| Aniline hydrochloride | 40 parts |
| Potassic chlorate | 20 parts |
| Copper sulphate | 40 parts |
| Chloride of ammonia (sal ammoniac) | 16 parts |
| Warm water at 60° F | 500 parts |
After warming a few minutes the mass froths up. The vapor should not be inhaled. Then set aside, and if the mass is not totally black in a few hours, again heat to 60° F., and expose to the air for a few days, and finally wash away all the soluble salts and the black is fit for use.
| Aniline (fluid measure) | 30 parts |
| Toluidine (by weight) | 10 parts |
| Pure hydrochloric acid, B. P. (fluid measure) | 60 parts |
| Soluble gum arabic (fluid measure) | 60 parts |
Dissolve the toluidine in the aniline and add the acid, and finally the mucilage.
II.—Mix together at gentle heat:
| Starch paste | 13 quarts |
| Potassic chlorate | 350 scruples |
| Sulphate of copper | 300 scruples |
| Sal ammoniac | 300 scruples |
| Aniline hydrochloride | 800 scruples |
Add 5 per cent of alizarine oil, and then steep it for 2 hours in the dye bath of red liquor of 2 1/2° Tw. Dye in a bath made up of 1/2 ounce of rose bengal and 1 1/2 ounces of red liquor to every 70 ounces of cotton fabric dyed, first entering the fabric at 112° F., and raising it to 140° F., working for 1 hour, or until the desirable shade is obtained; then rinse and dry.
Dissolve in a vessel (a) 8 1/2 parts of chloride of copper in 30 parts of water, and then add 10 parts chloride of sodium and 9 1/2 parts liquid ammonia.
In a second vessel dissolve (b) 30 parts aniline hydrochlorate in 20 parts of water, and add 20 parts of a solution of gum arabic prepared by dissolving 1 part of gum in 2 parts of water.
Finally mix 1 part of a with 4 parts of b; expose the mixture to the air for a few days to develop from a greenish to a black color. Dilute for use, or else dry the thick compound to a powder.
If new liquor is used as the mordant, mix 1 part of this with 4 parts of water, and after working the fabric for 1 to 2 hours in the cold liquor, wring or squeeze it out and dry; before working it in the dye liquor, thoroughly wet the fabric by rinsing it in hot water at a spring boil; then cool by washing in the dye bath until the shade desired is attained, and again rinse and dry.
The red liquor or acetate of aluminum may be made by dissolving 13 ounces of alum in 69 ounces of water and mixing this with a solution made by dissolving 7 1/2 ounces of acetate of lime, also dissolved in 69 ounces of water. Stir well, allow it to settle, and filter or decanter {280} off the clear fluid for use, and use this mixture 2 1/2° Tw.
The fabric is first put into the stannate of soda mordant for a few minutes, then wrung out and put into the alum mordant for about the same time; then it is again wrung out and entered in the dye bath at 120° F. and dyed to shade desired, and afterwards rinsed in cold water and dried.
The dye bath is made of 1/4 ounce of rose bengal per gallon of water. If fast pink is the dye used, the mordant used would be Turkey red oil and red liquor. Use 8 ounces of Turkey red oil per gallon of water. Put the fabric into this, then wring out the textile and work in red liquor of 7° Tw. for about 2 hours, then wring out and dye in a separate bath made up of eosine, or fast pink, in water in which a little alum has been dissolved.
No mordant is required in using this color in dyeing woolen goods. The dyeing operation consists simply in putting the goods into the dye bath at 190° F. and working them therein until the desired shade is obtained, then rinsing in cold water and drying.
If the water used in preparing the dye is at all alkaline, make use of the acid roseine dissolved in water in which a little sulphuric acid has been mixed, and work, gradually raising to the boiling point, and keep up the temperature for 30 minutes, or according to the shade desired. Put about 20 per cent sulphate of soda into the dye bath.
To prepare silk fabrics, wash them in a weak soap liquor that has been just sweetened (i. e., its alkalinity turned to a slight sourness) with a little sulphuric acid. Work the goods until dyed to shade, and then rinse them in cold water that has been slightly acidulated with acetic, tartaric, or citric acid.
The fulling stock for 72 ounces of beaver consists of a mixture of
| Black lead or plumbago | 16 ounces |
| Venetian red | 48 ounces |
| Indigo extract (fluid) | 5 ounces |
Ordinary Drab.—
| Common plumbago | 12 ounces |
| Best plumbago | 12 ounces |
| Archil extract (fluid) | 15 ounces |
| Indigo extract | 10 ounces |
Mix into fluid paste with water and add sulphuric acid at 30° Tw. For the dye liquor make a boiling-hot solution of the aniline dye and allow it to cool; then put into an earthenware vessel holding water and heat to 83° F., and add sufficient dye liquor to give the quantity of felt the desired shade. First moisten well the felted matter (or the hair, if dyed before felting) with water, and then work it about in the above dye bath at 140° F. To deepen the shade, add more dye liquor, lifting out the material to be dyed before adding the fresh dye liquor, so that it can be well stirred up and thoroughly mixed with the exhausted bath.
To prepare instead of buying it ready made, gradually add to a boiling solution of potassium ferricyanide (red prussiate of potash) an equivalent quantity of hot solution of ferrous sulphate, boiling for 2 hours and washing the precipitate on a filter until the washings assume a dark-blue color. The moist precipitate can at once be dissolved by the further addition of a sufficient quantity of water. About 64 parts of the iron salt is necessary to convert 100 parts of the potassium salt into the blue compound.
If the blue is to be sent out in the liquid form, it is desirable that the solution should be a perfect one. To attain that end the water employed should be free from mineral substances, and it is best to filter the solution through several thicknesses of fine cotton cloth before bottling; or if made in large quantities this method may be modified by allowing it to stand some days to settle, when the top portion can be siphoned off for use, the bottom only requiring filtration.
The ball blue sold for laundry use consists of ultramarine. Balls or tablets of this substance are formed by mixing it with glucose or glucose and dextrin, and pressing into shape. When glucose alone is used, the product has a tendency to become soft on keeping, which tendency may be counteracted by a proper proportion of dextrin. Bicarbonate of sodium is added as a filler to cheapen the product, the quantity used and the quality of the ultramarine employed being both regulated by the price at which the product is to sell.
When so prepared the feathers may be dyed by immersion in any dye liquor. An old-time recipe for black is immersion in a bath of ferric nitrate suitably diluted with water, and then in an infusion of equal parts of logwood and quercitron. Doubtless an aniline dye would prove equally efficient and would be less troublesome to use.
After dyeing, feathers are dipped in an emulsion formed by agitating any bland fixed oil with water containing a little potassium carbonate, and are then dried by gently swinging them in warm air. This operation gives the gloss.
Curling where required is effected by slightly warming the feathers before a fire, and then stroking with a blunt metallic edge, as the back of a knife. A certain amount of manual dexterity is necessary to carry the whole process to a successful ending.
DYES FOR FOOD: See Foods.
DYES FOR LEATHER: See Leather.
DYE STAINS, THEIR REMOVAL FROM THE SKIN: See Cleaning Preparations and Methods.
DYNAMITE: See Explosives.
EARTHENWARE: See Ceramics.
EAU DE QUININE: See Hair Preparations.
EBONY: See Wood.
EBONY LACQUER: See Lacquers.
Starch, French chalk, lycopodium, of each, 40 parts; bismuth subnitrate, 2 parts; salicylic acid, 2 parts; menthol, 1 part. Apply freely to the affected parts.
The age of eggs may be approximately judged by taking advantage of the fact that as they grow old their density decreases through evaporation of moisture. According to Siebel, a new-laid egg placed in a vessel of brine made in the proportion of 2 ounces of salt to 1 pint of water, will at once sink to the bottom. An egg 1 day old will sink below the surface, but not to the bottom, while one 3 days old will swim just immersed in the liquid. If more than 3 days old the egg will float on the surface, the amount of shell exposed increasing with age; and if 2 weeks old, only a little of the shell will dip in the liquid.
