II.—A brilliant silver color may be imparted to iron (from which all grease has been previously removed) by treating it with the following solution: Forty parts, by weight, chloride of antimony; 10 parts, by weight, powdered arsenious acid; and 80 parts levigated hematite are mixed with 1,000 parts of 90 per cent alcohol and gently heated for half an hour on a water bath. A partial solution takes place, and a small cotton pad is then dipped in the liquid and applied with a gentle pressure to the iron. A thin film consisting of arsenic and antimony is precipitated, as described by Dr. Langbein, in his “Handbuch der galv. Metallniederschläge.” The brilliancy of the effect depends upon the care with which the iron has previously been polished.
II.—Kayser’s silvering liquid, which is excellent for all kinds of metals, is prepared from lunar caustic, 11 parts; sodium hyposulphite, 20 parts; sal ammoniac, 12 parts; whiting, 20 parts; and distilled water, 200 parts. The articles must be cleaned well.
II.—Articles of zinc, brass, or copper may also be silver-plated by applying to them a pasty mass of the following composition: First dissolve 10 parts, by weight, of nitrate of silver in 50 parts, by weight, of distilled water; also 25 parts, by weight, of potassium cyanide in sufficient distilled water to dissolve it. Pour the two together, stir well, and filter. Now 100 parts, by weight, of whiting or levigated chalk and 400 parts, by weight, of potassium bitartrate, finely powdered, are moistened with the above solution sufficiently to form a soft paste, which may be applied to the objects, previously well cleansed, with a brush. After this coating has dried well, rinse it off, and dry the object in clean sawdust.
II.—The following is a process used when the jeweler has to repair certain pieces from which silvering has come off {589} in places, and which he would like to repair without having recourse to the battery, and specially without having to take out the stones or pearls: Take nitrate of silver, 25 parts, by weight; cyanide of potassium, 50 parts; cream of tartar, 20 parts; Paris white, 200 parts; distilled water, 200 parts; mercury, 2 parts. Dissolve the nitrate of silver in half of the distilled water and the cyanide in the other half; mix the two liquids; next bray well in a mortar the mercury, Paris white, and cream of tartar. Preserve the products of these two operations separately, and when you wish to use them make a rather soft paste of the two, which apply with a little cotton or a brush on the portion to be silvered. Let dry and subsequently rub with a soft brush.
PLATINIZING: See Plating.
PLATINOTYPE PAPER: See Photography. {590}
PLATINUM PAPERS AND THEIR DEVELOPMENT: See Photography, under Developing Papers.
PLATINUM WASTE, TO SEPARATE SILVER FROM: See Silver.
PLUMBAGO: See Lubricants.
PLUMES: See Feathers.
PLUSH, TO REMOVE GREASE SPOTS FROM: See Cleaning Preparations and Methods.
POISONS, ANTIDOTES FOR: See Antidotes.
II.—Aluminum is susceptible of taking a beautiful polish, but it is not white like that of silver or nickel, rather slightly bluish, like tin. The shade can be improved. First, the grease is to be removed from the object with pumice stone. Then, for polishing, use is made of an emery paste mingled with tallow, forming cakes which are rubbed on the polishing brushes. Finally, rouge powder is employed with oil of turpentine.
| I.— | Linseed oil | 8 ounces |
|---|---|---|
| Stale ale | 8 ounces | |
| Hydrochloric acid | 1 ounce | |
| Alcohol, 95 per cent | 1 ounce | |
| White of 1 egg. |
Mix. Shake before using. Clean out the dust, dirt, etc., using an appropriate brush, or a bit of cloth wrapped around a stick, then apply the above, with a soft brush, or a bit of cotton wrapped in a bit of silk—or, in fact, any convenient method of applying it.
| II.— | Japan wax | 1 av. ounce |
|---|---|---|
| Oil of turpentine | 3 fluidounces | |
| Linseed oil | 16 fluidounces | |
| Alcohol | 3 fluidounces | |
| Solution of potash | 1 1/2 fluidounces | |
| Water to make 32 fluidounces. | ||
Dissolve the wax in the turpentine, add the other ingredients, diluting the potash solution with the water before adding to the other ingredients, and stir briskly until well mixed.
