| 1. | Refined lake asphalt. | |
|---|---|---|
| 2. | Asphalt | 4 parts |
| Paraffine | 1 part | |
| 3. | Asphalt | 10 parts |
| Paraffine | 2 parts | |
| Boiled oil | 1 part | |
Any of these may be thinned with hot benzol or toluol. Toluol is less volatile than benzol and about as cheap, if not cheaper, the straw-colored grades being about 24 cents per gallon.
Examples of so-called “stone cement” are:
| 4. | Pitch | 8 parts |
|---|---|---|
| Rosin | 6 parts | |
| Wax | 1 part | |
| Plaster | 1/4 to 1/2 part | |
| 5. | Pitch | 8 parts |
| Rosin | 7 parts | |
| Sulphur | 2 parts | |
| Stone powder | 1 part |
These compositions are used to unite slate slabs and stoneware for domestic, engineering, and chemical purposes. Various rosin and pitch mixtures are used for these purposes, and the proportions of these two ingredients are determined by the consistency desired. Sulphur and stone powder are added to prevent the formation of cracks, sulphur acting chemically and stone powder mechanically. {34} Where the lute would come in contact with acid or vapors of the same, limestone should not be the powder used, otherwise it is about the best. Wax is a useful ingredient to keep the composition from getting brittle with age.
A class of lutes under this general grouping that are much used are so-called “marine glues” (q. v.). They must be tough and elastic. When used for calking on a vessel they must expand and contract with the temperature and not crack or come loose.
Formulas:
| 6. | Pitch | 3 parts |
|---|---|---|
| Shellac | 2 parts | |
| Pure crude rubber | 1 part | |
| 7. | Pitch | 1 part |
| Shellac | 1 part | |
| Rubber substitute | 1 part |
These are used by melting over a burner.
VI. Rosin, Shellac, and Wax.—A strong cement, used as a stone cement, is:
| 1. | Rosin | 8 parts |
|---|---|---|
| Wax | 1 part | |
| Turpentine | 1 part |
It has little or no body, and is used in thin layers.
For nitric and hydrochloric acid vapors:
| 2. | Rosin | 1 part |
|---|---|---|
| Sulphur | 1 part | |
| Fire clay | 2 parts |
Sulphur gives great hardness and permanency to rosin lutes, but this composition is somewhat brittle.
Good waterproof lutes of this class are:
| 3. | Rosin | 1 part |
|---|---|---|
| Wax | 1 part | |
| Powdered stone | 2 parts | |
| 4. | Shellac | 5 parts |
| Wax | 1 part | |
| Turpentine | 1 part | |
| Chalk, etc. | 8 to 10 parts |
For a soft air-tight paste for ground-glass surfaces:
| 5. | Wax | 1 part |
|---|---|---|
| Vaseline | 1 part |
6. A strong cement, without body, for metals (other than copper or alloys of same), porcelain, and glass is made by letting 1 part of finely powdered shellac stand with 10 parts of ammonia water until solution is effected.
VII. Rubber.—Because of its toughness, elasticity, and resistance to alterative influences, rubber is a very useful constituent in lutes, but its price makes its use very limited.
Leather Cement.
| 1. | Asphalt | 1 part |
|---|---|---|
| Rosin | 1 part | |
| Gutta percha | 4 parts | |
| Carbon disulphide | 20 parts |
To stand acid vapors:
| 2. | Rubber | 1 part |
|---|---|---|
| Linseed oil | 3 parts | |
| Fire clay | 3 parts |
3. Plain Rubber Cement.—Cut the crude rubber in small pieces and then add the solvent. Carbon disulphide is the best, benzol good and much cheaper, but gasoline is probably most extensively used because of its cheapness.
4. To make corks and wood impervious to steam and water, soak them in a rubber solution as above; if it is desired to protect them from oil vapors, use glue composition. (See Section IX.)
VIII. Linseed Oil.—This is one of the most generally useful substances we have for luting purposes, if absorbed by a porous substance that is inert.
Formulas: 1. China clay of general utility for aqueous vapors.
Linseed oil of general utility for aqueous vapors.
2. Lime forming the well-known putty.
Linseed oil forming the well-known putty.
3. Red or white lead and linseed oil.
These mixtures become very strong when set and are best diluted with powdered glass, clay, or graphite. There are almost an endless number of lutes using metallic oxides and linseed oil. A very good one, not getting as hard as those containing lead, is:
4. Oxide of iron and linseed oil.
IX. Casein, Albumen, and Glue.—These, if properly made, become very tough and tenacious; they stand moderate heat and oil vapors, but not acid vapors.
| 1. | Finely powdered casein | 12 parts |
|---|---|---|
| Slaked lime (fresh) | 50 parts | |
| Fine sand | 50 parts | |
| Water to thick mush. |
A very strong cement which stands moderate heat is the following:
| 2. | Casein in very fine powder | 1 part |
|---|---|---|
| Rubbed up with silicate of soda | 3 parts |
A strong lute for general purposes, {35} which must be used promptly when made:
3. White of egg made into a paste with slaked lime.
A composition for soaking corks, wood, packing, etc., to render them impervious to oil vapors, is:
| Gelatine or good glue | 2 parts | |
| Glycerine | 1/2 to 1 part | |
| Water | 6 parts | |
| Oil of wintergreen, etc., to keep from spoiling. | ||
X. Silicate of Oxychloride Cements.—For oil vapors, standing the highest heat:
1. A stiff paste of silicate of soda and asbestos.
Gaskets for superheated steam, retorts, furnaces, etc.:
2. Silicate of soda and powdered glass; dry the mixture and heat.
Not so strong, however, as the following:
| 3. | Silicate of soda | 50 parts |
|---|---|---|
| Asbestos | 15 parts | |
| Slaked lime | 10 parts |
Metal Cement:
| 4. | Silicate of soda | 1 part |
|---|---|---|
| Oxides of metal, such as zinc oxide; litharge, iron oxide, singly or mixed | 1 part |
Very hard and extra strong compositions:
| 5. | Zinc oxide | 2 parts |
|---|---|---|
| Zinc chloride | 1 part | |
| Water to make a paste. | ||
| 6. | Magnesium oxide | 2 parts |
| Magnesium chloride | 1 part | |
| Water to make a paste. |
XI. Flour and Starch Compositions.—
1. The well-known flaxseed poultice sets very tough, but does not stand water or condensed steam.
2. Flour and molasses, made by making a stiff composition of the two. This is an excellent lute to have at hand at all times for emergency use, etc.
3. Stiff paste of flour and strong zinc-chloride solution forms a more impervious lute, and is more permanent as a cement. This is good for most purposes, at ordinary temperature, where it would not be in contact with nitric-acid vapors or condensing steam.
4. A mixture of dextrine and fine sand makes a good composition, mainly used as core compound.
XII. Miscellaneous.—
| 1. | Litharge. | |
|---|---|---|
| Glycerine. |
Mixed to form a stiff paste, sets and becomes very hard and strong, and is very useful for inserting glass tubes, etc., in iron or brass.
For a high heat:
| 2. | Alumina | 1 part |
|---|---|---|
| Sand | 4 parts | |
| Slaked lime | 1 part | |
| Borax | 1/2 part | |
| Water sufficient. | ||
A class of mixtures that can be classified only according to their intended use are core compounds.
| I.— | Dextrine, about | 1 part |
|---|---|---|
| Sand, about | 10 parts | |
| With enough water to form a paste. | ||
II.—Powdered anthracite coal, with molasses to form a stiff paste.
| III.— | Rosin, partly saponified by soda lye | 1 part |
|---|---|---|
| Flour | 2 parts | |
| Sand (with sufficient water) | 4 parts |
(These proportions are approximate and the amount of sand can be increased for some purposes.)
| IV.— | Glue, powdered | 1 part |
|---|---|---|
| Flour | 4 parts | |
| Sand (with sufficient water) | 6 parts |
For some purposes the following mixture is used. It does not seem to be a gasket or a core compound:
| V.— | Oats (or wheat) ground | 25 parts |
|---|---|---|
| Glue, powdered | 6 parts | |
| Sal ammoniac | 1 part |
Paper read by Samuel S. Sadtler before the Franklin Institute.
