But even solutions of the best Syrian asphalt in the purest oil of turpentine, if they are allowed to stand undisturbed for a long time in large vessels, deposit a thick, semi-fluid precipitate which a large addition of oil of turpentine fails to convert into a uniform thin liquid. It may be assumed that this deposit consists of an insoluble or nearly insoluble part of the asphalt which, perhaps, has been deprived of solubility by the action of light. Hence, in order to obtain a uniform solution, this thick part must be removed. This can be done, though imperfectly, by carefully decanting the solution after it has stood for a long time in large vessels. This tedious and troublesome process may be avoided by filtering the solution as it is made, by the following simple and quite satisfactory method: The solution is made in a large cask, lying on its side, with a round hole about 8 inches in diameter in its upper bilge. This opening is provided with a well-fitting cover, to the bottom of which a hook is attached. The asphalt is placed in a bag of closely woven canvas, which is inclosed in a second bag of the same material. The diameter of the double bag, when filled, should be such as to allow it to pass easily through the opening in the cask, and its length such that, when it is hung on the hook, its lower end is about 8 inches above the bottom of the cask. The cask is then filled with rectified oil of turpentine, closed, and left undisturbed for several days. The oil of turpentine penetrates into the bag and dissolves the asphalt, and the solution, which is heavier than pure oil of turpentine, exudes through the canvas and sinks to the bottom of the cask. Those parts of the asphalt which are quite insoluble, or merely swell in the oil of turpentine, cannot pass through the canvas, and are removed with the bag, leaving a perfect solution. When all soluble portions have been dissolved, the bag, with the cover, is raised and hung over the opening to drain. If pulverized asphalt has {719} been used the bag is found to contain only a small quantity of semi-fluid residue. This, thinned with oil of turpentine and applied with a stiff brush and considerable force, forms a thick, weather-resisting, and very durable coating for planks, etc.
The proportion of asphalt to oil of turpentine is so chosen as to produce, in the cask, a pretty thick varnish, which may be thinned to any desired degree by adding more turpentine. For use, it should be just thick enough to cover bright tin and entirely conceal the metal with a single coat. When dry, this coat is very thin, but it adheres very firmly, and continually increases in hardness, probably because of the effect of light. This supposition is supported by the difficulty of removing an old coat of asphalt varnish, which will not dissolve in turpentine even after long immersion, and usually must be removed by mechanical means.
For a perfect, quick-drying asphalt varnish the purest asphalt must be used, such as Syrian, or the best Trinidad. Trinidad seconds, though better than some other asphalts, yield an inferior varnish, owing to the presence of impurities.
Of artificial asphalt, the best for this purpose is the sort known as “mineral caoutchouc,” which is especially suitable for the manufacture of elastic dressings for leather and other flexible substances. For wood and metal it is less desirable, as it never becomes as hard as natural asphalt.
I.—A solution of 1 part of caoutchouc in 16 parts of oil of turpentine or kerosene is mixed with a solution of 16 parts of copal in 8 parts of linseed-oil varnish. To the mixture is added a solution of 2 parts of asphalt in 3 or 4 parts of linseed-oil varnish diluted with 8 or 10 parts of oil of turpentine, and the whole is filtered. This is a fine elastic varnish.
II.—Coal-tar asphalt, American asphalt, rosin, benzine, each 20 parts; linseed-oil varnish, oil of turpentine, coal-tar oil, each 10 parts; binoxide of manganese, roasted lampblack, each 2 parts. The solid ingredients are melted together and mixed with the linseed-oil varnish, into which the lampblack has been stirred, and, finally, the other liquids are added. The varnish is strained through tow.
| II.— | Shellac | 4 parts |
|---|---|---|
| Borax | 2 parts | |
| Glycerine | 2 parts | |
| Aniline black | 5 parts | |
| Water | 50 parts |
Dissolve the borax in the water, add {720} the shellac, and heat until solution is effected; then add the other ingredients. This is a mat-black varnish.