Objects of polished copper, bronze, brass, and other alloys of copper tarnish through water and it is sometimes necessary to give them again their bright appearance. Pickle the articles in an acid bath; wash them next in a neutral bath; dry them, and subsequently rub them with a polishing powder. Such is the general formula; the processes indicated below are but variants adapted to divers cases and recommended by disinterested experimenters:
| I.— | Quartz sand, powdered and levigated | 20 parts |
|---|---|---|
| Paris red | 30 parts | |
| Vaseline | 50 parts | |
| Mix intimately and make a pomade. | ||
| II.— | Emery flour, finest levigated | 50 parts |
| Paris red | 50 parts | |
| Mutton suet | 40 parts | |
| Oleic acid | 40 parts | |
| III.— | Levigated emery powder | 100 parts |
| Anhydrous sodium carbonate | 5 parts | |
| Tallow soap | 20 parts | |
| Water | 100 parts | |
I.—Throw a handful of permanganate potash crystals into a pail of boiling water, and apply the mixture as hot as possible to the floor with a large flat brush. If the stain produced is not dark enough, apply one or two more coats as desired, leaving each wash to dry thoroughly before applying another. If it is desired to polish the surface with beeswax, a coat of size should be applied to the boards before staining, as this gives depth and richness to the color. After 3 or 4 days, polish well with a mixture of turpentine and beeswax. A few cents will cover the cost of both size and permanganate of potash.
| II.— | Potash | 1 part |
|---|---|---|
| Water | 4 parts | |
| Yellow beeswax | 5 parts | |
| Hot water, a sufficient quantity. | ||
Emulsify the wax by boiling it in the water in which the potash has been dissolved; stir the whole time. The exact amount of boiling is determined by the absence of any free water in the mass. Then remove the vessel from the fire, and gently pour in a little boiling water, and stir the mixture carefully. If a fat-like mass appears without traces of watery particles, one may know the mass is in a fit condition to be liquefied by the addition of more hot water without the water separating. Then put in the water to the extent of 200 to 225 parts, and reheat the compound for 5 to 10 minutes, without allowing it to reach the boiling point. Stir constantly until the mixture is cool, so as to prevent the separation of the wax, when a cream-like mass results which gives a quick and brilliant polish on woodwork, if applied in the usual way, on a piece of flannel rag, and polished by rubbing with another piece of flannel.
Nut Brown.—I.—Natural umber, 1/2 part; burnt umber, 1 part; and yellow ocher, 1 part, gives a fine red-brown color when incorporated with the same wax and soda mixture.
II.—Treat 5 pounds of wax with 15 pounds of caustic soda lye of 3° Bé. so that a uniform wax milk results; boil with 1/2 pound of annatto, 3 pounds of yellow ocher, and 2 pounds of burnt umber.
Mahogany Brown.—Boil 5 pounds of wax with 15 pounds of caustic soda lye as above. Then add 7 pounds of burnt umber very finely powdered, making it into a uniform mass by boiling again.
Yellow Ocher.—The wax milk obtained as above is boiled with 5 pounds of yellow ocher.
The mass on cooling has the consistency of a salve. If it is to be used for rubbing the floor it is stirred with sufficient boiling water so as to form a fluid of the consistency of thin syrup or oil. This is applied very thin on the floor, using a brush; then it is allowed to dry only half way, and is rubbed with a stiff floor brush. The polishing is continued with a woolen rag until a mirror-like gloss is obtained. It is best not to paint the whole room and then brush, but the deals should be taken one after the other, otherwise the coating would become too dry and give too dull a luster. The floors thus treated with gloss paste are very beautiful. To keep them in this condition they should be once in a while rubbed with a woolen rag, and if necessary the color has to be renewed in places. If there are parquet floors whose patterns are not to be covered up, the ocher (yellow) paste or, better still, the pure wax milk is used.