| I.— | Borax, powdered | 60 parts |
|---|---|---|
| Dextrine, light yellow | 480 parts | |
| Glucose | 50 parts | |
| Water | 420 parts |
By the aid of heat, dissolve the borax in the water and add the dextrine and glucose. Continue the heat, but do not let the mixture boil, and stir constantly until a homogeneous solution is obtained, from time to time renewing the water lost by evaporation with hot water. Finally, bring up to full weight (1,000 parts) by the addition of hot water, then strain through flannel. Prepared in this manner the paste remains bright and clear for a long time. It has extraordinary adhesive properties and dries very rapidly. If care is not taken to keep the cooking temperature below the boiling point of water, the paste is apt to become brown and to be very brittle on drying. {36}
II.—Dissolve in hot water a sufficient quantity of dextrine to bring it to the consistency of honey. This forms a strong adhesive paste that will keep a long time unchanged, if the water is not allowed to evaporate. Sheets of paper may be prepared for extempore labels by coating one side with the paste and allowing it to dry; by slightly wetting the gummed side, the label will adhere to glass. This paste is very useful in the office or laboratory.
III.—Pour over 1,000 parts of dextrine 450 parts of soft water and stir the mixture for 10 minutes. After the dextrine has absorbed the water, put the mixture over the fire, or, preferably, on a water bath, and heat, with lively stirring for 5 minutes, or until it forms a light milk-like liquid, on the surface of which little bubbles begin to form and the liquid is apparently beginning to boil. Do not allow it to come to a boil. Remove from the fire and set in a bucket of cold water to cool off. When cold add to every 1,000 parts of the solution 51 parts glycerine and as much salicylic acid as will stand on the tip of a knife blade. If the solution is too thick, thin it with water that has been boiled and cooled off again. Do not add any more glycerine or the solution will never set.
IV.—Soften 175 parts of thick dextrine with cold water and 250 parts of boiling water added. Boil for 5 minutes and then add 30 parts of dilute acetic acid, 30 parts glycerine, and a drop or two of clove oil.
V.—Powder coarsely 400 parts dextrine and dissolve in 600 parts of water. Add 20 parts glycerine and 10 parts glucose and heat to 90° C. (195° F.).
VI.—Stir 400 parts of dextrine with water and thin the mass with 200 parts more water, 20 parts glucose, and 10 parts aluminum sulphate. Heat the whole to 90° C. (195° F.) in the water bath until the whole mass becomes clear and liquid.
VII.—Warm 2 parts of dextrine, 5 parts of water, 1 part of acetic acid, 1 part of alcohol together, with occasional stirring until a complete solution is attained.
VIII.—Dissolve by the aid of heat 100 parts of builders’ glue in 200 parts of water add 2 parts of bleached shellac dissolved previously in 50 parts of alcohol. Dissolve by the aid of heat 50 parts of dextrine in 50 parts of water, and mix the two solutions by stirring the second slowly into the first. Strain the mixture through a cloth into a shallow dish and let it harden. When needed cut off a piece of sufficient size and warm until it becomes liquid and if necessary or advisable thin with water.
IX.—Stir up 10 parts of dextrine with sufficient water to make a thick broth. Then, over a light fire, heat and add 25 parts of sodium water glass.
X.—Dissolve 5 parts of dextrine in water and add 1 part of alum.
| Starch | 20 parts | |
| Sugar | 10 parts | |
| Zinc chloride | 1 part | |
| Water | 100 parts | |
Mix the ingredients and stir until a perfectly smooth liquid results entirely free from lumps, then warm gradually until the liquid thickens.
| (a) | Pulverized gum arabic | 2 ounces |
|---|---|---|
| White sugar | 4 drachms | |
| Boiling water | 3 fluidounces | |
| (b) | Common laundry starch | 1 1/2 ounces |
| Cold water | 3 fluidounces | |
| Make into a batter and pour into | ||
| Boiling water | 32 fluidounces | |
Mix (a) with (b), and keep in a wide-mouthed bottle.
| I.— | Chromic acid | 2 1/2 parts |
|---|---|---|
| Stronger ammonia | 15 parts | |
| Sulphuric acid | 1/2 part | |
| Cuprammonium solution | 30 parts | |
| Fine white paper | 4 parts | |
| II.— | Isinglass, a sufficient quantity | |
| Acetic acid | 1 part | |
| Water | 7 parts | |
Dissolve sufficient isinglass in the mixture of acetic acid and water to make a thin mucilage.
