[1]
Read at the stated meeting of the Franklin Institute, March 18, 1885.
[2]
Philadelphia Photographer, December, 1879, p. 365.
[3]
I intended this publication to be a very full and explicit one, and it was sufficiently so to be perfectly understood by most who saw it; but some may think I did not sufficiently emphasize the importance of using the particular kind of chlorophyl which I mentioned. In a brief communication to the editor of the Photo. News, in 1883, I described some experiments with eosine as a color sensitizer, and then called attention to the superiority of blue-myrtle chlorophyl for this purpose, stating that I had not been able to secure such results with any other kind of chlorophyl, and that a fresh solution from fresh leaves must be used to secure the greatest possible degree of sensitiveness. See Photo. News, Nov. 1883, p. 747.
[4]
Photo. News, London, September 5, 1884, p. 566, and Year Book of Photography for 1885, p. 111.
[5]
I originally recommended chlorophyl extracted from dried leaves, because I had not yet learned how to preserve the solution for more than a few weeks; and at some seasons it would be difficult, if not impossible, to obtain fresh leaves. The tea organifier which I recommended is also a color sensitizer, and when it is used in connection with the chlorophyl from dried leaves the plates are as sensitive to red as can be safely prepared and developed in the light of an ordinary photographic "dark-room." Plates prepared with chlorophyl from fresh leaves do not require treatment with the tea organifier to secure this degree of sensitiveness. Recently I have used the tea organifier and some other sensitizers, in connection with the solution from fresh myrtle-leaves, and in this way have produced plates having such an exalted color sensitiveness as to be unmanageable in ordinary "dark-room" light. Possibly, such plates might be prepared and developed in total darkness, by the aid of suitable mechanical contrivances, but I am not sure that they would work clear even then, because they appear to be sensitive to heat as well as to light.

DISTORTION FROM EXPANSION OF THE PAPER IN PHOTOGRAPHY.

The effect of the unequal expansion of paper, when wetted, in causing distortion of the photographic image impressed upon it, has, in the case of ordinary photographs upon albumenized paper, been well recognized; but the extent to which such distortion may exist under different treatment is worthy of some special consideration, particularly with reference to the method of printing upon gelatinized paper, which has been thought by some likely to supersede the method now usually employed with albumenized paper.

When a print upon the ordinary photographic (albumen) paper is wetted, the fiber expands more in one direction than in the other, so that the print becomes unequally enlarged, very slightly in one and much more so in the other way of the paper. When the paper is dried without any strain being put upon it, the fibers regain very nearly their original dimensions and position, so that the distortion which has existed in the wet condition nearly disappears.

If the photograph is cemented, while in the expanded condition, upon a rigid surface, the distortion then existing is fixed, and rendered permanent. Such a cementation or method of mounting is that which has been generally adopted, and the consequence has been that every now and then complaints have justly been made of the untruthfulness—owing to this particular distortion—of photographs; productions whose chief merit has often been asserted to consist in their absolute truthfulness. This distortion is very manifest when, in a set of portraits, some of the prints happen to have been made in one direction of the paper, and others with the long grain the other way. I have known a case where a proof happened to increase the face in width, and all the other prints increased it in length. Of course, neither was correct, but the proof had been accepted and liked, and the remainder of the set had to be reprinted with the grain of the paper running in the same direction as that in the first one which had been supplied.

Another evil arising from mounting prints while expanded with moisture is, that in drying the contraction of the paper pulls round the card into a curved form and although by rolling this curvature may be temporarily got rid of, the fiber of the paper is in a strained condition, and the bent state of the mount is, sooner or later, renewed thereby.

To remedy these evils it has been proposed to mount the print when dry, by forcible pressure against a slightly damped card, the back of the print having been previously coated with a cement and dried. This plan is, to a great extent, successful; but that it does not give absolute immunity from distortion is, I think, evident from the following consideration. The prints, after being mounted a few days, will show a certain tendency to curl inward. This curling, I take it, is a measure of the strain upon the print, produced by the more complete return to its original dimensions of the paper photograph. Probably it would be well to keep the prints a few days after drying, or to subject them to alternations of damp and dryness, in order to facilitate this complete return before being placed upon the card. The evil of distortion is, however, very slight—perhaps imperceptible—compared with that existing when the prints are mounted wet. I may mention, en passant, that I have found gum much more satisfactory as a mountant than starch paste in what is known as the "dry mounting" system.

