| Solution A | |
|---|---|
| Water | 32 ounces |
| Tolidol | 1 ounce |
| Sodium sulphite | 1 (2) ounce |
| Solution B | |
| Water | 32 ounces |
| Sodium sulphite | 2 (4) ounces |
| Solution C | |
| Water | 32 ounces |
| Sodium carbonate | 4 (10) ounces |
If preferred, stock solutions B and C can be made by hydrometer, instead of by weight as above. The solutions will then show:
| Solution B | |
|---|---|
| Sodium sulphite | 40 |
| Solution C | |
| Sodium carbonate | 75 |
| Or if potassium carbonate is preferred instead of sodium: | |
| Solution C | |
| Potassium carbonate | 60 |
For standard formula for dry plates and films, mix
| Solution A | 1 part |
| Solution B | 1 part |
| Solution C | 1 part |
| Water | 7 parts |
For strong negatives (for aristo-platino):
| Solution A | 1 1/2 to 2 parts |
| Solution B | 1 part |
| Solution C | 1 part |
| Water | 4 to 4 1/2 parts |
For tank development:
| Solution A | 1 part |
| Solution B | 1 part |
| Solution C | 1 part |
| Water | 35 parts |
For developing paper:
| Solution A | 2 parts |
| Solution B | 2 parts |
| Solution C | 1 part |
The reading of the hydrometer for stock solutions is the same whether dried chemicals or crystals are used. No water is used.
| Solution A | |
|---|---|
| Crystallized sulphite of soda | 386 grains |
| Pyrocatechin | 77 grains |
| Water | 8 ounces |
| Solution B | |
| Ordinary crystal phosphate of sodium | 725 grains |
| Caustic soda (purified in sticks) | 77 grains |
| Water | 8 ounces |
Mix 1 part of A with 1 part of B and from 1 to 3 parts of water. If the exposure is not absolutely normal we recommend to add to the above developer a few drops of a solution of bromide of potassium (1.10).
| Sulphite of soda crystallized | 25 1/2 drachms |
| Caustic soda (purified in sticks) | 3 1/2 drachms |
| Distilled water | 14 ounces |
| Pyrocatechin | 308 grains |
The pyrocatechin must not be added until the sulphite and caustic soda are entirely dissolved. For use the concentrated developer is to be diluted with from 10 to 20 times as much water. The normal proportion is 1 part of developer in 15 parts of water.
| Sulphite of soda crystallized | 468 grains |
| Water | 2 5/8 ounces |
| Caustic potash (purified in sticks) | 108 grains |
| Pyrocatechin | 108 grains |
Mix for a formally fixing plate of 5 x 7 inches.
| Developer | 3 drachms |
| Fixing soda solution (1:5) | 5 1/2 drachms |
| Water | 1 ounce |
The process of developing and fixing with this solution is accomplished in a {527} few minutes. The picture first appears usually, strengthens very quickly, and shortly after the fixing is entirely done.
Carbonate of potassium, 10 per cent solution (10 grams carbonate in 100 cubic centimeters of water).
For use take equal parts and add water as desired.
| I.— | Metabisulphite of potassium | 120 grains |
|---|---|---|
| Pyrogallic acid | 55 grains | |
| Bromide of potassium | 20 grains | |
| Metol | 45 grains | |
| Water | 20 ounces | |
| II.— | Carbonate of soda | 4 ounces |
| Water | 20 ounces |
For use mix equal parts I and II.
| Water | 4 ounces |
| Sulphite of sodium (saturated solution) | 4 drachms |
| Acetone | 2 drachms |
| Pyro | 10 grams |
| Water | 10 ounces |
| Sulphide of sodium, crystals | 4 ounces |
| Carbonate of potassium | 3 ounces |
| Adurol | 1/2 ounce |
For studio work and snap shots take 1 part with 3 parts water.