One of the solutions is applied to the surface of one sheet of paper and the other to the other sheet, and they are then pressed together.
III.—A fair knotting varnish free from surplus oil is by far the best adhesive for fixing labels, especially on metal surfaces. It dries instantly, insuring a speedy job and immediate packing, if needful, without fear of derangement. It has great tenacity, and is not only absolutely damp-proof itself, but is actually repellent of moisture, to which all water pastes are subject. It costs more, but the additional expense is often infinitesimal compared with the pleasure of a satisfactory result.
| Pale glue | 4 ounces |
| White loaf sugar | 2 ounces |
| Powdered starch | 1 ounce |
| White dextrine | 1/4 pound |
| Pure glycerine | 3 ounces |
| Carbolic acid | 1/4 ounce |
| Boiling water | 32 ounces |
Cut up the glue and steep it in 1/2 pint boiling water; when softened melt in a saucepan; add sugar, starch, and dextrine, and lastly the glycerine, in which carbolic acid has been mixed; add remainder of water, and boil until it thickens. Pour into jars or bottles.
| I.— | Wheat flour | 1 pound |
|---|---|---|
| Water, cold | 1 quart | |
| Nitric acid | 4 fluidrachms | |
| Boric acid | 40 grains | |
| Oil of cloves | 20 minims |
Mix the flour, boric acid, and water, then strain the mixture; add the nitric acid, apply heat with constant stirring until the mixture thickens; when nearly cold add the oil of cloves. This paste will have a pleasant smell, will not attract flies, and can be thinned by the addition of cold water as needed.
II.—Dissolve 4 ounces alum in 4 quarts hot water. When cool add as much flour as will make it of the usual consistency; then stir into it 1/2 ounce powdered rosin; next add a little water in which a dozen cloves have been steeped; then boil it until thick as mush, stirring from the bottom all the time. Thin with warm water for use.
I.—Use a cheap grade of rye or wheat flour, mix thoroughly with cold water to about the consistency of dough, or a little thinner, being careful to remove all lumps; stir in a tablespoonful of powdered alum to a quart of flour, then pour in boiling water, stirring rapidly until the flour is thoroughly cooked. Let this cool before using, and thin with cold water.
II.—Venetian Paste.—
Soak the 4 ounces of glue in the cold water for 4 hours; dissolve on a water bath (glue pot), and while hot stir in the Venice turpentine. Make up (c) into a batter free from lumps and pour into (d). Stir briskly, and finally add the glue solution. This makes a very strong paste, and it will adhere to a painted surface, owing to the Venice turpentine in its composition.
III.—Strong Adhesive Paste.—
Make (a) into a batter free from lumps; then pour into (b). Boil if necessary, and while hot stir in the pulverized rosin a little at a time. This paste is exceedingly strong, and will stick heavy wall paper or thin leather. If the paste be too thick, thin with a little hot water; never thin paste with cold water.
IV.—Flour Paste.—
Work the wheat flour into a batter free from lumps with the cold water. Dissolve the alum as designated in (b). Now stir in (a) and (c) and, if necessary, continue boiling until the paste thickens into a semitransparent mucilage, after which stir in solution (b). The above makes a very fine paste for wall paper.
V.—Elastic or Pliable Paste.—
Beat to a batter the ingredients of (a). Dissolve the borax in the boiling water; then add the glycerine, after which pour (a) into solution (b). Stir until it becomes translucent. This paste will not crack, and, being very pliable, is used for paper, cloth, leather, and other material where flexibility is required.
VI.—A paste with which wall paper can be attached to wood or masonry, adhering to it firmly in spite of dampness, is prepared, as usual, of rye flour, to which, however, are added, after the boiling, 8 1/3 parts, by weight, of good linseed-oil varnish and 8 1/3 parts, by weight, of turpentine to every 500 parts, by weight.