The paper which has recently been introduced for producing prints by development upon a gelatine surface does not generally, when dried in the usual way, give so good or so brilliant a surface as that of albumenized paper; but on the other hand it is very easy with it to obtain what is called an enamel surface, by simply allowing it to dry in contact with a prepared surface of glass. This method of finishing has therefore been much recommended and adopted, but without consideration of the effect of distortion in connection with it. In an ordinary photograph the print is mounted damp, but in the case of a print squeegeed on to the glass, the paper is saturated and thoroughly swollen, and the use of the squeegee strains it out to its fullest extent. By drying in the position in which it has been held by contact with the glass, the distortion becomes fixed, and if the print is mounted while in this state the distortion is made permanent. How long the strain and distortion remain in an unmounted print, and whether by time and alternations of moisture and dryness the strain would be lost, and if so, whether the brilliant enamel surface would go at the same time, are questions worthy of further investigation and discussion.

For mounting prints upon developed gelatine paper, it has been recommended to cement the edges only, so as to leave the greater part of the print with its enamel surface. This plan is unsatisfactory, for two reasons, besides the objection on the ground of distortion. There is a rough-looking margin which spoils the continuity of appearance, especially (as in the specimens I have seen) where the line of cement is not kept at an exact width, but encroaches here and there.

Secondly, the print, from not being attached to the mount all over, is apt, especially when in a large size, to be somewhat wavy and wanting in flatness. Another plan recommended, as giving a surface resembling albumen paper, is to paste the back of the print without moistening the surface, and so mount. Some prints that have been shown thus treated had so strongly curled the cards upon which they were mounted that it is evident there was considerable strain and consequent distortion.

A third plan recommended is to paste the back of the print while in contact with the glass upon which it has to dry; and, when dried, to mount by passing through a rolling press with a damped card. This plan looks, at first sight, like that recommended for albumen paper, and called "dry" mounting. Consideration, however, will show that there is a radical difference. In the case of the albumen paper the print has been dried without strain, and therefore but little change is to be looked for, while the print dried in contact with glass is strained to the utmost, causing present distortion and future curling of the mount. Perhaps the evil of distortion caused by enameling may be reduced to a minimum by soaking the print in alcohol previous to laying it upon the glass.

Since the distortion of the photograph arises from the unequal expansion of the paper when wet, it becomes a question whether something may not be done in the selection of the paper itself. It may be that some makes vary much less than others in the "length against width" extension of the surface by wetting. It must be remembered that for gelatine emulsion we are not nearly so limited in the selection of paper as when it is required to be albumenized. In the latter case the image is in the paper, whereas with gelatine the image is contained in the surface coating. I may mention that the best plain, i.e., not enameled, but resembling that of ordinary albumen paper, surface that I have seen upon gelatine paper was upon some foreign post that I had obtained for another purpose. The emulsion employed was that described by Mr. J.B.B. Wellington, and this gentleman agreed with me in attributing the superiority of the surface obtained to the fine quality of the paper upon which the emulsion had been coated. Some commercial samples appear to be coated upon paper of somewhat coarse texture. This does not show when the print is enameled.

The unequal expansion of paper is a subject of interest, not only in connection with gelatine paper for development, but with various photographic processes. In making carbon transparencies for instance, the gelatine film which is squeegeed against the glass necessarily takes its dimensions from the paper to which it is attached, and if that be expanded more in the one direction than another, the transparency is similarly deformed; and so, of course, is any negative, enlarged or otherwise, produced in the camera therefrom. A reproduced negative by contact printing may either have the distortion due to expansion of the paper bearing the gelatine film removed or doubled, according to the direction in which the paper is used for the new negative.—W.E. Debenham, in Br. Jour. of Photography.


MEASURING THE THICKNESS OF BOILER PLATES.