For time exposures out-door take 1 part with 5 parts water.
| I.— | Hot water | 10 ounces |
|---|---|---|
| Sulphite of sodium, crystals | 1 1/4 ounces | |
| Carbonate of sodium | 1/4 ounce | |
| Glycin | 1/2 ounce | |
| Add to water in order given | ||
| II.— | Water | 10 ounces |
| Carbonate of potash | 1 1/4 ounces | |
For normal exposure take I, 1 ounce; II, 2 ounces; water, 1 ounce.
| I.— | Hot water | 9 ounces |
|---|---|---|
| Sulphite of sodium, crystals | 385 grains | |
| Imogen | 123 grains | |
| II.— | Hot water | 4 1/2 ounces |
| Carbonate of sodium | 2 ounces |
For use take 2 ounces of I and 1 ounce of II.
| Water | 9 ounces |
| Sulphite of sodium | 3 1/2 ounces |
| Diogen | 7 drachms |
| Carbonate of potassium | 4 1/2 ounces |
For normal exposure take 4 drachms of this solution; dilute with 2 ounces, 1 drachm of water, and add 2 drops bromide of potassium, 10 per cent solution.
| I.— | Water | 1 ounce |
|---|---|---|
| Metabisulphite of potassium | 4 grains | |
| Ortol | 8 grains | |
| II.— | Water | 1 ounce |
| Sulphite of sodium | 48 grains | |
| Carbonate of potassium | 16 grains | |
| Carbonate of sodium | 32 grains |
For use take equal parts I and II, and an equal bulk of water.
| Metacarbol | 25 grains |
| Sulphite of soda, crystals | 100 grains |
| Caustic soda | 50 grains |
| Water | 10 ounces |
Dissolve the metacarbol in water, then add the sulphite, and when dissolved add the caustic soda and filter.
| By weight | ||
|---|---|---|
| I.— | Pyrogallol | 0.3 parts |
| Sodium bisulphite | 1.2 parts | |
| Sodium carbonate | 1.2 parts | |
| II.— | Eikonogen | 1.1 parts |
| Sodium sulphite | 2.4 parts | |
| Potassium carbonate | 1.5 parts | |
| III.— | Hydroquinone | 0.6 parts |
| Sodium sulphite | 3.4 parts | |
| Potassium bromide | 0.3 parts | |
| Sodium carbonate | 7.0 parts | |
These three formulas each yield one powder. The powders should be put up in oiled paper, and carefully inclosed, besides, in a wrapper of black paper. For use, one powder is dissolved in about 60 parts of distilled water.
Light.—The paper can be safely handled 8 feet from the source of light, {528} which may be Welsbach gas light, covered with post-office paper, incandescent light, ordinary gas light, kerosene light, or reduced daylight, the latter produced by covering a window with one or more thicknesses of orange post-office paper, as necessitated by strength of light.
Expose by holding the printing frame close to gas, lamp, or incandescent light, or to subdued daylight. Artificial light is recommended in preference to daylight because of uniformity, and it being in consequence easier to judge the proper length of time to expose.
Exposure.—The amount of exposure required varies with the strength of the light; it takes about the same time with an ordinary gas burner and an incandescent light; a Welsbach gas light requires only about one-half as much time as the ordinary gas burner, and a kerosene light of ordinary size about three times as much as an ordinary gas burner. If daylight is to be used the window should be covered with post-office paper, in which a sub-window about 1 foot square for making the exposure may be made. Cover this window first with a piece of white tissue paper, then with a piece of black cloth or post-office paper to exclude the white light when not wanted. Make exposure according to strength of light at from 1 to 2 feet away from the tissue paper. Keep the printing frame when artificial light is used constantly in motion during exposure.
Timing the Exposure.—The time necessary for exposing is regulated by density of negative and strength of light. The further away the negative is from the source of light at the time of exposure the weaker the light; hence, in order to secure uniformity in exposure it is desirable always to make the exposure at a given distance from the light used. With a negative of medium density exposed 1 foot from an ordinary gas burner, from 1 to 10 minutes’ exposure is required.