First make a paste to fill cracks as follows: Whiting, plaster of Paris, pumice stone, litharge, equal parts; japan dryer, boiled linseed oil, turpentine, coloring matter of sufficient quantity. Rub the solids intimately with a mixture of 1 part of the japan, 2 parts of the linseed oil, and 3 parts of turpentine, coloring to suit with Vandyke brown or sienna. Lay the filling on with a brush, let it set for about 20 minutes, and then rub off clean except where it is to remain. In 2 or 3 days it will be hard enough to polish.
After the surface has been thus prepared, the application of a coat of first-class copal varnish is in order. It is recommended that the varnish be applied in a moderately warm room, as it is injured by becoming chilled in drying. To get the best results in varnishing, some skill and experience are required. The varnish must be kept in an evenly warm temperature, and put on neither too plentifully nor too gingerly.
After a satisfactorily smooth and regular surface has been obtained, the polishing proper may be done. This may be accomplished by manual labor and dexterity, or consist in the application of a very thin, even coat of a very fine, transparent varnish.
If the hand-polishing method be preferred, it may be pursued by rubbing briskly and thoroughly with the following finishing polish:
| I.— | Alcohol | 8 ounces |
|---|---|---|
| Shellac | 2 drachms | |
| Gum benzoin | 2 drachms | |
| Best poppy oil | 2 drachms |
Dissolve the shellac and gum in the alcohol in a warm place, with frequent agitation, and, when cold, add the poppy oil. This may be applied on the end of a cylindrical rubber made by tightly rolling a piece of flannel which has been torn, not cut, into strips 4 to 6 inches wide.
A certain “oily sweating” of articles of polished wood occurs which has been ascribed to the oil used in polishing, but has been found to be due to a waxy substance present in shellac, which is often used in polishing. During the operation of polishing, this wax enters into close combination with the oil, forming a soft, greasy mass, which prevents the varnish from ever becoming really hard. This greasy matter exudes in the course of time. The remedy is to use only shellac from which the vegetable wax has been completely removed. This is accomplished by making a strong solution of the shellac in alcohol and then shaking it up with fresh seed lac or filtering it through seed lac. In this way the readily soluble rosins in the seed lac are dissolved, and with them traces of coloring matter. At the same time the vegetable wax, which is only slightly soluble, is deposited. The shellac solution which has exchanged its vegetable wax for rosin is not yet suitable for fine furniture polishing. It is not sufficiently taken up by the wood, and an essential oil must be added to give it the necessary properties, one of the best oils to employ for this purpose being that of rosemary. The following recipe is given:
II.—Twenty pounds of shellac and 4 pounds of benzoin are dissolved in the smallest possible quantity of alcohol, together with 1 pound of rosemary oil. The solution then obtained is filtered through seed lac so as to remove whatever vegetable wax may be present.
| Soft water | 6 pints |
| Turpentine | 6 pints |
| Beeswax | 3 pounds |
| White wax | 1 1/2 ounces |
| White soap | 18 ounces |
| Red lead | 12 ounces |
Cut up soap and dissolve in water by aid of heat; then evaporate to 6 pounds. Melt the waxes and add turpentine in which red lead has been stirred, pour into this the soap solution, and stir until it is nearly cold. If a darker color is wanted add more red lead, 4 to 6 ounces.
II.—Crush to powder cologne chalk, 60 parts, by weight; tripoli, 30 parts, by weight; bole, 15 parts, by weight. For use moisten the glass a little, dip a linen rag into the powder and rub the glass until it is clean.
III.—Tin ashes may be employed with advantage. The glass is rubbed with this substance and then washed off with a piece of soft felt. In this manner a very handsome polish is obtained.