An ingenious process for determining the thickness of iron plates in boilers, or places where they cannot otherwise be measured without cutting them, has been invented by M. Lebasteur. He spreads upon the plate the thickness of which he desires to find, and also upon a piece of sheet iron of known thickness, a layer of tallow about 0.01 inch thick. He then applies to each, for the same length of time, a small object, such as a surgeon's cauterizing instrument, heated as nearly as possible to a constant temperature. The tallow melts, and as in the thicker plate the heat of the cautery is conducted away more rapidly, while in the thin plate the heat is less freely conducted away, and the tallow is consequently melted over a large area, the diameters of the circles of bare metal around the heated point, bounded after cooling by a little ridge of tallow, will be to each other inversely as the thickness of the plates. The process is stated to have given in the inventor's hands, results of great accuracy.


GROUPS OF STATUARY FOR THE PEDIMENT OF THE HOUSE OF PARLIAMENT IN VIENNA.

The pediment of the central pavilion and the two side pavilions of the new House of Parliament, at Vienna, are to be ornamented with groups of statuary. The group in the middle pediment represents the granting of the constitution by the Emperor Francis Joseph, and was executed by Professor Helmer.

STATUARY FOR THE VIENNA HOUSE OF PARLIAMENT.—SCIENCE AND LITERATURE. (GROUP TO THE LEFT.)

STATUARY FOR THE VIENNA HOUSE OF PARLIAMENT.—SCIENCE AND LITERATURE. (GROUP TO THE LEFT.)

The pediment of the left wing is ornamented by a group representing Justice, and the pediment of the right wing by a group representing the Home Government.

Johannes Benk, the well known Austrian sculptor, designed and executed the last mentioned group. The two figures at the left hand end of this group represent Science and Literature, and those at the right hand end, Industry and Commerce. The entire group consists of nine figures, the middle figure being seated and the rest standing, sitting, and lying, as the space in the pediment allows.

A seated female figure studying a papyrus roll represents Science, and the adjacent female figure, resting one arm on the figure representing Science, and the other, on a lyre, represents Literature or Poetry.

Industry is represented by a strong and powerful woman holding a hammer, and the figure of Mercury and the prow of a vessel represent Commerce.

STATUARY FOR THE VIENNA HOUSE OF PARLIAMENT.—INDUSTRY AND COMMERCE. (GROUP TO THE RIGHT.)

STATUARY FOR THE VIENNA HOUSE OF PARLIAMENT.—INDUSTRY AND COMMERCE. (GROUP TO THE RIGHT.)

The modulation and formation of each figure conform strictly to Grecian models, as does also the entire arrangement of the figures in the group; and yet there is much of modern life in the figures, especially in the faces, in which the stereotyped Grecian profile has not been adopted. The attitudes of the figures are also freer and more easy than those of the Grecian period.—Illustrirte Zeitung.


ON THE FRITTS SELENIUM CELLS AND BATTERIES.[1]

By C.E. FRITTS, 42 Nassau St., New York, N.Y.

In all previous cells, so far as I am aware, the two portions or parts of the selenium at which the current enters and leaves it have been in substantially the same electrical state or condition. Furthermore, the paths of the current and of the light have been transverse to each other, so that the two forces partially neutralize each other in their action upon the selenium. Lastly, the current flows through not only the surface layer, which is acted upon by the light, but also the portion which is underneath, and not affected thereby, and which therefore detracts from the actual effect of the light upon the selenium at the surface.

My form of cell is a radical departure from all previous methods of employing selenium, in all of these respects. In the first place, I form the selenium in very thin plates, and polarize them, so that the opposite faces have different electrical states or properties. This I do by melting it upon a plate of metal with which it will form a chemical combination, sufficient, at least, to cause the selenium to adhere and make a good electrical connection with it. The other surface of the selenium is not so united or combined, but is left in a free state, and a conductor is subsequently applied over it by simple contact or pressure.

During the process of melting and crystallizing, the selenium is compressed between the metal plate upon which it is melted and another plate of steel or other substance with which it will not combine. Thus by the simultaneous application and action of heat, pressure, chemical affinity, and crystallization, it is formed into a sheet of granular selenium, uniformly polarized throughout, and having its two surfaces in opposite phases as regards its molecular arrangement. The non-adherent plate being removed after the cell has become cool, I then cover that surface with a transparent conductor of electricity, which may be a thin film of gold leaf. Platinum, silver, or other suitable material may also be employed. The whole surface of the selenium is therefore covered with a good electrical conductor, yet is practically bare to the light, which passes through the conductor to the selenium underneath.[2] My standard size of cell has about two by two and a half inches of surface, with a thickness of 1/1000 to 5/1000 inch of selenium. But the cells can, of course, be made of any size or form. A great advantage of this arrangement consists in the fact that it enables me to apply the current and the light to the selenium in the same plane or general direction, instead of transversely to each other as heretofore done, so that I can cause the two influences to either coincide in direction and action, or to act upon opposite faces of the selenium and oppose each other, according to the effect desired.