A test to ascertain the length of exposure should be made. Once the proper amount of exposure is ascertained with a given light, the amount of exposure required can be easily approximated by making subsequent exposures at the same distance from the same light; the only difference that it would then be necessary to make would be to allow for variation in density of different negatives.
Fixing.—Allow the prints to remain in the fixing solution 10 to 20 minutes, when they should be removed to a tray containing clear water.
Washing.—Wash 1 hour in running water, or in 10 or 12 changes of clear water, allowing prints to soak 2 to 3 minutes in each change.
| Solution A | |
|---|---|
| Pyrocatechin | 2 parts |
| Sulphite of soda, crystals | 2.5 parts |
| Water | 100 parts |
| Solution B | |
| Carbonate of soda | 10 parts |
| Water | 100 parts |
Before using mix 20 parts of Solution A, and 1/2 part of Solution B.
| Water | 10 ounces |
| Metol | 7 grains |
| Sodium sulphite, crystals, pure | 1/2 ounce |
| Hydroquinone | 30 grains |
| Sodium carbonate, dessicated (or 400 grains of crystallized carbonate). | 200 grains |
| Ten per cent bromide of potassium solution, about | 10 drops |
| Water | 4 ounces |
| Sodium sulphite, crystals, pure | 200 grains |
| Amidol, about | 20 grains |
| Ten per cent bromide of potassium solution, about | 5 drops |
If the blacks are greenish, add more amidol; if whites are grayish, add more bromide of potassium.
| Hypo | 16 ounces |
| Water | 64 ounces |
| Then add the following hardening solution: | |
| Water | 5 ounces |
| Sodium sulphite, crystals | 1/2 ounce |
| Commercial acetic acid (containing 25 per cent pure acid) | 3 ounces |
| Powdered alum | 1/2 ounce |
| Amidol | 2 grains |
| Sodium sulphite | 30 grains |
| Potassium bromide | 1 grain |
| Water | 1 ounce |
With a fairly correct exposure this will be found to produce prints of a rich black tone, and of good quality. The whole secret of successful bromide printing lies in correctness of exposure. It is generally taken for granted that any poor, flat negative is good enough to yield a bromide print, but this is not so. A negative of good printing quality on printing-out paper will also yield a good print on bromide paper, but considerable care and skill are necessary to obtain a good result from a poor negative. The above developer will not keep in solution, and should be freshly prepared as required. The same formula will also be found useful for the development of lantern plates, but will only yield black-toned slides.
The paper is exposed to daylight, in the printing frame, for about one-third of the time necessary for ordinary silver paper.
The print is then immersed in the developer for about 30 seconds, then cleared in 3 acid baths containing 1 part of muriatic acid C. P. to 60 parts of water, washed for a short time in running water, the whole operation of printing, clearing, and washing being complete in about half an hour.
As a general rule all parts of the picture except the highest lights should be visible when the exposure is complete.
When examining the prints in the printing frames, care should be taken not to expose them unduly to light; for the degradation of the whites of the paper due to slight action of light is not visible until after development.
Development.—Best results are obtained with the temperature of the developer from 60° to 80° F. Immerse the print in the developer with a quick sweeping motion to prevent air bells. Develop in artificial or weak daylight. The development of a print from a normal negative will require 40 seconds or more.
Formula for Developer.—
| Water | 50 ounces |
| Neutral oxalate of potash | 8 ounces |
| Potassium phosphate (monobasic) | 1 ounce |
Care must be used to obtain the monobasic potassium phosphate.
Immediately after prints are developed, place them face down in the first acid bath, composed of
| Muriatic acid, C. P. | 1 ounce |
| Water | 60 ounces |
After remaining in this bath for a period of about 5 minutes, transfer to the second acid bath of the same strength. The prints should pass through at least 3 and preferably 4 acid baths, to remove all traces of iron that may remain in the pores of the paper.
