CALCIUM SULPHIDE (LUMINOUS): See Paints.
CALFSKIN: See Leather.
CAMERA RENOVATION: See Photography.
| Naphthalene white, in scales | 3,000 parts |
| Camphor | 1,000 parts |
| Melt on the steam bath and add to the hot mass: | |
| Coumarin | 2 parts |
| Mirbane oil | 10 parts |
Cast in plates or compressed tablets. The preparation is employed as a moth preventive.
II.—Take equal parts of strong ether and alcohol to reduce the camphor to powder. It is claimed for this method that it only takes one-half of the time required when alcohol alone is used, and that the camphor dries more quickly. Before sifting add 1 per cent of white vaseline and 5 per cent of sugar of milk. Triturate fairly dry, spread out in the air, say 15 minutes, then pass through a moderately fine wire sieve, using a stubby shaving brush to assist in working it through. {145}
| Oil of bitter almonds | 1 drachm |
| Oil of cloves | 20 drops |
| Camphor | 1 1/2 ounces |
| White wax | 4 ounces |
| Lard, prepared | 1 pound |
Melt the wax and lard together, then add the camphor in saturated solution in spirit; put in the oils when nearly cold.
| I.— | White wax | 16 parts |
|---|---|---|
| Benzoated suet | 48 parts | |
| Camphor, powdered | 8 parts | |
| Essential oil, to perfume. |
Melt the wax and suet together. When nearly cold, add the camphor and perfume, mix well, and pour into molds.
| II.— | Oil of almond | 16 parts |
|---|---|---|
| White wax | 4 parts | |
| Spermaceti | 4 parts | |
| Paraffine | 8 parts | |
| Camphor, powdered | 1 part | |
| Perfume, quantity sufficient. |
Dissolve the camphor in the oil by the aid of a gentle heat. Melt the solids together, remove, and let cool, but before the mixture begins to set add the camphorated oil and the perfume, mix, and pour into molds.
| III.— | Stearine (stearic acid) | 8 pounds |
|---|---|---|
| Lard | 10 pounds | |
| White wax | 5 pounds | |
| Spermaceti | 5 pounds |
Melt on a water bath in an earthen or porcelain dish; strain into a similar vessel; add a solution of 2 ounces powdered borax in 1 pound of glycerine, previously warmed, to the melted substance when at the point of cooling; stir well; add camphor, 2 pounds, powdered by means of alcohol, 3 ounces; stir well and pour into molds.
CAMPHOR SUBSTITUTES IN THE PREPARATION OF CELLULOID: See Celluloid.
CAMPHOR AND RHUBARB AS A REMEDY FOR CHOLERA: See Cholera Remedies.
CAN VARNISH: See Varnishes.
The following is a formula much used by German canary-bird raisers:
| Sweet almonds, blanched | 16 parts |
| Pea meal | 32 parts |
| Butter, fresh (unsalted) | 3 parts |
| Honey, quantity sufficient to make a stiff paste. | |
The ingredients are worked into a stiff paste, which is pressed through a colander or large sieve to granulate the mass. Some add to every 5 pounds, 10 or 15 grains of saffron and the yolks of 2 eggs.
CANARY BIRDS AND THEIR DISEASES: See Veterinary Formulas.
I.—Paraffine wax, 70; stearine, 15; petroleum, 15.
II.—Paraffine wax, 90; stearine, 5; petroleum, 5. Recipe I of course gives candles more transparent than does recipe II. The 15 per cent may be regarded as the extreme limit consistent with proper solidity of the candles.
| Magnesium sulphate | 15 parts |
| Dextrin | 15 parts |
| Water | 100 parts |
The solution dries quickly and does not affect the burning of the candle. {146}
Stearine, owing to its acid character, dissolves the coal-tar colors much more readily than do the perfectly neutral paraffine and ozokerite waxes. For coloring stearine the necessary quantity of the color is added to the melted mass and well stirred in; if the solution effected happens to be incomplete, a small addition of alcohol will prove an effective remedy. It is also an advantage to dissolve the colors previously in alcohol and add the concentrated solution to the melted stearine. The alcohol soon evaporates, and has no injurious effect on the quality of the stearine.