II.—Tortoise-shell articles have a way of getting dull and dingy looking. To repolish dip the finger in linseed oil and rub over the whole surface. Very little oil should be used, and if the article is a patterned one it may be necessary to use a soft brush to get it into the crevices. Then rub with the palm of the hand until all oil has disappeared, and the shell feels hot and looks bright and shiny.
This mastic is usually composed of a mixture of yellow wax, rosin, and Burgundy pitch, mixed with a little sulphur and plaster passed through a fine sieve, which gives it the consistency of a thick paste; to color this paste to a tone analogous to the ground tints or natural cement of the material upon which it is placed, lampblack and rouge, with a little of the prevailing color of the material, are added. For green and red marbles, this mastic is sometimes made of gum lac, mixed with Spanish sealing wax of the color of the marble. It is applied with pincers, and these parts are polished with the rest. Sometimes crushed fragments of marble are introduced into the cement, but for fine marbles the same colors are employed which are used in painting, and which will produce the same tone as the ground; the gum lac is added to give it body and brilliancy.
The third operation in polishing consists in rubbing it again with a hard pumice stone, under which water is being constantly poured, unmixed with sand. For the fourth process, called {594} softening the ground, lead filings are mixed with the emery mud produced by the polishing of mirrors or the working of precious stones, and the marble is rubbed by a compact linen cushion well saturated with this mixture; rouge is also used for this polish. For some outside works, and for hearths and paving tiles, marble workers confine themselves to this polish. When the marbles have holes or grains, a lead muller is substituted for the linen cushion. In order to give a perfect brilliancy to the polish, the gloss is applied. Wash well the prepared surfaces and leave them until perfectly dry, then take a linen cushion, moistened only with water, and a little powder of calcined tin of the first quality. After rubbing with this for some time take another cushion of dry rags, rub with it lightly, brush away any foreign substance which might scratch the marble, and a perfect polish will be obtained. A little alum mixed with the water used penetrates the pores of the marble, and gives it a speedier polish. This polish spots very easily and is soon tarnished and destroyed by dampness. It is necessary when purchasing articles of polished marbles to subject them to the test of water; if there is too much alum, the marble absorbs the water and a whitish spot is left.
Polishing powders are advantageously prepared according to the following recipes:
I.—Four pounds magnesium carbonate, 4 pounds chalk, and 4 pounds rouge are intimately mixed.
II.—Four pounds magnesium carbonate are mixed with 1/4 pound fine rouge.
III.—Five pounds fine levigated whiting and 2 pounds Venetian red are ground together.
| IV.— | Kieselguhr | 42 pounds |
|---|---|---|
| Putty powder | 14 pounds | |
| Pipe clay | 14 pounds | |
| Tartaric acid | 1 1/2 pounds |
Powder the acid, mix well with the others. This is styled “free from mercury, poisonous mineral acids, alkalies, or grit.” It may be tinted with 12 ounces of oxide of iron if desired.
| I.— | Malt vinegar | 4 gallons |
|---|---|---|
| Lemon juice | 1 gallon | |
| Paraffine oil | 1 gallon | |
| Kieselguhr | 7 pounds | |
| Powdered bath brick | 3 pounds | |
| Oil lemon | 2 ounces | |
| II.— | Kieselguhr | 56 pounds |
| Paraffine oil | 3 gallons | |
| Methylated spirit | 1 1/2 gallons | |
| Camphorated spirit | 1/2 gallon | |
| Turpentine oil | 1/2 gallon | |
| Liquid ammonia fort | 3 pints | |
| III.— | Rotten stone | 16 av. ounces |
| Paraffine | 8 av. ounces | |
| Kerosene (coal oil) | 16 fluidounces | |
| Oil of mirbane enough to perfume. | ||
Melt the paraffine, incorporate the rotten stone, add the kerosene, and the oil of mirbane when cold.
| IV.— | Oxalic acid | 1/2 av. ounce |
|---|---|---|
| Rotten stone | 10 av. ounces | |
| Kerosene (coal oil) | 30 fluidounces | |
| Paraffine | 2 av. ounces |
Pulverize the oxalic acid and mix it with rotten stone; melt the paraffine, add to it the kerosene, and incorporate the powder; when cool, add oil of mirbane or lavender to perfume.