When thoroughly cleared, the print should be washed from 10 to 20 minutes in running water. If running water is not available, several changes of water in the tray will be necessary.
Print by direct light (sunlight preferred) until the shadows are clearly outlined in a deep canary color. At this stage the same detail will be observed in the half tones that the finished print will show. For developing, use plain water, heated to 120° F. (which will be as hot as they can bear).
The development will be practically instantaneous, and care must be taken to avoid air bubbles forming upon the surface of the prints. Place prints, after developing, directly into a clearing bath of muriatic acid, 1 drachm to 12 ounces of water, and let them remain in this bath about 10 minutes, when they are ready for the final washing of 15 minutes in running water, or 5 changes of about 3 minutes each. Lay out between blotters to dry, and mount by attaching the corners.
A.—For black tones:
| Neutral oxalate potassium | 8 ounces |
| Potassium phosphate | 1 ounce |
| Water | 30 ounces |
B.—For sepia tones:
| Of above mixed solution | 8 ounces |
| Saturated bichloride mercury solution | 1 ounce |
| Citrate soda | 5 grains |
If deep red tones are desired add to B
| Nitrate uranium | 10 grains |
Then filter and use as a developer.
Development should be conducted in a feeble white light, similar to that used when cutting up the paper, or by gas light.
It may take place immediately after the print is exposed, or at the end of the day’s printing.
Develop by floating the print, exposed side downwards, on the developing solution.
Development may take 30 seconds or more.
During the hot summer days it is not advisable to unduly delay the development of exposed prints. If possible develop within 1 hour after printing.
Either porcelain or agate—preferably porcelain—dishes are necessary to hold the developing solution.
To clear the developed prints: These must be washed in a series of baths (not less than three) of a weak solution of muriatic acid C. P. This solution is made by mixing 1 part of acid in 60 parts of water.
As soon as the print has been removed from the developing dish it must be immersed face downwards in the first bath of this acid, contained in a porcelain dish, in which it should remain about 5 minutes; meanwhile other prints follow until all are developed. The prints must then be removed to a second acid bath for about 10 minutes; afterwards to the third bath for about 15 minutes. While the prints remain in these acid baths they should be moved so that the solution has free access to their surfaces, but care should be taken not to abrade them by undue friction.
Pure muriatic acid must be used.
If commercial muriatic acid be used, the prints will be discolored and turn yellow.
For each batch of prints fresh acid baths must be used.
After the prints have passed through the acid baths they should be well washed in three changes of water during about a half hour. It is advisable to add a pinch of washing soda to the second washing water to neutralize any acid remaining in the print. Do not use water that contains iron, as it tends to turn paper yellow. Soft water is the best for this purpose.
The “sepia” paper is more easily affected by faint light, and, therefore, increased care must be taken when printing.
To develop, add to each ounce of the developing solution 1 1/2 drachms of sepia solution supplied for this purpose, and proceed as described for black paper.
The solution must be heated to a temperature of 150° to 160° F., to obtain the greatest amount of brilliance and the warmest color, but very good results can be obtained by using a cooler developer.
By this method of developing platinotype paper, many negatives which have been discarded on account of the dim, flat, non-contrasty results which they yield, in the hands of one possessing a little artistic skill, produce snappy, animated pictures. On the other hand, from the sharp and hard negative, soft, sketchy effects may be secured.
There are required for this process: Some glass jars; some soft brushes, varying from the fine spotter and the Japanese brush to the 1 1/2-inch duster, and several pieces of special blotting paper.
Manipulation.—Print the paper a trifle deeper than for the ordinary method of developing. Place the print face up on a piece of clean glass (should the print curl so that it is unmanageable, moisten the glass with glycerine), and, with the broad camel’s-hair brush, thinly coat the entire print with pure glycerine, blotting same off in 3 or 4 seconds; then recoat more thickly such portions as are desired especially restrained, or the details partly or entirely eliminated. Now brush or paint such portion of the print as is first desired with solution of 1 part glycerine and 4 parts normal developer, blotting the portion being developed from time to time to avoid developing too far. Full strength developer (without glycerine) is employed where a pronounced or deep shade is wanted.