| I Per Cent | II Per Cent | III Per Cent | IV Per Cent | V Per Cent | |
|---|---|---|---|---|---|
| Shellac | 14.5 | 6.5 | 13.5 | 6.3 | 8.3 |
| Mastic | 6.0 | 2.0 | — | — | 1.1 |
| Sandarac | 6.0 | 13.0 | — | 1.3 | 1.1 |
| Camphor | 1.0 | — | 0.5 | 1.5 | — |
| Benzoin | — | — | — | — | 13.7 |
| Alcohol | 72.5 | 78.5 | 86.0 | 79.2 | 75.8 |
Scent with oil of benzoin, of lavender, or of rosemary. Other authors give the following recipes:
| VI Per Cent | VII Per Cent | VIII Per Cent | IX Per Cent | |
|---|---|---|---|---|
| Blond shellac | 11.5 | 13.0 | 9.0 | — |
| White shellac | 11.5 | — | — | — |
| Camphor | — | 0.7 | — | — |
| Powdered sugar | — | 0.7 | — | — |
| Sandarac | — | — | 18.0 | 6.6 |
| Mastic | — | — | — | 13.0 |
| Venice turpentine | — | — | 2.0 | 6.6 |
| Alcohol | 77.0 | 85.6 | 71.0 | 73.8 |
All solutions may be prepared in the cold, but the fact that mastic does not dissolve entirely, must not be lost sight of.
Amber-colored bottles for substances acted upon by the actinic rays of light may be obtained from almost any manufacturer of bottles.
I.—Melt 8 pounds best copal and mix with 20 pounds very clear matured oil. Then boil 4 to 5 hours at moderate heat until it draws threads; now mix with 35 pounds oil of turpentine, strain and keep for use. This varnish dries rather slowly, therefore varnishers generally mix it one-half with another varnish, which is prepared by boiling for 4 hours, 20 pounds clear linseed oil and 8 pounds very pure, white anime rosin, to which is subsequently added 35 pounds oil of turpentine.
II.—Mix the following two varnishes:
(a) Eight pounds copal, 10 pounds linseed oil, 1/2 pound dried sugar of lead, 35 pounds oil of turpentine.
(b) Eight pounds good anime rosin, 10 pounds linseed oil, 1/4 pound zinc vitriol, 35 pounds oil of turpentine. Each of these two sets is boiled separately into varnish and strained, and then both are mixed. This varnish dries in 6 hours in winter, and in 4 hours in summer. For old articles which are to be re-varnished black, it is very suitable.
II.—Dissolve 1 part of the desiccated rubber in 8 parts of petroleum ether (benzine) and add 2 parts of fat copal varnish and stir in. Or, cover 2 parts of dried rubber with 1 part of ether; let stand for several days, or until the rubber has taken up as much of the ether as it will, then liquefy by standing in a vessel of moderately warm water. While still warm, stir in 2 parts of linseed oil, cut with 2 parts of turpentine oil.
The priming coat should be white lead thinned with turpentine, with only just sufficient linseed oil to bind it. After this is thoroughly dry, apply one or more coats of special bath-tub enamel, or a gloss paint made by mixing coach colors ground in Japan with hard-drying varnish of the best quality. Most first-class manufacturers have special grades that will stand hot water.
II.—The following preparation produces a brilliant surface on metals and is very durable, resisting the effect of blows without scaling or chipping off, and being therefore highly suitable for cycles and any other articles exposed to shock:
For the manufacture of 44 gallons, 11 pounds of red copper, 8.8 pounds of yellow copper, 4.4 pounds of hard steel, and 4.4 pounds of soft steel, all in a comminuted condition, are well washed in petroleum or mineral spirit, and are then treated with concentrated sulphuric acid in a lead-lined vessel, with continued stirring for 2 hours. After 12 hours’ rest the sulphuric acid is neutralized with Javel extract, and the fine powder left in the vessel is passed through a silk sieve to remove any fragments of metal, then ground along with linseed oil, ivory black, and petroleum, the finely divided mass being afterwards filtered through flannel and incorporated with a mixture of Bombay gum, 22 pounds; Damascus gum, 11 pounds; Judea bitumen, 22 pounds; Norwegian tar rosin, 11 pounds; and 11 pounds of ivory black ground very fine in refined petroleum. When perfectly homogeneous the mass is again filtered, and is then ready for use. It is laid on with a brush, and then fixed by exposure to a temperature of between 400° and 800° F. The ivory black may be replaced by other coloring matters, according to requirements.
White.—White lead or flake white.
Red.—Carmine or cinnabar (vermilion).
Blue.—Ultramarine or Prussian blue.
Green.—Scheele’s green or Schweinfurt green.
Brown.—Umber.
Yellow.—Ocher or chrome yellow.
The different shades are produced by mixing the colors.
The top enamel (hard) consists of 500 parts shellac, 125 parts French oil of turpentine, and 3,500 parts spirit (90 per cent). Boiling in the water bath until the solution appears clear can only be of advantage. According to the thickness desired, one may still dilute in the cold with high-strength spirit. Tinting may be done, as desired, with earth colors, viz., coffee brown with umber, red with English red, yellow with ocher, silver gray with earthy cerussite, and some lampblack. Before painting, dry out the vats and putty up the joints with a strip of dough which is prepared from ground enamel and finely sifted charcoal or brown coal ashes, and apply the enamel after the putty is dry. The varnish dries quickly, is odorless and tasteless, and extraordinarily durable. If a little annealed soot black is added to this vat enamel, a fine iron varnish is obtained which adheres very firmly. Leather (spattering leather on carriages) can also be nicely varnished with it.