By virtue of the process and arrangement described, my cells have a number of remarkable properties, among which are the following:

1. Their sensitiveness to light is much greater than ever before known. The most sensitive cell ever produced, previous to my investigations, was one made by Dr. Werner Siemens, which was 14.8 times as conductive in sunlight as in dark. In table A, I give results obtained from a number of my cells.

It will be observed that I have produced one cell which was 337.5 times as conductive in hazy sunlight as in dark. The tremendous change of resistance involved in the expression "337.5 times" may perhaps be more fully realized by saying that 99.704 per cent. of the resistance had disappeared temporarily, under the joint action of light and electricity, so that there remained less than 3/10 of 1 per cent. of the original resistance of the selenium in dark.

In order to obtain these high results, the cells must be protected from light when not in use. The resistance is first measured while the cell is still in total darkness. It is then exposed to sunlight and again measured. It is also necessary to send the current in at the gold electrode or face, as the cell is much less sensitive to light when the light acts upon one surface of the selenium and the current enters at the opposite surface. When the two influences, the light and the current, act through the gold, in conjunction, their forces are united; and, as every atom of the selenium is affected by the light, owing to the extreme thinness of the plate, we have the full effect shown in the measurements.

-----------------------------------------------------------------
                          TABLE A.
                   SENSITIVENESS TO LIGHT.
-----------------------------------------------------------------
Selenium  |  Battery  | Resistance in | Resistance in |
  cell.   |  power.   |     dark.     |   sunlight.   |  Ratio.
----------+-----------+---------------+---------------+----------
          |           |    ohms.      |   ohms.       |
No. 22   |5 elements.|    39,000     |    340        |114   to 1
  "  23³  |5     "    |    14,000     |    170        | 82.3  " "
  "  24  |5     "    |   648,000     |  2,400        |270    " "
  "  25   |5     "    |   180,000     |    930        |196.5  " "
  "  26   |5     "    |   135,000     |    710        |190    " "
  " 107   |5     "    |   118,000     |    740        |159    " "
  " 108   |5     "    |   200,000     |    900        |222    " "
  " 122   |5     "    |    56,000     |    220        |254.5  " "
  " 129³  |5     "    |   200,000     |    940        |212    " "
  " 137   |5     "    |   108,000     |    320        |337.5  " "
-----------------------------------------------------------------

Cells which are sensitive to light improve by being used daily, and their sensitiveness becomes less if they are laid aside and not used for a considerable length of time, especially if allowed to become overheated. They should be kept cool, and exposed to light frequently, whether they are used or not.

Mode of measuring cells.—So great is the sensitiveness of these cells to external influences, that it is necessary to adopt some particular system in measuring their resistance and to adhere strictly to that system, as every change in the method of measurement produces a difference in the result, and the different measurements would not be comparable with each other. The reason for this will be explained presently.

The system I have adopted is the Wheatstone's bridge arrangement, with equal sides, never using multipliers except for some experimental purpose. In each multiplier wire I have 500 ohms resistance. When the bridge is balanced, one-half of the current flows through the cell and acts upon the selenium. Between the bridge and the cell is a reversing switch, so that the current can be reversed through the cell without changing its course through the bridge. A Bradley tangent galvanometer is used, employing the coil of 160 ohms resistance. The Leclanche battery is exclusively used in measurements for comparison.

2. The kind of battery employed has a marked effect upon the sensitiveness to light, which is largely reduced or entirely destroyed when the bichromate battery is used. The same cells again become extremely sensitive with the Leclanche battery. We might expect that a change in the current employed would cause a change in the resistance of a cell, but it is not clear how or why it should affect the sensitiveness of selenium to light.