When any part of the print has reached the full development desired, blot that portion carefully with the blotter and coat with pure glycerine.
A brown effect may be obtained by using saturated solution of mercury in the developer (1 part mercury to 8 parts developer). By the use of diluted mercury the “flesh tones” are produced in portraits, etc.
When print has reached complete development, place in hydrochloric (muriatic) acid and wash as usual.
Short fixing gives red tones. Longer fixing produces a brown tone.
The paper used is coated on one surface with a mixture of gelatin and some pigment (the color of which depends upon the color the required print is to be), and then allowed to dry. When required for printing it is sensitized by floating upon a solution of bichromate of potassium, and then again drying, in the dark this time. The process is based upon the action of light upon this film of chromatized gelatin; wherever the light reaches, the gelatin is rendered insoluble, even in hot water.
The paper is exposed in the usual way. But as the appearance of the paper before and after printing is precisely the same, it is impossible to tell when it is printed by examining the print. This is usually accomplished by exposing a piece of gelatino-chloride paper under a negative of about the same density, and placing it alongside of the carbon print. When the gelatino-chloride paper is printed, the carbon will be finished. The paper is then removed from the printing frame and immersed in cold water, which removes a great deal of the bichromate of potassium, and also makes the print lie out flat. It is then floated on to what is known as a support, and pressed firmly upon it, face downwards, and allowed to remain for 5 or 10 minutes. Then the support, together with the print, is placed in hot water for a short time, and when the gelatin commences to ooze out at the edges the print is removed by stripping from the support, this process leaving the greater quantity of the gelatin and pigment {532} upon the support. The gelatin and pigment are then treated with hot water by running the hot water over the face of the support by means of a sponge. This removes the soluble gelatin, and leaves the gelatin, together with the pigment it contains, which was acted upon by light; this then constitutes the picture.
The reason for transferring the gelatin film is quite apparent, since the greater portion of the unacted-upon gelatin will be at the back of the film, and in order to get at it to remove it, it is necessary to transfer it to a support. In this condition the print can be dried and mounted, but on consideration it will be seen that the picture is in a reversed position, that is to say, that the right-hand side of the original has become the left, and vice versa.
If the picture be finished in this condition, it is said to have been done by the single transfer method. In some instances this reversal would be of no consequence, such as some portraits, but with views which are known this would never do. In order to remedy this state of affairs, the picture is transferred once more, by pressing, while wet, upon another support, and allowed to dry upon it; when separated, the picture remains upon the latter support, and is in its right position. This is what is known as the double transfer method. When the double transfer method is used, the first support consists of a specially prepared support, which has been waxed in order to prevent the pictures from adhering permanently to it; this is then known as a temporary support. The paper upon which the print is finally received is prepared with a coating of gelatin, and is known as the final support.
The making of a good slide begins with the making of the negative, the operations in both cases being closely allied, and he who has mastered the first, which is the corner stone to all successful results in any branch of photography, may well be expected to be able to make a good lantern slide. A slide is judged not by what it appears to be when held in the hand, but by its appearance when magnified two to five thousand times on the screen, where a small defect in the slide will show up as a gross fault. Patience and cleanliness are absolutely necessary. The greatest caution should be observed to keep the lantern plates free from dust, both before and after exposure and development, for small pinholes and dust spots, hardly noticeable on the slide, assume huge proportions on the screen and detract materially from the slide’s beauty.