In a closed stirrer or rolling cask place 21.5 parts, by weight, of finely powdered pale French rosin, 24 1/2 parts, by weight, of Manila copal, as well as 35 parts, by weight, of denaturized spirit (95 per cent), causing the cask or the stirrer to rotate until all the gum has completely dissolved, which, according to the temperature of the room in which the stirrer is and the hardness of the gums, requires 24 to 48 hours. When the gums are entirely dissolved add to the mixture a solution of 21 1/2 parts, by weight, of Venice oil turpentine in 0.025 parts, by weight, of denaturized spirit of 95 per cent, allowing the stirrer to run another 2 to 3 hours. For the purpose of removing any impurities present or any undissolved rosin from the varnish, it is poured through a hair sieve or through a threefold layer of fine muslin (organdie) into suitable tin vessels or zinc-lined barrels for further clarification. After 10 to 14 days the varnish is ready for use. By grinding this varnish with the corresponding dry pigments the desired shades of color may be obtained; but it is well to remark that chemically pure zinc white cannot be used with advantage because it thickens and loses its covering power. The grinding is best carried out twice on an ordinary funnel mill. Following are some recipes:
I.—Enamel White.—Lithopone, 2 parts, by weight; white lead, purest, 1/2 part, by weight; varnish, 20 parts, by weight.
II.—Enamel Black.—Ivory black, 2 parts, by weight; Paris blue, 0.01 part, by weight; varnish, 23 parts, by weight.
III.—Pale Gray.—Graphite, 2 parts, by weight; ultramarine, 0.01 part, by weight; lithopone, 40 parts, by weight; varnish, 100 parts, by weight.
IV.—Dark Gray.—Graphite, 3 parts, by weight; ivory black, 2 parts, by weight; lithopone, 40 parts, by weight; varnish, 110 parts, by weight. {723}
V.—Chrome Yellow, Pale.—Chrome yellow, 2 parts, by weight; lithopone, 2 parts, by weight; varnish, 40 parts, by weight; benzine, 1 1/2 parts, by weight.
VI.—Chrome Yellow, Dark.—Chrome yellow, dark, 2 parts, by weight; chrome orange, 1/8 part, by weight; lithopone, 1 part, by weight; varnish, 35 parts, by weight; benzine, 1 part, by weight.
VII.—Pink, Pale.—Carmine, 1/2 part, by weight; lithopone, 15 parts, by weight; varnish, 40 parts, by weight; benzine, 1 1/2 parts, by weight.
VIII.—Pink, Dark.—Carmine, 1/2 part, by weight; Turkey red, 1 part, by weight; lithopone, 15 parts, by weight; varnish, 40 parts, by weight.
IX.—Turkey Red.—Turkey red, pale, 2 parts, by weight; lithopone, 1 part, by weight; Turkey red, dark, 1 part, by weight; white lead, pure, 1/2 part, by weight; varnish, 18 parts, by weight; benzine, 1/2 part, by weight.
X.—Flesh Tint.—Chrome yellow, pale, 1 1/2 parts, by weight; graphite, 1/8 part, by weight; lithopone, 15 parts, by weight; Turkey red, pale, 2 parts, by weight; varnish, 42 parts, by weight; benzine, 1/2 part, by weight.
XI.—Carmine Red.—Lead sulphate, 5 parts, by weight; Turkey red, pale, 6 parts, by weight; carmine, 1 1/2 parts, by weight; orange minium, 3 parts, by weight; vermilion, 2 parts, by weight; varnish, 50 parts, by weight; benzine, 1 1/2 parts, by weight.
XII.—Sky Blue.—Ultramarine, 5 parts, by weight; lithopone, 5 parts, by weight; ultramarine green, 0.05 parts, by weight; varnish, 30 parts, by weight; benzine, 1 part, by weight.
XIII.—Ultramarine.—Ultra blue, 5 parts, by weight; varnish, 12 parts, by weight; benzine, 1/2 part, by weight.
XIV.—Violet.—Ultramarine, with red tinge, 10 parts, by weight; carmine, 0.5 parts, by weight; varnish, 25 parts, by weight.
XV.—Azure.—Paris blue, 10 parts, by weight; lithopone, 100 parts, by weight; varnish, 300 parts, by weight.