VII.—Paste for Wall Paper.—Soak 18 pounds of bolus (bole) in water, after it has been beaten into small fragments, and pour off the supernatant water. Boil 10 ounces of glue into glue water, mix it well with the softened bolus and 2 pounds plaster of Paris and strain through a sieve by means of a brush. Thin the mass with water to the consistency of a thin paste. The paste is now ready for use. It is not only much cheaper than other varieties, but has the advantage over them of adhering better to whitewashed walls, and especially such as have been repeatedly coated over the old coatings which were not thoroughly removed. For hanging fine wall paper this paste is less commendable, as it forms a white color, with which the paper might easily become soiled if great care is not exercised in applying it. If the fine wall paper is mounted on ground paper, however, it can be recommended for pasting the ground paper on the wall.
The following formulas for pastes of the type indicated were proposed by Leo Eliel:
| I.— | Tragacanth | 1 ounce |
|---|---|---|
| Acacia | 4 ounces | |
| Thymol | 14 grains | |
| Glycerine | 4 ounces | |
| Water, sufficient to make | 2 pints |
Dissolve the gums in 1 pint of water, strain, and add the glycerine, in which the thymol is suspended; shake well and add sufficient water to make 2 pints. This separates on standing, but a single shake mixes it sufficiently for use.
| II.— | Rye flour | 8 ounces |
|---|---|---|
| Powdered acacia | 1 ounce | |
| Glycerine | 2 ounces | |
| Oil of cloves | 40 drops |
Rub the rye flour and acacia to a smooth paste with 8 ounces of cold water; strain through cheese cloth, and pour into 1 pint of boiling water, and continue the heat until as thick as desired. When nearly cold add the glycerine and oil of cloves.
| III.— | Rye flour | 5 parts |
|---|---|---|
| Venice turpentine | 1 part | |
| Liquid glue, a sufficient quantity | ||
Rub up the flour with the turpentine and then add sufficient freshly prepared glue (glue or gelatine dissolved in water) to make a stiff paste. This paste dries slowly.
| IV.— | Dextrine | 2 parts |
|---|---|---|
| Acetic acid | 1 part | |
| Water | 5 parts | |
| Alcohol, 95 per cent. | 1 part |
Dissolve the dextrine and acetic acid in water by heating together in the water bath, and to the solution add the alcohol.
| V.— | Dextrine | 3 pounds |
|---|---|---|
| Borax | 2 ounces | |
| Glucose | 5 drachms | |
| Water | 3 pints 2 ounces |
Dissolve the borax in the water by warming, then add the dextrine and glucose, and continue to heat gently until dissolved.
Another variety is made by dissolving a cheap Ghatti gum in limewater, but it keeps badly.
VI.—Add tartaric acid to thick flour paste. The paste is to be boiled until quite thick, and the acid, previously dissolved in a little water, is added, the proportion being about 2 ounces to the pint of paste.
VII.—Gum arabic, 50 parts; glycerine, 10 parts; water, 30 parts; liq. Stibii chlorat., 2 parts.
VIII.—Boil rye flour and strong glue water into a mass to which are added, for 1,000 parts, good linseed-oil varnish 30 parts and oil of turpentine 30 parts. This mixture furnishes a gluing agent which, it is claimed, even renders the labels proof against being loosened by moisture.
IX.—Pour 140 parts of distilled cold water over 100 parts of gum arabic in a wide-necked bottle and dissolve by frequent shaking. To the solution, which is ready after standing for about 3 days, add 10 parts of glycerine; later, 20 parts of diluted acetic acid, and finally 6 parts of aluminum sulphate, then straining it through a fine-hair sieve.
X.—Good glue is said to be obtained by dissolving 1 part of powdered sugar in 4 parts of soda water glass.
XI.—A glue for bottle labels is prepared by dissolving borax in water; soak glue in this solution and dissolve the glue by boiling. Carefully drop as much acetic acid into the solution as will allow it to remain thin on cooling. Labels affixed with this agent adhere firmly and do not become moldy in damp cellars.
XII.—Dissolve some isinglass in acetic acid and brush the labels over with it. There will be no cause to complain of their coming off, nor of striking through the paper. Take a wide-mouthed bottle, fill about two-thirds with commercial acetic acid, and put in as much isinglass as the liquid will hold, and set aside in a warm place until completely dissolved. When cold it should form a jelly. To use it place the bottle in hot water. The cork should be well-fitting and smeared with vaseline or melted paraffine.