For a number of years there have been on the market so-called “fat colors,” formed by making concentrated solutions of the color, and also special preparations of the colors in stearine. They are more easily applied, and are, therefore, preferred to the powdered aniline colors, which are apt to cause trouble by being accidentally distributed in soluble particles, where they are not wanted. Since paraffine and ozokerite dissolve comparatively little, they will not become colored, and so must be colored indirectly. One way is to dissolve the color in oleic acid or in stearine acid and add the solution to the wax to be colored. Turpentine may be employed for the same purpose. Concerning the colors suitable for candles, there are the eosine colors previously mentioned, and also chroline yellow, auramine, taniline blue, tartrazine, brilliant green, etc. The latter, however, bleaches so rapidly that it can hardly be recommended. An interesting phenomenon is the change some colors undergo in a warm temperature; for instance, some blues turn red at a moderate degree of heat (120° F.) and return to blue only when completely cooled off; this will be noticed while the candle mixture is being melted previous to molding into candles.
CANDLES (FUMIGATING): See Fumigants.
CANDY COLORS AND FLAVORS: See Confectionery.
CANDY: See Confectionery.
CANVAS WATERPROOFING: See Waterproofing.
CAOUTCHOUC: See Rubber.
CAOUTCHOUC SOLUTION FOR PAINTS: See Paint.
CAPPING MIXTURES FOR BOTTLES: See Bottle-Capping Mixtures.
CAPSULE VARNISH: See Varnishes.
II.—The ordinary sugar coloring material is made from sugar or glucose by heating it, while being constantly stirred, up to a temperature of about 405° F. A metal pan capable of holding nearly ten times as much as the sugar used, is necessary so as to retain the mass in its swollen condition. As soon as it froths up so as nearly to fill the pan, an action which occurs suddenly, the fire must instantly be extinguished or removed. The finished product will be insoluble if more than about 15 per cent of its weight is driven off by the heat.
CARAMEL IN FOOD: See Food.
CARAMELS: See Confectionery. {147}
| I.— | Carbolic acid (cryst.) | 1 ounce |
|---|---|---|
| Alcohol | 1 ounce | |
| Oil bergamot | 10 minims | |
| Oil eucalyptus | 10 minims | |
| Oil citronella | 3 minims | |
| Tincture cudbear | 10 minims | |
| Water, to make | 10 ounces |
Set aside for several days, and then filter through fuller’s earth.
| II.— | Carbolic acid (cryst.) | 4 drachms |
|---|---|---|
| Cologne water | 4 drachms | |
| Dilute acetic acid | 9 ounces |
Keep in a cool place for a few days, and filter.
CARBOLIC SOAP: See Soap.
See also Paints and Wood.
II.—Sixty parts, by weight, of black coal tar oil of a specific gravity higher than 1.10; 25 parts, by weight, of creosote oil; 25 parts, by weight, of beechwood tar oil of a higher specific weight than 0.9. Mix together and heat to about 347° F., or until the fumes given off begin to deposit soot. The resulting carbolineum is brown, and of somewhat thick consistency; when cool it is ready for use and is packed in casks. This improved carbolineum is applied to wood or masonry with a brush; the surfaces treated dry quickly, very soon loose the odor of the carbolineum, and are effectively protected from dampness and formation of fungi.
CARBON PRINTING: See Photography.
CARBON PROCESS IN PHOTOGRAPHY: See Photography.
CARBONYLE: See Wood.
CARBUNCLE REMEDIES: See Boil Remedy.
CARDS (PLAYING), TO CLEAN: See Cleaning Preparations and Methods.
CARDBOARD, WATERPROOF GLUE FOR: See Adhesives under Cements and Waterproof Glues.
CARDBOARD, WATERPROOFING: See Waterproofing.
CARMINATIVES: See Pain Killers.
CARPET PRESERVATION: See Household Formulas.
CARPET SOAP: See Soap. {148}
CARRIAGE-TOP DRESSING: See Leather.
CARRON OIL: See Cosmetics.
CASE HARDENING: See Steel.
In the manufacture of fancy papers, or papers that are made to imitate the appearance of various cloths, laces, and silks, casein is very widely used. It is also largely used in waterproofing tissues, for preparation of waterproof products, and various articles prepared from agglomeration of cork (packing boards, etc.). With lime water casein makes a glue that resists heat, steam, etc. It also enters into the manufacture of the various articles made from artificial ivory (billiard balls, combs, toilet boxes, etc.), imitation of celluloid, meerschaum, etc., and is finding new uses every day.
Casein, as known, may act the part of an acid and combine with bases to form caseinates or caseates; among these compounds, caseinates of potash, of soda, and of ammonia are the only ones soluble in water; all the others are insoluble and may be readily prepared by double decomposition. Thus, for example, to obtain caseinate of alumina it is sufficient to add to a solution of casein in caustic soda, a solution of sulphate of alumina; an insoluble precipitate of casein, or caseinate of alumina, is instantly formed.
This precipitate ought to be freed from the sulphate of soda (formed by double decomposition), by means of prolonged washing. Pure, ordinary cellulose may be incorporated with it by this process, producing a new compound, cheaper than pure cellulose, although possessing the same properties, and capable of replacing it in all its applications.
According to the results desired, in transparency, color, hardness, etc., the most suitable caseinate should be selected. Thus, if a translucent compound is to be obtained, the caseinate of alumina yields the best. If a white compound is desired, the caseinate of zinc, or of magnesia, should be chosen; and for colored products the caseinates of iron, copper, and nickel will give varied tints.
The process employed for the new products, with a base of celluloid and caseinate, is as follows: On one hand casein is dissolved in a solution of caustic soda (100 parts of water for 10 to 25 parts of soda), and this liquid is filtered to separate the matters not dissolved and the impurities. On the other hand, a salt of the base of which the caseinate is desired is dissolved, and the solution filtered. It is well not to operate on too concentrated a solution. The two solutions are mixed in a receptacle provided with a mechanical stirrer, in order to obtain the insoluble caseinate precipitate in as finely divided a state as possible. This precipitate should be washed thoroughly, so as to free it from the soda salt formed by double decomposition, but on account of its gummy or pasty state, this washing presents certain difficulties, and should be done carefully. After the washing the mass is freed from the greater part of water contained, by draining, followed by drying, or energetic pressing; then it is washed in alcohol, dried or pressed again, and is ready to be incorporated in the plastic mass of the celluloid.
For the latter immersion and washing it has been found that an addition of 1 to 5 per cent of borax is advantageous, for it renders the mass more plastic, and facilitates the operation of mixing. This may be conducted in a mixing apparatus; but, in practice, it is found preferable to effect it with a rolling mill, operating as follows:
The nitro-cellulose is introduced in the plastic state, and moistened with a solution of camphor in alcohol (40 to 50 parts of camphor in 50 to 70 of alcohol for 100 of nitro-cellulose) as it is practiced in celluloid factories.
This plastic mass of nitro-cellulose is placed in a rolling mill, the cylinders of which are slightly heated at the same time as the caseinate, prepared as above; then the whole mass is worked by the cylinders until the mixture of the two {149} is perfectly homogeneous, and the final mass is sufficiently hard to be drawn out in leaves in the same way as practiced for pure celluloid.
These leaves are placed in hydraulic presses, where they are compressed, first hot, then cold, and the block thus formed is afterwards cut into leaves of the thickness desired. These leaves are dried in an apparatus in the same way as ordinary celluloid. The product resembles celluloid, and has all its properties. At 90° to 100° C. (194° to 212° F.), it becomes quite plastic, and is easily molded. It may be sawed, filed, turned, and carved without difficulty, and takes on a superb polish. It burns less readily than celluloid, and its combustibility diminishes in proportion as the percentage of caseinate increases; finally, the cost price is less than that of celluloid, and by using a large proportion of caseinate, products may be manufactured at an extremely low cost.
The phosphoric acid may be obtained by any convenient method; for example, by decomposing dicalcic or monocalcic phosphate with sulphuric acid. The commercial phosphoric acid may also be employed.
The casein may be precipitated from the skimmed milk by means of a suitable acid, and should be washed with cold water to remove impurities. A caseinate may also be employed, such as a compound of casein and an alkali or an alkaline earth.
The new compound is produced in the following way: A sufficient quantity of phosphoric acid is incorporated with the casein or a caseinate in such a way as to insure sufficient acidity in the resulting compound. The employment of 23 to 25 parts by weight of phosphoric acid with 75 to 77 parts of casein constitutes a good proportion.
An aqueous solution of phosphoric acid is made, and the casein introduced in the proportion of 25 to 50 per cent of the weight of the phosphoric acid present. The mixture is then heated till the curdled form of the casein disappears, and it assumes a uniform fluid form. Then the mixture is concentrated to a syrupy consistency. The remainder of the casein or of the caseinate is added and mixed with the solution until it is intimately incorporated and the mass becomes uniform. The compound is dried in a current of hot air, or in any other way that will not discolor it, and it is ground to a fine powder. The intimate union of the phosphoric acid and casein during the gradual concentration of the mixture and during the grinding and drying, removes the hydroscopic property of the phosphoric acid, and produces a dry and stable product, which may be regarded as a hyperphosphate of casein. When it is mixed with water, it swells and dissolves slowly. When this compound is mingled with its equivalent of sodium bicarbonate it yields about 17 per cent of gas.
CASEIN CEMENTS: See Adhesives.
CASEIN VARNISH: See Varnishes.
CASSIUS, PURPLE OF: See Gold.
CASKET TRIMMINGS: See Castings.
CASTS (PLASTER), PRESERVATION OF: See Plaster.
