravels, volcanic ashes, cinders, or other forms of clastic or pyroclastic material, may become hardened into firm rock either by pressure, or by cementation, or by both. Pressure and cementation commonly act together and aid each other. The ordinary pressures arise from the weight of the overlying material, and these of course increase with depth. Extraordinary pressures arise from the shrinkage of the earth and perhaps from other sources. The fragments of the clastic material, on being pressed together for long periods, weld more or less at the points of contact. If they are irregular, angular, or elongate, they come to interlock more or less like the fragments of macadam, and this coöperates with the welding. The process is greatly aided by water-bearing solutions of lime, silica, etc. which are deposited at the points where the fragments press upon each other. It is here that the capillary spaces are most minute and deposition is most liable to take place. Sometimes a film of mineral matter is laid down over the surfaces of the fragments and serves to bind them together. This process goes on wherever the ground-waters are in a depositing condition, just as the opposite process of disintegration takes place wherever the waters are in a solvent state. At and near the surface of the land, the waters are usually in the latter condition and disintegration is in progress, as already noted, but this is not always so. At times and places, the water from within the rock-mass may come to the surface and evaporate, and in so doing leave all its dissolved material on the surface, or within the outer pores of the mass, as cementing material. The exterior thus becomes firmly bound together, “case-hardened,” as it is termed. This may be seen in the drying of a lump of mud, the exterior of which often becomes quite firm. It is seen in quarry-rock, especially sandstone, which is sometimes soft and easily worked when taken wet from the earth, but which hardens as the water—the “sap” of the quarrymen—dries out and deposits its solutes in the capillary spaces of the grains of the surface. It is obvious that it is the very last of the “sap” which contains the most concentrated solutes, and that this last remnant is held in the minute capillary spaces where the grains touch each other, and hence the last stage of drying leaves the cement at the points where it is most effective. In natural exposures of sandstone, the pores of the outer shell sometimes become almost completely filled in this way with silicious deposits, and the sandstone is changed into a quartzite.
In the sea, and in the deep water underground, the common habit of the water is to deposit more than to dissolve, though it is doing more or less of both. As a rule, therefore, loose material in these situations becomes bound more or less firmly into rock, and hence what were originally loose sand beds become sandstones; what were soft muds become shales or limestone, according to composition; what was gravel becomes conglomerate; what was chipstone becomes breccia; what were volcanic ashes, cinders, and lapilli become tuffs; and what were masses of volcanic blocks and coarse fragments become agglomerates.