CHAPTER LII.
THE COLOURING MATTER OF LAC.

From the punctures of the insect Coccus lacca on certain East Indian trees, especially those belonging to the genus Ficus, flow at the same time resin and colouring matter in such quantities that the insects are frequently enclosed and large red masses are formed on the trees. The insects live in some measure in these masses, the females lay their eggs in the spaces and the larvæ are said to feed on the red sap contained in the mass. When the larvæ have left the incrustation, generally in November, it is broken off from the branches and collected. It is now known as stick-lac; it consists of large masses of resin of a fine deep red colour. In the interior the cells of the insects may still be perceived. On chewing, it becomes soft and colours the saliva a deep violet. When stick-lac is boiled in water a portion of the colouring matter dissolves. Good stick-lac contains 10 per cent. of colouring matter and 80 per cent. of resin.

Seed-lac has the same origin as stick-lac, but frequently the greater part of the colouring matter has been extracted; it rarely contains more than 2·5 per cent., and is consequently of little value for colouring purposes.

Lac Dye.—The colouring matter of stick-lac is generally separated from the resin in India and comes into the market under the name of lac dye. It is made by stirring coarsely powdered stick-lac in large vessels for several hours with warm water. Almost the whole of the colouring matter dissolves, whilst the resin remains as a ruby red mass which is melted and brought into the market under the name of shellac. The solution of the colouring matter is evaporated in shallow vessels in the sun or boiled down in pans; the residue is made into cakes. At present soda solution is used instead of pure water to extract the colouring matter; a larger yield is obtained. Lac dye usually contains 45 to 50 per cent. of colouring matter, 25 per cent. of resin, and, in addition, earthy substances which are to be regarded as intentional admixtures.

In the preparation of lac dye by Stephen’s method coarsely powdered stick-lac is boiled with soda, and the remainder of the colouring matter contained in the resin extracted by repeated boiling with water. All the extracts are then united and precipitated by alum. The colouring matter separates as a lake which still contains a large quantity of resin.

According to the patented process of Henley, the colouring matter of seed-lac is extracted by hydraulic presses. The lac is filled into press bags which are placed between iron boxes heated by steam. On applying pressure the melted resin, shellac, comes through the bags, whilst the colouring matter remains behind. If this method were employed on the large scale, presses similar to those used in stearin candle works would be suitable.

When lac dye is treated with hydrochloric acid the colouring matter dissolves; the solution can be used to dye wool, which it colours a beautiful red. The colouring matter is very similar in appearance to that of cochineal, but has the appearance of much greater fastness. It appears also to be similar in composition to carminic acid, but little is known as to its chemical constitution.

When lac dye is to be used for painting it must be freed from resin; this is accomplished by treating the finely powdered mass for a long time with boiling alcohol and separating the solution of resin from the undissolved colouring matter, which is then dried. In this way a lake is produced known commercially as Vienna red and little inferior to carmine lake. Unfortunately the price of lac dye, although it is imported in large quantities from India to England, is so high that it can only be used for artists’ colours.