"If one kind of battery current destroys its sensitiveness, may we not suppose that another kind might increase its sensitiveness? Although the Leclanche has operated well, some other may operate still better, and by its special fitness for use on selenium cells may intensify their actions, and so bring to light other properties yet unthought of. Is not here a promising field for experiment, in testing the various forms of battery already known, or even devising some new form especially adapted to the needs and peculiarities of selenium cells?"

One year ago I made the foregoing suggestion in a paper on A New Form of Selenium Cell, presented before this Association at Minneapolis. I am now at liberty to state that my photo-electric battery, presently to be described, marks an advance in the direction indicated. The current from this battery increases the sensitiveness of the cells to light, and also to reversal of current. One cell whose highest ratio in light was about 83 to 1, with the Leclanche battery, when measured with my battery gave a ratio of 120 to 1. It seems to make the resistance of the cell both higher in dark and lower in sunlight than with the Leclanche battery. But the field is yet open to others, for the discovery of a battery which may be still better for use with selenium cells.

3. The two surfaces of the selenium act differently toward currents sent into them from the contiguous conductors. One surface offers a higher resistance to the current than the other. The former I utilize as the anode surface, as I have found that the cell is more sensitive to light when the current enters at that surface, which is ordinarily the one covered by the gold or other transparent conductor. Some cells have this property but feebly developed; but in one instance the resistance offered to the current by the anode surface was 256 times as high as that offered by the cathode surface to the same current. In the majority of cases, however, the ratio does not exceed ten times. Table B gives some recent results.

-------------------------------------------------------------------
                          TABLE B.
         SENSITIVENESS TO REVERSAL OF DIRECTION OF CURRENT.
-----------------------+--------------+------------------+---------
                       |              |   Resistance     |
    No. of cell.       |   Battery.   | "gold  | "gold   | Ratio
                       |              | anode."|cathode."|
-----------------------+--------------+--------+---------+---------
                       |              |  ohms. |  ohms.  |
3/8 inch square. No. 4 |  5 elements. | 20,000 |  1,000  | 20  to 1
      "     "     "  3 |   Se. cell.  |  6,500 |    400  | 16.2 "
   Full size, No. 13   |  1 element.  |  9,000 |    800  | 11.2 "
     "    "    "  14   |  5    "      |  2,440 |    130  | 18   "
     "    "    "  15   |  5    "      |  4,640 |    210  | 22   "
     "    "    "  27   |  5    "      |  6,900 |    440  | 16   "
     "    "    " 126   |  1    "      |  5,000 |    330  | 15   "
-----------------------+--------------+--------+---------+---------

The direction of the current is always indicated by stating the position of the gold electrode, by the terms "gold anode" and "gold cathode." The above measurements were made in dark.

4. Sensitiveness to change of battery power.—My cells are extremely sensitive to any change in the strength or character of the current flowing through them, which is shown by a corresponding change in the resistance of the cell. I can, therefore, vary the resistance of one of my cells in many ways, and the following may be specified—

(a) By changing the potential or electromotive force of the current through the cell.

(b) By changing the "quantity" of the battery or current.

(c) By putting more or less resistance in the circuit.

(d) By dividing the current, by one or more branch circuits or shunts around the cell.

(e) By varying the resistance in any or all of said circuits.

A cell whose resistance becomes greater as the battery power becomes greater, and vice versa, I call an "L B cell" signifying Like the Battery power. A "U B cell" is one whose resistance becomes greater as the battery power (or strength of current) becomes less, and vice versa, being Unlike the Battery power, or current strength.

These changes of resistance are not due to heating of the conductor or the selenium, and the following instance will illustrate this. I have one cell in which the selenium has about one-fourth inch square of surface melted on a brass block one inch thick. This cell measured, with 25 elements of Leclanche, 40,000 ohms. On changing the battery to 5 elements the resistance fell instantly to 30 ohms, and there remained. On again using the current from 25 elements, the resistance instantly returned to 40,000 ohms. Had these results been due in any degree to heating, the resistance would have changed gradually as the heat became communicated to the brass, whereas no such change occurred, the resistances being absolutely steady. Moreover, even the fusion of the selenium would not produce any such change.