The New York State Experiment Station studied the changes in the specific gravity of the eggs on keeping and found that on an average fresh eggs had a specific gravity of 1.090; after they were 10 days old, of 1.072; after 20 days, of 1.053; and after 30 days, of 1.035. The test was not continued further. The changes in specific gravity correspond to the changes in water content. When eggs are kept they continually lose water by evaporation through the pores in the shell. After 10 days the average loss was found to be 1.60 per cent of the total water present in the egg when perfectly fresh; after 20 days, 3.16 per cent; and after 30 days, 5 per cent. The average temperature of the room where the eggs were kept was 63.8° F. The evaporation was found to increase somewhat with increased temperature. None of the eggs used in the 30-day test spoiled.
Fresh eggs are preserved in a number of ways which may, for convenience, be grouped under two general classes: (1) Use of low temperature, i. e., cold storage; and (2) excluding the air by coating, covering, or immersing the eggs, some material or solution being used which may or may not be a germicide. The two methods are often combined. The {283} first method owes its value to the fact that microörganisms, like larger forms of plant life, will not grow below a certain temperature, the necessary degree of cold varying with the species. So far as experiment shows, it is impossible to kill these minute plants, popularly called “bacteria” or “germs,” by any degree of cold; and so, very low temperature is unnecessary for preserving eggs, even if it were not undesirable for other reasons, such as injury by freezing and increased cost. According to a report of the Canadian commission of agriculture and dairying:
Eggs are sometimes removed from the shells and stored in bulk, usually on a commercial scale, in cans containing about 50 pounds each. The temperature recommended is about 30° F., or a little below freezing, and it is said they will keep any desired length of time. They must be used soon after they have been removed from storage and have been thawed.
Water glass or soluble glass is the popular name for potassium silicate, or sodium silicate, the commercial article often being a mixture of the two. The commercial water glass is used for preserving eggs, as it is much cheaper than the chemically pure article which is required for many scientific purposes. Water glass is commonly sold in two forms, a syrup-thick liquid of about the consistency of molasses, and a powder. The thick syrup, the form perhaps most usually seen, is sometimes sold wholesale as low as 1 3/4 cents per pound in carboy lots. The retail price varies, though 10 cents per pound, according to the North Dakota Experiment Station, seems to be the price commonly asked. According to the results obtained at this station a solution of the desired strength for preserving eggs may be made by dissolving 1 part of the syrup-thick water glass in 10 parts, by measure, of water. If the water-glass powder is used, less is required for a given quantity of water. Much of the water glass offered for sale is very alkaline. Such material should not be used, as the eggs preserved in it will not keep well. Only pure water should be used in making the solution, and it is best to boil it and cool it before mixing with the water glass.
The solution should be carefully poured over the eggs packed in a suitable vessel, which must be clean and sweet, and if wooden kegs or barrels are used they should be thoroughly scalded before packing the eggs in them. The packed eggs should be stored in a cool place. If they are placed where it is too warm, silicate deposits on the shell and the eggs do not keep well. The North Dakota Experiment Station found it best not to wash the eggs before packing, as this removes the natural mucilaginous coating on the outside of the shell. The station states that 1 gallon of the solution is sufficient for 50 dozen eggs if they are properly packed.
It is, perhaps, too much to expect that eggs packed in any way will be just as satisfactory for table use as the fresh article. The opinion seems to be, however, that those preserved with water glass are superior to most of those preserved otherwise. The shells of eggs preserved in water glass are apt to crack in boiling. It is stated that this may be prevented by puncturing the blunt end of the egg with a pin before putting it into the water.
This action is based on the fact that the air cavity in the big end of the egg increases in size and capacity, from day to day, as the egg grows older. An apparatus (originally devised by a German poultry fancier) based on this principle, and by means of which the age of an egg maintained at ordinary temperature may be told approximately to within a day, is made by placing a scale of degrees, drawn from O° to 90° (the latter representing the perpendicular) behind the vessel {284} containing the solution, and observing the angle made by the axis of the egg with the perpendicular line. This gives the age of the egg with great accuracy.
| Weight of | |||
|---|---|---|---|
| Whole Eggs, Grains |
Shell, Grains |
Net. | |
| Common hen, small | 635.60 | 84.86 | 550.54 |
| Common hen, mean | 738.35 | 92.58 | 645.77 |
| Common hen, large | 802.36 | 93.25 | 709.11 |
| Italian hen | 840.00 | 92.50 | 747.50 |
| Houdan | 956.60 | 93.50 | 853.10 |
| La Flesche | 926.50 | 94.25 | 835.25 |
| Brahma | 1,025.50 | 114.86 | 910.64 |
From this it will be seen that the Houdans and Brahmas are the most profitable producers, as far as food value of the product is concerned—provided, of course, they are equally prolific with the ordinary fowl.