The high lights in a slide should, in rare cases only, be represented by clear glass, and the shadows should always be transparent, even in the deepest part. The balance between these extremes should be a delicate gradation of tone from one to the other. The contrast between the strongest high light and the deepest shadow should be enough to give brilliancy without hardness and delicacy or softness without being flat. This is controlled also, to some extent, by the subject summer sunshine requiring a more vigorous rendering than hazy autumn effects, and herein each individual must decide for himself what is most necessary to give the correct portrayal of the subject. It is a good idea to procure a slide, as near technically perfect as possible, from some slide-making friend, or dealer, to use it as a standard, and to make slide after slide from the same negative until a satisfactory result is reached.
A black tone of good quality is usually satisfactory for most slides, but it is very agreeable to see interspersed a variety of tone, and beautiful slides can be made, where the subject warrants, in blue, brown, purple, and even red and green, by varying the exposure and development and by using gold or uranium toning baths and other solutions for that purpose, the formulas and materials for which are easily obtainable from the magazines and from stock dealers, respectively.
It must be understood, however, that these toning solutions generally act as intensifiers, and that if toning is contemplated, it should be borne in mind at the time of developing the slide, so that it may not finally appear too dense. Toning will improve otherwise weak slides, but will not help under-exposed ones, as its tendency will be in such case to increase the contrast, which in such slides is already too great. Another method of getting a fine quality of slides is to make rather strong exposures to over-develop, and then to reduce with persulphate of ammonium.
The popular methods of making the exposure are: First, by contact in the printing frame, just as prints are made on velox or other developing paper, provided the subject on the negative is of the right size for a lantern slide; and the other and better method is the camera {533} method, by which the subject of any negative, large or small, or any part thereof, can be reduced or enlarged, and thus brought to the proper size desired for the slide. This is quite a knack, and should be considered and studied by the slide maker very carefully.
Hard and inflexible rules cannot be laid down in this relation. Portrait studies of bust or three-fourths figures or baby figures need not be made for a larger opening than 1 1/2 by 2 inches, and often appear to good advantage if made quite a bit smaller. Figure or group compositions, with considerable background or accessories, may, of course, have a larger opening to suit the particular circumstances. Monuments, tall buildings, and the like should have the benefit of the whole height of mat opening of 2 3/4 inches, and should be made of a size to fill it out properly, providing, however, for sufficient foreground and a proper sky line. Landscapes and marine views generally can be made to fill out the full length of mat opening, which, however, should not exceed 2 7/8 inches, and may be of any height to suit the subject, up to 2 3/4 inches.
The subject should be well centered on the plate and the part intended to be shown as the picture should be well within the size of the mat opening decided upon, so that with a slight variation of the placing of the mat no part of the picture will be cut off by the carrier in the stereopticon. The horizon line in a landscape, and more particularly in a marine view, should always be in proper position, either below or above the center line of the slide, as may suit the subject, but should never divide the picture in the middle and should not appear to be running either up or down hill. And the vertical lines in the pictures should not be leaning, but should run parallel with the side lines of the mat; this refers especially to the vertical lines in architecture, except, however, the Tower of Pisa and kindred subjects, which should in every case be shown with their natural inclinations.
As to time of exposure, very little can be said. That varies with the different makes of plates, with the quality of the light, and the nature and density of each individual negative. Therefore every one must be a judge unto himself and make as good a guess as he can for the first trial from each negative and gauge further exposures from the results thus obtained; but this much may be said, that a negative strong in contrast should be given a long exposure, close to the light, if artificial light is used, or in strong daylight, and developed with a weak or very much diluted developer to make a soft slide with full tone values. And a flat, weak negative will yield better results if exposed farther from the light or to a weaker light, and developed by a normal or more aggressive developer. Over exposure and under exposure show the same results in slide plates as in negative plates, and the treatment should be similar in both kinds of plates except that, perhaps, in cases of under exposure of slide plates, the better plan would be to cast them aside and make them over, as very little can be done with them. For getting bright and clear effects it is now well understood that better and more satisfactory results are obtained by backing the slide plates as well as by backing negative plates. This is accomplished by coating the back or glass side of the plate with the following mixture: