CHAPTER LVI.
MANJIT (INDIAN MADDER).

The roots of the East Indian Rubia mungista contain purpurin and another characteristic colouring matter, manjistin. This material is a rarity in German commerce, but is imported into England from India in tolerable amount and used in dyeing. Manjistin may be extracted by boiling manjit repeatedly with a solution of aluminium sulphate, uniting the liquids and acidifying strongly with hydrochloric acid. In twenty-four hours a red precipitate forms in the liquid; it is dried and treated with boiling carbon disulphide, which extracts purpurin and manjistin and leaves undissolved a dark resin. The residue, after distilling off the carbon bisulphide, gives up purpurin to dilute acetic acid, manjistin remaining undissolved. When the purpurin has been completely extracted, the residue is treated with a little boiling alcohol and repeatedly recrystallised; manjistin is finally obtained in golden yellow crystals of the composition C₁₄H₁₅O₂(OH)₂.CO₂H.

When a solution of manjistin in a little alcohol is mixed with water no precipitate occurs; on then adding aluminium hydrate and long boiling an orange red lake is produced. Lead acetate produces a deep orange red lake when used in just sufficient quantity; with excess a fine scarlet lake is obtained.

If manjit were a common article in the German market, it would be used in the preparation of fine pigments with as much advantage as madder and the various madder preparations.

Chica Red, Curucuru, Carajuru.—The colouring matter known under these names rarely comes into commerce; it forms brownish-red masses which acquire a peculiar golden glitter on rubbing. It is obtained from the leaves of Bignonia chica, a native of tropical America. The leaves are superficially dried and then covered with water; in the warm climate the macerated leaves soon ferment, and a deep red powder separates at the bottom of the vessel: this is the colouring matter; it is dried, made into small cakes and brought into the market.

Chica red is only partially soluble in strong alcohol, the residue chiefly consists of plant cells. Alum and stannous chloride precipitate beautiful red lakes from the solution, which are distinguished by great permanence when exposed to light. On account of the present high price, this colouring matter has not yet obtained admission into the colour industries, though it would be a valuable recruit.

Chica red has been little studied; an investigation would certainly considerably increase our knowledge of the organic colouring matters. Towards reducing agents it behaves in a similar manner to indigo; in contact with caustic soda, grape sugar and water in closed flasks, a violet liquid is produced; when exposed in an open vessel the violet at once changes to brown, but if the liquid is syphoned off into dilute hydrochloric acid a pure red precipitate separates, which is to be regarded as the pure colouring matter.