XVI.—Leaf Green.—Chrome green, pale, 5 parts, by weight; varnish, 25 parts, by weight; benzine, 1/2 part, by weight.
XVII.—Silk Green.—Silk green, 10 parts, by weight; chrome yellow, pale, 1/2 part, by weight; lead sulphate, 5 parts, by weight; varnish, 30 parts, by weight; benzine, 1/2 part, by weight.
XVIII.—Brown.—English red, 10 parts, by weight; ocher, light, 3 parts, by weight; varnish, 30 parts, by weight; benzine, 1/2 part, by weight.
XIX.—Ocher.—French ocher, 10 parts, by weight; chrome yellow, dark, 1/2 part, by weight; varnish, 30 parts, by weight; benzine, 1/2 part, by weight.
XX.—Chocolate.—Umber, 10 parts, by weight; Florentine lake, 1/8 part, by weight; varnish, 25 parts, by weight; benzine, 1/2 part, by weight.
XXI.—Terra Cotta.—Chrome yellow, pale, 10 parts, by weight; Turkey red, dark, 3 parts, by weight; varnish, 35 parts, by weight.
XXII.—Olive, Greenish.—French ocher, 5 parts, by weight; Paris blue, 1/2 part, by weight; graphite, 1/2 part, by weight; varnish, 25 parts, by weight; lithopone, 5 parts, by weight.
XXIII.—Olive, Brownish.—Chrome orange, 5 parts, by weight; Paris blue, 2 parts, by weight; lead sulphate, 10 parts, by weight; English red, 1 part, by weight; varnish, 40 parts, by weight; benzine, 1 1/2 parts, by weight.
XXIV.—Olive, Reddish.—Turkey red, dark, 75 parts, by weight; sap green, 75 parts, by weight; ocher, pale, 5 parts, by weight; varnish, 300 parts, by weight; benzine, 1 1/2 parts, by weight.
In copper-plate engraving the plate must be covered with a dark-colored coating which, though entirely unaffected by the etching fluid, must be soft enough to allow the finest lines to be drawn with the needle and must also be susceptible of complete and easy removal when the etching is finished. Varnishes which possess these properties are called “etching grounds.” They are made according to various formulas, but in all cases the principal ingredient is asphalt, of which only the best natural varieties are suitable for this purpose. Another common ingredient is beeswax, or tallow.
Etching grounds are usually made in small quantities, at a single operation, by melting and stirring the solid ingredients together and allowing the mass to cool in thin sheets, which are then dissolved in oil of turpentine. The plate is coated uniformly with this varnish through which the engraver’s tool readily penetrates, laying bare the metal beneath. After the lines thus drawn have been etched by immersing the plate in acid, the varnish is washed off with oil of turpentine.
The following formulas for etching grounds have been extensively used by engravers: {724}
| I | II | III | IV | |
|---|---|---|---|---|
| Yellow wax | 50 | 30 | 110 | 40 parts |
| Syrian asphalt | 20 | 20 | 25 | 40 parts |
| Rosin | — | — | — | 20 parts |
| Amber | — | — | 20 | — parts |
| Mastic | 25 | 25 | 25 | — parts |
| Tallow | — | — | — | 2 parts |
| Bergundy pitch | — | — | — | 10 parts |
| I.— | Manila copal, spirit-soluble | 12 parts |
|---|---|---|
| Ruby shellac, powdered | 62 parts | |
| Venice, turpentine | 12 parts | |
| Spirit, 96 per cent | 250 parts |
The materials are dissolved cold in a covered vat with constant stirring, or better still, in a stirring machine, and filtered. For the pale shades take light ocher; for dark ones, Amberg earth, which are well ground with the varnish in a paint mill.
II.—Shellac, A C leaf, 1.2 parts; sandarac, 8 parts; Manila copal, 2 parts; rosin, 5 parts; castor or linoleic acid or wood oil acid, 1.50 parts; spirit (96 per cent), 65 parts.
For red, use 1 part of eosin to 49 parts of the bleached shellac solution. For blue, use 1 part of aniline blue to 24 parts of the bleached shellac solution, as the orange shellac solution would impart a greenish cast. For green, use 1 part of aniline green (brilliant green) to 49 parts of the orange shellac solution. For yellow, use either 2 parts of extract of turmeric or 1 part of gamboge to 24 parts of the solution, or 1 part of aniline yellow to 49 parts of the solution. For golden yellow, use 2 parts of gamboge and 1 part of dragon’s blood to 47 parts of the orange shellac solution. The gamboge and dragon’s blood should be dissolved first in a little alcohol.
| I.— | Powdered benzoin | 1 part |
|---|---|---|
| Alcohol enough to make | 10 parts. | |
| Pure saffron, roughly broken up, about 6 threads to the ounce. | ||
Macerate 3 days and filter. Vary the quantity of saffron according to the shade desired. Mastic and juniper gum may be added to this varnish if a heavier body is desired.
II.—Benzoin, juniper gum, gum mastic, equal parts.
Dissolve the gums in 9 times their weight of alcohol (varied more or less according to the consistency wanted), and color to the desired shade with threads of pure saffron. This varnish is very brilliant and dries at once.
II.—Dissolve 7 pounds of India rubber in 25 pounds of oil of turpentine. By continued heating dissolve 14 pounds of rosin in the mixture. Color while hot with 3 pounds of lampblack.
| Ozokerite | 17 parts |
| Carnauba wax | 3 parts |
| Turpentine oil | 15 parts |
Melt the ozokerite and Carnauba wax, then stir in the turpentine oil. This varnish is applied like a polish and imparts to the wood a dark natural color and a dull luster.
After these preliminaries, a paint of the shade desired, ground in linseed oil, is applied. For brown, umber may be used.
When the paint has been satisfactorily applied it should be hardened by heating, and then smoothed down by rubbing with ground pumice stone applied gently by means of a piece of felt moistened with water. To be done well, this requires care and patience, and, it might be added, some experience.
The vessel is next coated with a varnish, made by the following formula:
| Turpentine spirit | 8 ounces |
| Oil of lavender | 6 ounces |
| Camphor | 1 drachm |
| Bruised copal | 2 ounces |
Perhaps some other good varnish would give equally satisfactory results.
After this the vessel is put in an oven and heated to as high a temperature as it will bear without causing the varnish to {725} blister or run. When the varnish has become hard, the vessel is taken out and another coat is put on, which is submitted to heat as before. This process may be repeated till the judgment of the operator tells him that it is no longer advisable.
Some operators mix the coloring matter directly with the varnish; when this is done, care should be taken that the pigment is first reduced to an impalpable powder, and then thoroughly mixed with the liquid.
| I.— | Sandarac | 3 ounces av. |
|---|---|---|
| Mastic | 3/4 ounce av. | |
| Venice turpentine | 150 grains | |
| Alcohol | 16 fluidounces |
Macerate with repeated stirring until solution is effected, and then filter.
The paper labels are first sized with diluted mucilage, then dried, and then coated with this varnish. If the labels have been written with water-soluble inks or color, they are first coated with 2 coats of collodion, and then varnished.
II.—The varnished labels of stock vessels often suffer damage from the spilling of the contents and the dripping after much pouring.
Formalin gelatin is capable of withstanding the baneful influence of ether, benzine, water, spirit of wine, oil, and most substances. The following method of applying the preservative is recommended: Having thoroughly cleaned the surface of the vessel, paste the label on and allow it to dry well. Give it a coat of thin collodion to protect the letters from being dissolved out or caused to run, then after a few minutes paint over it a coat of gelatin warmed to fluidity—5 to 25—being careful to cover in all the edges. Just before it solidifies go over it with a tuft of cotton dipped into a 40 per cent formalin solution. It soon dries and becomes as glossy as varnish, and may be coated again and again without danger of impairing the clear white of the label or decreasing its transparency.
II.—Caoutchouc, 1 part; petroleum, 1 part; carbon bisulphide, 1 part; shellac, 4 parts; bone black, 2 parts; alcohol, 20 parts. First the caoutchouc is brought together with carbon bisulphide in a well-closed bottle and stood aside for a few days. As soon as the caoutchouc is soaked add the petroleum and the alcohol, then the finely powdered shellac, and heat to about 125° F. When the liquid appears pretty clear, which indicates the solution of all substances, the bone black is added by shaking thoroughly and the varnish is at once filled in bottles which are well closed. This pouch composition excels in drying quickly and produces upon the leather a smooth, deep black coating, which possesses a certain elasticity.
The purpose of these varnishes is to protect the metals from oxidation and to render them glossy.
II.—Reduce to powder, 160 parts, by weight, of turmeric of best quality, and pour over it 2 parts, by weight, of saffron, {726} and 1.700 parts, by weight, of spirit; digest in a warm place 24 hours, and filter. Next dissolve 80 parts, by weight, of dragon’s blood; 80 parts, by weight, of sandarac; 80 parts, by weight, of elemi gum; 50 parts, by weight, of gamboge; 70 parts, by weight, of seedlac. Mix these substances with 250 parts, by weight, of crushed glass, place them in a flask, and pour over this mixture the alcohol colored as above described. Assist the solution by means of a sand or water bath, and filter at the close of the operation. This is a fine varnish for brass scientific instruments.