CASTS, REPAIRING OF BROKEN: See Adhesives and Lutes.
CASTS FROM WAX MODELS: See Modeling.
The French bronzes, which are imitations, are cast in copper or brass molds. The material used is principally zinc and tin, and an unlimited number of castings can be made in the mold, but if a real bronze piece is to be produced it must be out of copper and the mold made in sand. To make the castings hollow, with sand, a core is required. This fills the inside of the figure so that the molten copper runs around it, and as the core is made out of sand, the same can be afterwards washed out. If the casting is to be hollow and is to be cast in a metal mold, then the process is very simple. The mold is filled with molten metal, and when the operator thinks the desired thickness has cooled next to the walls, he pours out the balance. An experienced man can make hollow castings in this way, and make the walls of any thickness.
Casket hardware trimmings, which are so extensively used on coffins, especially the handles, are nearly all cast out of tin and antimony, and in brass molds. The metal used is brittle, and requires strengthening at the weak portions, and this is mostly done with wood filling or with iron rods, which are secured in the molds before the metal is poured in.
Aluminum castings, which one has procured at the foundries, are usually alloyed with zinc. This has a close affinity with aluminum, and alloys readily; but this mixture is a detriment and causes much trouble afterwards. While this alloy assists the molder to produce his castings easily, on the other hand it will not polish well and will corrode in a short time. Those difficulties may be avoided if pure aluminum is used.
Plaster of Paris molds are the easiest made for pieces where only a few castings are wanted. The only difficulty is that it requires a few days to dry the plaster thoroughly, and that is absolutely necessary to use them successfully. Not only can the softer metals be run into plaster molds, but gold and silver can be run into them. A plaster mold should be well smoked over a gaslight, or until well covered with a layer of soot, and the metal should be poured in as cool a state as it will run.
As the geometrically exact contour of the coin or medal is often the cause of breaking of the edges, the operator sometimes uses wax to make the edges appear half round and it also allows the casting to be more easily removed from the second half of the mold. Each half of the mold should be about the thickness of the finger. The keys, so called, of every plaster casting must not be forgotten. In the first casting some little half-spherical cavities should be scooped out, which will appear in the second half-round knobs, and which, by engaging with the depressions, will ensure exactness in the finished mold.
After the plaster has set, cut a canal for the flow of the molten casting material, then dry the mold thoroughly in an oven strongly heated. The halves are now ready to be bound together with a light wire. When bound heat the mold gradually and slowly and let the mouth of the canal remain underneath while the heating is in progress, in order to prevent the possible entry of dirt or foreign matter. The heating should be continued as long as there is a suspicion of remaining moisture. When finally assured of this fact, take out the mold, open it, and blow it out, to make sure of absolute cleanness. Close and bind again and place on a hearth of fine, hot sand. The mold should still be glowing when the casting is made. The ladle should contain plenty of metal, so as to hold the heat while the casting is being made. The presence of a little zinc in the metal ensures a sharp casting. Finally, to ensure success, it is always better to provide two molds in case of accident. Even the most practiced metal molders take this precaution, especially when casting delicate objects.
II.—To obtain a full casting in brass molds for soft metal two important points should be observed. One is to have the deep recesses vented so the air will escape, and the other is to have the mold properly blued. The bluing is best done by dipping the mold in sulphuric acid, then placing it on a gas stove until the mold is a dark color. Unless this bluing is done it will be impossible to obtain a sharp casting.
II.—Molds for the use of soft metal castings may be made out of soft metal. This is done with articles that are not numerous, or not often used; and may be looked upon as temporary. The molds are made in part the same as when of brass, and out of tin that contains as much hardening as possible. The hardening consists of antimony and copper. This metal mold must be painted over several times with Spanish red, which tends to prevent the metal from melting. The metal must not be used too hot, otherwise it will melt the mold. By a little careful manipulation many pieces can be cast with these molds.
III.—New iron or brass molds must be blued before they can be used for casting purposes. This is done by placing the mold face downward on a charcoal fire, or by swabbing with sulphuric acid, then placing over a gas flame or charcoal fire until the mold is perfectly oxidized.
IV.—A good substantial mold for small castings of soft metal is made of brass. The expense of making the cast mold is considerable, however, and, on that account, some manufacturers are making their molds by electro-deposition. This produces a much cheaper mold, which can be made very quickly. The electro-deposited mold, however, is very frail in comparison with a brass casting, and consequently must be handled very carefully to keep its shape. The electro-deposited ones are made out of copper, and the backs filled in with a softer metal. The handles are secured with screws.
CASTING IN WAX: See Modeling.
CASTINGS, TO SOFTEN IRON: See Iron. {153}