The "U B" property does not ordinarily change the resistance of the cell to exceed ten times, i.e., the resistance with a weak current will not be over ten times as high as with a strong one. But I have developed the "L B" property to a far higher degree. Table C gives some recent results obtained with L B cells, including one whose resistance, with 25 elements Leclanche, was 11,381 times as high as with 8 elements, and which, after standing steadily at 123 ohms (and then at 325 ohms with 1 element), on receiving the current from 25 elements again returned to its previous figure of 1,400,000 ohms.

---------------------------------------------------------------
                          TABLE C.
            SENSITIVENESS TO CHANGE OF BATTERY POWER.
-----------------------+------------+------------+-------------
                       | Resistance | Resistance |
       No. of cell.    |   with 25  |   with 5   |  Ratio of
                       |  elements. |  elements. |   Change.
-----------------------+------------+------------+-------------
                       |  ohms.     |  ohms.     |
3/8 inch square, No. 1 |    40,000  |     30     |  1,333 to 1
3/8  "     "      "  2 |    13,000  |     40     |    325  "
1/4  "     "      "  1 | 1,400,000  |    123     | 11,381  "
1/2  "     "      "  2 |   500,000  |     62     |  8,064  "
1/2  "     "      "  5 |     3,500  |     21     |    167  "
   Full size, No. 81   |    68,000  |    121     |    561  "
    "    "     "  82   |     9,000  |     64     |    140  "
    "    "     "  83   |    17,300  |     74     |    233  "
    "    "     " 119   |    35,600  |     19     |  1,894  "
-----------------------+------------+------------+-------------

The results in the table were obtained by changing the strength of current by throwing in more or less of the battery. Like results can be obtained by varying the current through the cell by any of the other methods before specified. The above measurements were in dark.

5. Dual state of selenium.—My cells, when first made seem to have two states or conditions. In one, their resistance is very low, in the other it is high. When in the low state they are usually not very sensitive, in any respect. I therefore raise the resistance, by sending an intermittent or an alternating current though the cells, and in their new condition they at once become extremely sensitive to light, currents, and other influences. In some cases they drop to the low state again, and require to be again brought up, until, after a number of such treatments, they remain in the sensitive state. Occasionally a cell will persist in remaining in the insensitive state. The before mentioned treatment raises it up for a moment, but, before the bridge can be balanced and the resistance measured, it again drops into the low or insensitive state. Some cells have been thus stimulated into the high or sensitive state repeatedly, and every means used to make them stay there, but without avail; and they have had to be laid aside as intractable.

In the earlier stages of my investigations, before the discovery of this dual state and the method of changing a cell from the insensitive to the sensitive condition, hundreds of cells were made, finished, and tested, only to be then ruthlessly destroyed and melted over, under the impression that they were worthless. Now, I consider nothing worthless, but expect sooner or later to make every cell useful for one purpose or another.

The most singular part of this phenomenon is the wide difference in the resistance of the cells in the two states. In the low state, it may be a few ohms, or even a few hundredths of an ohm. In the high state, it is the normal working resistance of the cell, usually between 5,000 and 200,000 ohms, but is often up among the millions. The spectacle of a little selenium being stimulated, by a few interruptions of the current through it, into changing its resistance from a fraction of an ohm up to a million or several millions of ohms, and repeatedly and instantly changing back and forth, up and down, through such a wide range, we might almost say changing from zero to infinity, and the reverse, instantly, is one which suggests some very far-reaching inquiries to the electrician and the physicist. What is the nature of electrical conductivity or resistance, and how is it so greatly and so suddenly changed?

6. Radio-electric current generators.—My cells can be so treated that will generate a current by simple exposure to light or heat. The light, for instance, passes through the gold and acts upon its junction with the selenium, developing an electromotive force which results in a current proceeding from the metal back, through the external circuit, to the gold in front, thus forming a photo-electric dry pile or battery. It should preferably be protected from overheating, by an alum water cell or other well known means.

The current thus produced is radiant energy converted into electrical energy directly and without chemical action, and flowing in the same direction as the original radiant energy, which thus continues its course, but through a new conducting medium suited to its present form. This current is continuous, constant, and of considerable electromotive force. A number of cells can be arranged in multiple arc or in series, like any other battery. The current appears instantly when the light is thrown upon the cell, and ceases instantly when the light is shut off. If the light is varied properly, by any suitable means, a telephonic or other corresponding current is produced, which can be utilized by any suitable apparatus, thus requiring no battery but the selenium cell itself. The strength of the current varies with the amount of light on the cell, and with the extent of the surface which is lighted.