Another calculation is the number of eggs to the pound, of the various weights. This is as follows:
| Small ordinary eggs (635 grains) | 12.20 to pound |
| Large ordinary eggs (802 grains) | 9.25 to pound |
| Houdan eggs | 8.0 to pound |
| Brahma, mean | 7.4 to pound |
| Brahma, large | 7.1 to pound |
| Yolks of eggs (about 250) | 5.0 parts |
| Distilled water | 0.3 parts |
Beat this together and heat the mass with constant stirring in a dish on the water bath until it thickens and a sample exhibits oil upon pressing between the fingers. Squeeze out between hot plates, mix the turbid oil obtained with 0.05 parts of dehydrated Glauber’s salt, shake repeatedly, and finally allow to settle. The oil, which must be decanted clear from the sediment, gives a yield of at least 0.5 parts of egg oil.
| Yellow beeswax | 0.2 parts |
| Cacao oil | 0.5 parts |
Melt on the water bath and gradually add 9 parts of olive oil.
| Sodium bicarbonate | 8 ounces |
| Tartaric acid | 3 ounces |
| Cream tartar | 5 ounces |
| Turmeric, powdered | 3 drachms |
| Ground rice | 16 ounces |
Mix and pass through a fine sieve. One teaspoonful to a dessertspoonful (according to article to be made), to be mixed with each half pound of flour.
Eggs are often packed in lime, salt, or other products, or are put in cold storage for winter use, but such eggs are very far from being perfect when they come upon the market. German authorities declare that water glass more closely conforms to the requirements of a good preservative than any of the substances commonly employed. A 10 per cent solution of water glass is said to preserve eggs so effectually that at the end of three and one-half months eggs still appeared to be perfectly fresh. In most packed eggs the yolk settles to one side, and the egg is then inferior in quality. In eggs preserved in water glass the yolk retained its normal position in the egg, and in taste they were not to be distinguished from fresh, unpacked store eggs.
Of twenty methods tested in Germany, the three which proved most effective were coating the eggs with vaseline, preserving them in limewater, and preserving them in water glass. The conclusion was reached that the last is preferable, because varnishing the eggs with vaseline takes considerable time, and treating them with limewater is likely to give the eggs a limy flavor. {285}
Other methods follow:
I.—Eggs can be preserved for winter use by coating them, when perfectly fresh, with paraffine. As the spores of fungi get into eggs almost as soon as they are laid, it is necessary to rub every egg with chloroform or wrap it a few minutes in a chloroform soaked rag before dipping it into the melted paraffine. If only a trace of the chloroform enters the shell the development of such germs as may have gained access to freshly laid eggs is prevented. The paraffine coating excludes all future contamination from germ-laden air, and with no fungi growing within, they retain their freshness and natural taste.
II.—Preserving with Lime.—Dissolve in each gallon of water 12 ounces of quicklime, 6 ounces of common salt, 1 drachm of soda, 1/2 drachm saltpeter, 1/2 drachm tartar, and 1 1/2 drachms of borax. The fluid is brought into a barrel and sufficient quicklime to cover the bottom is then poured in. Upon this is placed a layer of eggs, quicklime is again thrown in and so on until the barrel is filled so that the liquor stands about 10 inches deep over the last layer of eggs. The barrel is then covered with a cloth, upon which is scattered some lime.
III.—Melt 4 ounces of clear beeswax in a porcelain dish over a gentle fire, and stir in 8 ounces of olive oil. Let the solution of wax in oil cool somewhat, then dip the fresh eggs one by one into it so as to coat every part of the shell. A momentary dip is sufficient, all excess of the mixture being wiped off with a cotton cloth. The oil is absorbed in the shell, the wax hermetically closing all the pores.
IV.—The Reinhard method is said to cause such chemical changes in the surface of the eggshell that it is closed up perfectly air-tight and an admittance of air is entirely excluded, even in case of long-continued storing. The eggs are for a short time exposed to the direct action of sulphuric acid, whereby the surface of the eggshell, which consists chiefly of lime carbonate, is transformed into lime sulphate. The dense texture of the surface thus produced forms a complete protection against the access of the outside air, which admits of storing the egg for a very long time, without the contents of the egg suffering any disadvantageous changes regarding taste and odor. The egg does not require any special treatment to prevent cracking on boiling, etc.
Some object to this on the ground that sulphuric acid is a dangerous poison, that might, on occasion, penetrate the shell.
V.—Take about half a dozen eggs and place them in a netting (not so many as would chill the water below the boiling point, even for an instant), into a boiling solution of boric acid, withdraw immediately, and pack. Or put up, in oil, carrying 2 per cent or 3 per cent of salicylic acid. Eggs treated in this way are said to taste, after six months, absolutely as fresh as they were when first put up. The eggs should be as fresh as possible, and should be thoroughly clean before dipping. The philosophy of the process is that the dipping in boiling boric acid solution not only kills all bacteria existing on, or in, the shell and membrane, but reinforces these latter by a very thin layer of coagulated albumen; while the packing in salicylated oil prevents the admission of fresh germs from the atmosphere. Salicylic acid is objected to on the same grounds as sulphuric acid.
VI.—Dissolve sodium silicate in boiling water, to about the consistency of a syrup (or about 1 part of the silicate to 3 parts water). The eggs should be as fresh as possible, and must be thoroughly clean. They should be immersed in the solution in such manner that every part of each egg is covered with the liquid, then removed and let dry. If the solution is kept at or near the boiling temperature, the preservative effect is said to be much more certain and to last longer.
EGG CHOCOLATE: See Beverages.
EGG DYES: See Dyes.
EGG LEMONADE: See Beverages, under Lemonade.
EGG PHOSPHATE: See Beverages.
EGG-STAIN REMOVER: See Cleaning Preparations and Methods.
EGGS, TESTS FOR: See Foods.
EIKONOGEN DEVELOPER: See Photography.
EKTOGAN: See Antiseptics. {286}
A substitute for elaine for woolen yarns is obtained by boiling 4 pounds carrageen moss in 25 gallons water for 3 hours. The soda is then put in and the boiling continued for another half hour; 2 pounds fleabane seeds are gradually added, and a little water to make up for the evaporation. After a further 1 1/2 hours boiling, the extract is passed through a fine sieve and well mixed with 25 pounds cottonseed oil, 12 1/2 pounds sweet oil, and 12 1/2 pounds ammonia solution of 0.96 specific gravity. Next day stir in 25 pounds saponified elaine and 13 pounds of odorless petroleum of 0.885 specific gravity. The resulting emulsion keeps well, dissolves perfectly in lukewarm water, and answers its purpose excellently.
ELECTRODEPOSITION PROCESSES: See Plating.
ELECTROLYSIS IN BOILERS: See Boiler Compounds.
(See also Plating.)
First, clean the articles to be plated. To remove grease, warm the pieces before a slow fire of charcoal or coke, or in a dull red stove. Delicate or soldered articles should be boiled in a solution of caustic potash, the latter being dissolved in 10 times its weight of water.
The scouring bath is composed of 100 parts of water to from 5 to 20 parts of sulphuric acid. The articles may be put in hot and should be left in the bath till the surface turns to an ocher red tint.
The articles, after having been cleansed of grease by the potash solution, must be washed in water and rinsed before being scoured. Copper or glass tongs must then be used for moving the articles, as they must not afterwards be handled. For small pieces, suitable earthenware or porcelain strainers may be used.
The next stage is the spent nitric acid bath. This consists of nitric acid weakened by previous use. The articles are left in until the red color disappears, so that after rinsing they show a uniform metallic tint. The rinsing should be thoroughly carried out.
Having been well shaken and drained, the articles are next subjected to the strong nitric acid bath, which is made up as follows:
| Nitric acid of 36° Bé | 100 volumes |
| Chloride of sodium (common salt) | 1 volume |
| Calcined soot (lampblack) | 1 volume |
The articles must be immersed in this bath for only a few seconds. Avoid overheating or using too cold a bath. They are next rinsed thoroughly with cold water and are again subjected to a strong nitric acid bath to give them a bright or dull appearance as required.
To produce a bright finish, plunge them for a few seconds (moving them about rapidly at the same time) in a cold bath of the following composition:
| Nitric acid | 100 volumes |
| Sulphuric acid | 100 volumes |
| Chloride of sodium | 1 volume |
Again rinse thoroughly in cold water. The corresponding bath giving a dull or matt appearance is composed of:
| Nitric acid | 200 volumes |
| Sulphuric acid | 100 volumes |
| Sea salt | 1 volume |
| Sulphate of zinc | 1 to 5 volumes |
The duration of immersion in this bath varies from 5 to 20 minutes, according to the dullness required. Wash with plenty of water. The articles will then have an unpleasant appearance, which will disappear on plunging them for a moment into the brightening bath and rinsing quickly.
The pieces are next treated with the nitrate of mercury bath for a few seconds.
| Plain water | 10,000 parts |
| Nitrate of mercury | 10 parts |
| Sulphuric acid | 20 parts |
It is necessary to stir this bath before using it. For large articles the proportion of mercury should be greater. An article badly cleaned will come out in various shades and lacking its metallic brightness. It is better to throw a spent bath away than attempt to strengthen it.
The various pieces, after having passed through these several processes, are then ready for the plating bath.
A few words on the subject of gilding may not be amiss. Small articles are gilded hot, large ones cold. The cold cyanide of gold and potassium bath is composed as follows:
| Distilled water | 10,000 parts |
| Pure cyanide of potassium | 200 parts |
| Pure gold | 100 parts |
The gold, transformed into chloride, is dissolved in 2,000 parts of water and {287} the cyanide in 8,000 parts. The two solutions are then mixed and boiled for half an hour.
The anode must be entirely submerged in the bath, suspended from platinum wires and withdrawn immediately the bath is out of action.
The following are the formulas for the other metals per 10,000 parts of distilled water:
Crystallized phosphate of soda, 600 parts; alloys rich in copper castings, 500 parts.
Bisulphide of soda, 100 parts; alloys rich in copper, 125 parts.
Pure cyanide of potassium, 10 parts; alloys rich in copper, 5 parts. Pure gold transformed into chloride, 10 parts; alloys rich in copper, 10 parts.
Dissolve the phosphate of soda hot in 8,000 parts water, let the chloride of gold cool in 1,000 parts water; mix little by little the second solution with the first; dissolve the cyanide and bisulphide in 1,000 parts water and mix this last solution with the other two. The temperature of the bath may vary between 122° and 175° F.
With excess of current the pieces become gray, and blacken. In the cold bath anodes of platinum or silver should be employed. Old baths are, in this case, preferable to new. They may, if required, be artificially aged by the addition of 1 or 2 parts in 1,000 of liquid ammonia.
If the anode blackens, the bath is too weak. If it becomes white, there is too much current, and the deposit, being too rapid, does not adhere. The deposit may be taken as normal and regular when the anode becomes gray during the passage of the current and white again when it ceases to flow.
The nickel vat should be of glass, porcelain, or earthenware, or a case lined with impermeable gum. The best nickel bath is prepared by dissolving to saturation, in hot distilled water, nickel sulphate and ammonium, free from oxides or alkalies and alkaline earthy metals. The proportion of salt to dissolve is 1 part, by weight, to 10 of water. Filter after cooling and the bath is then ready for use.