Pour the ammonia into the oil, methylated spirits, and turpentine, add the camphorated spirit and mix with the kieselguhr. To prevent setting, keep well agitated during filling. The color may be turned red by using a little sesquioxide of iron and less kieselguhr. Apply with a cloth, and when dry use another clean cloth or a brush.
| I.— | Powdered pipe clay | 112 pounds |
|---|---|---|
| Tallow soap | 16 pounds | |
| Tartaric acid | 1 1/4 pounds |
Grind until pasty, afterwards press into blocks by the machine.
| II.— | Levigated flint | 60 pounds |
|---|---|---|
| Whiting | 52 pounds | |
| Tallow | 20 pounds | |
| Caustic soda | 5 pounds | |
| Water | 2 gallons |
Dissolve the soda in water and add to the tallow; when saponified, stir in the others, pressing as before.
| III.— | Saponified cocoanut oil | 56 pounds |
|---|---|---|
| Kieselguhr | 12 pounds | |
| Alum | 5 1/2 pounds | |
| Flake white | 5 1/2 pounds | |
| Tartaric acid | 1 3/4 pounds |
Make as before.
| IV.— | Tallow soap | 98 pounds |
|---|---|---|
| Liquid glycerine soap | 14 pounds | |
| Whiting | 18 pounds | |
| Levigated flint | 14 pounds | |
| Powdered pipe clay | 14 pounds |
| I.— | White petroleum jelly | 90 pounds |
|---|---|---|
| Kieselguhr | 30 pounds | |
| Refined paraffine wax | 10 pounds | |
| Refined chalk or whiting | 10 pounds | |
| Sodium hyposulphite | 8 pounds |
Melt wax and jelly, stir in others and grind.
It is an undecided point as to whether a scented paste is better than one without perfume. The latter is added merely to hide the nasty smell of some of the greases used, and it is not very nice to have spoons, etc., smelling, even tasting, of mirbane, so perhaps citronelle is best for this purpose. It is likely to be more pure. The dose of scent is usually at the rate of 4 ounces to the hundredweight.
| II.— | Dehydrated soda | 5 parts |
|---|---|---|
| Curd soap | 20 parts | |
| Emery flour | 100 parts |
To be stirred together on a water bath with water, 100 parts, until soft.
| III.— | Turpentine | 1 part |
|---|---|---|
| Emery flour | 1 part | |
| Paris red | 2 parts | |
| Vaseline | 2 parts |
Mix well and perfume.
| IV.— | Stearine | 8 to 9 parts |
|---|---|---|
| Mutton suet | 32 to 38 parts | |
| Stearine oil | 2 to 2.5 parts |
Melt together and mix with Vienna chalk, in fine powder, 48 to 60 parts; Paris red, 20 parts.
| V.— | Rotten stone | 1 part |
|---|---|---|
| Iron subcarbonate | 3 parts | |
| Lard oil, a sufficient quantity. | ||
| VI.— | Iron oxide | 10 parts |
| Pumice stone | 32 parts | |
| Oleic acid, a sufficient quantity. | ||
| VII.— | Soap, cut fine | 16 parts |
| Precipitated chalk | 2 parts | |
| Jewelers’ rouge | 1 part | |
| Cream of tartar | 1 part | |
| Magnesium carbonate | 1 part | |
| Water, a sufficient quantity. | ||
Dissolve the soap in the smallest quantity of water over a water bath. Add the other ingredients to the solution while still hot, stirring all the time to make sure of complete homogeneity. Pour the mass into a box with shallow sides, and afterwards cut into cubes.