I produce current not only by exposure to sunlight, but also to dim diffused daylight, to moonlight, and even to lamplight. I use this current for actual working purposes, among others, for measuring the resistance of other selenium cells, with the usual Wheatstone's bridge arrangement, and for telephonic and similar purposes. Its use for photometric purposes and in current regulators will be mentioned further on. It is undoubtedly available for all uses for which other battery currents are employed, and I regard it as the most constant, convenient, lasting, readily used, and easily managed pile or battery of which I have any knowledge. On the commercial scale, it could be produced very cheaply, and its use is attended by no expense, inasmuch as no liquids or chemicals are used, the whole cell being of solid metal with a glass in front, for protection against moisture and dust. It can be transported or carried around as easily and safely as an electro-magnet, and as easily connected in a circuit for use wherever required. The current, if not wanted immediately, can either be "stored" where produced, in storage batteries of improved construction devised by me, or transmitted over suitable conductors to a distance, and there used, or stored as usual till required.

7. Singing and speaking cells.—When a current of electricity flowing through one of my selenium cells is rapidly interrupted, a sound is given out by the cell, and that sound is the tone having the same number of air vibrations per second as the number of interruptions in the current. The strength of the sound appears to be independent of the direction of the current through the cell. It is produced on the face of the cell, no sound being audible from the back of the cell. An alternating current also produces a sound corresponding to the number of changes of direction. Experiments also show that, if a telephonically undulating current is passed through the cell, it will give out the speech or other sound corresponding to the undulations of the current—and, furthermore, that the cell will sing or speak in like manner, without the use of a current, if a suitably varied light is thrown upon it while in closed circuit.

My experiments having been devoted especially to those branches of the subject which promised to be more immediately practically valuable, I have not pursued this inquiry very far, and offer it for your consideration as being not only interesting, but possibly worthy of full investigation.

GENERAL OBSERVATIONS ON THE PROPERTIES OF CELLS.

From the number of different properties possessed by my cells, it might be anticipated that the different combinations of those properties would result in cells having every variety of action. This is found to be the case. As a general rule, the cells are noteworthy in one respect only. Thus, if a cell is extremely sensitive to light, it may not be specially remarkable in other respects. As a matter of fact, however, the cells most sensitive to the light are also "U B cells."

The property of sensitiveness to light is independent of the power to generate current by exposure to light—the best current-generating cells being only very moderately sensitive to light, and some of the most sensitive cells generate scarcely any current at all. Current-generating cells are, almost without exception, "U B cells;" and the best current-generating cells are strongly polarized, showing a considerable change of resistance by reversing the direction of a current through them; and they are also strong "anode cells," i.e., the surface next to the gold offers a higher resistance to a battery current than the other surface of the selenium does. The power to generate a current is temporarily weakened by sending a battery current through the cell while exposed to light, in either direction. The current generated by exposure to light is also weakened by warming the cell, unless the cell is arranged for producing current by exposure to heat.

The properties of sensitiveness to light and to change of battery power are independent of each other, as I have cells which are sensitive to change of current but absolutely insensitive to light—their resistance remaining exactly the same whether the cells are in darkness or in sunlight. I also have cells which are sensitive to light, but are unaffected by change of battery power, or by reversing the direction of the current through them.

The sensitiveness to change of battery power is also independent of the sensitiveness to reversal of direction of the current. Among the best "L B cells," some are "anode cells" and others are "cathode cells," while still others are absolutely insensitive to reversal of current or to the action of light.

Constancy of the resistance.—A noticeable point in my cells is the remarkable constancy of the resistance in sunlight. Allowing for differences in the temperature, the currents, and the light, at different times, the resistance of a cell in sunlight will remain practically constant during months of use and experiments, although during that time the treatments received may have varied the resistance in dark hundreds of thousands of ohms—sometimes carrying it up, and at others carrying it down again, perhaps scores of times, until it is "matured," or reaches the condition in which its resistance becomes constant.