When the bath is ready and the battery set up, the wires from the latter are joined by binding screws to two metal bars resting on the edge of the vat. The bar joined to the positive pole of the battery supports, through the intervention of a nickel-plated copper hook, a plate of nickel, constituting the soluble anode, which restores to the bath the metal deposited on the cathode by the electrolytic action. From the other bar are suspended the articles to be plated. These latter should be well polished before being put into the bath. To remove all grease, scrub them with brushes soaked in a hot solution of whiting, boiled in water and carbonate of soda.
Copper and its alloys are cleaned well in a few seconds by immersion in a bath composed of 10 parts, by weight, of water, and 1 part of nitric acid. For rough articles, 2 parts water, 1 nitric acid, and 1 sulphuric acid. For steel and polished castings, 100 parts water to 1 sulphuric acid. The articles should remain in the bath until the whole surface is of a uniform gray tint. They are then rubbed with powdered pumice stone till the solid metal appears. Iron and steel castings are left in the bath for three or four hours and then scrubbed with well-sifted sand.
If the current be too strong, the nickel is deposited gray or even black. An hour or so is time enough to render the coat sufficiently thick and in a condition to stand polishing. When the articles are removed from the bath they are washed in water and dried in hot sawdust.
To polish the articles they should be taken in one hand and rubbed rapidly backward and forward on a strip of cloth soaked in polishing powder boiled in water, the cloth being firmly fixed at one end and held in the other hand. The hollow parts are polished by means of cloth pads of various sizes fixed on sticks. These pads must be dipped in the polishing paste when using them. The articles, when well brightened, are washed in water to get rid of the paste and the wool threads, and finally dried in sawdust. {288}
The first step in the process is the preparation of the mold. The substance originally used for the construction of this was plaster of Paris. This substance is, however, porous and must be rendered impermeable. The materials most commonly used of later years are stearine, wax, marine glue, gelatin, india rubber, and fusible alloys. With hollow molds it is a good plan to arrange an internal skeleton of platinum, for ultimate connection with the anodes, in order to secure a good electrical contact with all parts of the mold. When covering several pieces at once, it is as well to connect each of them with the negative pole by an iron or lead wire of suitable dimensions.
Having prepared the molds in the usual way—by obtaining an impression in the material when soft, and allowing it to set—they should be given a metallic coating on their active surfaces of pure powdered plumbago applied with a polishing brush.
For delicate and intricate objects, the wet process is most suitable. It consists in painting the object with two or more coats of nitrate of silver and ultimately reducing it by a solution of phosphorus in bisulphide of carbon.
The plating baths are prepared as follows:
A quantity of water is put in a jar and to it is added from 8 to 10 parts in 100 of sulphuric acid, in small quantities, stirring continually in order to dissipate the heat generated by the admixture of acid and water. Sulphate of copper (bluestone) is then dissolved in the acidulated water at the normal temperature until it will take up no more. The solution is always used cold and must be maintained in a saturated condition by the addition of copper sulphate crystals or suitable anodes.
For use it should be poured into vessels of clay, porcelain, glass, hard brown earthenware, or india rubber. For large baths wood may be used, lined on the interior with an impervious coating of acid-proof cement, india rubber, marine glue, or even varnished lead sheets.
If the solution be too weak and the current on the other hand be too strong, the resulting deposit will be of a black color. If too concentrated a solution and too weak a current be employed, a crystalline deposit is obtained. To insure a perfect result, a happy medium in all things is necessary.
During the process of deposition, the pieces should be moved about in the bath as much as possible in order to preserve the homogeneity of the liquid. If this be not attended to, stratification and circulation of the liquid is produced by the decomposition of the anode, and is rendered visible by the appearance of long, vertical lines on the cathode.
For amateurs and others performing small and occasional experiments, the following simple apparatus will be serviceable. Place the solution of sulphate of copper in an earthenware or porcelain jar, in the center of which is a porous pot containing amalgamated zinc and a solution of sulphuric acid and water, about 2 or 3 parts in 100. At the top of the zinc a brass rod is fixed, supporting a circle of the same metal, the diameter of which is between that of the containing vessel and the porous pot. From this metallic circle the pieces are suspended in such a manner that the parts to be covered are turned toward the porous pot. Two small horsehair bags filled with copper sulphate crystals are suspended in the solution to maintain its saturation.