As has already been stated, the sensitiveness of a cell to light is increased by proper usage. This increased sensitiveness is shown, not by a lowered resistance in light, but by an increased resistance in dark. This change in the cells goes on, more or less rapidly, according as it is retarded or favored by the treatment it receives, until a maximum is reached, after which the resistance remains practically constant in both light and dark, and the cell is then "matured," or finished. The resistance in dark may now be 50 or even 100 times as high as when the cell was first made, yet, whenever exposed to sunlight it promptly shows the same resistance that it did in the beginning. The various treatments, and even accidents, through which it has passed in the mean time, seem not to have stirred its molecular arrangement under the action of light, but to have expended their forces in modifying the positions which the molecules must normally assume in darkness.

Practical applications.—There are many peculiarities of action occasionally found, and the causes of such actions are not always discernible. In practice, I have been accustomed to find the peculiarities and weaknesses of each cell by trial, developing its strongest properties and avoiding its weaknesses, until, when the cell is finished, it has a definite and known character, and is fitted for certain uses and a certain line of treatment, which should not be departed from, as it will be at the risk of temporarily disabling it. In consequence of the time and labor expended in making cells, in the small way, testing, repairing damages done during experiments, etc., the cost of the cells now is unavoidably rather high. But if made in a commercial way, all this would be reduced to a system, and the cost would be small. I may say here that I do not make cells for sale.

The applications or uses for these cells are almost innumerable, embracing every branch of electrical science, especially telegraphy, telephony, and electric lighting, but I refrain from naming them. I may be permitted, however, to lay before you two applications, because they are of such general scientific interest. The first is my

Photometer.—The light to be measured is caused to shine upon a photo-electric current-generating cell, and the current thus produced flows through a galvano-metric coil in circuit, whose index indicates upon its scale the intensity of the light. The scale may be calibrated by means of standard candles, and the deflections of the index will then give absolute readings showing the candle power of the light being tested. Or, the current produced by that light and that produced by the standard candle may be compared, according to any of the known ways of arranging and comparing different lights—the cell being lastly exposed alternately to the two lights, to see if the index gives exactly the same deflection with each light.

This arrangement leaves untouched the old difficulty in photometry, that arising from the different colors of different lights. I propose to obviate that difficulty in the following manner. As is well known, gold transmits the green rays, silver the blue rays, and so on; therefore, a cell faced with gold will be acted upon by the green rays, one faced with silver by the blue rays, etc. Now, if we construct three cells (or any other number), so faced that the three, collectively, will be acted upon by all the colors, and arrange them around the light to be tested, at equal distances therefrom, each cell will produce a current corresponding to the colored rays suited to it, and all together will produce a current corresponding to all the rays emitted by the light, no matter what the proportions of the different colors may be. The three currents may act upon the same index, but each should have its own coil, not only for the sake of being able to join or to isolate their influences upon the index, but also to avoid the resistances of the other cells. If a solid transparent conductor of electricity could be found which could be thick enough for practical use and yet would transmit all the rays perfectly, i.e., transmit white light unchanged, that would be still better. I have not yet found a satisfactory conductor of that kind, but I think the plan stated will answer the same purpose. This portion of my system I have not practically tested, but it appears to me to give good promise of removing the color stumbling-block, which has so long defied all efforts to remove it, and I therefore offer it for your consideration.

Photo-electric regulator.—My regulator consists of a current-generating cell arranged in front of a light, say an electric lamp, whose light represents the varying strength of the current which supports it. The current produced in the cell by this light flows through an electro-magnetic apparatus by means of which mechanical movement is produced, and this motion is utilized for changing resistances, actuating a valve, rotating brushes, moving switches, levers, or other devices. This has been constructed on a small scale, and operates well, and I think it is destined to be largely used, as a most sensitive, simple, and perfect regulator for currents, lights, dynamos, motors, etc., etc., whether large or small.

In conclusion, I would say that the investigation of the physical properties of selenium still offers a rare opportunity for making very important discoveries. But candor compels me to add that whoever undertakes the work will find it neither an easy nor a short one. My own experience would enable me to describe to you scores of curious experiments and still more curious and suggestive results, but lack of time prevents my giving more than this very incomplete outline of my discoveries.